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Eight new silver(I) trifluoroacetate complexes based on a series of designed ligands, each featuring an alicyclic ring with enediyne functionality, have been synthesized and characterized by single-crystal X-ray diffraction. Each ethynide terminal is inserted into an Agn (n = 4-5) basket, leading to the generation of coordination chain or layer structures, but the well shielded ethenyl group does not take part in silver-olefin bonding. Variation in ring size of the alicycles is shown to influence the construction of the organosilver(I) coordination networks, which are consolidated by weak intermolecular interactions in the crystal structures. The effect of adding ancillary N-donor ligands to the reaction system on the coordination and supramolecular network assembly is also investigated.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S2052520614000171/bi5014sup1.cif
Contains datablocks I, II, III, IV, V, VI, VII, VIII, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520614000171/bi5014Isup2.hkl
Contains datablock I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520614000171/bi5014IIsup3.hkl
Contains datablock II

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520614000171/bi5014IIIsup4.hkl
Contains datablock III

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520614000171/bi5014IVsup5.hkl
Contains datablock IV

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520614000171/bi5014Vsup6.hkl
Contains datablock V

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520614000171/bi5014VIsup7.hkl
Contains datablock VI

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520614000171/bi5014VIIsup8.hkl
Contains datablock VII

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S2052520614000171/bi5014VIIIsup9.hkl
Contains datablock VIII

pdf

Portable Document Format (PDF) file https://doi.org/10.1107/S2052520614000171/bi5014sup10.pdf
Additional figures and synthesis details

CCDC references: 952547; 952548; 952549; 952550; 952551; 952552; 952553; 952554

Computing details top

For all compounds, data collection: APEX2 (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL2013 (Sheldrick, 2008); molecular graphics: DIAMOND (Brandenburg, 2009); software used to prepare material for publication: SHELXL2013.

Figures top
[Figure 1]
[Figure 2]
[Figure 3]
[Figure 4]
[Figure 5]
[Figure 6]
[Figure 7]
[Figure 8]
(I) top
Crystal data top
22(Ag+)·3(C10H82)·16(C2F3O2)·12(C2H6SO)Z = 4
Mr = 5503.48F(000) = 10488
Monoclinic, C2/cDx = 2.445 Mg m3
a = 22.076 (3) ÅMo Kα radiation, λ = 0.71073 Å
b = 14.7930 (18) ŵ = 3.11 mm1
c = 45.863 (6) ÅT = 173 K
β = 93.501 (3)°Block, yellow
V = 14950 (3) Å30.50 × 0.50 × 0.40 mm
Data collection top
Bruker APEX-II CCD
diffractometer
9700 reflections with I > 2σ(I)
φ and ω scanRint = 0.158
Absorption correction: multi-scan
SADABS (Bruker, 2003)
θmax = 25.3°, θmin = 1.7°
Tmin = 0.306, Tmax = 0.370h = 2626
102163 measured reflectionsk = 1717
13534 independent reflectionsl = 5554
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.076Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.200H-atom parameters constrained
S = 1.08 w = 1/[σ2(Fo2) + (0.096P)2 + 292.8881P]
where P = (Fo2 + 2Fc2)/3
13534 reflections(Δ/σ)max = 0.001
967 parametersΔρmax = 3.61 e Å3
606 restraintsΔρmin = 1.64 e Å3
Crystal data top
22(Ag+)·3(C10H82)·16(C2F3O2)·12(C2H6SO)V = 14950 (3) Å3
Mr = 5503.48Z = 4
Monoclinic, C2/cMo Kα radiation
a = 22.076 (3) ŵ = 3.11 mm1
b = 14.7930 (18) ÅT = 173 K
c = 45.863 (6) Å0.50 × 0.50 × 0.40 mm
β = 93.501 (3)°
Data collection top
Bruker APEX-II CCD
diffractometer
13534 independent reflections
Absorption correction: multi-scan
SADABS (Bruker, 2003)
9700 reflections with I > 2σ(I)
Tmin = 0.306, Tmax = 0.370Rint = 0.158
102163 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.076606 restraints
wR(F2) = 0.200H-atom parameters constrained
S = 1.08 w = 1/[σ2(Fo2) + (0.096P)2 + 292.8881P]
where P = (Fo2 + 2Fc2)/3
13534 reflectionsΔρmax = 3.61 e Å3
967 parametersΔρmin = 1.64 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.79033 (4)0.31570 (6)0.49150 (2)0.0245 (2)
Ag20.78628 (5)0.17130 (7)0.44545 (3)0.0418 (3)
Ag30.76039 (5)0.36734 (6)0.43049 (2)0.0295 (2)
Ag40.66712 (5)0.38185 (6)0.48665 (2)0.0298 (2)
Ag50.55130 (5)0.38358 (6)0.34034 (2)0.0278 (2)
