[(η⁵-C₅R₅)TiCl₂(η⁵-C₅H₄SiMe₂)]₂O·nCH₂Cl₂ (R = H, Me; n = 1, 0)

The first title metallocene, 1,3-bis(dichlorotitanocene)-1,1,3,3-tetramethyldisiloxane dichloromethane solvate, [(η⁵-C₅H₅)­TiCl₂­(η⁵-C₅H₄­Si­Me₂)]₂O·­CH₂Cl₂, (I), crystallizes in space group P2₁/c. Compound (I) represents the first crystal structure of a bimetallic siloxy-bridged titanocene. The geometric parameters of (I) are similar to those of the parent titanocene; however, the disiloxane substituents adopt an unexpected eclipsed conformation. The second title metallocene, 1,3-bis­[(penta­methyl­cyclo­penta­dienyl)­(cyclo­penta­dien­yl)­titanium dichloride]-1,1,3,3-tetra­methyl­disiloxane, [(η⁵-C₅-Me₅)­TiCl₂­(η⁵-C₅H₄­Si­Me₂)]₂O, (II), represents the second crystal structure of a bimetallic siloxy-bridged titanocene and crystallizes in the space group P2₁/n. Compound (I) possesses non-crystallographic twofold molecular symmetry and both metal centers adopt pseudo-tetrahedral geometries. The geometric parameters of (II) are similar to those of the mixed titanocene Cp*CpTiCl₂ (Cp* = C₅Me₅) and the disiloxane substituents adopt a staggered conformation.

S1. Comment

The title compounds, (I) and (II), were obtained as byproducts in the synthesis of [η⁵-(dimethylfenchoxysilyl)cyclopentadienyl](η⁵-cyclopentadienyl) titanium dichloride, (C₁₀H₁₇OSiMe₂C₅H₄)C₅H₅TiCl₂ (Grimmond & Corey, 1998) and [η⁵-(dimethylfenchoxysilyl)cyclopentadienyl](η⁵-pentamethyl cyclopentadienyl)titanium dichloride, (C₁₀H₁₇OSiMe₂C₅H₄)C₅Me₅TiCl₂, respectively, upon crystallization from ethyl acetate at 298 K. A Cambridge Database search indicated that these substituted metallocenes are the first crystallographically characterized examples of bimetallic siloxy-bridged titanocenes, although other structures of cyclopentadienyl transition metal complexes involving siloxane bridges are known (Schubert & Grubert, 1998; Ciruelos et al., 1998). The synthesis of compound (I) by alternative means has also been described by Noh et al. (1996). There is one CH₂Cl₂ molecule of solvation per molecule for metallocene (I) and no solvation for (II). Neither structure exhibits molecular disorder. For both compounds, there are no significant intermolecular close contacts resulting from crystal packing. Selected bond lengths and angles for (I) and (II) are listed in Tables 1 and 2, and perspective views of the two metallocenes are presented in Figs. 1 and 2.

In compounds (I) and (II), the cyclopentadienyl rings are planar within experimental error and adopt η⁵ bonding modes with respect to each Ti atom. The following geometric parameters described for (I) are compared in parentheses with the corresponding values for the parent titanocene dichloride (Clearfield et al., 1975). The average Cp_centroid—Ti distance is 2.06 (2.06 Å) and the Cp_centroid—Ti—Cp_centroid angle is 130.70 (130.98°). Additionally, compound (I) has a mean Ti—Cl bond length of 2.37 (2.36 Å) with a Cl—Ti—Cl angle of 93.25 (94.52°), indicating that all major aspects of the substituted metallocene architecture compare well with those of titanocene dichloride.

A similar comparison of (II) with the parent mixed titanocene dichloride Cp^*CpTiCl₂ (Cp^* = C₅Me₅) indicated no significant deviations in the geometry of (II) from the base structure. The following geometric parameters described for (II) are compared in parentheses with the corresponding values for the parent mixed titanocene dichloride (Rodgers et al., 1985). The average Cp_centroid—Ti distance is 2.07 (2.07 Å), while the mean Cp^*_centroid-Ti distance is 2.10 (2.10 Å). The Cp^*_centroid-Ti—Cp_centroid angle is 132.60 (131.98°). Additionally, compound (II) has a mean Ti—Cl bond length of 2.35 (2.35 Å) with a slightly extended Cl—Ti—Cl angle of 95.94 (94.44°).

The conformations of the siloxy chains within (I) and (II) are different. The conformational geometry of the siloxy linkage in (I) is cisoid, in contrast to the transoid siloxy conformation observed in (II). In (I), a nearly eclipsed geometry for the Si1—O—Si2 linkage is observed in the crystal structure and this is highlighted by the C6—Si1···Si2—C8 torsion angle of 8.30°. Indeed, the C₅H₄ groups are also disposed in a periplanar or cis conformation with respect to one another, and the C1—Si1···Si2—C10 torsion angle of 6.20° emphasizes the nearly ideal eclipsed conformation of the silicon substituents. However, for (II), a staggered geometry of the substituents about the Si1—O—Si2 linkage is observed in the crystal structure in the solid state, which is highlighted by the C6—Si1···Si2—C9 torsion angle of 160.1°. The C₅H₄ groups are also disposed in an antiperiplanar or trans conformation with respect to one another, and the C1—Si1···Si2—C10 torsion angle is 168.3°, further emphasizing the staggered conformation of the Si substituents.

In compound (I), the two monosubstituted C₅ planes are aligned in a nearly parallel fashion with a C₅H₄-centroid–C₅H₄-centroid distance of 3.86 Å, suggesting that a small degree of π-stacking may also be responsible for the observed geometry. However, in (II), a staggered conformation of the Si1—O—Si2 bridge substituents appeared to be a conformational energy minimum. Presumably, the steric repulsion of the Cp^* ligands was too great to allow the cis conformation of the siloxane substituents which was observed for (I). It is also possible that net packing forces contributed to the opposing conformations observed between (I) and (II). For (I) and (II), all Si—C bond lengths approximate to the average Sisp³—Cspⁿ (n = 2 or 3) distance within the margins of experimental error (Orpen et al., 1989).

All other cases of metallocenes that involve the same siloxane bridging unit are ansa-metallocenes, wherein both Cp units of the same ligand are bound to the same metal (Curtis et al., 1983; Angelokos et al., 1994; Ciruelos et al., 1995). For such ansa-metallocenes, the siloxane methyl substituents are constrained to be eclipsed in order to accommodate the metal center and so do not offer a legitimate comparison to the title compounds where free rotation about the Si1—O—Si2 axis is possible.

S2. Experimental

Compounds (I) and (II) were generated by slow hydrolysis of the corresponding alkoxysilane precursor in CH₂Cl₂. Red needle-like crystals of both (I) and (II) were obtained by slow evaporation of an ethyl acetate solution at ambient temperature.

S3. Refinement

Only data up to 2θ_max = 48.0° could be used for (I) as the crystals were very weak diffractors (mean I/σ = 1.8 for a resolution of 0.90 Å). For (I), intensity data were collected using a longer exposure time of 60 s per frame to improve data quality.

Computing details

For both compounds, data collection: SMART (Bruker, 1997a); cell refinement: SMART; data reduction: SAINT (Bruker, 1997a); program(s) used to solve structure: SHELXTL-Plus (Sheldrick, 1999); program(s) used to refine structure: SHELXTL-Plus; molecular graphics: SHELXTL (Bruker, 1997b); software used to prepare material for publication: SHELXTL.

Figures

	Fig. 1. View of (I) showing the labelling of the non-H atoms. Displacement ellipsoids are shown at 50% probability levels, H atoms are drawn as spheres of arbitrary radii and the dichloromethane solvate is omitted.
	Fig. 2. View of (II) showing the labelling of the non-H atoms. Displacement ellipsoids are shown at 50% probability levels and H atoms are drawn as spheres of arbitrary radii.

(I) [m-1,2(h⁵)-1,3-dicyclopentadienyl-1,1,3,3-tetramethyldisiloxanyl] bis[dichloro(h⁵-cyclopentadienyl)titanium] dichloromethane solvate

Crystal data

[TiCl2(C5H5)(C7H10Si)]2O·CH2Cl2	F(000) = 1456
Mr = 713.19	Dx = 1.504 Mg m^−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
a = 13.6494 (2) Å	Cell parameters from 4922 reflections
b = 12.8573 (2) Å	θ = 2–24°
c = 18.4995 (3) Å	µ = 1.11 mm^−1
β = 103.977 (1)°	T = 223 K
V = 3150.44 (8) Å^3	Needle, red
Z = 4	0.40 × 0.18 × 0.10 mm

Data collection

Bruker CCD area detector diffractometer	4950 independent reflections
Radiation source: normal-focus sealed tube	2810 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.13
ϕ and ω scans	θmax = 24°, θmin = 1.5°
Absorption correction: empirical (using intensity measurements) (SADABS; Blessing, 1995)	h = −15→15
Tmin = 0.67, Tmax = 0.90	k = −14→14
27882 measured reflections	l = −21→21

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.070	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.179	H-atom parameters constrained
S = 1.05	w = 1/[σ^2(Fo^2) + (0.0647P)^2 + 10.5834P] where P = (Fo^2 + 2Fc^2)/3
4950 reflections	(Δ/σ)max = 0.001
325 parameters	Δρmax = 0.77 e Å^−3
0 restraints	Δρmin = −0.66 e Å^−3

Special details

Experimental. Data were collected by the double-pass method using the CCD area detector system. The first 50 frames of data were re-collected at the end of data collection and no crystal decay was observed for either compound.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

The structures were solved by the Patterson method and refined successfully in the monoclinic space groups P2₁/c and P2₁/n. Full matrix least-squares refinement was carried out by minimizing w(F_o²-F_c²)². The non-H atoms were refined anisotropically to convergence. H atoms were treated using appropriate riding models [SHELXTL-Plus command AFIX = m3 (Sheldrick, 1999)], where the atomic position of the H atom rides on the coordinates of the non-H atom to which it is attached and the displacement parameters are fixed at 1.2 times those of the parent atom.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ti1	0.72111 (9)	0.89568 (10)	0.01272 (8)	0.0321 (4)
Ti2	1.21117 (9)	0.60279 (10)	−0.01995 (8)	0.0337 (4)
Cl1	0.65521 (15)	1.01670 (16)	−0.08251 (11)	0.0456 (6)
Cl2	0.72088 (16)	1.01740 (16)	0.10911 (12)	0.0482 (6)
Cl3	1.13817 (14)	0.47371 (15)	−0.10729 (11)	0.0435 (5)
Cl4	1.23535 (14)	0.48462 (16)	0.08196 (11)	0.0453 (5)
Si1	0.82779 (17)	0.87783 (19)	−0.16077 (13)	0.0451 (6)
Si2	1.00345 (17)	0.72606 (18)	−0.17783 (13)	0.0429 (6)
O	0.9291 (4)	0.8254 (4)	−0.1775 (3)	0.0528 (15)
C1	0.8477 (5)	0.8740 (6)	−0.0569 (4)	0.0350 (19)
C2	0.8492 (5)	0.7850 (6)	−0.0116 (4)	0.036 (2)
H2	0.8389	0.7125	−0.0301	0.043*
C3	0.8767 (5)	0.8146 (7)	0.0640 (5)	0.043 (2)
H3	0.8913	0.7668	0.1073	0.052*
C4	0.8986 (5)	0.9214 (7)	0.0659 (5)	0.047 (2)
H4	0.9282	0.9625	0.1112	0.056*
C5	0.8792 (5)	0.9577 (6)	−0.0065 (5)	0.038 (2)
H5	0.8921	1.0296	−0.0211	0.045*
C6	0.8239 (7)	1.0134 (7)	−0.1946 (5)	0.059 (3)
H6A	0.8135	1.0135	−0.2483	0.089*
H6B	0.8872	1.0477	−0.1721	0.089*
H6C	0.7688	1.0502	−0.1811	0.089*
C7	0.7155 (7)	0.8014 (8)	−0.2078 (5)	0.075 (3)
H7A	0.7073	0.8049	−0.2613	0.112*
H7B	0.6560	0.8297	−0.1951	0.112*
H7C	0.7244	0.7295	−0.1917	0.112*
C8	1.0928 (6)	0.7687 (7)	−0.2336 (5)	0.058 (2)
H8A	1.0564	0.7781	−0.2851	0.087*
H8B	1.1447	0.7163	−0.2308	0.087*
H8C	1.1239	0.8340	−0.2140	0.087*
C9	0.9298 (6)	0.6120 (7)	−0.2181 (5)	0.058 (2)
H9A	0.8984	0.6250	−0.2702	0.087*
H9B	0.8780	0.5984	−0.1915	0.087*
H9C	0.9741	0.5521	−0.2139	0.087*
C10	1.0660 (5)	0.7055 (6)	−0.0771 (4)	0.0343 (19)
C11	1.1382 (5)	0.7707 (5)	−0.0324 (5)	0.037 (2)
H11	1.1680	0.8328	−0.0506	0.044*
C12	1.1548 (6)	0.7411 (6)	0.0444 (5)	0.042 (2)
H12	1.1949	0.7793	0.0881	0.050*
C13	1.0875 (6)	0.6586 (6)	0.0454 (5)	0.039 (2)
H13	1.0756	0.6255	0.0908	0.047*
C14	1.0370 (5)	0.6349 (6)	−0.0261 (4)	0.0345 (19)
H14	0.9825	0.5825	−0.0399	0.041*
C15	1.3511 (6)	0.7164 (7)	−0.0068 (7)	0.060 (3)
H15	1.3569	0.7867	0.0156	0.072*
C16	1.3172 (7)	0.6940 (9)	−0.0805 (7)	0.066 (3)
H16	1.2943	0.7461	−0.1204	0.079*
C17	1.3332 (7)	0.5913 (11)	−0.0921 (7)	0.078 (4)
H17	1.3237	0.5567	−0.1411	0.094*
C18	1.3758 (7)	0.5468 (8)	−0.0234 (8)	0.071 (3)
H18	1.4021	0.4749	−0.0148	0.085*
C19	1.3884 (6)	0.6252 (10)	0.0295 (6)	0.070 (3)
H19	1.4246	0.6189	0.0826	0.084*
C20	0.6674 (7)	0.7321 (6)	0.0457 (7)	0.060 (3)
H20	0.7120	0.6755	0.0708	0.072*
C21	0.6211 (7)	0.8042 (7)	0.0799 (5)	0.054 (2)
H21	0.6276	0.8092	0.1343	0.065*
C22	0.5554 (6)	0.8621 (7)	0.0262 (6)	0.057 (3)
H22	0.5071	0.9148	0.0356	0.068*
C23	0.5592 (7)	0.8231 (8)	−0.0425 (6)	0.058 (3)
H23	0.5146	0.8432	−0.0911	0.069*
C24	0.6303 (7)	0.7428 (7)	−0.0304 (6)	0.058 (3)
H24	0.6439	0.6952	−0.0690	0.070*
C1S	1.5728 (9)	0.4814 (9)	−0.2543 (5)	0.092 (4)
H1SA	1.6399	0.5129	−0.2384	0.110*
H1SB	1.5466	0.4979	−0.3072	0.110*
Cl1S	1.4992 (3)	0.5352 (4)	−0.2076 (2)	0.1503 (18)
Cl2S	1.5860 (3)	0.3417 (4)	−0.2446 (2)	0.1600 (18)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ti1	0.0282 (7)	0.0270 (8)	0.0448 (9)	0.0026 (6)	0.0157 (6)	0.0008 (7)
Ti2	0.0270 (7)	0.0279 (8)	0.0488 (9)	0.0003 (6)	0.0144 (6)	−0.0004 (7)
Cl1	0.0422 (12)	0.0438 (12)	0.0549 (14)	0.0125 (10)	0.0197 (10)	0.0123 (10)
Cl2	0.0545 (13)	0.0422 (12)	0.0560 (14)	−0.0040 (10)	0.0291 (11)	−0.0103 (11)
Cl3	0.0415 (12)	0.0356 (11)	0.0549 (13)	0.0021 (9)	0.0145 (10)	−0.0094 (10)
Cl4	0.0425 (12)	0.0411 (12)	0.0516 (13)	0.0026 (10)	0.0103 (10)	0.0083 (10)
Si1	0.0433 (13)	0.0508 (15)	0.0425 (14)	0.0127 (12)	0.0130 (11)	0.0014 (12)
Si2	0.0439 (14)	0.0456 (14)	0.0433 (14)	0.0082 (11)	0.0188 (11)	0.0007 (12)
O	0.056 (4)	0.057 (4)	0.050 (4)	0.025 (3)	0.022 (3)	0.004 (3)
C1	0.028 (4)	0.035 (5)	0.047 (5)	0.004 (4)	0.017 (4)	0.002 (4)
C2	0.025 (4)	0.037 (5)	0.050 (6)	0.013 (4)	0.019 (4)	−0.009 (4)
C3	0.034 (5)	0.056 (6)	0.040 (5)	0.017 (4)	0.010 (4)	0.015 (4)
C4	0.027 (4)	0.069 (7)	0.046 (6)	−0.002 (4)	0.014 (4)	−0.007 (5)
C5	0.029 (4)	0.037 (5)	0.054 (6)	−0.006 (4)	0.023 (4)	−0.002 (4)
C6	0.073 (6)	0.065 (6)	0.046 (6)	0.019 (5)	0.026 (5)	0.020 (5)
C7	0.070 (7)	0.105 (9)	0.048 (6)	−0.006 (6)	0.013 (5)	−0.022 (6)
C8	0.059 (6)	0.065 (6)	0.059 (6)	0.005 (5)	0.029 (5)	−0.005 (5)
C9	0.054 (6)	0.075 (7)	0.046 (5)	−0.005 (5)	0.010 (4)	−0.006 (5)
C10	0.029 (4)	0.030 (4)	0.048 (5)	0.006 (4)	0.018 (4)	0.002 (4)
C11	0.033 (4)	0.016 (4)	0.066 (6)	0.002 (3)	0.022 (4)	−0.006 (4)
C12	0.044 (5)	0.034 (5)	0.048 (6)	0.006 (4)	0.013 (4)	−0.014 (4)
C13	0.041 (5)	0.038 (5)	0.042 (5)	0.010 (4)	0.019 (4)	0.005 (4)
C14	0.029 (4)	0.027 (4)	0.052 (6)	0.005 (3)	0.020 (4)	0.000 (4)
C15	0.034 (5)	0.045 (6)	0.105 (9)	−0.010 (5)	0.022 (5)	−0.014 (6)
C16	0.044 (6)	0.073 (8)	0.090 (9)	0.001 (5)	0.037 (6)	0.032 (7)
C17	0.035 (6)	0.122 (11)	0.091 (9)	−0.026 (7)	0.040 (6)	−0.038 (9)
C18	0.028 (5)	0.041 (6)	0.151 (12)	0.003 (4)	0.035 (6)	0.002 (7)
C19	0.017 (5)	0.112 (10)	0.076 (7)	−0.025 (6)	0.000 (4)	0.016 (7)
C20	0.048 (6)	0.024 (5)	0.112 (9)	−0.002 (4)	0.026 (6)	0.016 (5)
C21	0.060 (6)	0.050 (6)	0.061 (6)	−0.015 (5)	0.033 (5)	0.010 (5)
C22	0.027 (5)	0.045 (6)	0.108 (9)	0.003 (4)	0.036 (5)	0.016 (6)
C23	0.047 (6)	0.058 (7)	0.063 (7)	−0.026 (5)	0.005 (5)	0.014 (5)
C24	0.051 (6)	0.048 (6)	0.081 (8)	−0.022 (5)	0.029 (5)	−0.021 (6)
C1S	0.114 (10)	0.106 (10)	0.046 (6)	0.003 (8)	0.002 (6)	−0.028 (7)
Cl1S	0.095 (3)	0.250 (5)	0.106 (3)	0.023 (3)	0.024 (2)	−0.001 (3)
Cl2S	0.142 (4)	0.234 (6)	0.105 (3)	−0.020 (4)	0.030 (3)	−0.047 (3)

