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The two independent bis(3,5-di­methyl­pyrazole)silver(I) cations in crystalline [Ag(C5H7N2)2]NO3 display N—Ag—N angles of 175.51 (14) and 174.44 (13)°, and an average Ag—N distance of 2.124 (5) Å. The nitrate anion is situated between [Ag(C5H7N2)2]+ units and interacts via hydrogen bonds with the NH groups. The two 3,5-di­methyl­pyrazole ligands are trans about the silver center. Only a small deviation from linearity is observed in the coordination around silver.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270102002044/bk1637sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270102002044/bk1637Isup2.hkl
Contains datablock I

CCDC reference: 184465

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SAINT (Bruker, 1999); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Siemens, 1996); software used to prepare material for publication: SHELXL97.

(I) top
Crystal data top
[Ag(C5H7N2)2](NO3)Z = 4
Mr = 362.15F(000) = 728
Triclinic, P1Dx = 1.680 Mg m3
a = 10.030 (1) ÅMo Kα radiation, λ = 0.71073 Å
b = 11.336 (1) ÅCell parameters from 4477 reflections
c = 13.656 (2) Åθ = 2.5–27.5°
α = 90.99 (2)°µ = 1.42 mm1
β = 109.47 (2)°T = 213 K
γ = 101.01 (3)°Plate, colourless
V = 1431.4 (3) Å30.46 × 0.12 × 0.09 mm
Data collection top
Bruker SMART
diffractometer
4913 independent reflections
Radiation source: normal-focus sealed tube3871 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.022
ω scansθmax = 25.0°, θmin = 1.8°
Absorption correction: multi-scan
(SADABS; Blessing, 1995)
h = 1111
Tmin = 0.703, Tmax = 0.884k = 1213
7378 measured reflectionsl = 1016
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.040Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.094H-atom parameters constrained
S = 1.06 w = 1/[σ2(Fo2) + (0.037P)2 + 1.P]
where P = (Fo2 + 2Fc2)/3
4913 reflections(Δ/σ)max = 0.022
351 parametersΔρmax = 1.14 e Å3
0 restraintsΔρmin = 1.02 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag11.13535 (4)1.11512 (3)1.37322 (3)0.04379 (13)
Ag20.63916 (4)0.63958 (3)0.88521 (3)0.03984 (13)
N11.0365 (4)1.2331 (3)1.1675 (3)0.0347 (9)
H1D0.99951.16201.13600.042*
N21.1037 (4)1.2546 (3)1.2720 (3)0.0354 (9)
N31.1544 (4)0.9791 (3)1.4786 (3)0.0360 (9)
N41.2254 (4)1.0088 (3)1.5825 (3)0.0344 (9)
H4A1.27541.07951.60880.041*
N50.6696 (4)0.8963 (3)0.8080 (3)0.0343 (9)
H5D0.72340.92550.87020.041*
N60.6055 (4)0.7774 (3)0.7813 (3)0.0344 (9)
N70.6555 (4)0.4905 (3)0.9781 (3)0.0308 (8)
N80.5927 (4)0.3762 (3)0.9345 (3)0.0321 (9)
H8B0.55430.35700.86840.039*
N90.8795 (4)0.9419 (3)1.0669 (3)0.0369 (9)
N100.4473 (5)0.2894 (3)0.6684 (3)0.0448 (11)
C10.9633 (5)1.3317 (4)1.0038 (4)0.0431 (12)
