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The title complex, tri-tert-butoxy-1κ2O,2κO-trichloro-1κCl,2κ2Cl-bis(N,N-dimethylamine)- 1κN,2κN-ditungsten(W[triple bond]W), [W2Cl3(C4H9O)3(C2H7N)2], adopts a dinuclear structure in which two tungsten(III) atoms are united by a W[triple bond]W bond unsupported by bridging ligands. Both W atoms are coordinated to four ligand atoms that lie in a roughly square plane. The two W atoms have different coordination environments: one is ligated by two cis-OR groups, one Cl ligand, and one HNMe2 ligand, while the other is ligated by two trans-Cl ligands, one OR group, and one HNMe2 ligand.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, global

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 129512

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