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In the centrosymmetric formula unit of the title complex, C8H16O4.2C12H11NO4S2, the disulfonylamine molecules are linked to 12-crown-4 via a slightly bent N—H...O hydrogen bond [N...O 2.771 (2) Å]. The macrocycle adopts the [66] conformation and the (PhSO2)2NH molecules have an open pseudo-C2 symmetric conformation with the phenyl groups lying on opposite sides of the S—N—S plane.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks leticron, global

fcf

Structure factor file (CIF format)
Contains datablock leticron

CCDC reference: 130056

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