Geometric parameters (Å, º)

Ti1—C3	2.351 (7)	Si1—C1	1.876 (8)
Ti1—C20	2.356 (8)	Si2—O	1.633 (5)
Ti1—C24	2.358 (8)	Si2—C9	1.832 (9)
Ti1—Cl1	2.360 (2)	Si2—C8	1.861 (8)
Ti1—C21	2.369 (8)	Si2—C10	1.872 (8)
Ti1—Cl2	2.373 (2)	C1—C2	1.415 (10)
Ti1—C22	2.374 (7)	C1—C5	1.421 (10)
Ti1—C2	2.381 (7)	C2—C3	1.411 (10)
Ti1—C23	2.389 (8)	C3—C4	1.404 (11)
Ti1—C5	2.406 (7)	C4—C5	1.383 (11)
Ti1—C1	2.408 (7)	C10—C11	1.402 (10)
Ti1—C4	2.408 (8)	C10—C14	1.432 (10)
Ti2—C16	2.347 (8)	C11—C12	1.436 (11)
Ti2—Cl3	2.362 (2)	C12—C13	1.405 (10)
Ti2—C11	2.366 (7)	C13—C14	1.370 (10)
Ti2—C15	2.370 (8)	C15—C16	1.361 (13)
Ti2—C12	2.370 (7)	C15—C19	1.386 (13)
Ti2—C18	2.376 (8)	C16—C17	1.363 (14)
Ti2—C17	2.378 (9)	C17—C18	1.388 (14)
Ti2—Cl4	2.381 (2)	C18—C19	1.386 (14)
Ti2—C14	2.389 (7)	C20—C21	1.362 (12)
Ti2—C19	2.388 (8)	C20—C24	1.383 (13)
Ti2—C10	2.403 (7)	C21—C22	1.383 (11)
Ti2—C13	2.411 (7)	C22—C23	1.379 (12)
Si1—O	1.633 (5)	C23—C24	1.398 (12)
Si1—C6	1.849 (8)	C1S—Cl1S	1.629 (11)
Si1—C7	1.852 (9)	C1S—Cl2S	1.810 (12)
C3—Ti1—C20	78.9 (3)	C12—Ti2—C19	98.0 (4)
C3—Ti1—C24	96.7 (3)	C18—Ti2—C19	33.8 (3)
C20—Ti1—C24	34.1 (3)	C17—Ti2—C19	56.0 (4)
C3—Ti1—Cl1	137.6 (2)	Cl4—Ti2—C19	80.8 (3)
C20—Ti1—Cl1	134.1 (3)	C14—Ti2—C19	154.4 (4)
C24—Ti1—Cl1	102.9 (3)	C16—Ti2—C10	93.1 (3)
C3—Ti1—C21	98.5 (3)	Cl3—Ti2—C10	85.31 (19)
C20—Ti1—C21	33.5 (3)	C11—Ti2—C10	34.2 (2)
C24—Ti1—C21	56.0 (3)	C15—Ti2—C10	105.4 (3)
Cl1—Ti1—C21	123.7 (2)	C12—Ti2—C10	58.4 (3)
C3—Ti1—Cl2	98.9 (2)	C18—Ti2—C10	147.1 (4)
C20—Ti1—Cl2	109.7 (3)	C17—Ti2—C10	113.7 (4)
C24—Ti1—Cl2	135.1 (2)	Cl4—Ti2—C10	129.83 (18)
Cl1—Ti1—Cl2	93.25 (9)	C14—Ti2—C10	34.8 (2)
C21—Ti1—Cl2	80.1 (2)	C19—Ti2—C10	138.9 (4)
C3—Ti1—C22	131.9 (3)	C16—Ti2—C13	132.7 (4)
C20—Ti1—C22	56.4 (3)	Cl3—Ti2—C13	108.7 (2)
C24—Ti1—C22	56.5 (3)	C11—Ti2—C13	56.5 (3)
Cl1—Ti1—C22	89.8 (2)	C15—Ti2—C13	114.2 (3)
C21—Ti1—C22	33.9 (3)	C12—Ti2—C13	34.2 (3)
Cl2—Ti1—C22	82.4 (3)	C18—Ti2—C13	152.3 (4)
C3—Ti1—C2	34.7 (3)	C17—Ti2—C13	166.0 (4)
C20—Ti1—C2	78.7 (3)	Cl4—Ti2—C13	76.9 (2)
C24—Ti1—C2	77.7 (3)	C14—Ti2—C13	33.2 (2)
Cl1—Ti1—C2	114.7 (2)	C19—Ti2—C13	122.6 (4)
C21—Ti1—C2	110.2 (3)	C10—Ti2—C13	56.9 (3)
Cl2—Ti1—C2	132.1 (2)	O—Si1—C6	106.4 (4)
C22—Ti1—C2	132.3 (3)	O—Si1—C7	109.5 (4)
C3—Ti1—C23	130.7 (3)	C6—Si1—C7	112.9 (4)
C20—Ti1—C23	56.5 (3)	O—Si1—C1	105.2 (3)
C24—Ti1—C23	34.3 (3)	C6—Si1—C1	110.9 (4)
Cl1—Ti1—C23	78.0 (2)	C7—Si1—C1	111.5 (4)
C21—Ti1—C23	55.9 (3)	O—Si2—C9	110.4 (4)
Cl2—Ti1—C23	114.2 (3)	O—Si2—C8	105.2 (4)
C22—Ti1—C23	33.6 (3)	C9—Si2—C8	112.3 (4)
C2—Ti1—C23	109.4 (3)	O—Si2—C10	103.9 (3)
C3—Ti1—C5	56.7 (3)	C9—Si2—C10	111.4 (4)
C20—Ti1—C5	132.9 (3)	C8—Si2—C10	113.1 (4)
C24—Ti1—C5	130.0 (3)	Si2—O—Si1	151.5 (4)
Cl1—Ti1—C5	82.2 (2)	C2—C1—C5	105.5 (7)
C21—Ti1—C5	153.3 (3)	C2—C1—Si1	127.2 (6)
Cl2—Ti1—C5	93.2 (2)	C5—C1—Si1	126.7 (6)
C22—Ti1—C5	170.7 (3)	C2—C1—Ti1	71.8 (4)
C2—Ti1—C5	56.2 (3)	C5—C1—Ti1	72.8 (4)
C23—Ti1—C5	146.7 (3)	Si1—C1—Ti1	126.8 (4)
C3—Ti1—C1	57.9 (3)	C3—C2—C1	109.3 (7)
C20—Ti1—C1	110.1 (3)	C3—C2—Ti1	71.5 (4)
C24—Ti1—C1	96.2 (3)	C1—C2—Ti1	73.9 (4)
Cl1—Ti1—C1	82.57 (19)	C4—C3—C2	107.0 (7)
C21—Ti1—C1	143.3 (3)	C4—C3—Ti1	75.1 (5)
Cl2—Ti1—C1	127.6 (2)	C2—C3—Ti1	73.8 (4)
C22—Ti1—C1	149.3 (3)	C5—C4—C3	108.5 (8)
C2—Ti1—C1	34.4 (2)	C5—C4—Ti1	73.3 (4)
C23—Ti1—C1	115.8 (3)	C3—C4—Ti1	70.6 (4)
C5—Ti1—C1	34.3 (2)	C4—C5—C1	109.6 (7)
C3—Ti1—C4	34.3 (3)	C4—C5—Ti1	73.4 (4)
C20—Ti1—C4	111.2 (3)	C1—C5—Ti1	72.9 (4)
C24—Ti1—C4	130.4 (3)	C11—C10—C14	104.9 (7)
Cl1—Ti1—C4	112.3 (2)	C11—C10—Si2	126.1 (6)
C21—Ti1—C4	120.3 (3)	C14—C10—Si2	127.8 (6)
Cl2—Ti1—C4	77.7 (2)	C11—C10—Ti2	71.5 (4)
C22—Ti1—C4	150.7 (3)	C14—C10—Ti2	72.0 (4)
C2—Ti1—C4	56.4 (3)	Si2—C10—Ti2	130.1 (4)
C23—Ti1—C4	164.6 (3)	C10—C11—C12	110.2 (7)
C5—Ti1—C4	33.4 (3)	C10—C11—Ti2	74.4 (4)
C1—Ti1—C4	56.8 (3)	C12—C11—Ti2	72.5 (4)
C16—Ti2—Cl3	103.4 (3)	C13—C12—C11	105.4 (7)
C16—Ti2—C11	78.0 (3)	C13—C12—Ti2	74.5 (4)
Cl3—Ti2—C11	118.4 (2)	C11—C12—Ti2	72.2 (4)
C16—Ti2—C15	33.5 (3)	C14—C13—C12	109.5 (7)
Cl3—Ti2—C15	134.4 (3)	C14—C13—Ti2	72.5 (4)
C11—Ti2—C15	76.0 (3)	C12—C13—Ti2	71.3 (4)
C16—Ti2—C12	100.3 (4)	C13—C14—C10	109.9 (7)
Cl3—Ti2—C12	137.4 (2)	C13—C14—Ti2	74.3 (4)
C11—Ti2—C12	35.3 (3)	C10—C14—Ti2	73.2 (4)
C15—Ti2—C12	80.7 (3)	C16—C15—C19	107.7 (9)
C16—Ti2—C18	56.1 (3)	C16—C15—Ti2	72.3 (5)
Cl3—Ti2—C18	90.8 (3)	C19—C15—Ti2	73.8 (5)
C11—Ti2—C18	130.8 (3)	C15—C16—C17	109.5 (10)
C15—Ti2—C18	56.3 (3)	C15—C16—Ti2	74.1 (5)
C12—Ti2—C18	131.7 (4)	C17—C16—Ti2	74.5 (5)
C16—Ti2—C17	33.5 (3)	C16—C17—C18	107.6 (10)
Cl3—Ti2—C17	79.0 (3)	C16—C17—Ti2	72.0 (5)
C11—Ti2—C17	109.7 (4)	C18—C17—Ti2	72.9 (6)
C15—Ti2—C17	55.9 (3)	C19—C18—C17	107.5 (9)
C12—Ti2—C17	133.3 (4)	C19—C18—Ti2	73.6 (5)
C18—Ti2—C17	33.9 (3)	C17—C18—Ti2	73.1 (5)
C16—Ti2—Cl4	135.5 (3)	C18—C19—C15	107.7 (9)
Cl3—Ti2—Cl4	92.76 (8)	C18—C19—Ti2	72.6 (5)
C11—Ti2—Cl4	129.3 (2)	C15—C19—Ti2	72.3 (5)
C15—Ti2—Cl4	111.0 (3)	C21—C20—C24	108.0 (9)
C12—Ti2—Cl4	94.6 (2)	C21—C20—Ti1	73.8 (5)
C18—Ti2—Cl4	82.9 (3)	C24—C20—Ti1	73.0 (5)
C17—Ti2—Cl4	115.0 (4)	C20—C21—C22	109.0 (9)
C16—Ti2—C14	127.8 (3)	C20—C21—Ti1	72.7 (5)
Cl3—Ti2—C14	80.7 (2)	C22—C21—Ti1	73.3 (5)
C11—Ti2—C14	56.4 (2)	C23—C22—C21	107.7 (8)
C15—Ti2—C14	131.8 (3)	C23—C22—Ti1	73.7 (5)
C12—Ti2—C14	56.9 (3)	C21—C22—Ti1	72.8 (4)
C18—Ti2—C14	171.3 (3)	C22—C23—C24	107.5 (9)
C17—Ti2—C14	143.9 (4)	C22—C23—Ti1	72.6 (5)
Cl4—Ti2—C14	95.39 (19)	C24—C23—Ti1	71.7 (5)
C16—Ti2—C19	55.8 (3)	C20—C24—C23	107.8 (9)
Cl3—Ti2—C19	124.6 (3)	C20—C24—Ti1	72.9 (5)
C11—Ti2—C19	106.9 (4)	C23—C24—Ti1	74.1 (5)
C15—Ti2—C19	33.9 (3)	Cl1S—C1S—Cl2S	115.3 (8)
C9—Si2—O—Si1	47.0 (9)	Ti2—C13—C14—C10	−65.1 (5)
C8—Si2—O—Si1	168.3 (8)	C12—C13—C14—Ti2	62.1 (5)
C10—Si2—O—Si1	−72.6 (9)	C11—C10—C14—C13	1.4 (8)
C6—Si1—O—Si2	−175.9 (8)	Si2—C10—C14—C13	−166.9 (5)
C7—Si1—O—Si2	−53.6 (9)	Ti2—C10—C14—C13	65.8 (5)
C1—Si1—O—Si2	66.4 (9)	C11—C10—C14—Ti2	−64.4 (5)
O—Si1—C1—C2	−69.2 (7)	Si2—C10—C14—Ti2	127.3 (6)
C6—Si1—C1—C2	176.2 (6)	C16—Ti2—C14—C13	−112.5 (6)
C7—Si1—C1—C2	49.5 (8)	Cl3—Ti2—C14—C13	147.8 (5)
O—Si1—C1—C5	100.7 (7)	C11—Ti2—C14—C13	−78.7 (5)
C6—Si1—C1—C5	−13.9 (8)	C15—Ti2—C14—C13	−68.7 (7)
C7—Si1—C1—C5	−140.6 (7)	C12—Ti2—C14—C13	−36.1 (5)
O—Si1—C1—Ti1	−163.7 (4)	C18—Ti2—C14—C13	134 (3)
C6—Si1—C1—Ti1	81.7 (5)	C17—Ti2—C14—C13	−155.8 (7)
C7—Si1—C1—Ti1	−45.0 (6)	Cl4—Ti2—C14—C13	55.9 (5)
C3—Ti1—C1—C2	36.6 (4)	C19—Ti2—C14—C13	−24.0 (10)
C20—Ti1—C1—C2	−25.2 (6)	C10—Ti2—C14—C13	−117.0 (7)
C24—Ti1—C1—C2	−57.4 (5)	C16—Ti2—C14—C10	4.5 (7)
Cl1—Ti1—C1—C2	−159.6 (4)	Cl3—Ti2—C14—C10	−95.2 (4)
C21—Ti1—C1—C2	−20.0 (7)	C11—Ti2—C14—C10	38.3 (4)
Cl2—Ti1—C1—C2	112.0 (4)	C15—Ti2—C14—C10	48.3 (7)
C22—Ti1—C1—C2	−82.6 (7)	C12—Ti2—C14—C10	80.8 (5)
C23—Ti1—C1—C2	−86.8 (5)	C18—Ti2—C14—C10	−109 (3)
C5—Ti1—C1—C2	113.3 (6)	C17—Ti2—C14—C10	−38.8 (8)
C4—Ti1—C1—C2	77.6 (5)	Cl4—Ti2—C14—C10	172.9 (4)
C3—Ti1—C1—C5	−76.7 (5)	C19—Ti2—C14—C10	93.0 (8)
C20—Ti1—C1—C5	−138.6 (5)	C13—Ti2—C14—C10	117.0 (7)
C24—Ti1—C1—C5	−170.7 (5)	Cl3—Ti2—C15—C16	27.0 (8)
Cl1—Ti1—C1—C5	87.1 (4)	C11—Ti2—C15—C16	−89.3 (7)
C21—Ti1—C1—C5	−133.3 (6)	C12—Ti2—C15—C16	−125.1 (7)
Cl2—Ti1—C1—C5	−1.3 (5)	C18—Ti2—C15—C16	78.0 (7)
C22—Ti1—C1—C5	164.1 (6)	C17—Ti2—C15—C16	36.8 (6)
C2—Ti1—C1—C5	−113.3 (6)	Cl4—Ti2—C15—C16	143.5 (6)
C23—Ti1—C1—C5	159.8 (5)	C14—Ti2—C15—C16	−97.9 (7)
C4—Ti1—C1—C5	−35.7 (4)	C19—Ti2—C15—C16	115.1 (9)
C3—Ti1—C1—Si1	160.0 (6)	C10—Ti2—C15—C16	−71.7 (6)
C20—Ti1—C1—Si1	98.1 (5)	C13—Ti2—C15—C16	−131.9 (6)
C24—Ti1—C1—Si1	65.9 (5)	C16—Ti2—C15—C19	−115.1 (9)
Cl1—Ti1—C1—Si1	−36.3 (4)	Cl3—Ti2—C15—C19	−88.1 (8)
C21—Ti1—C1—Si1	103.4 (6)	C11—Ti2—C15—C19	155.6 (8)
Cl2—Ti1—C1—Si1	−124.7 (4)	C12—Ti2—C15—C19	119.8 (7)
C22—Ti1—C1—Si1	40.7 (8)	C18—Ti2—C15—C19	−37.1 (6)
C2—Ti1—C1—Si1	123.3 (7)	C17—Ti2—C15—C19	−78.3 (7)
C23—Ti1—C1—Si1	36.5 (6)	Cl4—Ti2—C15—C19	28.4 (7)
C5—Ti1—C1—Si1	−123.4 (7)	C14—Ti2—C15—C19	147.0 (6)
C4—Ti1—C1—Si1	−159.1 (6)	C10—Ti2—C15—C19	173.2 (7)
C5—C1—C2—C3	2.4 (8)	C13—Ti2—C15—C19	113.0 (7)
Si1—C1—C2—C3	174.0 (5)	C19—C15—C16—C17	−0.8 (10)
Ti1—C1—C2—C3	−63.1 (5)	Ti2—C15—C16—C17	−66.7 (6)
C5—C1—C2—Ti1	65.5 (5)	C19—C15—C16—Ti2	65.9 (6)
Si1—C1—C2—Ti1	−122.9 (6)	Cl3—Ti2—C16—C15	−160.5 (6)
C20—Ti1—C2—C3	−86.7 (6)	C11—Ti2—C16—C15	82.7 (7)
C24—Ti1—C2—C3	−121.6 (6)	C12—Ti2—C16—C15	55.2 (7)
Cl1—Ti1—C2—C3	139.7 (4)	C18—Ti2—C16—C15	−78.7 (7)
C21—Ti1—C2—C3	−75.2 (5)	C17—Ti2—C16—C15	−116.1 (9)
Cl2—Ti1—C2—C3	19.7 (6)	Cl4—Ti2—C16—C15	−52.3 (8)
C22—Ti1—C2—C3	−105.8 (6)	C14—Ti2—C16—C15	111.0 (6)
C23—Ti1—C2—C3	−134.9 (5)	C19—Ti2—C16—C15	−37.6 (6)
C5—Ti1—C2—C3	78.9 (5)	C10—Ti2—C16—C15	113.5 (6)
C1—Ti1—C2—C3	117.4 (7)	C13—Ti2—C16—C15	67.5 (7)
C4—Ti1—C2—C3	38.5 (5)	Cl3—Ti2—C16—C17	−44.5 (8)
C3—Ti1—C2—C1	−117.4 (7)	C11—Ti2—C16—C17	−161.2 (8)
C20—Ti1—C2—C1	155.9 (5)	C15—Ti2—C16—C17	116.1 (9)
C24—Ti1—C2—C1	121.0 (5)	C12—Ti2—C16—C17	171.2 (8)
Cl1—Ti1—C2—C1	22.4 (5)	C18—Ti2—C16—C17	37.3 (6)
C21—Ti1—C2—C1	167.4 (5)	Cl4—Ti2—C16—C17	63.7 (10)
Cl2—Ti1—C2—C1	−97.7 (5)	C14—Ti2—C16—C17	−133.0 (7)
C22—Ti1—C2—C1	136.8 (5)	C19—Ti2—C16—C17	78.5 (7)
C23—Ti1—C2—C1	107.7 (5)	C10—Ti2—C16—C17	−130.4 (8)
C5—Ti1—C2—C1	−38.5 (4)	C13—Ti2—C16—C17	−176.4 (7)
C4—Ti1—C2—C1	−78.9 (5)	C15—C16—C17—C18	1.7 (10)
C1—C2—C3—C4	−3.7 (8)	Ti2—C16—C17—C18	−64.7 (6)
Ti1—C2—C3—C4	−68.3 (5)	C15—C16—C17—Ti2	66.5 (6)
C1—C2—C3—Ti1	64.7 (5)	Cl3—Ti2—C17—C16	136.0 (8)
C20—Ti1—C3—C4	−160.7 (6)	C11—Ti2—C17—C16	19.5 (8)