H1A0.93231.24950.97400.065*
H1B1.03081.37500.97450.065*
H1C0.88101.36870.98890.065*
C21.0339 (5)1.3344 (3)1.1184 (4)0.0345 (10)
C31.1050 (5)1.4272 (4)1.1957 (4)0.0393 (12)
H3A1.12261.50921.18670.047*
C41.1453 (5)1.3747 (4)1.2893 (4)0.0378 (11)
C51.2211 (6)1.4338 (4)1.3974 (4)0.0595 (15)
H5A1.26011.37581.44290.089*
H5B1.15381.46491.42140.089*
H5C1.29821.49881.39750.089*
C60.9983 (6)0.7969 (4)1.3669 (4)0.0533 (14)
H6A0.98800.85291.31430.080*
H6B0.90470.76111.36920.080*
H6C1.04280.73501.35070.080*
C71.0908 (5)0.8621 (3)1.4707 (4)0.0342 (10)
C81.1223 (5)0.8199 (3)1.5690 (4)0.0357 (11)
H8A1.09110.74221.58450.043*
C91.2088 (5)0.9157 (3)1.6391 (3)0.0339 (10)
C101.2773 (5)0.9259 (4)1.7547 (4)0.0475 (12)
H10A1.28271.00581.78220.071*
H10B1.37300.91021.77290.071*
H10C1.22040.86831.78340.071*
C110.4445 (6)0.6525 (4)0.6212 (4)0.0555 (14)
H11A0.47800.58740.65940.083*
H11B0.45360.64650.55360.083*
H11C0.34500.64820.61340.083*
C120.5330 (5)0.7697 (4)0.6788 (4)0.0365 (11)
C130.5519 (5)0.8837 (4)0.6418 (4)0.0429 (12)
H13A0.51290.90260.57340.051*
C140.6394 (5)0.9622 (3)0.7262 (4)0.0347 (10)
C150.6953 (5)1.0954 (4)0.7378 (4)0.0481 (13)
H15A0.79701.11330.77710.072*
H15B0.64541.13410.77360.072*
H15C0.67951.12450.67010.072*
C160.5368 (5)0.1645 (3)0.9785 (4)0.0451 (13)
H16A0.47200.15150.90760.068*
H16B0.48530.13411.02380.068*
H16C0.61420.12300.98610.068*
C170.5975 (5)0.2966 (3)1.0065 (3)0.0316 (10)
C180.6648 (5)0.3622 (3)1.1019 (4)0.0336 (10)
H18A0.68370.33251.16710.040*
C190.6992 (4)0.4824 (3)1.0811 (3)0.0307 (10)
C200.7729 (5)0.5900 (4)1.1576 (4)0.0451 (12)
H20A0.77560.66151.12110.068*
H20B0.86980.58261.19640.068*
H20C0.72070.59511.20450.068*
O10.8255 (4)0.8369 (3)1.0302 (3)0.0665 (12)
O20.9716 (4)0.9676 (3)1.1554 (3)0.0578 (10)
O30.8419 (4)1.0251 (3)1.0123 (3)0.0540 (10)
O40.4103 (5)0.2569 (4)0.5752 (3)0.0844 (14)
O50.5410 (5)0.3810 (3)0.7099 (3)0.0757 (13)
O60.3939 (4)0.2258 (3)0.7247 (3)0.0588 (10)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0531 (3)0.0446 (2)0.0421 (2)0.01650 (16)0.02301 (19)0.01914 (16)
Ag20.0406 (2)0.03845 (19)0.0433 (3)0.01120 (15)0.01593 (18)0.01510 (16)
N10.037 (2)0.0322 (17)0.033 (2)0.0043 (15)0.0118 (17)0.0027 (16)
N20.040 (2)0.0368 (18)0.031 (2)0.0104 (15)0.0134 (17)0.0078 (16)
N30.038 (2)0.0372 (18)0.030 (2)0.0061 (15)0.0085 (17)0.0041 (16)
N40.034 (2)0.0302 (16)0.033 (2)0.0034 (14)0.0047 (17)0.0013 (16)
N50.034 (2)0.0366 (17)0.031 (2)0.0072 (15)0.0086 (17)0.0029 (16)
N60.034 (2)0.0335 (17)0.036 (2)0.0073 (15)0.0120 (17)0.0052 (16)
N70.034 (2)0.0287 (16)0.030 (2)0.0054 (14)0.0120 (17)0.0012 (15)
N80.034 (2)0.0316 (16)0.027 (2)0.0053 (14)0.0074 (16)0.0030 (15)