Ag60.59620 (6)0.43755 (7)0.40950 (2)0.0387 (3)
Ag70.67050 (5)0.44516 (6)0.35846 (2)0.0263 (2)
Ag80.66188 (5)0.26565 (6)0.33484 (2)0.0363 (3)
Ag90.54827 (5)0.27076 (6)0.28916 (2)0.0364 (3)
Ag100.63744 (5)0.42288 (6)0.29427 (2)0.0308 (3)
Ag110.43231 (6)0.38098 (9)0.29400 (3)0.0475 (3)
C10.7108 (5)0.2672 (7)0.4616 (2)0.018 (2)
C20.6746 (5)0.2425 (7)0.4419 (2)0.014 (2)
C30.6308 (5)0.2149 (8)0.4194 (3)0.022 (3)
C40.6242 (5)0.2795 (7)0.3950 (2)0.019 (2)
C50.6208 (6)0.3299 (8)0.3740 (2)0.023 (3)
C60.6003 (6)0.1366 (8)0.4188 (3)0.024 (3)
C70.6058 (7)0.0635 (8)0.4411 (3)0.037 (3)
H7A0.58310.07940.45840.045*
H7B0.64880.05310.44750.045*
C80.5788 (8)0.0195 (11)0.4260 (4)0.059 (5)
H8A0.60960.05190.41520.071*
H8B0.56190.06140.44030.071*
C90.5294 (8)0.0183 (11)0.4055 (4)0.053 (4)
H9A0.49210.02920.41580.064*
H9B0.51990.02410.38910.064*
C100.5544 (7)0.1069 (9)0.3942 (3)0.039 (3)
H10A0.52180.15230.39090.047*
H10B0.57460.09750.37570.047*
C110.5363 (6)0.4162 (9)0.2925 (3)0.033 (3)
C120.5173 (6)0.4728 (8)0.2753 (3)0.026 (3)
C130.50000.5259 (11)0.25000.024 (4)
C140.50000.6183 (11)0.25000.028 (4)
C150.5178 (7)0.6751 (9)0.2762 (3)0.040 (3)
H15A0.56000.66250.28370.048*
H15B0.49010.66540.29210.048*
C160.5115 (11)0.7697 (12)0.2637 (4)0.078 (6)
H16A0.48500.80580.27590.093*
H16B0.55190.79890.26450.093*
S10.7834 (3)0.1041 (3)0.37065 (10)0.0648 (13)
O170.7644 (6)0.1757 (8)0.3910 (3)0.070 (4)
C330.7396 (10)0.0091 (15)0.3777 (5)0.085 (7)
H33A0.69740.01980.37060.128*
H33B0.74130.00230.39880.128*
H33C0.75550.04360.36770.128*
C340.8542 (10)0.0650 (14)0.3854 (5)0.078 (6)
H34A0.88510.11150.38300.118*
H34B0.86550.00990.37510.118*
H34C0.85150.05160.40620.118*
S20.82363 (18)0.4145 (3)0.36429 (8)0.0441 (9)
O180.7685 (4)0.4105 (6)0.38215 (19)0.033 (2)
C350.8789 (9)0.3462 (12)0.3833 (5)0.071 (6)
H35A0.86770.28240.38090.106*
H35B0.88100.36200.40410.106*
H35C0.91860.35650.37540.106*
C360.8576 (9)0.5228 (12)0.3733 (4)0.068 (5)
H36A0.83260.57110.36420.102*
H36B0.89840.52530.36600.102*
H36C0.86030.53080.39450.102*
S30.70907 (17)0.5873 (2)0.44468 (8)0.0356 (8)
O190.6878 (4)0.4922 (6)0.4353 (2)0.043 (2)
C370.7223 (10)0.6420 (11)0.4116 (4)0.068 (5)
H37A0.75910.61750.40370.101*
H37B0.72740.70700.41510.101*
H37C0.68760.63200.39760.101*
C380.6416 (7)0.6438 (9)0.4534 (3)0.040 (4)
H38A0.62800.62030.47190.061*
H38B0.61000.63370.43790.061*
H38C0.64960.70880.45540.061*
S40.51124 (18)0.4043 (3)0.47009 (9)0.0425 (9)
O200.5716 (4)0.4224 (6)0.45803 (19)0.034 (2)
C390.4597 (8)0.4772 (13)0.4490 (4)0.070 (5)
H39A0.46710.54020.45470.105*
H39B0.41780.46090.45260.105*
H39C0.46610.46990.42810.105*
C400.4865 (8)0.2971 (10)0.4553 (4)0.060 (5)
H40A0.51080.24860.46470.090*
H40B0.49160.29620.43420.090*
H40C0.44360.28790.45880.090*
S50.3088 (2)0.5051 (3)0.27010 (8)0.0454 (10)
O210.3551 (5)0.4355 (7)0.2618 (2)0.046 (3)
C410.3514 (10)0.5748 (13)0.2961 (5)0.083 (6)
H41A0.38110.61050.28600.125*
H41B0.37250.53650.31080.125*
H41C0.32370.61560.30560.125*
C420.2631 (8)0.4540 (12)0.2951 (4)0.059 (5)
H42A0.23490.41200.28480.088*
H42B0.24000.50060.30490.088*
H42C0.28870.42090.30970.088*
S60.4067 (3)0.1429 (5)0.2665 (2)0.051 (3)0.80 (2)
O220.4347 (5)0.2377 (6)0.2630 (2)0.040 (2)0.80 (2)
C430.3977 (11)0.1294 (14)0.3043 (4)0.080 (6)0.80 (2)
H43A0.43730.11740.31440.120*0.80 (2)
H43B0.37030.07850.30730.120*0.80 (2)
H43C0.38040.18480.31210.120*0.80 (2)
C440.3282 (11)0.1635 (17)0.2543 (5)0.094 (7)0.80 (2)
H44A0.32520.17190.23310.141*0.80 (2)
H44B0.31360.21790.26380.141*0.80 (2)
H44C0.30330.11160.25940.141*0.80 (2)
S6'0.3876 (12)0.183 (2)0.2793 (5)0.043 (11)0.20 (2)
O22'0.4347 (5)0.2377 (6)0.2630 (2)0.040 (2)0.20 (2)
C43'0.3977 (11)0.1294 (14)0.3043 (4)0.080 (6)0.20 (2)
H43D0.43360.15150.31580.120*0.20 (2)
H43E0.40430.06660.29850.120*0.20 (2)
H43F0.36220.13250.31610.120*0.20 (2)
C44'0.3282 (11)0.1635 (17)0.2543 (5)0.094 (7)0.20 (2)
H44D0.32890.20810.23850.141*0.20 (2)
H44E0.28980.16850.26390.141*0.20 (2)
H44F0.33180.10260.24620.141*0.20 (2)
O10.8358 (5)0.4502 (6)0.4931 (2)0.041 (2)
O20.8421 (5)0.4603 (6)0.4445 (2)0.039 (2)
C170.8513 (7)0.4860 (9)0.4706 (3)0.032 (3)
C180.8906 (5)0.5717 (7)0.4748 (2)0.047 (4)
F10.8779 (7)0.6305 (7)0.4542 (2)0.131 (6)
F20.9470 (4)0.5522 (7)0.4736 (3)0.112 (5)
F30.8830 (5)0.6127 (7)0.4992 (2)0.095 (4)
O30.7305 (5)0.4797 (6)0.5506 (2)0.041 (2)
O40.6765 (5)0.5152 (5)0.5090 (2)0.036 (2)
C190.7088 (6)0.5299 (8)0.5318 (3)0.028 (3)
C200.7266 (5)0.6312 (8)0.5361 (2)0.043 (4)