C24—Ti1—C3—C4	170.0 (5)	C15—Ti2—C17—C16	−36.8 (6)
Cl1—Ti1—C3—C4	52.6 (6)	C12—Ti2—C17—C16	−11.9 (10)
C21—Ti1—C3—C4	−133.4 (5)	C18—Ti2—C17—C16	−115.7 (9)
Cl2—Ti1—C3—C4	−52.2 (5)	Cl4—Ti2—C17—C16	−136.1 (7)
C22—Ti1—C3—C4	−139.9 (6)	C14—Ti2—C17—C16	79.2 (8)
C2—Ti1—C3—C4	113.1 (7)	C19—Ti2—C17—C16	−78.0 (7)
C23—Ti1—C3—C4	174.8 (5)	C10—Ti2—C17—C16	56.2 (8)
C5—Ti1—C3—C4	35.8 (5)	C13—Ti2—C17—C16	10.9 (19)
C1—Ti1—C3—C4	76.9 (5)	C16—Ti2—C17—C18	115.7 (9)
C20—Ti1—C3—C2	86.2 (5)	Cl3—Ti2—C17—C18	−108.3 (7)
C24—Ti1—C3—C2	56.9 (5)	C11—Ti2—C17—C18	135.2 (7)
Cl1—Ti1—C3—C2	−60.5 (6)	C15—Ti2—C17—C18	78.8 (6)
C21—Ti1—C3—C2	113.5 (5)	C12—Ti2—C17—C18	103.7 (9)
Cl2—Ti1—C3—C2	−165.3 (4)	Cl4—Ti2—C17—C18	−20.4 (8)
C22—Ti1—C3—C2	107.0 (6)	C14—Ti2—C17—C18	−165.2 (6)
C23—Ti1—C3—C2	61.7 (6)	C19—Ti2—C17—C18	37.6 (6)
C5—Ti1—C3—C2	−77.3 (5)	C10—Ti2—C17—C18	171.8 (6)
C1—Ti1—C3—C2	−36.3 (4)	C13—Ti2—C17—C18	126.6 (15)
C4—Ti1—C3—C2	−113.1 (7)	C16—C17—C18—C19	−2.0 (10)
C2—C3—C4—C5	3.5 (8)	Ti2—C17—C18—C19	−66.1 (6)
Ti1—C3—C4—C5	−63.9 (5)	C16—C17—C18—Ti2	64.1 (6)
C2—C3—C4—Ti1	67.5 (5)	C16—Ti2—C18—C19	77.7 (7)
C3—Ti1—C4—C5	117.1 (7)	Cl3—Ti2—C18—C19	−176.7 (7)
C20—Ti1—C4—C5	137.5 (5)	C11—Ti2—C18—C19	53.4 (10)
C24—Ti1—C4—C5	104.1 (6)	C15—Ti2—C18—C19	37.1 (6)
Cl1—Ti1—C4—C5	−27.5 (5)	C12—Ti2—C18—C19	5.9 (10)
C21—Ti1—C4—C5	173.5 (5)	C17—Ti2—C18—C19	114.6 (9)
Cl2—Ti1—C4—C5	−115.9 (5)	Cl4—Ti2—C18—C19	−84.0 (7)
C22—Ti1—C4—C5	−163.9 (6)	C14—Ti2—C18—C19	−163 (2)
C2—Ti1—C4—C5	78.2 (5)	C10—Ti2—C18—C19	100.7 (10)
C23—Ti1—C4—C5	102.3 (13)	C13—Ti2—C18—C19	−40.8 (10)
C1—Ti1—C4—C5	36.8 (4)	C16—Ti2—C18—C17	−36.9 (6)
C20—Ti1—C4—C3	20.3 (6)	Cl3—Ti2—C18—C17	68.7 (7)
C24—Ti1—C4—C3	−13.0 (7)	C11—Ti2—C18—C17	−61.2 (9)
Cl1—Ti1—C4—C3	−144.6 (4)	C15—Ti2—C18—C17	−77.5 (7)
C21—Ti1—C4—C3	56.3 (6)	C12—Ti2—C18—C17	−108.7 (8)
Cl2—Ti1—C4—C3	126.9 (5)	Cl4—Ti2—C18—C17	161.4 (7)
C22—Ti1—C4—C3	78.9 (8)	C14—Ti2—C18—C17	82 (2)
C2—Ti1—C4—C3	−38.9 (5)	C19—Ti2—C18—C17	−114.6 (9)
C23—Ti1—C4—C3	−14.9 (14)	C10—Ti2—C18—C17	−13.9 (11)
C5—Ti1—C4—C3	−117.1 (7)	C13—Ti2—C18—C17	−155.4 (8)
C1—Ti1—C4—C3	−80.4 (5)	C17—C18—C19—C15	1.5 (10)
C3—C4—C5—C1	−2.1 (8)	Ti2—C18—C19—C15	−64.3 (6)
Ti1—C4—C5—C1	−64.4 (5)	C17—C18—C19—Ti2	65.8 (6)
C3—C4—C5—Ti1	62.2 (5)	C16—C15—C19—C18	−0.5 (10)
C2—C1—C5—C4	−0.2 (8)	Ti2—C15—C19—C18	64.4 (6)
Si1—C1—C5—C4	−171.8 (5)	C16—C15—C19—Ti2	−64.9 (6)
Ti1—C1—C5—C4	64.7 (5)	C16—Ti2—C19—C18	−78.6 (7)
C2—C1—C5—Ti1	−64.8 (5)	Cl3—Ti2—C19—C18	4.1 (8)
Si1—C1—C5—Ti1	123.5 (6)	C11—Ti2—C19—C18	−140.5 (7)
C3—Ti1—C5—C4	−36.8 (5)	C15—Ti2—C19—C18	−115.7 (9)
C20—Ti1—C5—C4	−59.3 (7)	C12—Ti2—C19—C18	−175.6 (7)
C24—Ti1—C5—C4	−105.2 (6)	C17—Ti2—C19—C18	−37.8 (6)
Cl1—Ti1—C5—C4	154.5 (5)	Cl4—Ti2—C19—C18	91.0 (7)
C21—Ti1—C5—C4	−12.6 (9)	C14—Ti2—C19—C18	174.2 (7)
Cl2—Ti1—C5—C4	61.6 (5)	C10—Ti2—C19—C18	−125.7 (8)
C22—Ti1—C5—C4	123 (2)	C13—Ti2—C19—C18	158.9 (6)
C2—Ti1—C5—C4	−78.8 (5)	C16—Ti2—C19—C15	37.2 (6)
C23—Ti1—C5—C4	−151.8 (6)	Cl3—Ti2—C19—C15	119.8 (7)
C1—Ti1—C5—C4	−117.3 (7)	C11—Ti2—C19—C15	−24.8 (8)
C3—Ti1—C5—C1	80.5 (5)	C12—Ti2—C19—C15	−59.8 (7)
C20—Ti1—C5—C1	58.0 (7)	C18—Ti2—C19—C15	115.7 (9)
C24—Ti1—C5—C1	12.1 (7)	C17—Ti2—C19—C15	78.0 (7)
Cl1—Ti1—C5—C1	−88.2 (4)	Cl4—Ti2—C19—C15	−153.2 (7)
C21—Ti1—C5—C1	104.7 (7)	C14—Ti2—C19—C15	−70.1 (10)
Cl2—Ti1—C5—C1	179.0 (4)	C10—Ti2—C19—C15	−10.0 (10)
C22—Ti1—C5—C1	−120 (2)	C13—Ti2—C19—C15	−85.4 (7)
C2—Ti1—C5—C1	38.6 (4)	C3—Ti1—C20—C21	124.7 (7)
C23—Ti1—C5—C1	−34.5 (8)	C24—Ti1—C20—C21	−115.1 (8)
C4—Ti1—C5—C1	117.3 (7)	Cl1—Ti1—C20—C21	−86.4 (7)
O—Si2—C10—C11	−70.4 (7)	Cl2—Ti1—C20—C21	29.2 (7)
C9—Si2—C10—C11	170.8 (6)	C22—Ti1—C20—C21	−36.8 (6)
C8—Si2—C10—C11	43.2 (7)	C2—Ti1—C20—C21	160.1 (7)
O—Si2—C10—C14	95.6 (7)	C23—Ti1—C20—C21	−77.4 (6)
C9—Si2—C10—C14	−23.2 (7)	C5—Ti1—C20—C21	143.7 (5)
C8—Si2—C10—C14	−150.8 (6)	C1—Ti1—C20—C21	174.3 (6)
O—Si2—C10—Ti2	−166.1 (4)	C4—Ti1—C20—C21	113.2 (6)
C9—Si2—C10—Ti2	75.1 (5)	C3—Ti1—C20—C24	−120.2 (6)
C8—Si2—C10—Ti2	−52.5 (6)	Cl1—Ti1—C20—C24	28.8 (7)
C16—Ti2—C10—C11	−63.2 (6)	C21—Ti1—C20—C24	115.1 (8)
Cl3—Ti2—C10—C11	−166.4 (4)	Cl2—Ti1—C20—C24	144.3 (5)
C15—Ti2—C10—C11	−31.5 (5)	C22—Ti1—C20—C24	78.4 (6)
C12—Ti2—C10—C11	37.0 (4)	C2—Ti1—C20—C24	−84.8 (6)
C18—Ti2—C10—C11	−82.1 (8)	C23—Ti1—C20—C24	37.7 (5)
C17—Ti2—C10—C11	−90.5 (5)	C5—Ti1—C20—C24	−101.2 (6)
Cl4—Ti2—C10—C11	104.0 (4)	C1—Ti1—C20—C24	−70.6 (6)
C14—Ti2—C10—C11	113.2 (6)	C4—Ti1—C20—C24	−131.7 (6)
C19—Ti2—C10—C11	−25.7 (7)	C24—C20—C21—C22	−0.7 (9)
C13—Ti2—C10—C11	77.7 (5)	Ti1—C20—C21—C22	64.8 (6)
C16—Ti2—C10—C14	−176.4 (5)	C24—C20—C21—Ti1	−65.5 (6)
Cl3—Ti2—C10—C14	80.4 (4)	C3—Ti1—C21—C20	−54.6 (7)
C11—Ti2—C10—C14	−113.2 (6)	C24—Ti1—C21—C20	37.8 (6)
C15—Ti2—C10—C14	−144.7 (5)	Cl1—Ti1—C21—C20	120.5 (6)
C12—Ti2—C10—C14	−76.3 (5)	Cl2—Ti1—C21—C20	−152.2 (6)
C18—Ti2—C10—C14	164.6 (6)	C22—Ti1—C21—C20	116.7 (9)
C17—Ti2—C10—C14	156.2 (5)	C2—Ti1—C21—C20	−20.8 (7)
Cl4—Ti2—C10—C14	−9.3 (5)	C23—Ti1—C21—C20	79.4 (6)
C19—Ti2—C10—C14	−139.0 (6)	C5—Ti1—C21—C20	−75.0 (9)
C13—Ti2—C10—C14	−35.6 (4)	C1—Ti1—C21—C20	−9.0 (9)
C16—Ti2—C10—Si2	58.8 (6)	C4—Ti1—C21—C20	−82.9 (7)
Cl3—Ti2—C10—Si2	−44.4 (4)	C3—Ti1—C21—C22	−171.4 (6)
C11—Ti2—C10—Si2	122.0 (7)	C20—Ti1—C21—C22	−116.7 (9)
C15—Ti2—C10—Si2	90.5 (5)	C24—Ti1—C21—C22	−78.9 (6)
C12—Ti2—C10—Si2	158.9 (6)	Cl1—Ti1—C21—C22	3.8 (7)
C18—Ti2—C10—Si2	39.9 (9)	Cl2—Ti1—C21—C22	91.1 (6)
C17—Ti2—C10—Si2	31.4 (6)	C2—Ti1—C21—C22	−137.5 (6)
Cl4—Ti2—C10—Si2	−134.1 (4)	C23—Ti1—C21—C22	−37.3 (5)
C14—Ti2—C10—Si2	−124.8 (7)	C5—Ti1—C21—C22	168.3 (6)
C19—Ti2—C10—Si2	96.2 (6)	C1—Ti1—C21—C22	−125.7 (7)
C13—Ti2—C10—Si2	−160.4 (6)	C4—Ti1—C21—C22	160.3 (6)
C14—C10—C11—C12	0.6 (8)	C20—C21—C22—C23	1.6 (9)
Si2—C10—C11—C12	169.2 (5)	Ti1—C21—C22—C23	66.0 (6)
Ti2—C10—C11—C12	−64.2 (5)	C20—C21—C22—Ti1	−64.4 (6)
C14—C10—C11—Ti2	64.8 (5)	C3—Ti1—C22—C23	−103.5 (7)
Si2—C10—C11—Ti2	−126.7 (5)	C20—Ti1—C22—C23	−78.7 (6)
C16—Ti2—C11—C10	114.3 (5)	C24—Ti1—C22—C23	−37.4 (6)
Cl3—Ti2—C11—C10	15.5 (5)	Cl1—Ti1—C22—C23	68.2 (6)
C15—Ti2—C11—C10	148.7 (5)	C21—Ti1—C22—C23	−115.0 (8)
C12—Ti2—C11—C10	−117.6 (6)	Cl2—Ti1—C22—C23	161.5 (6)
C18—Ti2—C11—C10	134.8 (6)	C2—Ti1—C22—C23	−56.1 (7)
C17—Ti2—C11—C10	103.5 (5)	C5—Ti1—C22—C23	99 (2)
Cl4—Ti2—C11—C10	−105.5 (4)	C1—Ti1—C22—C23	−6.9 (9)
C14—Ti2—C11—C10	−39.0 (4)	C4—Ti1—C22—C23	−151.4 (7)
C19—Ti2—C11—C10	162.6 (5)	C3—Ti1—C22—C21	11.5 (8)
C13—Ti2—C11—C10	−79.0 (5)	C20—Ti1—C22—C21	36.3 (5)
C16—Ti2—C11—C12	−128.0 (5)	C24—Ti1—C22—C21	77.5 (6)
Cl3—Ti2—C11—C12	133.2 (4)	Cl1—Ti1—C22—C21	−176.9 (6)
C15—Ti2—C11—C12	−93.6 (5)	Cl2—Ti1—C22—C21	−83.6 (6)
C18—Ti2—C11—C12	−107.6 (6)	C2—Ti1—C22—C21	58.9 (8)
C17—Ti2—C11—C12	−138.9 (5)	C23—Ti1—C22—C21	115.0 (8)
Cl4—Ti2—C11—C12	12.2 (5)	C5—Ti1—C22—C21	−145.7 (19)
C14—Ti2—C11—C12	78.7 (5)	C1—Ti1—C22—C21	108.1 (8)
C19—Ti2—C11—C12	−79.7 (5)	C4—Ti1—C22—C21	−36.5 (9)
C10—Ti2—C11—C12	117.6 (6)	C21—C22—C23—C24	−1.8 (9)
C13—Ti2—C11—C12	38.6 (4)	Ti1—C22—C23—C24	63.6 (6)
C10—C11—C12—C13	−2.4 (8)	C21—C22—C23—Ti1	−65.4 (6)
Ti2—C11—C12—C13	−67.7 (5)	C3—Ti1—C23—C22	107.3 (6)
C10—C11—C12—Ti2	65.4 (5)	C20—Ti1—C23—C22	78.2 (6)
C16—Ti2—C12—C13	163.7 (5)	C24—Ti1—C23—C22	115.8 (8)
Cl3—Ti2—C12—C13	40.8 (6)	Cl1—Ti1—C23—C22	−108.4 (6)
C11—Ti2—C12—C13	112.2 (6)	C21—Ti1—C23—C22	37.6 (5)
C15—Ti2—C12—C13	−168.9 (6)	Cl2—Ti1—C23—C22	−20.2 (6)
C18—Ti2—C12—C13	−143.0 (6)	C2—Ti1—C23—C22	139.4 (6)
C17—Ti2—C12—C13	170.4 (6)	C5—Ti1—C23—C22	−163.1 (5)
Cl4—Ti2—C12—C13	−58.4 (5)	C1—Ti1—C23—C22	176.1 (5)
C14—Ti2—C12—C13	35.1 (4)	C4—Ti1—C23—C22	118.3 (13)
C19—Ti2—C12—C13	−139.7 (5)	C3—Ti1—C23—C24	−8.5 (8)
C10—Ti2—C12—C13	76.5 (5)	C20—Ti1—C23—C24	−37.6 (5)
C16—Ti2—C12—C11	51.5 (5)	Cl1—Ti1—C23—C24	135.8 (6)
Cl3—Ti2—C12—C11	−71.4 (5)	C21—Ti1—C23—C24	−78.2 (6)
C15—Ti2—C12—C11	78.9 (5)	Cl2—Ti1—C23—C24	−136.0 (6)
C18—Ti2—C12—C11	104.8 (6)	C22—Ti1—C23—C24	−115.8 (8)
C17—Ti2—C12—C11	58.2 (7)	C2—Ti1—C23—C24	23.6 (7)
Cl4—Ti2—C12—C11	−170.6 (4)	C5—Ti1—C23—C24	81.0 (8)
C14—Ti2—C12—C11	−77.2 (5)	C1—Ti1—C23—C24	60.3 (7)
C19—Ti2—C12—C11	108.1 (5)	C4—Ti1—C23—C24	2.5 (16)
C10—Ti2—C12—C11	−35.8 (4)	C21—C20—C24—C23	−0.4 (10)
C13—Ti2—C12—C11	−112.2 (6)	Ti1—C20—C24—C23	−66.4 (6)
C11—C12—C13—C14	3.2 (8)	C21—C20—C24—Ti1	66.0 (6)
Ti2—C12—C13—C14	−62.9 (5)	C22—C23—C24—C20	1.3 (9)
C11—C12—C13—Ti2	66.1 (5)	Ti1—C23—C24—C20	65.6 (6)
C16—Ti2—C13—C14	96.4 (6)	C22—C23—C24—Ti1	−64.2 (6)
Cl3—Ti2—C13—C14	−33.7 (5)	C3—Ti1—C24—C20	58.7 (6)
C11—Ti2—C13—C14	78.5 (5)	Cl1—Ti1—C24—C20	−159.2 (5)
C15—Ti2—C13—C14	130.5 (5)	C21—Ti1—C24—C20	−37.1 (5)
C12—Ti2—C13—C14	118.4 (7)	Cl2—Ti1—C24—C20	−51.1 (7)
C18—Ti2—C13—C14	−166.4 (6)	C22—Ti1—C24—C20	−78.1 (6)
C17—Ti2—C13—C14	88.3 (15)	C2—Ti1—C24—C20	87.9 (6)
Cl4—Ti2—C13—C14	−122.2 (5)	C23—Ti1—C24—C20	−114.9 (8)
C19—Ti2—C13—C14	168.0 (5)	C5—Ti1—C24—C20	110.2 (6)
C10—Ti2—C13—C14	37.3 (4)	C1—Ti1—C24—C20	117.0 (6)
C16—Ti2—C13—C12	−22.0 (7)	C4—Ti1—C24—C20	66.0 (7)
Cl3—Ti2—C13—C12	−152.2 (4)	C3—Ti1—C24—C23	173.5 (6)
C11—Ti2—C13—C12	−39.9 (4)	C20—Ti1—C24—C23	114.9 (8)
C15—Ti2—C13—C12	12.0 (6)	Cl1—Ti1—C24—C23	−44.4 (6)
C18—Ti2—C13—C12	75.1 (8)	C21—Ti1—C24—C23	77.8 (6)
C17—Ti2—C13—C12	−30.2 (16)	Cl2—Ti1—C24—C23	63.8 (8)
Cl4—Ti2—C13—C12	119.4 (5)	C22—Ti1—C24—C23	36.7 (5)
C14—Ti2—C13—C12	−118.4 (7)	C2—Ti1—C24—C23	−157.3 (7)
C19—Ti2—C13—C12	49.5 (6)	C5—Ti1—C24—C23	−135.0 (6)
C10—Ti2—C13—C12	−81.1 (5)	C1—Ti1—C24—C23	−128.1 (6)
C12—C13—C14—C10	−3.0 (8)	C4—Ti1—C24—C23	−179.1 (5)

