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The novel title fluoride source, C7H15N4+F-.4H2O, was crystallized from methanol. The cations adopt an alternating up-down arrangement and are separated into layers by an extended hydrogen-bonded fluoride-water sheet network.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock shelxl

fcf

Structure factor file (CIF format)
Contains datablock shelxl

CCDC reference: 128711

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