F40.7642 (7)0.6451 (8)0.5580 (2)0.127 (6)
F50.6781 (5)0.6773 (8)0.5400 (3)0.141 (6)
F60.7498 (6)0.6657 (7)0.5133 (2)0.103 (4)
O50.6034 (5)0.2585 (7)0.5098 (2)0.049 (3)
O60.6144 (5)0.2934 (7)0.5579 (2)0.052 (3)
C210.5864 (7)0.2642 (8)0.5350 (3)0.034 (3)
C220.5244 (6)0.2205 (8)0.5387 (3)0.054 (4)
F70.4820 (7)0.2768 (11)0.5322 (4)0.179 (8)
F80.5152 (7)0.1517 (11)0.5212 (3)0.167 (8)
F90.5180 (6)0.1891 (10)0.5644 (2)0.120 (5)
O70.5077 (6)0.5260 (9)0.3533 (3)0.077 (4)
O80.5634 (6)0.5731 (8)0.3921 (3)0.065 (3)
C230.5306 (8)0.5817 (10)0.3701 (3)0.043 (4)
C240.5156 (5)0.6815 (9)0.3613 (2)0.065 (5)
F100.4639 (4)0.6895 (8)0.3468 (2)0.095 (4)
F110.5150 (7)0.7343 (8)0.3838 (2)0.127 (6)
F120.5571 (5)0.7110 (8)0.3450 (2)0.097 (4)
O90.4691 (6)0.3061 (9)0.3605 (3)0.070 (4)
O100.3852 (5)0.3534 (7)0.3355 (2)0.046 (3)
C250.4143 (7)0.3162 (9)0.3571 (3)0.038 (3)
C260.3771 (5)0.2873 (7)0.3825 (3)0.046 (4)
F130.3775 (7)0.3520 (7)0.4018 (3)0.127 (5)
F140.3994 (5)0.2170 (6)0.3958 (2)0.084 (4)
F150.3218 (5)0.2709 (10)0.3745 (3)0.132 (6)
O110.7035 (5)0.5743 (6)0.3443 (2)0.040 (2)
O120.6556 (5)0.5806 (6)0.2995 (2)0.043 (3)
C270.6845 (6)0.6136 (8)0.3205 (3)0.028 (3)
C280.7020 (5)0.7143 (8)0.3196 (2)0.041 (4)
F160.6700 (5)0.7583 (6)0.3000 (2)0.089 (4)
F170.6965 (5)0.7559 (5)0.34445 (17)0.068 (3)
F180.7586 (4)0.7211 (7)0.3138 (3)0.093 (4)
O130.7485 (5)0.2641 (7)0.3109 (3)0.053 (3)
O140.7372 (5)0.4017 (7)0.2922 (3)0.054 (3)
C290.7647 (7)0.3312 (9)0.2978 (3)0.040 (3)
C300.8298 (6)0.3294 (8)0.2869 (2)0.059 (5)
F190.8502 (6)0.4081 (7)0.2805 (3)0.139 (6)
F200.8288 (6)0.2806 (10)0.2635 (2)0.121 (5)
F210.8688 (4)0.2935 (7)0.3056 (2)0.069 (3)
O150.6403 (5)0.1136 (6)0.3253 (2)0.048 (3)
O160.5505 (5)0.1268 (6)0.3006 (2)0.050 (3)
C310.5912 (7)0.0866 (9)0.3143 (3)0.036 (3)
C320.5811 (5)0.0179 (7)0.3160 (2)0.042 (4)
F220.5981 (5)0.0565 (7)0.2924 (2)0.096 (4)
F230.5249 (4)0.0376 (6)0.3187 (3)0.087 (4)
F240.6119 (5)0.0553 (6)0.3377 (2)0.096 (4)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0249 (5)0.0271 (4)0.0210 (5)0.0101 (4)0.0024 (4)0.0049 (4)
Ag20.0314 (6)0.0283 (5)0.0662 (8)0.0006 (4)0.0080 (6)0.0119 (5)
Ag30.0333 (6)0.0311 (5)0.0237 (5)0.0052 (4)0.0013 (4)0.0109 (4)
Ag40.0348 (6)0.0268 (5)0.0271 (5)0.0032 (4)0.0025 (4)0.0047 (4)
Ag50.0298 (6)0.0360 (5)0.0167 (5)0.0012 (4)0.0073 (4)0.0064 (4)
Ag60.0527 (8)0.0388 (6)0.0246 (6)0.0067 (5)0.0031 (5)0.0005 (4)
Ag70.0317 (6)0.0252 (4)0.0213 (5)0.0052 (4)0.0037 (4)0.0061 (4)
Ag80.0471 (7)0.0270 (5)0.0358 (6)0.0024 (5)0.0100 (5)0.0037 (4)
Ag90.0454 (7)0.0256 (5)0.0365 (6)0.0002 (4)0.0110 (5)0.0009 (4)
Ag100.0369 (6)0.0343 (5)0.0209 (5)0.0023 (4)0.0015 (4)0.0020 (4)
Ag110.0414 (7)0.0674 (8)0.0335 (6)0.0065 (6)0.0010 (5)0.0164 (6)
C10.015 (5)0.024 (5)0.014 (5)0.003 (4)0.002 (4)0.000 (4)
C20.010 (5)0.017 (4)0.015 (5)0.003 (4)0.005 (4)0.008 (4)
C30.016 (6)0.027 (5)0.021 (5)0.004 (4)0.002 (5)0.002 (4)
C40.019 (6)0.023 (5)0.016 (5)0.007 (4)0.004 (4)0.003 (4)
C50.029 (6)0.027 (5)0.013 (5)0.003 (5)0.005 (5)0.008 (4)
C60.018 (6)0.034 (5)0.020 (5)0.005 (5)0.000 (5)0.003 (5)
C70.039 (7)0.029 (6)0.043 (7)0.012 (5)0.002 (6)0.017 (5)
C80.065 (8)0.053 (7)0.058 (8)0.018 (7)0.012 (7)0.018 (6)
C90.045 (8)0.059 (7)0.055 (8)0.028 (6)0.007 (6)0.007 (6)
C100.035 (7)0.042 (6)0.040 (7)0.005 (6)0.001 (6)0.002 (5)
C110.034 (7)0.033 (6)0.030 (6)0.001 (5)0.002 (5)0.001 (5)
C120.029 (6)0.026 (5)0.022 (6)0.003 (5)0.000 (5)0.004 (5)
C130.029 (8)0.024 (6)0.020 (7)0.0000.000 (6)0.000
C140.033 (8)0.027 (7)0.024 (7)0.0000.001 (6)0.000
C150.045 (7)0.033 (6)0.041 (7)0.000 (5)0.001 (6)0.017 (5)
C160.091 (10)0.059 (8)0.083 (9)0.000 (8)0.003 (8)0.011 (7)
S10.077 (4)0.071 (3)0.048 (3)0.026 (3)0.014 (2)0.017 (2)
O170.069 (7)0.067 (6)0.074 (7)0.015 (6)0.015 (6)0.013 (6)
C330.084 (13)0.087 (12)0.081 (13)0.003 (11)0.022 (11)0.008 (10)
C340.076 (13)0.076 (11)0.085 (13)0.022 (10)0.020 (11)0.007 (10)
S20.035 (2)0.073 (3)0.0245 (19)0.0011 (19)0.0019 (16)0.0006 (17)
O180.029 (5)0.041 (4)0.030 (5)0.006 (4)0.001 (4)0.005 (4)
C350.050 (10)0.063 (10)0.101 (13)0.021 (8)0.017 (10)0.021 (9)
C360.059 (11)0.070 (10)0.077 (12)0.009 (9)0.018 (9)0.019 (9)
S30.035 (2)0.0343 (17)0.038 (2)0.0040 (15)0.0066 (17)0.0047 (15)
O190.033 (5)0.031 (4)0.065 (6)0.004 (4)0.003 (5)0.001 (4)
C370.104 (13)0.054 (9)0.048 (9)0.041 (9)0.027 (9)0.003 (7)
C380.037 (8)0.042 (7)0.042 (8)0.009 (6)0.001 (7)0.004 (6)