N90.038 (2)0.0362 (18)0.036 (2)0.0047 (16)0.0140 (18)0.0028 (17)
N100.059 (3)0.0337 (19)0.034 (3)0.0085 (18)0.007 (2)0.0021 (18)
C10.043 (3)0.046 (2)0.038 (3)0.012 (2)0.009 (2)0.011 (2)
C20.034 (3)0.035 (2)0.038 (3)0.0118 (18)0.014 (2)0.010 (2)
C30.048 (3)0.030 (2)0.039 (3)0.0069 (19)0.014 (2)0.007 (2)
C40.037 (3)0.039 (2)0.039 (3)0.0062 (19)0.017 (2)0.003 (2)
C50.067 (4)0.061 (3)0.042 (3)0.004 (3)0.012 (3)0.004 (3)
C60.058 (3)0.051 (3)0.039 (3)0.001 (2)0.010 (3)0.008 (2)
C70.034 (3)0.035 (2)0.034 (3)0.0065 (18)0.013 (2)0.0015 (19)
C80.036 (3)0.032 (2)0.042 (3)0.0058 (17)0.016 (2)0.008 (2)
C90.034 (3)0.036 (2)0.033 (3)0.0112 (18)0.010 (2)0.0057 (19)
C100.047 (3)0.057 (3)0.036 (3)0.013 (2)0.010 (2)0.009 (2)
C110.058 (4)0.049 (3)0.051 (4)0.003 (2)0.013 (3)0.007 (2)
C120.038 (3)0.039 (2)0.035 (3)0.0118 (19)0.014 (2)0.004 (2)
C130.046 (3)0.051 (3)0.032 (3)0.019 (2)0.009 (2)0.011 (2)
C140.030 (2)0.037 (2)0.042 (3)0.0108 (18)0.016 (2)0.011 (2)
C150.053 (3)0.040 (2)0.057 (3)0.016 (2)0.023 (3)0.010 (2)
C160.052 (3)0.031 (2)0.047 (3)0.0027 (19)0.013 (2)0.003 (2)
C170.032 (2)0.0303 (19)0.034 (3)0.0075 (17)0.013 (2)0.0041 (18)
C180.036 (3)0.037 (2)0.030 (3)0.0099 (18)0.012 (2)0.0049 (19)
C190.030 (2)0.0330 (19)0.032 (3)0.0087 (17)0.013 (2)0.0026 (18)
C200.047 (3)0.039 (2)0.044 (3)0.006 (2)0.011 (2)0.007 (2)
O10.077 (3)0.0333 (16)0.070 (3)0.0009 (16)0.008 (2)0.0077 (17)
O20.060 (2)0.063 (2)0.037 (2)0.0139 (17)0.0003 (18)0.0058 (17)
O30.071 (3)0.0379 (16)0.044 (2)0.0144 (16)0.0070 (18)0.0064 (15)
O40.124 (4)0.080 (3)0.030 (2)0.001 (2)0.012 (2)0.007 (2)
O50.097 (3)0.0482 (19)0.060 (3)0.022 (2)0.019 (2)0.0059 (18)
O60.066 (3)0.0550 (19)0.060 (3)0.0025 (17)0.034 (2)0.0043 (18)
Geometric parameters (Å, º) top
Ag1—N22.119 (3)C5—H5A0.9600
Ag1—N32.120 (3)C5—H5B0.9600
Ag1—O23.140 (3)C5—H5C0.9600
Ag1—Ag28.0395 (8)C6—C71.498 (6)
Ag2—N62.127 (3)C6—H6A0.9600
Ag2—N72.129 (3)C6—H6B0.9600
N1—C21.340 (5)C6—H6C0.9600
N1—N21.354 (5)C7—C81.388 (6)
N1—H1D0.8600C8—C91.377 (6)
N2—C41.337 (5)C8—H8A0.9300
N3—C71.342 (5)C9—C101.489 (6)
N3—N41.361 (5)C10—H10A0.9600
N4—C91.336 (5)C10—H10B0.9600
N4—H4A0.8600C10—H10C0.9600
N5—C141.337 (5)C11—C121.489 (6)
N5—N61.364 (4)C11—H11A0.9600
N5—H5D0.8600C11—H11B0.9600
N6—C121.338 (5)C11—H11C0.9600
N7—C191.337 (5)C12—C131.398 (6)
N7—N81.357 (4)C13—C141.372 (6)
N8—C171.343 (5)C13—H13A0.9300
N8—H8B0.8600C14—C151.493 (5)
N9—O11.230 (4)C15—H15A0.9600
N9—O21.241 (4)C15—H15B0.9600
N9—O31.249 (4)C15—H15C0.9600
N10—O41.230 (5)C16—C171.495 (5)
N10—O51.238 (5)C16—H16A0.9600
N10—O61.242 (5)C16—H16B0.9600
C1—C21.484 (6)C16—H16C0.9600
C1—H1A0.9600C17—C181.376 (6)
C1—H1B0.9600C18—C191.399 (5)
C1—H1C0.9600C18—H18A0.9300
C2—C31.379 (6)C19—C201.490 (6)
