metal-organic compounds
The title compound, [Cr(C5H4NOS)3].(CH3)2CO, contains a Cr(III)(mpo)3 unit (Hmpo = 2-mercaptopyridine-N-oxide) and (CH3)2CO. Each mpo- ligand chelates to the Cr atom via one O and one S atom with an average bite angle of 83.3 (1)°, forming a distorted octahedral O3S3 coordination around the Cr atom. The average Cr-S and Cr-O bond distances are 2.363 (1) and 1.986 (2) Å, respectively.
Supporting information
Crystallographic Information File (CIF) |
CCDC reference: 126690