S40.035 (2)0.048 (2)0.046 (2)0.0058 (17)0.0084 (18)0.0016 (17)
O200.026 (5)0.048 (5)0.028 (5)0.004 (4)0.002 (4)0.006 (4)
C390.043 (10)0.081 (11)0.088 (12)0.013 (9)0.015 (9)0.025 (10)
C400.058 (10)0.043 (8)0.075 (11)0.023 (7)0.029 (9)0.002 (8)
S50.056 (3)0.046 (2)0.035 (2)0.0217 (19)0.0122 (19)0.0084 (16)
O210.048 (6)0.061 (5)0.029 (5)0.021 (5)0.005 (4)0.000 (4)
C410.074 (12)0.064 (10)0.113 (14)0.018 (9)0.021 (11)0.027 (10)
C420.060 (11)0.060 (9)0.056 (10)0.005 (8)0.001 (9)0.008 (8)
S60.068 (4)0.044 (3)0.043 (5)0.013 (3)0.008 (3)0.002 (3)
O220.041 (5)0.039 (4)0.039 (5)0.003 (4)0.002 (4)0.001 (4)
C430.091 (12)0.080 (10)0.070 (10)0.015 (9)0.004 (9)0.014 (9)
C440.088 (12)0.118 (13)0.074 (11)0.021 (10)0.007 (10)0.000 (10)
S6'0.047 (16)0.071 (19)0.010 (11)0.027 (13)0.001 (9)0.007 (11)
O22'0.041 (5)0.039 (4)0.039 (5)0.003 (4)0.002 (4)0.001 (4)
C43'0.091 (12)0.080 (10)0.070 (10)0.015 (9)0.004 (9)0.014 (9)
C44'0.088 (12)0.118 (13)0.074 (11)0.021 (10)0.007 (10)0.000 (10)
O10.054 (6)0.043 (5)0.025 (5)0.026 (4)0.006 (4)0.010 (4)
O20.039 (5)0.045 (5)0.032 (5)0.021 (4)0.007 (4)0.004 (4)
C170.042 (7)0.036 (6)0.019 (6)0.007 (5)0.003 (5)0.000 (5)
C180.050 (8)0.043 (6)0.047 (7)0.015 (6)0.004 (6)0.001 (6)
F10.201 (14)0.070 (7)0.115 (10)0.071 (8)0.036 (10)0.046 (7)
F20.056 (7)0.087 (8)0.195 (13)0.035 (6)0.016 (8)0.043 (8)
F30.112 (9)0.080 (7)0.097 (8)0.072 (7)0.035 (7)0.049 (6)
O30.056 (6)0.029 (4)0.037 (5)0.012 (4)0.003 (5)0.005 (4)
O40.051 (6)0.019 (4)0.036 (5)0.002 (4)0.011 (4)0.005 (3)
C190.033 (6)0.024 (5)0.027 (6)0.003 (5)0.011 (5)0.002 (5)
C200.057 (8)0.034 (6)0.039 (7)0.006 (6)0.006 (6)0.003 (6)
F40.194 (13)0.062 (7)0.118 (10)0.057 (8)0.054 (10)0.005 (7)
F50.144 (12)0.054 (7)0.233 (15)0.009 (7)0.072 (11)0.036 (8)
F60.160 (12)0.059 (6)0.092 (8)0.050 (7)0.029 (8)0.002 (6)
O50.039 (6)0.066 (6)0.042 (5)0.018 (5)0.000 (5)0.010 (5)
O60.040 (6)0.061 (6)0.056 (6)0.011 (5)0.011 (5)0.009 (5)
C210.034 (7)0.030 (6)0.038 (7)0.008 (5)0.013 (6)0.001 (5)
C220.046 (8)0.061 (8)0.056 (8)0.015 (7)0.008 (7)0.003 (7)
F70.074 (9)0.184 (14)0.284 (17)0.021 (10)0.040 (11)0.109 (13)
F80.125 (12)0.205 (14)0.172 (14)0.104 (11)0.020 (10)0.056 (12)
F90.094 (9)0.183 (12)0.084 (8)0.081 (9)0.015 (7)0.028 (8)
O70.075 (7)0.069 (6)0.084 (7)0.020 (6)0.015 (6)0.023 (6)
O80.088 (7)0.056 (6)0.046 (6)0.010 (5)0.021 (6)0.002 (5)
C230.055 (8)0.043 (6)0.033 (7)0.013 (6)0.009 (6)0.007 (6)
C240.070 (9)0.073 (8)0.051 (8)0.022 (7)0.001 (7)0.003 (7)
F100.079 (8)0.121 (9)0.084 (8)0.053 (7)0.005 (7)0.030 (7)
F110.216 (14)0.088 (8)0.074 (8)0.080 (9)0.016 (9)0.027 (6)
F120.095 (9)0.082 (8)0.110 (9)0.006 (7)0.014 (8)0.015 (7)
O90.054 (7)0.078 (7)0.079 (7)0.006 (6)0.007 (6)0.044 (6)
O100.043 (6)0.065 (6)0.030 (5)0.000 (5)0.002 (4)0.015 (4)
C250.030 (7)0.041 (6)0.042 (7)0.003 (5)0.008 (6)0.007 (5)
C260.041 (7)0.046 (7)0.051 (7)0.014 (6)0.010 (6)0.008 (6)
F130.185 (14)0.120 (10)0.084 (9)0.001 (10)0.059 (9)0.006 (8)
F140.097 (9)0.083 (7)0.074 (7)0.021 (6)0.013 (6)0.037 (6)
F150.075 (9)0.230 (14)0.088 (9)0.062 (9)0.007 (7)0.072 (9)
O110.048 (6)0.039 (4)0.031 (5)0.011 (4)0.012 (4)0.014 (4)
O120.057 (6)0.032 (4)0.039 (5)0.004 (4)0.011 (5)0.001 (4)
C270.031 (6)0.025 (5)0.029 (6)0.006 (5)0.003 (5)0.004 (5)
C280.043 (7)0.045 (6)0.035 (7)0.003 (6)0.004 (6)0.011 (6)
F160.133 (10)0.048 (5)0.079 (7)0.024 (6)0.056 (7)0.036 (5)
F170.103 (8)0.033 (4)0.067 (6)0.008 (5)0.001 (6)0.010 (4)
F180.074 (8)0.075 (7)0.133 (10)0.028 (6)0.045 (7)0.004 (7)
O130.054 (6)0.046 (5)0.061 (6)0.008 (5)0.017 (5)0.003 (5)
O140.048 (6)0.047 (5)0.069 (6)0.006 (5)0.006 (5)0.012 (5)
C290.044 (7)0.039 (6)0.037 (7)0.007 (6)0.008 (6)0.005 (5)
C300.066 (9)0.060 (8)0.051 (8)0.004 (7)0.011 (7)0.010 (7)
F190.078 (9)0.124 (10)0.222 (15)0.001 (8)0.060 (10)0.066 (10)
F200.087 (9)0.220 (14)0.059 (7)0.026 (9)0.027 (7)0.029 (9)
F210.038 (6)0.092 (7)0.076 (7)0.010 (5)0.001 (5)0.018 (6)
O150.055 (6)0.031 (4)0.058 (6)0.002 (4)0.009 (5)0.005 (4)
O160.058 (6)0.038 (5)0.053 (6)0.001 (5)0.009 (5)0.004 (4)
C310.040 (7)0.025 (5)0.043 (7)0.002 (5)0.005 (6)0.002 (5)
C320.039 (7)0.032 (6)0.055 (8)0.003 (6)0.010 (6)0.000 (6)
F220.143 (11)0.043 (5)0.102 (9)0.001 (6)0.005 (8)0.035 (6)
F230.072 (8)0.048 (5)0.140 (10)0.016 (5)0.004 (7)0.025 (6)
F240.124 (10)0.039 (5)0.116 (9)0.014 (6)0.063 (8)0.025 (5)
Geometric parameters (Å, º) top
Ag1—O12.228 (9)C33—H33C0.9800
Ag1—C12.277 (11)C34—H34A0.9800
Ag1—C1i2.478 (11)C34—H34B0.9800
