metal-organic compounds
The cation of the title compound, 3,5-bis(2-methylphenyl)-1,2,4-dithiazolylium hexafluoroarsenate(V), (C16H14NS2)+.[AsF6]−, has a central planar five-membered NCSSC ring with two o-tolyl substituents lying 29.11 (9)° out of this plane because of the steric hindrance of the methyl groups; the cation has a twofold rotation axis through the nitrogen atom and the mid-point of the S—S bond. Interionic interactions include short SF and NF contacts, but the cations are well separated with no SS or NS interactions.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 127170