(II) [m-1,2(h⁵)-1,3-dicyclopentadienyl-1,1,3,3-tetramethyldisiloxanyl]bis [dichloro(h⁵-pentamethylcyclopentadienyl)titanium]

Crystal data

[TiCl2(C10H15)(C7H10Si)]2O	F(000) = 1608
Mr = 768.52	Dx = 1.313 Mg m^−3
Monoclinic, P21/n	Mo Kα radiation, λ = 0.71073 Å
a = 8.1319 (1) Å	Cell parameters from 8192 reflections
b = 22.2503 (3) Å	θ = 2–25°
c = 21.6970 (3) Å	µ = 0.77 mm^−1
β = 97.97 (1)°	T = 223 K
V = 3887.84 (9) Å^3	Plate, brown
Z = 4	0.38 × 0.20 × 0.10 mm

Data collection

Bruker CCD area detector diffractometer	6849 independent reflections
Radiation source: normal-focus sealed tube	4852 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.11
ϕ and ω scans	θmax = 25°, θmin = 1.3°
Absorption correction: empirical (using intensity measurements) (SADABS; Blessing, 1995)	h = −9→9
Tmin = 0.76, Tmax = 0.93	k = −26→26
62999 measured reflections	l = −25→25

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.051	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.122	H-atom parameters constrained
S = 1.02	w = 1/[σ^2(Fo^2) + (0.0451P)^2 + 6.1721P] where P = (Fo^2 + 2Fc^2)/3
6849 reflections	(Δ/σ)max < 0.001
388 parameters	Δρmax = 0.72 e Å^−3
0 restraints	Δρmin = −0.51 e Å^−3

Special details

Experimental. Data were collected by the double-pass method using the CCD area detector system. The first 50 frames of data were re-collected at the end of data collection and no crystal decay was observed for either compound.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

