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The title compound, sodium manganate tellurate, was obtained by hydrothermal synthesis and adopts a superstructure related to the CaFe2O4 structure type, with the Mn and Te atoms ordered along the b axis (short axis in the CaFe2O4 structure). Electron counting schemes show that this compound is a mixed-valence MnII/MnIII compound, and bond valence sums are used to suggest that there is no site preference for the higher charged Mn atom.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock bd0786jwkcrfnamnteo

sft

Structure factor file (SHELXL table format)
Supplementary material

-1
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