Ag1—O5i2.594 (11)C34—H34C0.9800
Ag1—Ag1i2.7796 (18)S2—O181.509 (10)
Ag1—Ag42.8863 (15)S2—C351.772 (17)
Ag1—Ag32.9366 (13)S2—C361.806 (19)
Ag1—Ag23.0012 (14)C35—H35A0.9800
Ag1—Ag4i3.2113 (13)C35—H35B0.9800
Ag2—O6i2.268 (11)C35—H35C0.9800
Ag2—O3i2.272 (9)C36—H36A0.9800
Ag2—C12.343 (11)C36—H36B0.9800
Ag2—O172.514 (13)C36—H36C0.9800
Ag2—C22.678 (11)S3—O191.536 (9)
Ag2—Ag33.0265 (14)S3—C371.760 (16)
Ag2—Ag4i3.3140 (17)S3—C381.775 (14)
Ag3—O182.324 (9)C37—H37A0.9800
Ag3—O22.327 (9)C37—H37B0.9800
Ag3—C12.371 (11)C37—H37C0.9800
Ag3—O192.465 (10)C38—H38A0.9800
Ag4—O42.227 (8)C38—H38B0.9800
Ag4—C12.294 (11)C38—H38C0.9800
Ag4—O202.489 (9)S4—O201.497 (10)
Ag4—O52.572 (10)S4—C401.798 (15)
Ag4—Ag1i3.2113 (13)S4—C391.806 (18)
Ag4—Ag2i3.3141 (16)C39—H39A0.9800
Ag5—C112.253 (13)C39—H39B0.9800
Ag5—C52.253 (12)C39—H39C0.9800
Ag5—O92.381 (12)C40—H40A0.9800
Ag5—O72.407 (12)C40—H40B0.9800
Ag5—Ag72.8597 (14)C40—H40C0.9800
Ag5—Ag92.8776 (14)S5—O211.516 (10)
Ag5—Ag102.9849 (15)S5—C421.745 (18)
Ag5—Ag83.0235 (15)S5—C411.80 (2)
Ag5—Ag113.2766 (15)O21—Ag10ii2.595 (10)
Ag5—Ag63.3611 (14)C41—H41A0.9800
Ag6—O82.260 (11)C41—H41B0.9800
Ag6—O202.334 (9)C41—H41C0.9800
Ag6—C52.363 (11)C42—H42A0.9800
Ag6—O192.419 (10)C42—H42B0.9800
Ag6—C42.518 (11)C42—H42C0.9800
Ag6—Ag72.9412 (15)S6—O221.546 (11)
Ag7—O112.158 (9)S6—C431.77 (2)
Ag7—C52.172 (12)S6—C441.82 (2)
Ag7—O182.416 (9)O22—Ag9ii2.492 (10)
Ag7—Ag82.8699 (13)C43—H43A0.9800
Ag7—Ag103.0080 (14)C43—H43B0.9800
Ag8—O132.263 (11)C43—H43C0.9800
Ag8—C52.271 (12)C44—H44A0.9800
Ag8—O152.335 (9)C44—H44B0.9800
Ag8—Ag103.0069 (14)C44—H44C0.9800
Ag8—Ag93.1693 (16)O1—C171.230 (15)
Ag9—C112.175 (13)O2—C171.257 (15)
Ag9—O162.193 (10)C17—C181.541 (17)
Ag9—O22'ii2.492 (10)C18—F21.283 (9)
Ag9—O22ii2.492 (10)C18—F31.291 (9)
Ag9—Ag102.9894 (15)C18—F11.301 (9)
Ag9—Ag113.0545 (17)O3—C191.216 (15)
Ag10—O142.232 (11)O3—Ag2i2.272 (9)
Ag10—C112.231 (14)O4—C191.246 (15)
Ag10—O122.377 (9)C19—C201.559 (16)
Ag10—O21ii2.595 (10)C20—F41.281 (9)
Ag11—O102.263 (10)C20—F51.291 (9)
Ag11—O212.330 (10)C20—F61.298 (9)
Ag11—C112.359 (14)O5—C211.240 (17)
Ag11—C122.510 (13)O5—Ag1i2.594 (11)
Ag11—O222.555 (9)O6—C211.263 (17)
C1—C21.226 (15)O6—Ag2i2.268 (11)
C1—Ag1i2.478 (11)C21—C221.532 (19)
C2—C31.428 (16)C22—F71.273 (9)
C3—C61.341 (16)C22—F91.282 (9)
C3—C41.472 (15)C22—F81.303 (9)
C4—C51.216 (16)O7—C231.217 (19)
C6—C71.489 (17)O8—C231.212 (18)
C6—C101.534 (17)C23—C241.56 (2)
C7—C81.51 (2)C24—F101.291 (9)
C7—H7A0.9900C24—F111.293 (9)
C7—H7B0.9900C24—F121.295 (10)
C8—C91.50 (2)O9—C251.218 (18)
C8—H8A0.9900O10—C251.270 (16)
C8—H8B0.9900C25—C261.53 (2)
C9—C101.53 (2)C26—F151.276 (9)
C9—H9A0.9900C26—F141.290 (9)
C9—H9B0.9900C26—F131.304 (9)
C10—H10A0.9900O11—C271.288 (15)
C10—H10B0.9900O12—C271.223 (15)
C11—C121.208 (17)C27—C281.540 (16)
C12—C131.432 (15)C28—F161.287 (9)
C13—C141.37 (2)C28—F181.297 (9)
C13—C12ii1.432 (15)C28—F171.306 (9)
C14—C15ii1.500 (15)O13—C291.226 (17)
C14—C151.500 (15)O14—C291.226 (17)
C15—C161.52 (2)C29—C301.55 (2)
C15—H15A0.9900C30—F191.289 (9)
C15—H15B0.9900C30—F211.292 (9)
C16—C16ii1.33 (4)C30—F201.293 (9)
C16—H16A0.9900O15—C311.234 (17)
C16—H16B0.9900O16—C311.219 (17)
S1—O171.490 (14)C31—C321.564 (16)
S1—C331.75 (2)C32—F231.288 (9)
S1—C341.76 (2)C32—F241.292 (9)
C33—H33A0.9800C32—F221.300 (9)
C33—H33B0.9800
O1—Ag1—C1129.1 (4)Ag1—C1—Ag478.3 (3)
O1—Ag1—C1i116.2 (3)C2—C1—Ag291.8 (8)
C1—Ag1—C1i108.6 (3)Ag1—C1—Ag281.0 (4)
O1—Ag1—O5i88.4 (4)Ag4—C1—Ag2159.2 (5)
C1—Ag1—O5i121.3 (4)C2—C1—Ag392.7 (7)
C1i—Ag1—O5i82.3 (4)Ag1—C1—Ag378.4 (3)
O1—Ag1—Ag1i155.5 (3)Ag4—C1—Ag393.6 (4)
C1—Ag1—Ag1i57.7 (3)Ag2—C1—Ag379.9 (4)
C1i—Ag1—Ag1i50.9 (3)C2—C1—Ag1i116.9 (8)
O5i—Ag1—Ag1i107.8 (2)Ag1—C1—Ag1i71.4 (3)
O1—Ag1—Ag496.9 (3)Ag4—C1—Ag1i84.5 (4)
C1—Ag1—Ag451.1 (3)Ag2—C1—Ag1i91.1 (4)
C1i—Ag1—Ag4100.1 (3)Ag3—C1—Ag1i149.5 (5)
O5i—Ag1—Ag4172.3 (2)C1—C2—C3178.2 (12)
Ag1i—Ag1—Ag469.02 (4)C1—C2—Ag261.0 (7)
O1—Ag1—Ag382.8 (2)C3—C2—Ag2120.8 (8)
C1—Ag1—Ag352.2 (3)C6—C3—C2125.4 (10)
C1i—Ag1—Ag3160.5 (3)C6—C3—C4121.2 (10)
O5i—Ag1—Ag3103.9 (2)C2—C3—C4113.3 (10)
Ag1i—Ag1—Ag3109.79 (5)C5—C4—C3176.5 (13)
Ag4—Ag1—Ag371.47 (4)C5—C4—Ag668.6 (7)
O1—Ag1—Ag2130.8 (3)C3—C4—Ag6114.6 (8)
C1—Ag1—Ag250.5 (3)C4—C5—Ag7137.2 (10)
C1i—Ag1—Ag2104.9 (3)C4—C5—Ag5139.9 (10)
O5i—Ag1—Ag270.8 (2)Ag7—C5—Ag580.5 (4)
Ag1i—Ag1—Ag273.00 (4)C4—C5—Ag8111.1 (9)
Ag4—Ag1—Ag2101.52 (4)Ag7—C5—Ag880.5 (4)
Ag3—Ag1—Ag261.28 (4)Ag5—C5—Ag883.9 (4)
