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The title compound, 3-hydroxy-2-phenylpropenonitrile (α-hydroxymethylene-α-phenylacetonitrile), C9H7NO, exists in the solid state as the Z–enol tautomer, forming one-dimensional chains via hydrogen bonding between the enol OH group and the nitrile N atom.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks 1b, global

fcf

Structure factor file (CIF format)
Contains datablock p21c

CCDC reference: 128712

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