The structures were solved by the Patterson method and refined successfully in the monoclinic space groups P2₁/c and P2₁/n. Full matrix least-squares refinement was carried out by minimizing w(F_o²-F_c²)². The non-H atoms were refined anisotropically to convergence. H atoms were treated using appropriate riding models [SHELXTL-Plus command AFIX = m3 (Sheldrick, 1999)], where the atomic position of the H atom rides on the coordinates of the non-H atom to which it is attached and the displacement parameters are fixed at 1.2 times those of the parent atom.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ti1	0.09992 (8)	0.23619 (3)	0.56643 (3)	0.02936 (17)
Ti2	0.24721 (8)	−0.02970 (3)	0.22787 (3)	0.02984 (17)
Cl1	0.16455 (17)	0.24427 (5)	0.46548 (5)	0.0614 (3)
Cl2	0.37801 (13)	0.22898 (6)	0.61567 (6)	0.0628 (3)
Cl3	−0.00893 (12)	−0.07319 (5)	0.24167 (5)	0.0500 (3)
Cl4	0.13230 (18)	0.06215 (5)	0.19172 (5)	0.0646 (4)
Si1	0.23902 (14)	0.08699 (5)	0.49426 (5)	0.0378 (3)
Si2	0.11684 (16)	0.08288 (5)	0.34899 (5)	0.0451 (3)
O	0.1351 (4)	0.08264 (13)	0.42481 (12)	0.0513 (7)
C1	0.0997 (4)	0.12825 (15)	0.54177 (17)	0.0340 (8)
C2	−0.0584 (5)	0.15257 (17)	0.5210 (2)	0.0428 (10)
H2	−0.1144	0.1510	0.4776	0.051*
C3	−0.1311 (5)	0.17388 (17)	0.5715 (2)	0.0454 (10)
H3	−0.2475	0.1873	0.5702	0.054*
C4	−0.0169 (5)	0.16387 (17)	0.6255 (2)	0.0474 (11)
H4	−0.0396	0.1690	0.6688	0.057*
C5	0.1211 (5)	0.13468 (16)	0.60723 (18)	0.0410 (9)
H5	0.2163	0.1188	0.6360	0.049*
C6	0.2655 (6)	0.00979 (19)	0.5272 (2)	0.0604 (13)
H6A	0.3372	−0.0133	0.5038	0.091*
H6B	0.1580	−0.0097	0.5244	0.091*
H6C	0.3151	0.0121	0.5704	0.091*
C7	0.4443 (5)	0.1224 (2)	0.4932 (3)	0.0643 (14)
H7A	0.5086	0.0984	0.4677	0.096*
H7B	0.5024	0.1246	0.5353	0.096*
H7C	0.4295	0.1625	0.4759	0.096*
C8	−0.1016 (6)	0.0623 (2)	0.3222 (2)	0.0623 (13)
H8A	−0.1743	0.0934	0.3343	0.093*
H8B	−0.1269	0.0244	0.3410	0.093*
H8C	−0.1183	0.0582	0.2773	0.093*
C9	0.1717 (8)	0.1581 (2)	0.3219 (2)	0.087 (2)
H9A	0.0932	0.1875	0.3334	0.131*
H9B	0.1678	0.1576	0.2771	0.131*
H9C	0.2828	0.1686	0.3412	0.131*
C10	0.2673 (5)	0.02466 (16)	0.32742 (16)	0.0361 (9)
C11	0.4158 (5)	0.0329 (2)	0.30025 (18)	0.0481 (11)
H11	0.4611	0.0724	0.2900	0.058*
C12	0.4979 (5)	−0.0221 (2)	0.29673 (19)	0.0501 (11)
H12	0.6112	−0.0279	0.2860	0.060*
C13	0.3986 (5)	−0.0665 (2)	0.32073 (18)	0.0472 (11)
H13	0.4307	−0.1090	0.3292	0.057*
C14	0.2627 (5)	−0.03741 (17)	0.34053 (16)	0.0384 (9)
H14	0.1784	−0.0572	0.3625	0.046*
C15	0.2905 (5)	−0.02847 (17)	0.11831 (17)	0.0370 (9)
C16	0.1763 (5)	−0.07428 (18)	0.12539 (17)	0.0389 (9)
C17	0.2602 (5)	−0.11872 (17)	0.16513 (18)	0.0408 (10)
C18	0.4253 (5)	−0.09906 (17)	0.18274 (18)	0.0397 (9)
C19	0.4415 (4)	−0.04183 (17)	0.15572 (17)	0.0359 (9)
C20	0.1447 (6)	0.34273 (18)	0.5823 (2)	0.0559 (13)
C21	0.0982 (5)	0.3183 (2)	0.6381 (2)	0.0525 (12)
C22	−0.0682 (5)	0.29836 (17)	0.62398 (18)	0.0390 (9)
C23	−0.1180 (5)	0.30941 (17)	0.56017 (19)	0.0413 (10)
C24	0.0110 (6)	0.33824 (18)	0.5357 (2)	0.0510 (11)
C25	−0.2910 (6)	0.3024 (2)	0.5251 (2)	0.0682 (14)
H25A	−0.3548	0.3385	0.5300	0.102*
H25B	−0.3450	0.2682	0.5414	0.102*
H25C	−0.2842	0.2961	0.4813	0.102*
C26	−0.1821 (6)	0.2808 (2)	0.6702 (2)	0.0609 (13)
H26A	−0.2319	0.3166	0.6851	0.091*
H26B	−0.1189	0.2599	0.7049	0.091*
H26C	−0.2687	0.2545	0.6501	0.091*
C27	0.1952 (7)	0.3200 (3)	0.7022 (3)	0.100 (2)
H27A	0.1743	0.3577	0.7221	0.150*
H27B	0.3128	0.3165	0.6992	0.150*
H27C	0.1612	0.2869	0.7266	0.150*
C28	0.3088 (7)	0.3733 (2)	0.5762 (3)	0.100 (2)
H28A	0.2999	0.4160	0.5845	0.150*
H28B	0.3353	0.3676	0.5344	0.150*
H28C	0.3959	0.3560	0.6060	0.150*
C29	−0.0034 (8)	0.3663 (2)	0.4714 (3)	0.087 (2)
H29A	−0.0418	0.4075	0.4733	0.131*
H29B	−0.0819	0.3435	0.4428	0.131*
H29C	0.1044	0.3659	0.4571	0.131*
C30	0.2629 (6)	0.0230 (2)	0.0728 (2)	0.0615 (13)
H30A	0.2905	0.0103	0.0327	0.092*
H30B	0.3330	0.0566	0.0881	0.092*
H30C	0.1474	0.0353	0.0683	0.092*
C31	0.0027 (5)	−0.0781 (3)	0.0914 (2)	0.0687 (15)
H31A	0.0044	−0.0976	0.0516	0.103*
H31B	−0.0427	−0.0379	0.0849	0.103*
H31C	−0.0659	−0.1012	0.1160	0.103*
C32	0.1937 (7)	−0.17945 (19)	0.1789 (3)	0.0712 (15)
H32A	0.2143	−0.2076	0.1467	0.107*
H32B	0.0751	−0.1766	0.1801	0.107*
H32C	0.2486	−0.1934	0.2189	0.107*
C33	0.5640 (6)	−0.1379 (2)	0.2145 (2)	0.0600 (13)
H33A	0.6121	−0.1609	0.1834	0.090*
H33B	0.5203	−0.1652	0.2431	0.090*
H33C	0.6487	−0.1126	0.2373	0.090*
C34	0.5985 (5)	−0.0058 (2)	0.1549 (2)	0.0584 (12)
H34A	0.6553	−0.0195	0.1211	0.088*
H34B	0.6704	−0.0111	0.1941	0.088*
H34C	0.5707	0.0364	0.1491	0.088*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ti1	0.0277 (3)	0.0269 (3)	0.0346 (4)	−0.0016 (3)	0.0080 (3)	−0.0030 (3)
Ti2	0.0316 (3)	0.0288 (3)	0.0286 (4)	0.0009 (3)	0.0020 (3)	0.0002 (3)
Cl1	0.1001 (9)	0.0443 (6)	0.0483 (7)	0.0088 (6)	0.0396 (6)	0.0034 (5)
Cl2	0.0336 (6)	0.0637 (7)	0.0877 (9)	−0.0020 (5)	−0.0039 (6)	−0.0093 (7)
Cl3	0.0349 (5)	0.0729 (8)	0.0427 (6)	−0.0091 (5)	0.0070 (4)	−0.0054 (5)
Cl4	0.1140 (10)	0.0410 (6)	0.0389 (6)	0.0304 (6)	0.0109 (6)	0.0043 (5)
Si1	0.0444 (6)	0.0309 (6)	0.0388 (6)	0.0026 (5)	0.0078 (5)	−0.0049 (5)
Si2	0.0692 (8)	0.0336 (6)	0.0340 (6)	−0.0006 (6)	0.0124 (6)	−0.0021 (5)
O	0.073 (2)	0.0480 (17)	0.0329 (16)	−0.0034 (15)	0.0091 (14)	−0.0074 (13)
C1	0.037 (2)	0.0240 (19)	0.040 (2)	−0.0014 (16)	0.0038 (17)	−0.0041 (16)
C2	0.037 (2)	0.034 (2)	0.056 (3)	−0.0100 (18)	−0.0026 (19)	−0.0104 (19)
C3	0.033 (2)	0.033 (2)	0.072 (3)	−0.0104 (17)	0.015 (2)	−0.004 (2)
C4	0.066 (3)	0.033 (2)	0.049 (3)	−0.005 (2)	0.027 (2)	0.0013 (19)
C5	0.053 (2)	0.030 (2)	0.040 (2)	0.0025 (18)	0.0068 (19)	0.0037 (17)
C6	0.074 (3)	0.044 (3)	0.064 (3)	0.017 (2)	0.010 (3)	0.001 (2)
C7	0.053 (3)	0.047 (3)	0.097 (4)	0.001 (2)	0.024 (3)	−0.011 (3)
C8	0.066 (3)	0.077 (3)	0.043 (3)	0.017 (3)	0.005 (2)	−0.008 (2)
C9	0.170 (6)	0.041 (3)	0.060 (3)	−0.013 (3)	0.048 (4)	−0.005 (2)
C10	0.046 (2)	0.036 (2)	0.026 (2)	−0.0096 (18)	0.0009 (17)	−0.0043 (16)
C11	0.050 (3)	0.057 (3)	0.036 (2)	−0.024 (2)	0.0035 (19)	−0.010 (2)
C12	0.032 (2)	0.074 (3)	0.040 (2)	−0.002 (2)	−0.0067 (18)	−0.011 (2)
C13	0.052 (3)	0.051 (3)	0.033 (2)	0.011 (2)	−0.0087 (19)	0.0044 (19)
C14	0.048 (2)	0.040 (2)	0.025 (2)	−0.0042 (19)	−0.0011 (17)	0.0009 (17)
C15	0.045 (2)	0.036 (2)	0.031 (2)	0.0046 (18)	0.0118 (18)	−0.0012 (17)
C16	0.041 (2)	0.046 (2)	0.030 (2)	0.0000 (19)	0.0054 (17)	−0.0109 (18)
C17	0.051 (2)	0.030 (2)	0.045 (2)	−0.0051 (18)	0.018 (2)	−0.0083 (18)
C18	0.044 (2)	0.037 (2)	0.040 (2)	0.0107 (18)	0.0117 (18)	0.0019 (18)
C19	0.034 (2)	0.038 (2)	0.037 (2)	−0.0009 (17)	0.0107 (17)	−0.0049 (17)
C20	0.059 (3)	0.028 (2)	0.090 (4)	−0.009 (2)	0.043 (3)	−0.020 (2)
C21	0.054 (3)	0.047 (3)	0.056 (3)	0.006 (2)	0.006 (2)	−0.028 (2)
C22	0.045 (2)	0.034 (2)	0.042 (2)	0.0027 (18)	0.0182 (19)	−0.0029 (18)
C23	0.042 (2)	0.033 (2)	0.052 (3)	0.0129 (18)	0.0197 (19)	0.0040 (19)
C24	0.064 (3)	0.032 (2)	0.063 (3)	0.009 (2)	0.031 (3)	0.007 (2)
C25	0.054 (3)	0.077 (4)	0.071 (3)	0.025 (3)	0.001 (2)	0.020 (3)
C26	0.077 (3)	0.054 (3)	0.060 (3)	0.007 (2)	0.040 (3)	−0.002 (2)
C27	0.088 (4)	0.130 (6)	0.076 (4)	0.009 (4)	−0.008 (3)	−0.062 (4)
C28	0.072 (4)	0.049 (3)	0.191 (7)	−0.024 (3)	0.065 (4)	−0.031 (4)
C29	0.125 (5)	0.059 (3)	0.093 (4)	0.034 (3)	0.069 (4)	0.036 (3)
C30	0.084 (3)	0.064 (3)	0.040 (3)	0.019 (3)	0.021 (2)	0.017 (2)
C31	0.048 (3)	0.109 (4)	0.047 (3)	−0.011 (3)	0.000 (2)	−0.028 (3)
C32	0.088 (4)	0.033 (2)	0.101 (4)	−0.013 (2)	0.045 (3)	−0.007 (3)
C33	0.061 (3)	0.057 (3)	0.064 (3)	0.026 (2)	0.015 (2)	0.011 (2)
C34	0.045 (3)	0.066 (3)	0.066 (3)	−0.009 (2)	0.018 (2)	0.003 (3)

Geometric parameters (Å, º)

