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The cations and anions of the title compound, [(C6H5)4P][W(HS)S3], are separated by normal van der Waals distances. The ions each lie on \overline{4} sites, such that the H atom of the anion is disordered over four sites with 0.25 occupancies. The W-S distances in the anion are 2.171 (2) Å, with S-W-S angles of 108.1 (1) and 112.4 (2)°. In the cation, identical P-C distances of 1.793 (6) Å are observed, with C-P-C angles of 106.3 (4) and 111.1 (2)°.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock Sulfido_Tungstate

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 128564

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