O1—Ag1—Ag4i132.8 (3)C4—C5—Ag682.8 (8)
C1—Ag1—Ag4i95.8 (3)Ag7—C5—Ag680.8 (4)
C1i—Ag1—Ag4i45.3 (3)Ag5—C5—Ag693.4 (4)
O5i—Ag1—Ag4i51.3 (2)Ag8—C5—Ag6161.2 (6)
Ag1i—Ag1—Ag4i57.06 (4)C3—C6—C7126.4 (11)
Ag4—Ag1—Ag4i126.08 (3)C3—C6—C10124.8 (11)
Ag3—Ag1—Ag4i125.35 (4)C7—C6—C10108.7 (11)
Ag2—Ag1—Ag4i64.37 (3)C6—C7—C8105.2 (12)
O6i—Ag2—O3i113.2 (4)C6—C7—H7A110.7
O6i—Ag2—C1126.2 (4)C8—C7—H7A110.7
O3i—Ag2—C1116.6 (4)C6—C7—H7B110.7
O6i—Ag2—O1793.1 (4)C8—C7—H7B110.7
O3i—Ag2—O1794.7 (4)H7A—C7—H7B108.8
C1—Ag2—O17101.6 (4)C9—C8—C7103.5 (13)
O6i—Ag2—C2142.7 (4)C9—C8—H8A111.1
O3i—Ag2—C2103.7 (3)C7—C8—H8A111.1
C1—Ag2—C227.2 (4)C9—C8—H8B111.1
O17—Ag2—C279.0 (4)C7—C8—H8B111.1
O6i—Ag2—Ag184.0 (3)H8A—C8—H8B109.0
O3i—Ag2—Ag1129.9 (3)C8—C9—C10105.6 (12)
C1—Ag2—Ag148.5 (3)C8—C9—H9A110.6
O17—Ag2—Ag1132.5 (3)C10—C9—H9A110.6
C2—Ag2—Ag175.6 (2)C8—C9—H9B110.6
O6i—Ag2—Ag386.2 (3)C10—C9—H9B110.6
O3i—Ag2—Ag3158.5 (3)H9A—C9—H9B108.7
C1—Ag2—Ag350.5 (3)C9—C10—C6103.4 (11)
O17—Ag2—Ag374.2 (3)C9—C10—H10A111.1
C2—Ag2—Ag356.6 (2)C6—C10—H10A111.1
Ag1—Ag2—Ag358.31 (3)C9—C10—H10B111.1
O6i—Ag2—Ag4i82.7 (3)C6—C10—H10B111.1
O3i—Ag2—Ag4i74.7 (2)H10A—C10—H10B109.0
C1—Ag2—Ag4i91.9 (3)C12—C11—Ag9132.8 (11)
O17—Ag2—Ag4i165.7 (3)C12—C11—Ag10107.5 (11)
C2—Ag2—Ag4i112.5 (2)Ag9—C11—Ag1085.4 (5)
Ag1—Ag2—Ag4i60.89 (3)C12—C11—Ag5144.1 (11)
Ag3—Ag2—Ag4i118.94 (4)Ag9—C11—Ag581.0 (4)
O18—Ag3—O289.9 (3)Ag10—C11—Ag583.5 (5)
O18—Ag3—C1144.2 (3)C12—C11—Ag1182.7 (9)
O2—Ag3—C1125.5 (3)Ag9—C11—Ag1184.6 (5)
O18—Ag3—O1988.2 (3)Ag10—C11—Ag11169.0 (6)
O2—Ag3—O1991.7 (3)Ag5—C11—Ag1190.5 (5)
C1—Ag3—O1995.0 (4)C11—C12—C13166.7 (13)
O18—Ag3—Ag1162.6 (2)C11—C12—Ag1168.8 (9)
O2—Ag3—Ag176.4 (2)C13—C12—Ag11114.0 (7)
C1—Ag3—Ag149.4 (3)C14—C13—C12123.2 (7)
O19—Ag3—Ag1102.7 (3)C14—C13—C12ii123.2 (7)
O18—Ag3—Ag2117.1 (2)C12—C13—C12ii113.5 (14)
O2—Ag3—Ag2111.8 (3)C13—C14—C15ii124.0 (8)
C1—Ag3—Ag249.7 (3)C13—C14—C15124.0 (8)
O19—Ag3—Ag2144.4 (2)C15ii—C14—C15111.9 (16)
Ag1—Ag3—Ag260.42 (3)C14—C15—C16101.5 (13)
O4—Ag4—C1148.8 (4)C14—C15—H15A111.5
O4—Ag4—O2094.7 (3)C16—C15—H15A111.5
C1—Ag4—O20106.4 (4)C14—C15—H15B111.5
O4—Ag4—O5118.4 (4)C16—C15—H15B111.5
C1—Ag4—O586.5 (4)H15A—C15—H15B109.3
O20—Ag4—O585.5 (3)C16ii—C16—C15112.3 (9)
O4—Ag4—Ag1101.8 (3)C16ii—C16—H16A109.1
C1—Ag4—Ag150.6 (3)C15—C16—H16A109.1
O20—Ag4—Ag1152.5 (2)C16ii—C16—H16B109.1
O5—Ag4—Ag1105.3 (3)C15—C16—H16B109.1
O4—Ag4—Ag1i130.1 (2)H16A—C16—H16B107.9
C1—Ag4—Ag1i50.2 (3)O17—S1—C33105.9 (10)
O20—Ag4—Ag1i127.3 (2)O17—S1—C34105.7 (9)
O5—Ag4—Ag1i51.9 (3)C33—S1—C3498.7 (10)
Ag1—Ag4—Ag1i53.92 (3)S1—O17—Ag2124.1 (7)
O4—Ag4—Ag2i76.2 (2)S1—C33—H33A109.5
C1—Ag4—Ag2i100.3 (3)S1—C33—H33B109.5
O20—Ag4—Ag2i139.2 (2)H33A—C33—H33B109.5
O5—Ag4—Ag2i65.8 (2)S1—C33—H33C109.5
Ag1—Ag4—Ag2i67.06 (3)H33A—C33—H33C109.5
Ag1i—Ag4—Ag2i54.74 (3)H33B—C33—H33C109.5
C11—Ag5—C5142.8 (5)S1—C34—H34A109.5
C11—Ag5—O9114.3 (5)S1—C34—H34B109.5
C5—Ag5—O993.9 (4)H34A—C34—H34B109.5
C11—Ag5—O790.9 (5)S1—C34—H34C109.5
C5—Ag5—O7113.9 (4)H34A—C34—H34C109.5
O9—Ag5—O789.9 (5)H34B—C34—H34C109.5
C11—Ag5—Ag7107.0 (4)O18—S2—C35105.3 (8)
C5—Ag5—Ag748.5 (3)O18—S2—C36104.4 (8)
O9—Ag5—Ag7138.6 (3)C35—S2—C3697.4 (10)
O7—Ag5—Ag791.4 (3)S2—O18—Ag3129.8 (5)
C11—Ag5—Ag948.3 (3)S2—O18—Ag7118.5 (5)
C5—Ag5—Ag9109.6 (3)Ag3—O18—Ag7111.6 (4)
O9—Ag5—Ag993.3 (4)S2—C35—H35A109.5
O7—Ag5—Ag9136.1 (3)S2—C35—H35B109.5
Ag7—Ag5—Ag9113.39 (5)H35A—C35—H35B109.5
C11—Ag5—Ag1048.0 (4)S2—C35—H35C109.5
C5—Ag5—Ag1096.8 (3)H35A—C35—H35C109.5
O9—Ag5—Ag10154.5 (4)H35B—C35—H35C109.5
O7—Ag5—Ag10106.7 (4)S2—C36—H36A109.5
Ag7—Ag5—Ag1061.91 (4)S2—C36—H36B109.5
Ag9—Ag5—Ag1061.28 (4)H36A—C36—H36B109.5
C11—Ag5—Ag896.5 (4)S2—C36—H36C109.5
C5—Ag5—Ag848.3 (3)H36A—C36—H36C109.5
O9—Ag5—Ag8113.2 (3)H36B—C36—H36C109.5
O7—Ag5—Ag8149.7 (3)O19—S3—C37104.1 (7)
Ag7—Ag5—Ag858.31 (3)O19—S3—C38104.3 (6)
Ag9—Ag5—Ag864.91 (4)C37—S3—C3899.4 (9)
Ag10—Ag5—Ag860.05 (3)S3—O19—Ag6132.5 (6)
C11—Ag5—Ag1146.1 (4)S3—O19—Ag3121.5 (5)
C5—Ag5—Ag11157.7 (3)Ag6—O19—Ag3103.5 (3)
O9—Ag5—Ag1169.3 (3)S3—C37—H37A109.5
O7—Ag5—Ag1181.6 (3)S3—C37—H37B109.5
Ag7—Ag5—Ag11151.55 (4)H37A—C37—H37B109.5
Ag9—Ag5—Ag1159.09 (4)S3—C37—H37C109.5
Ag10—Ag5—Ag1193.63 (4)H37A—C37—H37C109.5
Ag8—Ag5—Ag11123.95 (4)H37B—C37—H37C109.5
C11—Ag5—Ag6152.4 (3)S3—C38—H38A109.5
C5—Ag5—Ag644.6 (3)S3—C38—H38B109.5
O9—Ag5—Ag686.3 (3)H38A—C38—H38B109.5
O7—Ag5—Ag670.0 (3)S3—C38—H38C109.5
Ag7—Ag5—Ag655.73 (3)H38A—C38—H38C109.5
Ag9—Ag5—Ag6153.95 (4)H38B—C38—H38C109.5