Ti1—Cl1	2.3291 (12)	Si2—C10	1.885 (4)
Ti1—C4	2.339 (4)	C1—C2	1.410 (5)
Ti1—C3	2.349 (4)	C1—C5	1.414 (5)
Ti1—Cl2	2.3687 (12)	C2—C3	1.397 (6)
Ti1—C2	2.395 (4)	C3—C4	1.408 (6)
Ti1—C23	2.397 (4)	C4—C5	1.401 (5)
Ti1—C21	2.399 (4)	C10—C14	1.412 (5)
Ti1—C22	2.411 (4)	C10—C11	1.427 (5)
Ti1—C20	2.416 (4)	C11—C12	1.401 (6)
Ti1—C5	2.423 (4)	C12—C13	1.420 (6)
Ti1—C24	2.447 (4)	C13—C14	1.399 (5)
Ti1—C1	2.461 (3)	C15—C16	1.402 (5)
Ti2—Cl4	2.3369 (12)	C15—C19	1.406 (5)
Ti2—Cl3	2.3532 (12)	C15—C30	1.509 (5)
Ti2—C13	2.358 (4)	C16—C17	1.422 (5)
Ti2—C12	2.360 (4)	C16—C31	1.501 (6)
Ti2—C11	2.385 (4)	C17—C18	1.414 (5)
Ti2—C19	2.389 (4)	C17—C32	1.501 (5)
Ti2—C17	2.414 (4)	C18—C19	1.416 (5)
Ti2—C18	2.415 (4)	C18—C33	1.509 (5)
Ti2—C16	2.430 (4)	C19—C34	1.509 (5)
Ti2—C14	2.436 (4)	C20—C24	1.382 (7)
Ti2—C15	2.451 (4)	C20—C21	1.425 (6)
Ti2—C10	2.461 (4)	C20—C28	1.520 (6)
Si1—O	1.625 (3)	C21—C22	1.416 (6)
Si1—C7	1.849 (4)	C21—C27	1.501 (7)
Si1—C6	1.861 (4)	C22—C23	1.409 (6)
Si1—C1	1.874 (4)	C22—C26	1.507 (5)
Si2—O	1.631 (3)	C23—C24	1.396 (6)
Si2—C8	1.848 (5)	C23—C25	1.512 (6)
Si2—C9	1.848 (5)	C24—C29	1.518 (6)
Cl1—Ti1—C4	136.89 (11)	Cl4—Ti2—C10	80.77 (9)
Cl1—Ti1—C3	112.05 (12)	Cl3—Ti2—C10	92.45 (9)
C4—Ti1—C3	34.96 (15)	C13—Ti2—C10	57.14 (14)
Cl1—Ti1—Cl2	95.94 (5)	C12—Ti2—C10	57.51 (14)
C4—Ti1—Cl2	98.12 (12)	C11—Ti2—C10	34.20 (13)
C3—Ti1—Cl2	131.18 (12)	C19—Ti2—C10	131.39 (13)
Cl1—Ti1—C2	81.48 (11)	C17—Ti2—C10	153.55 (13)
C4—Ti1—C2	56.97 (15)	C18—Ti2—C10	134.37 (13)
C3—Ti1—C2	34.22 (14)	C16—Ti2—C10	169.15 (13)
Cl2—Ti1—C2	123.90 (10)	C14—Ti2—C10	33.50 (12)
Cl1—Ti1—C23	98.96 (10)	C15—Ti2—C10	147.64 (13)
C4—Ti1—C23	98.35 (14)	O—Si1—C7	111.6 (2)
C3—Ti1—C23	79.28 (14)	O—Si1—C6	108.56 (19)
Cl2—Ti1—C23	136.36 (11)	C7—Si1—C6	109.9 (2)
C2—Ti1—C23	98.84 (14)	O—Si1—C1	105.25 (16)
Cl1—Ti1—C21	124.94 (13)	C7—Si1—C1	114.48 (19)
C4—Ti1—C21	97.43 (16)	C6—Si1—C1	106.71 (19)
C3—Ti1—C21	110.02 (15)	O—Si2—C8	105.38 (19)
Cl2—Ti1—C21	81.40 (11)	O—Si2—C9	109.3 (2)
C2—Ti1—C21	143.75 (15)	C8—Si2—C9	112.9 (3)
C23—Ti1—C21	56.54 (15)	O—Si2—C10	106.07 (16)
Cl1—Ti1—C22	131.35 (10)	C8—Si2—C10	112.35 (19)
C4—Ti1—C22	78.96 (13)	C9—Si2—C10	110.5 (2)
C3—Ti1—C22	78.47 (14)	Si1—O—Si2	153.9 (2)
Cl2—Ti1—C22	112.31 (11)	C2—C1—C5	105.1 (3)
C2—Ti1—C22	110.34 (14)	C2—C1—Si1	127.3 (3)
C23—Ti1—C22	34.08 (13)	C5—C1—Si1	127.1 (3)
C21—Ti1—C22	34.23 (14)	C2—C1—Ti1	70.6 (2)
Cl1—Ti1—C20	90.51 (12)	C5—C1—Ti1	71.7 (2)
C4—Ti1—C20	131.44 (15)	Si1—C1—Ti1	127.99 (18)
C3—Ti1—C20	132.71 (14)	C3—C2—C1	110.3 (4)
Cl2—Ti1—C20	83.49 (13)	C3—C2—Ti1	71.1 (2)
C2—Ti1—C20	151.96 (17)	C1—C2—Ti1	75.7 (2)
C23—Ti1—C20	55.73 (15)	C2—C3—C4	107.2 (4)
C21—Ti1—C20	34.44 (16)	C2—C3—Ti1	74.7 (2)
C22—Ti1—C20	56.53 (13)	C4—C3—Ti1	72.1 (2)
Cl1—Ti1—C5	113.68 (10)	C5—C4—C3	107.4 (4)
C4—Ti1—C5	34.15 (13)	C5—C4—Ti1	76.2 (2)
C3—Ti1—C5	56.63 (14)	C3—C4—Ti1	72.9 (2)
Cl2—Ti1—C5	75.93 (10)	C4—C5—C1	109.8 (4)
C2—Ti1—C5	55.47 (14)	C4—C5—Ti1	69.6 (2)
C23—Ti1—C5	131.96 (14)	C1—C5—Ti1	74.6 (2)
C21—Ti1—C5	118.64 (15)	C14—C10—C11	104.9 (4)
C22—Ti1—C5	111.24 (13)	C14—C10—Si2	125.9 (3)
C20—Ti1—C5	149.42 (17)	C11—C10—Si2	129.1 (3)
Cl1—Ti1—C24	76.64 (11)	C14—C10—Ti2	72.3 (2)
C4—Ti1—C24	131.32 (14)	C11—C10—Ti2	70.0 (2)
C3—Ti1—C24	110.62 (15)	Si2—C10—Ti2	126.09 (18)
Cl2—Ti1—C24	114.42 (13)	C12—C11—C10	110.3 (4)
C2—Ti1—C24	119.15 (16)	C12—C11—Ti2	71.9 (2)
C23—Ti1—C24	33.47 (13)	C10—C11—Ti2	75.8 (2)
C21—Ti1—C24	56.10 (16)	C11—C12—C13	106.8 (4)
C22—Ti1—C24	56.05 (13)	C11—C12—Ti2	73.8 (2)
C20—Ti1—C24	33.00 (16)	C13—C12—Ti2	72.4 (2)
C5—Ti1—C24	165.38 (14)	C14—C13—C12	107.7 (4)
Cl1—Ti1—C1	82.20 (9)	C14—C13—Ti2	76.1 (2)
C4—Ti1—C1	57.29 (13)	C12—C13—Ti2	72.6 (2)
C3—Ti1—C1	57.16 (13)	C13—C14—C10	110.3 (4)
Cl2—Ti1—C1	90.21 (9)	C13—C14—Ti2	70.0 (2)
C2—Ti1—C1	33.72 (12)	C10—C14—Ti2	74.2 (2)
C23—Ti1—C1	132.29 (13)	C16—C15—C19	108.8 (3)
C21—Ti1—C1	152.11 (15)	C16—C15—C30	125.7 (4)
C22—Ti1—C1	133.57 (13)	C19—C15—C30	125.2 (4)
C20—Ti1—C1	169.84 (13)	C16—C15—Ti2	72.5 (2)
C5—Ti1—C1	33.65 (12)	C19—C15—Ti2	70.7 (2)
C24—Ti1—C1	148.78 (15)	C30—C15—Ti2	127.9 (3)
Cl4—Ti2—Cl3	94.74 (5)	C15—C16—C17	107.6 (3)
Cl4—Ti2—C13	136.71 (11)	C15—C16—C31	125.4 (4)
Cl3—Ti2—C13	96.59 (11)	C17—C16—C31	126.7 (4)
Cl4—Ti2—C12	114.83 (12)	C15—C16—Ti2	74.1 (2)
Cl3—Ti2—C12	130.60 (12)	C17—C16—Ti2	72.3 (2)
C13—Ti2—C12	35.03 (15)	C31—C16—Ti2	124.0 (3)
Cl4—Ti2—C11	82.94 (12)	C18—C17—C16	107.8 (3)
Cl3—Ti2—C11	126.47 (10)	C18—C17—C32	125.4 (4)
C13—Ti2—C11	57.03 (15)	C16—C17—C32	126.2 (4)
C12—Ti2—C11	34.34 (15)	C18—C17—Ti2	73.0 (2)
Cl4—Ti2—C19	98.56 (10)	C16—C17—Ti2	73.5 (2)
Cl3—Ti2—C19	135.60 (10)	C32—C17—Ti2	125.5 (3)
C13—Ti2—C19	101.91 (14)	C17—C18—C19	107.8 (3)
C12—Ti2—C19	80.28 (14)	C17—C18—C33	124.6 (4)
C11—Ti2—C19	97.21 (13)	C19—C18—C33	126.7 (4)
Cl4—Ti2—C17	125.10 (11)	C17—C18—Ti2	72.9 (2)
Cl3—Ti2—C17	80.96 (10)	C19—C18—Ti2	71.8 (2)
C13—Ti2—C17	97.95 (15)	C33—C18—Ti2	129.3 (3)
C12—Ti2—C17	108.31 (15)	C15—C19—C18	107.8 (3)
C11—Ti2—C17	141.66 (15)	C15—C19—C34	123.6 (4)
C19—Ti2—C17	56.85 (13)	C18—C19—C34	127.6 (4)
Cl4—Ti2—C18	131.08 (10)	C15—C19—Ti2	75.6 (2)
Cl3—Ti2—C18	112.34 (10)	C18—C19—Ti2	73.9 (2)
C13—Ti2—C18	81.54 (14)	C34—C19—Ti2	125.8 (3)
C12—Ti2—C18	77.78 (15)	C24—C20—C21	108.6 (4)
C11—Ti2—C18	108.52 (15)	C24—C20—C28	125.5 (5)
C19—Ti2—C18	34.27 (13)	C21—C20—C28	125.7 (5)
C17—Ti2—C18	34.05 (13)	C24—C20—Ti1	74.8 (2)
Cl4—Ti2—C16	90.96 (10)	C21—C20—Ti1	72.2 (2)
Cl3—Ti2—C16	81.18 (10)	C28—C20—Ti1	123.0 (3)
C13—Ti2—C16	132.04 (14)	C22—C21—C20	107.1 (4)
C12—Ti2—C16	133.07 (14)	C22—C21—C27	124.9 (5)
C11—Ti2—C16	151.97 (14)	C20—C21—C27	127.6 (5)
C19—Ti2—C16	56.55 (13)	C22—C21—Ti1	73.3 (2)
C17—Ti2—C16	34.15 (13)	C20—C21—Ti1	73.4 (2)
C18—Ti2—C16	56.48 (13)	C27—C21—Ti1	124.7 (3)
Cl4—Ti2—C14	111.16 (10)	C23—C22—C21	107.1 (4)
Cl3—Ti2—C14	76.52 (10)	C23—C22—C26	125.4 (4)
C13—Ti2—C14	33.88 (13)	C21—C22—C26	126.5 (4)
C12—Ti2—C14	56.63 (14)	C23—C22—Ti1	72.4 (2)
C11—Ti2—C14	55.63 (13)	C21—C22—Ti1	72.4 (2)
C19—Ti2—C14	134.65 (13)	C26—C22—Ti1	129.8 (3)
C17—Ti2—C14	120.51 (13)	C24—C23—C22	109.0 (4)
C18—Ti2—C14	114.29 (13)	C24—C23—C25	123.5 (4)
C16—Ti2—C14	149.54 (13)	C22—C23—C25	126.7 (4)
Cl4—Ti2—C15	76.66 (9)	C24—C23—Ti1	75.2 (2)
Cl3—Ti2—C15	112.14 (10)	C22—C23—Ti1	73.5 (2)
C13—Ti2—C15	134.78 (14)	C25—C23—Ti1	126.0 (3)
C12—Ti2—C15	112.67 (14)	C20—C24—C23	108.2 (4)
C11—Ti2—C15	119.03 (14)	C20—C24—C29	126.5 (4)
C19—Ti2—C15	33.75 (12)	C23—C24—C29	124.9 (5)
C17—Ti2—C15	55.87 (13)	C20—C24—Ti1	72.2 (2)
C18—Ti2—C15	55.87 (13)	C23—C24—Ti1	71.3 (2)
C16—Ti2—C15	33.38 (13)	C29—C24—Ti1	127.9 (3)
C14—Ti2—C15	168.37 (13)
C7—Si1—O—Si2	18.4 (5)	C11—Ti2—C16—C17	101.8 (4)
C6—Si1—O—Si2	−103.0 (5)	C19—Ti2—C16—C17	78.8 (2)
C1—Si1—O—Si2	143.1 (4)	C18—Ti2—C16—C17	37.5 (2)
C8—Si2—O—Si1	173.2 (4)	C14—Ti2—C16—C17	−43.7 (4)
C9—Si2—O—Si1	−65.3 (5)	C15—Ti2—C16—C17	114.9 (3)
C10—Si2—O—Si1	53.9 (5)	C10—Ti2—C16—C17	−141.4 (6)
O—Si1—C1—C2	−2.5 (4)	Cl4—Ti2—C16—C31	−58.7 (4)
C7—Si1—C1—C2	120.4 (4)	Cl3—Ti2—C16—C31	35.9 (4)
C6—Si1—C1—C2	−117.7 (4)	C13—Ti2—C16—C31	126.8 (4)
O—Si1—C1—C5	168.5 (3)	C12—Ti2—C16—C31	175.1 (4)
C7—Si1—C1—C5	−68.6 (4)	C11—Ti2—C16—C31	−135.4 (4)
C6—Si1—C1—C5	53.3 (4)	C19—Ti2—C16—C31	−158.4 (4)
O—Si1—C1—Ti1	−96.2 (2)	C17—Ti2—C16—C31	122.8 (5)
C7—Si1—C1—Ti1	26.7 (3)	C18—Ti2—C16—C31	160.2 (4)
C6—Si1—C1—Ti1	148.5 (2)	C14—Ti2—C16—C31	79.1 (5)
Cl1—Ti1—C1—C2	−86.3 (2)	C15—Ti2—C16—C31	−122.3 (5)
C4—Ti1—C1—C2	78.2 (3)	C10—Ti2—C16—C31	−18.6 (9)
C3—Ti1—C1—C2	36.3 (2)	C15—C16—C17—C18	0.8 (4)
Cl2—Ti1—C1—C2	177.7 (2)	C31—C16—C17—C18	174.9 (4)
C23—Ti1—C1—C2	8.7 (3)	Ti2—C16—C17—C18	−65.5 (3)
C21—Ti1—C1—C2	105.9 (3)	C15—C16—C17—C32	−171.4 (4)
C22—Ti1—C1—C2	55.9 (3)	C31—C16—C17—C32	2.7 (7)
C20—Ti1—C1—C2	−130.8 (9)	Ti2—C16—C17—C32	122.3 (4)
C5—Ti1—C1—C2	114.1 (3)	C15—C16—C17—Ti2	66.3 (3)
C24—Ti1—C1—C2	−38.8 (4)	C31—C16—C17—Ti2	−119.6 (4)
Cl1—Ti1—C1—C5	159.6 (2)	Cl4—Ti2—C17—C18	113.2 (2)
C4—Ti1—C1—C5	−35.9 (2)	Cl3—Ti2—C17—C18	−157.3 (2)
C3—Ti1—C1—C5	−77.8 (3)	C13—Ti2—C17—C18	−61.8 (2)
