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Potassium pentasilver trisulfide, KAg5S3 was synthesized in supercritical ethylenediamine, using techniques previously reported [Wood et al. (1992). J. Am. Chem. Soc. 114, 9233-9235]. Dark-red crystals of KAg5S3 crystallize in the hexagonal space group P\overline{6}2c. The compound has an open-channeled structure composed of Ag and S atoms, with K+ cations sitting in the middle of these channels.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks BD0614, I

sft

Structure factor file (SHELXL table format)
Supplementary material

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