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The title compound, [BiI2(C6H18N3OP)4][I5], contains the pseudo-octahedral BiIII cation [BiI2{OP(NMe2)3}4]+, which has crystallographic \overline{4} symmetry, and trans iodide ligands. The central iodine atom of the disordered [I5]- anion is also situated on a site of \overline{4} symmetry, and the atoms of this anion form an infinite three-dimensional network, resulting in a `cage' type structure. The cations are situated within the `cage' cavities.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, bibl

fcf

Structure factor file (CIF format)
Contains datablock bibl

CCDC reference: 129849

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