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The crystal structure of the title mixed-valence copper–cyanide complex comprises infinite polymeric double chains. The geometry about the CuI centres is approximately trigonal pyramidal, and each CuII centre adopts a slightly distorted square-pyramidal coordination, with one NH3 ligand being disordered equally over two alternative sites.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, bm1284

hkl

Structure factor file (CIF format)
Supplementary material

-1
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