Ag10—Ag5—Ag6117.25 (4)O20—S4—C40106.0 (8)
Ag8—Ag5—Ag691.30 (4)O20—S4—C39103.9 (7)
Ag11—Ag5—Ag6142.51 (5)C40—S4—C3999.0 (9)
O8—Ag6—O20109.5 (4)S4—O20—Ag6129.3 (5)
O8—Ag6—C5115.9 (4)S4—O20—Ag4120.4 (5)
O20—Ag6—C5132.0 (4)Ag6—O20—Ag4106.7 (4)
O8—Ag6—O1996.7 (4)S4—C39—H39A109.5
O20—Ag6—O1978.6 (3)S4—C39—H39B109.5
C5—Ag6—O19110.0 (4)H39A—C39—H39B109.5
O8—Ag6—C4144.0 (4)S4—C39—H39C109.5
O20—Ag6—C4103.8 (3)H39A—C39—H39C109.5
C5—Ag6—C428.6 (4)H39B—C39—H39C109.5
O19—Ag6—C4103.2 (3)S4—C40—H40A109.5
O8—Ag6—Ag782.4 (3)S4—C40—H40B109.5
O20—Ag6—Ag7159.4 (2)H40A—C40—H40B109.5
C5—Ag6—Ag746.8 (3)S4—C40—H40C109.5
O19—Ag6—Ag783.5 (3)H40A—C40—H40C109.5
C4—Ag6—Ag770.6 (3)H40B—C40—H40C109.5
O8—Ag6—Ag578.9 (3)O21—S5—C42107.2 (8)
O20—Ag6—Ag5143.6 (2)O21—S5—C41102.8 (9)
C5—Ag6—Ag542.0 (3)C42—S5—C4196.5 (10)
O19—Ag6—Ag5137.0 (3)S5—O21—Ag11123.7 (6)
C4—Ag6—Ag566.0 (2)S5—O21—Ag10ii112.5 (5)
Ag7—Ag6—Ag553.47 (3)Ag11—O21—Ag10ii121.0 (4)
O11—Ag7—C5168.6 (4)S5—C41—H41A109.5
O11—Ag7—O1890.8 (3)S5—C41—H41B109.5
C5—Ag7—O1898.2 (4)H41A—C41—H41B109.5
O11—Ag7—Ag5121.1 (3)S5—C41—H41C109.5
C5—Ag7—Ag551.0 (3)H41A—C41—H41C109.5
O18—Ag7—Ag5147.8 (2)H41B—C41—H41C109.5
O11—Ag7—Ag8136.2 (3)S5—C42—H42A109.5
C5—Ag7—Ag851.3 (3)S5—C42—H42B109.5
O18—Ag7—Ag890.6 (2)H42A—C42—H42B109.5
Ag5—Ag7—Ag863.70 (4)S5—C42—H42C109.5
O11—Ag7—Ag6119.2 (3)H42A—C42—H42C109.5
C5—Ag7—Ag652.5 (3)H42B—C42—H42C109.5
O18—Ag7—Ag699.3 (2)O22—S6—C43106.0 (9)
Ag5—Ag7—Ag670.80 (4)O22—S6—C44101.3 (9)
Ag8—Ag7—Ag6103.75 (4)C43—S6—C4499.2 (12)
O11—Ag7—Ag1082.5 (2)S6—O22—Ag9ii111.3 (6)
C5—Ag7—Ag1097.9 (3)S6—O22—Ag11132.2 (7)
O18—Ag7—Ag10125.0 (2)Ag9ii—O22—Ag11112.4 (3)
Ag5—Ag7—Ag1061.09 (3)S6—C43—H43A109.5
Ag8—Ag7—Ag1061.48 (3)S6—C43—H43B109.5
Ag6—Ag7—Ag10131.38 (5)H43A—C43—H43B109.5
O13—Ag8—C5141.1 (4)S6—C43—H43C109.5
O13—Ag8—O1593.9 (4)H43A—C43—H43C109.5
C5—Ag8—O15117.7 (4)H43B—C43—H43C109.5
O13—Ag8—Ag798.9 (3)S6—C44—H44A109.5
C5—Ag8—Ag748.3 (3)S6—C44—H44B109.5
O15—Ag8—Ag7166.0 (3)H44A—C44—H44B109.5
O13—Ag8—Ag1080.4 (3)S6—C44—H44C109.5
C5—Ag8—Ag1095.8 (3)H44A—C44—H44C109.5
O15—Ag8—Ag10127.0 (3)H44B—C44—H44C109.5
Ag7—Ag8—Ag1061.52 (3)C17—O1—Ag1120.3 (8)
O13—Ag8—Ag5139.2 (3)C17—O2—Ag3121.4 (9)
C5—Ag8—Ag547.8 (3)O1—C17—O2129.1 (12)
O15—Ag8—Ag5114.5 (3)O1—C17—C18115.5 (11)
Ag7—Ag8—Ag557.99 (3)O2—C17—C18115.3 (11)
Ag10—Ag8—Ag559.34 (3)F2—C18—F3108.6 (9)
O13—Ag8—Ag9109.8 (3)F2—C18—F1106.6 (9)
C5—Ag8—Ag9100.1 (3)F3—C18—F1106.3 (9)
O15—Ag8—Ag975.8 (3)F2—C18—C17110.4 (10)
Ag7—Ag8—Ag9105.01 (4)F3—C18—C17113.3 (10)
Ag10—Ag8—Ag957.83 (3)F1—C18—C17111.4 (10)
Ag5—Ag8—Ag955.32 (3)C19—O3—Ag2i126.7 (8)
C11—Ag9—O16161.0 (5)C19—O4—Ag4125.0 (8)
C11—Ag9—O22'ii106.7 (4)O3—C19—O4132.0 (11)
O16—Ag9—O22'ii92.1 (4)O3—C19—C20114.4 (11)
C11—Ag9—O22ii106.7 (4)O4—C19—C20113.6 (10)
O16—Ag9—O22ii92.1 (4)F4—C20—F5108.0 (9)
C11—Ag9—Ag550.7 (3)F4—C20—F6107.5 (9)
O16—Ag9—Ag5111.6 (3)F5—C20—F6106.1 (9)
O22'ii—Ag9—Ag5154.1 (2)F4—C20—C19113.5 (10)
O22ii—Ag9—Ag5154.1 (2)F5—C20—C19108.8 (10)
C11—Ag9—Ag1048.1 (4)F6—C20—C19112.6 (10)
O16—Ag9—Ag10135.0 (3)C21—O5—Ag4122.7 (9)
O22'ii—Ag9—Ag1094.9 (2)C21—O5—Ag1i112.0 (9)
O22ii—Ag9—Ag1094.9 (2)Ag4—O5—Ag1i76.9 (3)
Ag5—Ag9—Ag1061.13 (3)C21—O6—Ag2i116.7 (9)
C11—Ag9—Ag1150.3 (4)O5—C21—O6129.7 (14)
O16—Ag9—Ag11120.5 (3)O5—C21—C22113.4 (12)
O22'ii—Ag9—Ag11110.5 (2)O6—C21—C22116.6 (12)
O22ii—Ag9—Ag11110.5 (2)F7—C22—F9109.3 (10)
Ag5—Ag9—Ag1166.98 (4)F7—C22—F8106.4 (10)
Ag10—Ag9—Ag1198.24 (4)F9—C22—F8105.1 (9)
C11—Ag9—Ag894.1 (4)F7—C22—C21110.3 (12)
O16—Ag9—Ag879.2 (3)F9—C22—C21113.8 (11)
O22'ii—Ag9—Ag8118.0 (2)F8—C22—C21111.6 (12)
O22ii—Ag9—Ag8118.0 (2)C23—O7—Ag5126.4 (11)
Ag5—Ag9—Ag859.77 (3)C23—O8—Ag6123.3 (10)
Ag10—Ag9—Ag858.36 (3)O8—C23—O7131.3 (15)
Ag11—Ag9—Ag8126.70 (5)O8—C23—C24114.9 (13)
O14—Ag10—C11168.5 (4)O7—C23—C24113.8 (14)
O14—Ag10—O1288.9 (4)F10—C24—F11107.6 (9)
C11—Ag10—O12102.1 (4)F10—C24—F12107.8 (9)
O14—Ag10—O21ii81.1 (4)F11—C24—F12107.4 (10)
C11—Ag10—O21ii95.2 (4)F10—C24—C23112.7 (12)
O12—Ag10—O21ii90.5 (3)F11—C24—C23112.2 (11)
O14—Ag10—Ag5132.5 (3)F12—C24—C23108.9 (11)
C11—Ag10—Ag548.6 (3)C25—O9—Ag5131.7 (10)
O12—Ag10—Ag5103.4 (3)C25—O10—Ag11119.7 (10)
O21ii—Ag10—Ag5142.9 (2)O9—C25—O10127.2 (15)
O14—Ag10—Ag9122.5 (3)O9—C25—C26116.3 (12)
C11—Ag10—Ag946.5 (3)O10—C25—C26116.3 (12)
O12—Ag10—Ag9148.6 (3)F15—C26—F14108.2 (9)
O21ii—Ag10—Ag993.3 (2)F15—C26—F13107.5 (10)
Ag5—Ag10—Ag957.59 (3)F14—C26—F13106.4 (9)
O14—Ag10—Ag877.2 (3)F15—C26—C25112.7 (11)
