metal-organic compounds
The title complex, tri-tert-butoxy-1κ2O,2κO-trichloro-1κCl,2κ2Cl-bis(N,N-dimethylamine)- 1κN,2κN-ditungsten(WW), [W2Cl3(C4H9O)3(C2H7N)2], adopts a dinuclear structure in which two tungsten(III) atoms are united by a WW bond unsupported by bridging ligands. Both W atoms are coordinated to four ligand atoms that lie in a roughly square plane. The two W atoms have different coordination environments: one is ligated by two cis-OR groups, one Cl ligand, and one HNMe2 ligand, while the other is ligated by two trans-Cl ligands, one OR group, and one HNMe2 ligand.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 129512