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The title compound, octakis(tetramethylammonium) docosavanadate acetate hydrate, was synthesized and found to crystallize in the tetragonal system space group P42/n. 22 vanadium square pyramids form a barrel-shaped cluster which hosts the acetate ion; this is the first case where an organic molecule is hosted by a vanadium oxide cluster. The clusters are linked into a three-dimensional net by hydrogen bonds with water molecules. Tetramethylammonium ions fill the space between the clusters.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, TMA8V22O54

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 130454

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