metal-organic compounds
The crystal structure of the title compound, trans-bis(methylamine-N)bis(4-amino-1-methyl-2(1H)-pyrimidinone-N3)platinum(II) bis[tetrachlorothallate(III)], [Pt(CH5N)2(C5H7N3O)2][TlCl4]2, consists of square-planar PtII cations arranged on a crystallographic inversion center and distorted tetrahedral TlCl4- anions. The compound is very similar to known cytosine complexes of the trans-[(NH3)2Pt(1-methylcytosine)2]X2 type. The distortion in TlCl4- and in other anion-containing compounds is discussed.
Supporting information
Crystallographic Information File (CIF) |
CCDC reference: 127987