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The title compound, [Ti(C5H5)2(CHO2)2], has a `bent metallocene' structural type typically found for Cp2MXY complexes. The Ti-O-C bond angles are larger than in related titanocene alkoxy complexes, suggesting enhanced π-character in the Ti-O bonds of the title compound; however, the Ti-O bond lengths are longer than those in related alkoxy compounds.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock Ticp

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 126909

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