Cl2—Ti1—C1—C5	63.6 (2)	C12—Ti2—C17—C18	−27.4 (3)
C2—Ti1—C1—C5	−114.1 (3)	C11—Ti2—C17—C18	−17.0 (3)
C23—Ti1—C1—C5	−105.4 (3)	C19—Ti2—C17—C18	37.2 (2)
C21—Ti1—C1—C5	−8.1 (4)	C16—Ti2—C17—C18	115.1 (3)
C22—Ti1—C1—C5	−58.2 (3)	C14—Ti2—C17—C18	−88.9 (2)
C20—Ti1—C1—C5	115.1 (9)	C15—Ti2—C17—C18	78.0 (2)
C24—Ti1—C1—C5	−152.9 (3)	C10—Ti2—C17—C18	−80.2 (4)
Cl1—Ti1—C1—Si1	36.4 (2)	Cl4—Ti2—C17—C16	−1.9 (3)
C4—Ti1—C1—Si1	−159.1 (3)	Cl3—Ti2—C17—C16	87.6 (2)
C3—Ti1—C1—Si1	159.1 (3)	C13—Ti2—C17—C16	−177.0 (2)
Cl2—Ti1—C1—Si1	−59.6 (2)	C12—Ti2—C17—C16	−142.5 (2)
C2—Ti1—C1—Si1	122.7 (4)	C11—Ti2—C17—C16	−132.1 (3)
C23—Ti1—C1—Si1	131.5 (2)	C19—Ti2—C17—C16	−77.9 (2)
C21—Ti1—C1—Si1	−131.3 (3)	C18—Ti2—C17—C16	−115.1 (3)
C22—Ti1—C1—Si1	178.61 (19)	C14—Ti2—C17—C16	156.0 (2)
C20—Ti1—C1—Si1	−8.1 (11)	C15—Ti2—C17—C16	−37.1 (2)
C5—Ti1—C1—Si1	−123.2 (3)	C10—Ti2—C17—C16	164.7 (3)
C24—Ti1—C1—Si1	83.9 (3)	Cl4—Ti2—C17—C32	−125.0 (4)
C5—C1—C2—C3	0.7 (4)	Cl3—Ti2—C17—C32	−35.5 (4)
Si1—C1—C2—C3	173.3 (3)	C13—Ti2—C17—C32	59.9 (4)
Ti1—C1—C2—C3	−63.2 (3)	C12—Ti2—C17—C32	94.4 (4)
C5—C1—C2—Ti1	63.9 (3)	C11—Ti2—C17—C32	104.7 (4)
Si1—C1—C2—Ti1	−123.5 (3)	C19—Ti2—C17—C32	159.0 (4)
Cl1—Ti1—C2—C3	−153.5 (3)	C18—Ti2—C17—C32	121.8 (5)
C4—Ti1—C2—C3	38.5 (2)	C16—Ti2—C17—C32	−123.1 (5)
Cl2—Ti1—C2—C3	115.0 (2)	C14—Ti2—C17—C32	32.9 (4)
C23—Ti1—C2—C3	−55.7 (3)	C15—Ti2—C17—C32	−160.2 (5)
C21—Ti1—C2—C3	−12.7 (4)	C10—Ti2—C17—C32	41.6 (6)
C22—Ti1—C2—C3	−22.5 (3)	C16—C17—C18—C19	2.0 (4)
C20—Ti1—C2—C3	−78.7 (4)	C32—C17—C18—C19	174.3 (4)
C5—Ti1—C2—C3	79.9 (3)	Ti2—C17—C18—C19	−63.8 (3)
C24—Ti1—C2—C3	−84.1 (3)	C16—C17—C18—C33	−167.8 (4)
C1—Ti1—C2—C3	117.8 (4)	C32—C17—C18—C33	4.5 (6)
Cl1—Ti1—C2—C1	88.7 (2)	Ti2—C17—C18—C33	126.4 (4)
C4—Ti1—C2—C1	−79.2 (3)	C16—C17—C18—Ti2	65.8 (3)
C3—Ti1—C2—C1	−117.8 (4)	C32—C17—C18—Ti2	−121.9 (4)
Cl2—Ti1—C2—C1	−2.8 (3)	Cl4—Ti2—C18—C17	−94.1 (2)
C23—Ti1—C2—C1	−173.5 (2)	Cl3—Ti2—C18—C17	24.3 (2)
C21—Ti1—C2—C1	−130.5 (3)	C13—Ti2—C18—C17	118.0 (2)
C22—Ti1—C2—C1	−140.2 (2)	C12—Ti2—C18—C17	153.4 (3)
C20—Ti1—C2—C1	163.5 (3)	C11—Ti2—C18—C17	169.0 (2)
C5—Ti1—C2—C1	−37.9 (2)	C19—Ti2—C18—C17	−115.9 (3)
C24—Ti1—C2—C1	158.1 (2)	C16—Ti2—C18—C17	−37.6 (2)
C1—C2—C3—C4	0.8 (4)	C14—Ti2—C18—C17	109.1 (2)
Ti1—C2—C3—C4	−65.3 (3)	C15—Ti2—C18—C17	−78.0 (2)
C1—C2—C3—Ti1	66.1 (3)	C10—Ti2—C18—C17	142.1 (2)
Cl1—Ti1—C3—C2	28.4 (3)	Cl4—Ti2—C18—C19	21.8 (3)
C4—Ti1—C3—C2	−114.3 (4)	Cl3—Ti2—C18—C19	140.2 (2)
Cl2—Ti1—C3—C2	−91.8 (3)	C13—Ti2—C18—C19	−126.1 (2)
C23—Ti1—C3—C2	123.8 (3)	C12—Ti2—C18—C19	−90.6 (2)
C21—Ti1—C3—C2	172.0 (2)	C11—Ti2—C18—C19	−75.1 (2)
C22—Ti1—C3—C2	158.5 (3)	C17—Ti2—C18—C19	115.9 (3)
C20—Ti1—C3—C2	141.1 (3)	C16—Ti2—C18—C19	78.3 (2)
C5—Ti1—C3—C2	−76.2 (3)	C14—Ti2—C18—C19	−135.0 (2)
C24—Ti1—C3—C2	111.8 (3)	C15—Ti2—C18—C19	37.9 (2)
C1—Ti1—C3—C2	−35.8 (2)	C10—Ti2—C18—C19	−101.9 (2)
Cl1—Ti1—C3—C4	142.7 (2)	Cl4—Ti2—C18—C33	144.8 (3)
Cl2—Ti1—C3—C4	22.5 (3)	Cl3—Ti2—C18—C33	−96.7 (4)
C2—Ti1—C3—C4	114.3 (4)	C13—Ti2—C18—C33	−3.1 (4)
C23—Ti1—C3—C4	−121.9 (3)	C12—Ti2—C18—C33	32.4 (4)
C21—Ti1—C3—C4	−73.7 (3)	C11—Ti2—C18—C33	47.9 (4)
C22—Ti1—C3—C4	−87.2 (2)	C19—Ti2—C18—C33	123.0 (5)
C20—Ti1—C3—C4	−104.6 (3)	C17—Ti2—C18—C33	−121.1 (5)
C5—Ti1—C3—C4	38.1 (2)	C16—Ti2—C18—C33	−158.6 (4)
C24—Ti1—C3—C4	−133.9 (2)	C14—Ti2—C18—C33	−12.0 (4)
C1—Ti1—C3—C4	78.5 (2)	C15—Ti2—C18—C33	160.9 (4)
C2—C3—C4—C5	−2.0 (4)	C10—Ti2—C18—C33	21.1 (5)
Ti1—C3—C4—C5	−69.0 (3)	C16—C15—C19—C18	4.6 (4)
C2—C3—C4—Ti1	67.0 (3)	C30—C15—C19—C18	−169.2 (4)
Cl1—Ti1—C4—C5	58.1 (3)	Ti2—C15—C19—C18	67.4 (3)
C3—Ti1—C4—C5	113.5 (4)	C16—C15—C19—C34	173.5 (4)
Cl2—Ti1—C4—C5	−49.6 (2)	C30—C15—C19—C34	−0.3 (6)
C2—Ti1—C4—C5	75.8 (3)	Ti2—C15—C19—C34	−123.6 (4)
C23—Ti1—C4—C5	170.9 (3)	C16—C15—C19—Ti2	−62.9 (3)
C21—Ti1—C4—C5	−132.0 (3)	C30—C15—C19—Ti2	123.3 (4)
C22—Ti1—C4—C5	−160.9 (3)	C17—C18—C19—C15	−4.0 (4)
C20—Ti1—C4—C5	−138.1 (3)	C33—C18—C19—C15	165.5 (4)
C24—Ti1—C4—C5	177.4 (2)	Ti2—C18—C19—C15	−68.6 (3)
C1—Ti1—C4—C5	35.4 (2)	C17—C18—C19—C34	−172.4 (4)
Cl1—Ti1—C4—C3	−55.3 (3)	C33—C18—C19—C34	−2.9 (7)
Cl2—Ti1—C4—C3	−163.1 (2)	Ti2—C18—C19—C34	123.1 (4)
C2—Ti1—C4—C3	−37.7 (2)	C17—C18—C19—Ti2	64.6 (3)
C23—Ti1—C4—C3	57.5 (3)	C33—C18—C19—Ti2	−125.9 (4)
C21—Ti1—C4—C3	114.6 (2)	Cl4—Ti2—C19—C15	−49.8 (2)
C22—Ti1—C4—C3	85.6 (2)	Cl3—Ti2—C19—C15	56.0 (3)
C20—Ti1—C4—C3	108.4 (3)	C13—Ti2—C19—C15	168.5 (2)
C5—Ti1—C4—C3	−113.5 (3)	C12—Ti2—C19—C15	−163.7 (2)
C24—Ti1—C4—C3	64.0 (3)	C11—Ti2—C19—C15	−133.7 (2)
C1—Ti1—C4—C3	−78.1 (2)	C17—Ti2—C19—C15	76.8 (2)
C3—C4—C5—C1	2.5 (4)	C18—Ti2—C19—C15	113.8 (3)
Ti1—C4—C5—C1	−64.2 (3)	C16—Ti2—C19—C15	35.6 (2)
C3—C4—C5—Ti1	66.8 (3)	C14—Ti2—C19—C15	178.7 (2)
C2—C1—C5—C4	−2.0 (4)	C10—Ti2—C19—C15	−135.0 (2)
Si1—C1—C5—C4	−174.6 (3)	Cl4—Ti2—C19—C18	−163.6 (2)
Ti1—C1—C5—C4	61.1 (3)	Cl3—Ti2—C19—C18	−57.7 (3)
C2—C1—C5—Ti1	−63.1 (2)	C13—Ti2—C19—C18	54.8 (3)
Si1—C1—C5—Ti1	124.3 (3)	C12—Ti2—C19—C18	82.5 (2)
Cl1—Ti1—C5—C4	−140.7 (2)	C11—Ti2—C19—C18	112.5 (2)
C3—Ti1—C5—C4	−39.0 (2)	C17—Ti2—C19—C18	−37.0 (2)
Cl2—Ti1—C5—C4	129.0 (3)	C16—Ti2—C19—C18	−78.1 (2)
C2—Ti1—C5—C4	−80.5 (3)	C14—Ti2—C19—C18	65.0 (3)
C23—Ti1—C5—C4	−12.1 (3)	C15—Ti2—C19—C18	−113.8 (3)
C21—Ti1—C5—C4	57.2 (3)	C10—Ti2—C19—C18	111.2 (2)
C22—Ti1—C5—C4	20.1 (3)	Cl4—Ti2—C19—C34	71.4 (3)
C20—Ti1—C5—C4	79.8 (4)	Cl3—Ti2—C19—C34	177.3 (3)
C24—Ti1—C5—C4	−7.7 (7)	C13—Ti2—C19—C34	−70.2 (4)
C1—Ti1—C5—C4	−118.5 (4)	C12—Ti2—C19—C34	−42.5 (4)
Cl1—Ti1—C5—C1	−22.2 (2)	C11—Ti2—C19—C34	−12.5 (4)
C4—Ti1—C5—C1	118.5 (4)	C17—Ti2—C19—C34	−162.0 (4)
C3—Ti1—C5—C1	79.5 (2)	C18—Ti2—C19—C34	−125.0 (4)
Cl2—Ti1—C5—C1	−112.5 (2)	C16—Ti2—C19—C34	156.9 (4)
C2—Ti1—C5—C1	38.0 (2)	C14—Ti2—C19—C34	−60.0 (4)
C23—Ti1—C5—C1	106.4 (3)	C15—Ti2—C19—C34	121.2 (4)
C21—Ti1—C5—C1	175.7 (2)	C10—Ti2—C19—C34	−13.8 (4)
C22—Ti1—C5—C1	138.6 (2)	Cl1—Ti1—C20—C24	64.0 (2)
C20—Ti1—C5—C1	−161.7 (3)	C4—Ti1—C20—C24	−104.9 (3)
C24—Ti1—C5—C1	110.8 (6)	C3—Ti1—C20—C24	−57.2 (3)
O—Si2—C10—C14	61.9 (4)	Cl2—Ti1—C20—C24	160.0 (3)
C8—Si2—C10—C14	−52.8 (4)	C2—Ti1—C20—C24	−8.6 (5)
C9—Si2—C10—C14	−179.8 (3)	C23—Ti1—C20—C24	−36.5 (2)
O—Si2—C10—C11	−111.9 (3)	C21—Ti1—C20—C24	−115.8 (4)
C8—Si2—C10—C11	133.4 (4)	C22—Ti1—C20—C24	−77.8 (3)
C9—Si2—C10—C11	6.4 (4)	C5—Ti1—C20—C24	−152.4 (3)
O—Si2—C10—Ti2	155.44 (19)	C1—Ti1—C20—C24	108.0 (9)
C8—Si2—C10—Ti2	40.8 (3)	Cl1—Ti1—C20—C21	179.8 (3)
C9—Si2—C10—Ti2	−86.2 (3)	C4—Ti1—C20—C21	10.8 (4)
Cl4—Ti2—C10—C14	155.2 (2)	C3—Ti1—C20—C21	58.5 (4)
Cl3—Ti2—C10—C14	60.8 (2)	Cl2—Ti1—C20—C21	−84.3 (3)
C13—Ti2—C10—C14	−35.4 (2)	C2—Ti1—C20—C21	107.2 (4)
C12—Ti2—C10—C14	−77.3 (3)	C23—Ti1—C20—C21	79.3 (3)
C11—Ti2—C10—C14	−113.8 (4)	C22—Ti1—C20—C21	38.0 (2)
C19—Ti2—C10—C14	−111.4 (2)	C5—Ti1—C20—C21	−36.7 (4)
C17—Ti2—C10—C14	−13.7 (4)	C24—Ti1—C20—C21	115.8 (4)
C18—Ti2—C10—C14	−64.2 (3)	C1—Ti1—C20—C21	−136.3 (8)
C16—Ti2—C10—C14	114.5 (7)	Cl1—Ti1—C20—C28	−58.7 (5)
C15—Ti2—C10—C14	−158.6 (2)	C4—Ti1—C20—C28	132.3 (4)
Cl4—Ti2—C10—C11	−91.0 (2)	C3—Ti1—C20—C28	−180.0 (4)
Cl3—Ti2—C10—C11	174.6 (2)	Cl2—Ti1—C20—C28	37.2 (5)
C13—Ti2—C10—C11	78.3 (3)	C2—Ti1—C20—C28	−131.3 (5)
C12—Ti2—C10—C11	36.4 (3)	C23—Ti1—C20—C28	−159.2 (6)
C19—Ti2—C10—C11	2.3 (3)	C21—Ti1—C20—C28	121.5 (6)
C17—Ti2—C10—C11	100.1 (4)	C22—Ti1—C20—C28	159.5 (6)
C18—Ti2—C10—C11	49.6 (3)	C5—Ti1—C20—C28	84.8 (5)
C16—Ti2—C10—C11	−131.8 (7)	C24—Ti1—C20—C28	−122.7 (6)
C14—Ti2—C10—C11	113.8 (4)	C1—Ti1—C20—C28	−14.8 (13)
C15—Ti2—C10—C11	−44.9 (4)	C24—C20—C21—C22	0.3 (5)
Cl4—Ti2—C10—Si2	33.4 (2)	C28—C20—C21—C22	175.7 (4)
Cl3—Ti2—C10—Si2	−61.1 (2)	Ti1—C20—C21—C22	−66.1 (3)
C13—Ti2—C10—Si2	−157.3 (3)	C24—C20—C21—C27	−172.1 (4)
C12—Ti2—C10—Si2	160.8 (3)	C28—C20—C21—C27	3.2 (7)
C11—Ti2—C10—Si2	124.4 (4)	Ti1—C20—C21—C27	121.4 (5)
C19—Ti2—C10—Si2	126.7 (2)	C24—C20—C21—Ti1	66.5 (3)
C17—Ti2—C10—Si2	−135.6 (3)	C28—C20—C21—Ti1	−118.2 (4)
C18—Ti2—C10—Si2	173.92 (18)	Cl1—Ti1—C21—C22	113.9 (2)
C16—Ti2—C10—Si2	−7.4 (8)	C4—Ti1—C21—C22	−57.6 (3)
C14—Ti2—C10—Si2	−121.9 (3)	C3—Ti1—C21—C22	−24.0 (3)
C15—Ti2—C10—Si2	79.5 (3)	Cl2—Ti1—C21—C22	−154.8 (3)