C3—C41.388 (6)C20—H20A0.9600
C3—H3A0.9300C20—H20B0.9600
C4—C51.493 (6)C20—H20C0.9600
N2—Ag1—N3175.51 (14)N3—C7—C8110.0 (4)
N6—Ag2—N7174.44 (12)N3—C7—C6120.8 (4)
C2—N1—N2112.8 (3)C8—C7—C6129.2 (4)
C2—N1—H1D123.6C9—C8—C7106.6 (4)
N2—N1—H1D123.6C9—C8—H8A126.7
C4—N2—N1105.1 (3)C7—C8—H8A126.7
C4—N2—Ag1131.9 (3)N4—C9—C8106.1 (4)
N1—N2—Ag1123.0 (2)N4—C9—C10122.3 (4)
C7—N3—N4105.0 (3)C8—C9—C10131.7 (4)
C7—N3—Ag1133.9 (3)C9—C10—H10A109.5
N4—N3—Ag1120.3 (2)C9—C10—H10B109.5
C9—N4—N3112.4 (3)H10A—C10—H10B109.5
C9—N4—H4A123.8C9—C10—H10C109.5
N3—N4—H4A123.8H10A—C10—H10C109.5
C14—N5—N6112.3 (3)H10B—C10—H10C109.5
C14—N5—H5D123.9C12—C11—H11A109.5
N6—N5—H5D123.9C12—C11—H11B109.5
C12—N6—N5105.1 (3)H11A—C11—H11B109.5
C12—N6—Ag2130.3 (3)C12—C11—H11C109.5
N5—N6—Ag2124.3 (3)H11A—C11—H11C109.5
C19—N7—N8105.5 (3)H11B—C11—H11C109.5
C19—N7—Ag2132.8 (3)N6—C12—C13109.9 (4)
N8—N7—Ag2120.8 (3)N6—C12—C11120.9 (4)
C17—N8—N7112.1 (3)C13—C12—C11129.1 (4)
C17—N8—H8B124.0C14—C13—C12106.4 (4)
N7—N8—H8B124.0C14—C13—H13A126.8
O1—N9—O2122.2 (4)C12—C13—H13A126.8
O1—N9—O3118.7 (4)N5—C14—C13106.4 (4)
O2—N9—O3119.1 (3)N5—C14—C15121.4 (4)
O4—N10—O5122.5 (5)C13—C14—C15132.2 (4)
O4—N10—O6119.2 (4)C14—C15—H15A109.5
O5—N10—O6118.2 (4)C14—C15—H15B109.5
C2—C1—H1A109.5H15A—C15—H15B109.5
C2—C1—H1B109.5C14—C15—H15C109.5
H1A—C1—H1B109.5H15A—C15—H15C109.5
C2—C1—H1C109.5H15B—C15—H15C109.5
H1A—C1—H1C109.5C17—C16—H16A109.5
H1B—C1—H1C109.5C17—C16—H16B109.5
N1—C2—C3105.4 (4)H16A—C16—H16B109.5
N1—C2—C1121.8 (4)C17—C16—H16C109.5
C3—C2—C1132.8 (4)H16A—C16—H16C109.5
C2—C3—C4106.8 (4)H16B—C16—H16C109.5
C2—C3—H3A126.6N8—C17—C18106.3 (3)
C4—C3—H3A126.6N8—C17—C16122.5 (4)
N2—C4—C3110.0 (4)C18—C17—C16131.2 (4)
N2—C4—C5120.9 (4)C17—C18—C19106.3 (4)
C3—C4—C5129.1 (4)C17—C18—H18A126.9
C4—C5—H5A109.5C19—C18—H18A126.9
C4—C5—H5B109.5N7—C19—C18109.8 (4)
H5A—C5—H5B109.5N7—C19—C20122.3 (4)
C4—C5—H5C109.5C18—C19—C20127.8 (4)
H5A—C5—H5C109.5C19—C20—H20A109.5
H5B—C5—H5C109.5C19—C20—H20B109.5
C7—C6—H6A109.5H20A—C20—H20B109.5
C7—C6—H6B109.5C19—C20—H20C109.5
H6A—C6—H6B109.5H20A—C20—H20C109.5
C7—C6—H6C109.5H20B—C20—H20C109.5
H6A—C6—H6C109.5N9—O2—Ag1156.9 (3)
H6B—C6—H6C109.5
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1—H1D···O20.862.202.945 (5)145
N1—H1D···O30.862.233.029 (5)155
N1—H1D···N90.862.563.417 (5)171
N4—H4A···O6i0.862.142.956 (5)159
N4—H4A···O4i0.862.343.083 (5)144
N4—H4A···N10i0.862.593.446 (5)171
N5—H5D···O30.862.082.930 (5)170
N5—H5D···O10.862.413.069 (5)134
N5—H5D···N90.862.603.430 (5)162
N8—H8B···O50.862.152.937 (5)153
N8—H8B···O60.862.353.133 (5)151
N8—H8B···N100.862.623.477 (5)177
Symmetry code: (i) x+1, y+1, z+1.
 

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