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A new CdII/NbV compound, bis(pyridinium) decafluoro-2κ5F, 3κ5F-di-μ-oxo-1:2κ2O; 1:3κ2O-tetrakis(pyridine-N)cadmiumdiniobium(2—), (C5H6N)2[CdNb2F10O2(C5H5N)4], has been synthesized. The complex contains [CdNb2(py)4F10O2]2−, anions (py is pyridine) linked via the pyridinium cation through N—H+...F hydrogen bonding. The anion is composed of two [NbF5O1/2] octahedra connected by O2− to a central [Cd(py)4O2/2] octahedron.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock BK1219

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 127975

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