C14—C10—C11—C12	0.2 (4)	C2—Ti1—C21—C22	−16.4 (4)
Si2—C10—C11—C12	175.1 (3)	C23—Ti1—C21—C22	37.5 (2)
Ti2—C10—C11—C12	−64.2 (3)	C20—Ti1—C21—C22	114.2 (4)
C14—C10—C11—Ti2	64.4 (2)	C5—Ti1—C21—C22	−86.0 (3)
Si2—C10—C11—Ti2	−120.8 (3)	C24—Ti1—C21—C22	78.0 (3)
Cl4—Ti2—C11—C12	−158.7 (3)	C1—Ti1—C21—C22	−80.9 (4)
Cl3—Ti2—C11—C12	110.6 (2)	Cl1—Ti1—C21—C20	−0.3 (3)
C13—Ti2—C11—C12	38.7 (2)	C4—Ti1—C21—C20	−171.8 (3)
C19—Ti2—C11—C12	−60.9 (3)	C3—Ti1—C21—C20	−138.2 (3)
C17—Ti2—C11—C12	−17.7 (4)	Cl2—Ti1—C21—C20	91.0 (3)
C18—Ti2—C11—C12	−27.6 (3)	C2—Ti1—C21—C20	−130.6 (3)
C16—Ti2—C11—C12	−80.0 (4)	C23—Ti1—C21—C20	−76.7 (3)
C14—Ti2—C11—C12	79.6 (3)	C22—Ti1—C21—C20	−114.2 (4)
C15—Ti2—C11—C12	−88.2 (3)	C5—Ti1—C21—C20	159.8 (3)
C10—Ti2—C11—C12	117.4 (4)	C24—Ti1—C21—C20	−36.2 (3)
Cl4—Ti2—C11—C10	84.0 (2)	C1—Ti1—C21—C20	164.9 (3)
Cl3—Ti2—C11—C10	−6.7 (3)	Cl1—Ti1—C21—C27	−124.8 (4)
C13—Ti2—C11—C10	−78.7 (3)	C4—Ti1—C21—C27	63.6 (5)
C12—Ti2—C11—C10	−117.4 (4)	C3—Ti1—C21—C27	97.3 (5)
C19—Ti2—C11—C10	−178.2 (2)	Cl2—Ti1—C21—C27	−33.6 (4)
C17—Ti2—C11—C10	−135.0 (3)	C2—Ti1—C21—C27	104.8 (5)
C18—Ti2—C11—C10	−145.0 (2)	C23—Ti1—C21—C27	158.7 (5)
C16—Ti2—C11—C10	162.6 (3)	C22—Ti1—C21—C27	121.2 (6)
C14—Ti2—C11—C10	−37.7 (2)	C20—Ti1—C21—C27	−124.6 (6)
C15—Ti2—C11—C10	154.4 (2)	C5—Ti1—C21—C27	35.2 (5)
C10—C11—C12—C13	1.3 (4)	C24—Ti1—C21—C27	−160.8 (5)
Ti2—C11—C12—C13	−65.4 (3)	C1—Ti1—C21—C27	40.3 (6)
C10—C11—C12—Ti2	66.7 (3)	C20—C21—C22—C23	1.6 (4)
Cl4—Ti2—C12—C11	23.4 (3)	C27—C21—C22—C23	174.3 (4)
Cl3—Ti2—C12—C11	−97.7 (3)	Ti1—C21—C22—C23	−64.6 (3)
C13—Ti2—C12—C11	−114.0 (4)	C20—C21—C22—C26	−166.9 (4)
C19—Ti2—C12—C11	118.4 (3)	C27—C21—C22—C26	5.8 (7)
C17—Ti2—C12—C11	168.6 (2)	Ti1—C21—C22—C26	126.9 (4)
C18—Ti2—C12—C11	153.3 (3)	C20—C21—C22—Ti1	66.2 (3)
C16—Ti2—C12—C11	140.7 (2)	C27—C21—C22—Ti1	−121.1 (5)
C14—Ti2—C12—C11	−76.4 (3)	Cl1—Ti1—C22—C23	21.5 (3)
C15—Ti2—C12—C11	108.7 (3)	C4—Ti1—C22—C23	−123.5 (3)
C10—Ti2—C12—C11	−36.3 (2)	C3—Ti1—C22—C23	−87.9 (2)
Cl4—Ti2—C12—C13	137.5 (2)	Cl2—Ti1—C22—C23	142.1 (2)
Cl3—Ti2—C12—C13	16.4 (3)	C2—Ti1—C22—C23	−75.2 (3)
C11—Ti2—C12—C13	114.0 (4)	C21—Ti1—C22—C23	115.1 (4)
C19—Ti2—C12—C13	−127.5 (3)	C20—Ti1—C22—C23	76.9 (3)
C17—Ti2—C12—C13	−77.4 (3)	C5—Ti1—C22—C23	−134.9 (2)
C18—Ti2—C12—C13	−92.7 (3)	C24—Ti1—C22—C23	36.9 (2)
C16—Ti2—C12—C13	−105.3 (3)	C1—Ti1—C22—C23	−104.5 (3)
C14—Ti2—C12—C13	37.6 (2)	Cl1—Ti1—C22—C21	−93.6 (3)
C15—Ti2—C12—C13	−137.2 (2)	C4—Ti1—C22—C21	121.4 (3)
C10—Ti2—C12—C13	77.8 (3)	C3—Ti1—C22—C21	157.1 (3)
C11—C12—C13—C14	−2.4 (4)	Cl2—Ti1—C22—C21	27.1 (3)
Ti2—C12—C13—C14	−68.7 (3)	C2—Ti1—C22—C21	169.8 (3)
C11—C12—C13—Ti2	66.3 (3)	C23—Ti1—C22—C21	−115.1 (4)
Cl4—Ti2—C13—C14	50.5 (3)	C20—Ti1—C22—C21	−38.2 (3)
Cl3—Ti2—C13—C14	−53.6 (2)	C5—Ti1—C22—C21	110.1 (3)
C12—Ti2—C13—C14	113.9 (4)	C24—Ti1—C22—C21	−78.1 (3)
C11—Ti2—C13—C14	76.0 (3)	C1—Ti1—C22—C21	140.4 (3)
C19—Ti2—C13—C14	167.0 (2)	Cl1—Ti1—C22—C26	143.2 (4)
C17—Ti2—C13—C14	−135.4 (2)	C4—Ti1—C22—C26	−1.8 (4)
C18—Ti2—C13—C14	−165.3 (3)	C3—Ti1—C22—C26	33.9 (4)
C16—Ti2—C13—C14	−137.7 (2)	Cl2—Ti1—C22—C26	−96.1 (4)
C15—Ti2—C13—C14	175.9 (2)	C2—Ti1—C22—C26	46.6 (4)
C10—Ti2—C13—C14	35.0 (2)	C23—Ti1—C22—C26	121.7 (5)
Cl4—Ti2—C13—C12	−63.4 (3)	C21—Ti1—C22—C26	−123.2 (5)
Cl3—Ti2—C13—C12	−167.5 (2)	C20—Ti1—C22—C26	−161.4 (5)
C11—Ti2—C13—C12	−37.9 (2)	C5—Ti1—C22—C26	−13.1 (4)
C19—Ti2—C13—C12	53.0 (3)	C24—Ti1—C22—C26	158.7 (5)
C17—Ti2—C13—C12	110.7 (3)	C1—Ti1—C22—C26	17.2 (5)
C18—Ti2—C13—C12	80.8 (3)	C21—C22—C23—C24	−2.9 (4)
C16—Ti2—C13—C12	108.4 (3)	C26—C22—C23—C24	165.7 (4)
C14—Ti2—C13—C12	−113.9 (4)	Ti1—C22—C23—C24	−67.5 (3)
C15—Ti2—C13—C12	62.0 (3)	C21—C22—C23—C25	−172.5 (4)
C10—Ti2—C13—C12	−78.9 (3)	C26—C22—C23—C25	−3.8 (6)
C12—C13—C14—C10	2.6 (4)	Ti1—C22—C23—C25	122.9 (4)
Ti2—C13—C14—C10	−63.7 (3)	C21—C22—C23—Ti1	64.6 (3)
C12—C13—C14—Ti2	66.3 (3)	C26—C22—C23—Ti1	−126.8 (4)
C11—C10—C14—C13	−1.8 (4)	Cl1—Ti1—C23—C24	−48.5 (3)
Si2—C10—C14—C13	−176.8 (3)	C4—Ti1—C23—C24	171.1 (3)
Ti2—C10—C14—C13	61.1 (3)	C3—Ti1—C23—C24	−159.4 (3)
C11—C10—C14—Ti2	−62.8 (2)	Cl2—Ti1—C23—C24	60.0 (3)
Si2—C10—C14—Ti2	122.2 (3)	C2—Ti1—C23—C24	−131.2 (3)
Cl4—Ti2—C14—C13	−145.4 (2)	C21—Ti1—C23—C24	77.7 (3)
Cl3—Ti2—C14—C13	124.7 (2)	C22—Ti1—C23—C24	115.4 (4)
C12—Ti2—C14—C13	−38.9 (3)	C20—Ti1—C23—C24	36.0 (3)
C11—Ti2—C14—C13	−80.6 (3)	C5—Ti1—C23—C24	178.0 (3)
C19—Ti2—C14—C13	−18.1 (3)	C1—Ti1—C23—C24	−136.1 (3)
C17—Ti2—C14—C13	53.9 (3)	Cl1—Ti1—C23—C22	−163.9 (2)
C18—Ti2—C14—C13	16.0 (3)	C4—Ti1—C23—C22	55.8 (3)
C16—Ti2—C14—C13	80.6 (4)	C3—Ti1—C23—C22	85.2 (2)
C15—Ti2—C14—C13	−14.6 (8)	Cl2—Ti1—C23—C22	−55.4 (3)
C10—Ti2—C14—C13	−119.1 (4)	C2—Ti1—C23—C22	113.5 (2)
Cl4—Ti2—C14—C10	−26.3 (2)	C21—Ti1—C23—C22	−37.6 (2)
Cl3—Ti2—C14—C10	−116.2 (2)	C20—Ti1—C23—C22	−79.4 (3)
C13—Ti2—C14—C10	119.1 (4)	C5—Ti1—C23—C22	62.6 (3)
C12—Ti2—C14—C10	80.2 (3)	C24—Ti1—C23—C22	−115.4 (4)
C11—Ti2—C14—C10	38.6 (2)	C1—Ti1—C23—C22	108.6 (3)
C19—Ti2—C14—C10	101.0 (3)	Cl1—Ti1—C23—C25	72.4 (4)
C17—Ti2—C14—C10	173.0 (2)	C4—Ti1—C23—C25	−68.0 (4)
C18—Ti2—C14—C10	135.1 (2)	C3—Ti1—C23—C25	−38.5 (4)
C16—Ti2—C14—C10	−160.3 (3)	Cl2—Ti1—C23—C25	−179.1 (3)
C15—Ti2—C14—C10	104.5 (6)	C2—Ti1—C23—C25	−10.3 (4)
Cl4—Ti2—C15—C16	−113.0 (2)	C21—Ti1—C23—C25	−161.4 (4)
Cl3—Ti2—C15—C16	−23.3 (2)	C22—Ti1—C23—C25	−123.7 (5)
C13—Ti2—C15—C16	102.0 (3)	C20—Ti1—C23—C25	156.9 (4)
C12—Ti2—C15—C16	135.3 (2)	C5—Ti1—C23—C25	−61.1 (4)
C11—Ti2—C15—C16	173.0 (2)	C24—Ti1—C23—C25	120.9 (5)
C19—Ti2—C15—C16	117.9 (3)	C1—Ti1—C23—C25	−15.2 (4)
C17—Ti2—C15—C16	38.0 (2)	C21—C20—C24—C23	−2.1 (5)
C18—Ti2—C15—C16	79.4 (2)	C28—C20—C24—C23	−177.5 (4)
C14—Ti2—C15—C16	113.4 (6)	Ti1—C20—C24—C23	62.6 (3)
C10—Ti2—C15—C16	−160.0 (2)	C21—C20—C24—C29	170.8 (4)
Cl4—Ti2—C15—C19	129.1 (2)	C28—C20—C24—C29	−4.5 (7)
Cl3—Ti2—C15—C19	−141.2 (2)	Ti1—C20—C24—C29	−124.4 (4)
C13—Ti2—C15—C19	−15.9 (3)	C21—C20—C24—Ti1	−64.8 (3)
C12—Ti2—C15—C19	17.4 (3)	C28—C20—C24—Ti1	119.9 (4)
C11—Ti2—C15—C19	55.1 (3)	C22—C23—C24—C20	3.1 (5)
C17—Ti2—C15—C19	−79.9 (2)	C25—C23—C24—C20	173.1 (4)
C18—Ti2—C15—C19	−38.5 (2)	Ti1—C23—C24—C20	−63.2 (3)
C16—Ti2—C15—C19	−117.9 (3)	C22—C23—C24—C29	−169.9 (4)
C14—Ti2—C15—C19	−4.5 (8)	C25—C23—C24—C29	0.0 (7)
C10—Ti2—C15—C19	82.1 (3)	Ti1—C23—C24—C29	123.7 (4)
Cl4—Ti2—C15—C30	8.9 (4)	C22—C23—C24—Ti1	66.4 (3)
Cl3—Ti2—C15—C30	98.7 (4)	C25—C23—C24—Ti1	−123.7 (4)
C13—Ti2—C15—C30	−136.0 (4)	Cl1—Ti1—C24—C20	−112.5 (3)
C12—Ti2—C15—C30	−102.7 (4)	C4—Ti1—C24—C20	105.3 (3)
C11—Ti2—C15—C30	−65.0 (4)	C3—Ti1—C24—C20	138.7 (3)
C19—Ti2—C15—C30	−120.1 (5)	Cl2—Ti1—C24—C20	−22.0 (3)
C17—Ti2—C15—C30	159.9 (4)	C2—Ti1—C24—C20	175.4 (2)
C18—Ti2—C15—C30	−158.6 (4)	C23—Ti1—C24—C20	117.0 (4)
C16—Ti2—C15—C30	122.0 (5)	C21—Ti1—C24—C20	37.9 (2)
C14—Ti2—C15—C30	−124.6 (6)	C22—Ti1—C24—C20	79.4 (3)
C10—Ti2—C15—C30	−38.1 (5)	C5—Ti1—C24—C20	111.1 (6)
C19—C15—C16—C17	−3.3 (4)	C1—Ti1—C24—C20	−161.1 (3)
C30—C15—C16—C17	170.4 (4)	Cl1—Ti1—C24—C23	130.5 (3)
Ti2—C15—C16—C17	−65.1 (3)	C4—Ti1—C24—C23	−11.7 (4)
C19—C15—C16—C31	−177.5 (4)	C3—Ti1—C24—C23	21.7 (3)
C30—C15—C16—C31	−3.7 (6)	Cl2—Ti1—C24—C23	−139.0 (2)
Ti2—C15—C16—C31	120.8 (4)	C2—Ti1—C24—C23	58.4 (3)
C19—C15—C16—Ti2	61.7 (3)	C21—Ti1—C24—C23	−79.2 (3)
C30—C15—C16—Ti2	−124.5 (4)	C22—Ti1—C24—C23	−37.6 (2)
Cl4—Ti2—C16—C15	63.6 (2)	C20—Ti1—C24—C23	−117.0 (4)
Cl3—Ti2—C16—C15	158.2 (2)	C5—Ti1—C24—C23	−6.0 (8)
C13—Ti2—C16—C15	−110.8 (3)	C1—Ti1—C24—C23	81.9 (3)
C12—Ti2—C16—C15	−62.6 (3)	Cl1—Ti1—C24—C29	10.3 (4)
C11—Ti2—C16—C15	−13.1 (4)	C4—Ti1—C24—C29	−131.9 (4)
C19—Ti2—C16—C15	−36.0 (2)	C3—Ti1—C24—C29	−98.5 (5)
C17—Ti2—C16—C15	−114.9 (3)	Cl2—Ti1—C24—C29	100.9 (5)
C18—Ti2—C16—C15	−77.4 (2)	C2—Ti1—C24—C29	−61.8 (5)
C14—Ti2—C16—C15	−158.6 (3)	C23—Ti1—C24—C29	−120.2 (6)
C10—Ti2—C16—C15	103.7 (7)	C21—Ti1—C24—C29	160.7 (5)
Cl4—Ti2—C16—C17	178.5 (2)	C22—Ti1—C24—C29	−157.8 (5)
Cl3—Ti2—C16—C17	−86.9 (2)	C20—Ti1—C24—C29	122.8 (6)
C13—Ti2—C16—C17	4.1 (3)	C5—Ti1—C24—C29	−126.1 (6)
C12—Ti2—C16—C17	52.3 (3)	C1—Ti1—C24—C29	−38.3 (6)