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A new polymorph of NaCoPO4, sodium cobalt(II) phosphate, crystallizes with a monoclinic modification of the zeolite ABW structure. The five-coordinate Na+ cations reside within channels running through an open cobalt-phosphate framework constructed from four-, six- and eight-membered rings of alternating CoO4 and PO4 tetrahedra.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, br1238

hkl

Structure factor file (CIF format)
Contains datablock CRYSTALS_cif

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