C11—Ag10—Ag897.5 (3)F14—C26—C25112.4 (11)
O12—Ag10—Ag8132.4 (2)F13—C26—C25109.3 (11)
O21ii—Ag10—Ag8130.5 (2)C27—O11—Ag7123.8 (8)
Ag5—Ag10—Ag860.61 (3)C27—O12—Ag10123.2 (8)
Ag9—Ag10—Ag863.81 (4)O12—C27—O11128.0 (11)
O14—Ag10—Ag782.9 (3)O12—C27—C28119.1 (11)
C11—Ag10—Ag7102.9 (3)O11—C27—C28112.9 (10)
O12—Ag10—Ag776.4 (2)F16—C28—F18108.1 (9)
O21ii—Ag10—Ag7159.4 (2)F16—C28—F17107.2 (9)
Ag5—Ag10—Ag757.00 (3)F18—C28—F17106.6 (9)
Ag9—Ag10—Ag7106.17 (4)F16—C28—C27112.2 (9)
Ag8—Ag10—Ag757.00 (3)F18—C28—C27109.0 (10)
O10—Ag11—O21103.8 (4)F17—C28—C27113.4 (9)
O10—Ag11—C11124.3 (4)C29—O13—Ag8120.6 (10)
O21—Ag11—C11125.4 (4)C29—O14—Ag10126.0 (11)
O10—Ag11—C12141.1 (4)O13—C29—O14129.6 (16)
O21—Ag11—C1297.4 (4)O13—C29—C30116.5 (12)
C11—Ag11—C1228.5 (4)O14—C29—C30113.9 (13)
O10—Ag11—O22110.2 (4)F19—C30—F21107.2 (10)
O21—Ag11—O2288.5 (3)F19—C30—F20107.6 (10)
C11—Ag11—O2296.5 (4)F21—C30—F20107.4 (9)
C12—Ag11—O22102.5 (4)F19—C30—C29113.6 (11)
O10—Ag11—Ag9113.3 (3)F21—C30—C29112.8 (10)
O21—Ag11—Ag9136.3 (2)F20—C30—C29107.9 (11)
C11—Ag11—Ag945.1 (3)C31—O15—Ag8123.5 (9)
C12—Ag11—Ag967.5 (3)C31—O16—Ag9127.1 (10)
O22—Ag11—Ag958.1 (2)O16—C31—O15130.8 (13)
O10—Ag11—Ag581.3 (3)O16—C31—C32113.9 (12)
O21—Ag11—Ag5159.0 (3)O15—C31—C32115.0 (11)
C11—Ag11—Ag543.4 (3)F23—C32—F24107.0 (9)
C12—Ag11—Ag568.3 (3)F23—C32—F22108.0 (9)
O22—Ag11—Ag5109.2 (2)F24—C32—F22106.8 (9)
Ag9—Ag11—Ag553.93 (3)F23—C32—C31111.7 (10)
C2—C1—Ag1169.3 (10)F24—C32—C31113.1 (10)
C2—C1—Ag4108.4 (8)F22—C32—C31110.1 (10)
Ag1—C1—C2—Ag247 (5)Ag2i—O3—C19—O46 (2)
Ag4—C1—C2—Ag2174.7 (8)Ag2i—O3—C19—C20176.9 (8)
Ag3—C1—C2—Ag280.0 (4)Ag4—O4—C19—O319 (2)
Ag1i—C1—C2—Ag292.1 (7)Ag4—O4—C19—C20157.9 (8)
Ag2—C2—C3—C675.6 (14)O3—C19—C20—F43.7 (16)
Ag2—C2—C3—C4100.8 (10)O4—C19—C20—F4174.0 (12)
C6—C3—C4—Ag6126.4 (11)O3—C19—C20—F5116.5 (13)
C2—C3—C4—Ag657.0 (12)O4—C19—C20—F565.8 (14)
Ag6—C4—C5—Ag768.0 (12)O3—C19—C20—F6126.2 (13)
Ag6—C4—C5—Ag586.8 (13)O4—C19—C20—F651.5 (15)
Ag6—C4—C5—Ag8166.9 (8)Ag4—O5—C21—O640 (2)
C2—C3—C6—C70 (2)Ag1i—O5—C21—O648.3 (18)
C4—C3—C6—C7176.1 (13)Ag4—O5—C21—C22146.6 (9)
C2—C3—C6—C10178.6 (12)Ag1i—O5—C21—C22125.2 (10)
C4—C3—C6—C102 (2)Ag2i—O6—C21—O57 (2)
C3—C6—C7—C8162.1 (14)Ag2i—O6—C21—C22166.6 (9)
C10—C6—C7—C816.6 (16)O5—C21—C22—F786.7 (15)
C6—C7—C8—C932.9 (18)O6—C21—C22—F798.9 (15)
C7—C8—C9—C1037.2 (19)O5—C21—C22—F9150.1 (13)
C8—C9—C10—C626.6 (18)O6—C21—C22—F924.3 (17)
C3—C6—C10—C9175.3 (14)O5—C21—C22—F831.4 (16)
C7—C6—C10—C96.0 (16)O6—C21—C22—F8143.0 (14)
Ag9—C11—C12—C1329 (7)Ag6—O8—C23—O71 (3)
Ag10—C11—C12—C1371 (6)Ag6—O8—C23—C24177.5 (9)
Ag5—C11—C12—C13175 (4)Ag5—O7—C23—O833 (3)
Ag11—C11—C12—C13105 (6)Ag5—O7—C23—C24145.4 (11)
Ag9—C11—C12—Ag1175.6 (13)O8—C23—C24—F10152.3 (14)
Ag10—C11—C12—Ag11175.9 (8)O7—C23—C24—F1028.7 (18)
Ag5—C11—C12—Ag1180.7 (18)O8—C23—C24—F1130.5 (19)
C11—C12—C13—C14146 (6)O7—C23—C24—F11150.4 (14)
Ag11—C12—C13—C14114.6 (5)O8—C23—C24—F1288.2 (16)
C11—C12—C13—C12ii34 (6)O7—C23—C24—F1290.8 (16)
Ag11—C12—C13—C12ii65.4 (5)Ag5—O9—C25—O1022 (3)
C12—C13—C14—C15ii179.9 (10)Ag5—O9—C25—C26152.7 (10)
C12ii—C13—C14—C15ii0.1 (10)Ag11—O10—C25—O914 (2)
C12—C13—C14—C150.1 (10)Ag11—O10—C25—C26171.3 (8)
C12ii—C13—C14—C15179.9 (10)O9—C25—C26—F15158.1 (14)
C13—C14—C15—C16178.2 (10)O10—C25—C26—F1526.4 (17)
C15ii—C14—C15—C161.8 (10)O9—C25—C26—F1435.4 (17)
C14—C15—C16—C16ii6 (3)O10—C25—C26—F14149.0 (12)
C33—S1—O17—Ag269.1 (11)O9—C25—C26—F1382.5 (16)
C34—S1—O17—Ag235.0 (12)O10—C25—C26—F1393.1 (14)
C35—S2—O18—Ag318.1 (10)Ag10—O12—C27—O119 (2)
C36—S2—O18—Ag383.9 (9)Ag10—O12—C27—C28170.9 (8)
C35—S2—O18—Ag7158.2 (8)Ag7—O11—C27—O1216 (2)
C36—S2—O18—Ag799.7 (8)Ag7—O11—C27—C28164.3 (8)
C37—S3—O19—Ag669.0 (11)O12—C27—C28—F1617.8 (16)
C38—S3—O19—Ag634.8 (10)O11—C27—C28—F16162.5 (11)
C37—S3—O19—Ag389.8 (10)O12—C27—C28—F18101.9 (14)
C38—S3—O19—Ag3166.4 (7)O11—C27—C28—F1877.8 (13)
C40—S4—O20—Ag660.5 (9)O12—C27—C28—F17139.4 (12)
C39—S4—O20—Ag643.4 (10)O11—C27—C28—F1740.8 (15)
C40—S4—O20—Ag495.2 (8)Ag8—O13—C29—O149 (2)
C39—S4—O20—Ag4160.9 (8)Ag8—O13—C29—C30169.3 (8)
C42—S5—O21—Ag1167.7 (10)Ag10—O14—C29—O1316 (2)
C41—S5—O21—Ag1133.4 (11)Ag10—O14—C29—C30165.2 (8)
C42—S5—O21—Ag10ii131.2 (7)O13—C29—C30—F19162.5 (13)
C41—S5—O21—Ag10ii127.7 (9)O14—C29—C30—F1916.4 (17)
C43—S6—O22—Ag9ii179.8 (9)O13—C29—C30—F2140.2 (17)
C44—S6—O22—Ag9ii77.1 (10)O14—C29—C30—F21138.7 (12)
C43—S6—O22—Ag1125.0 (12)O13—C29—C30—F2078.3 (15)
C44—S6—O22—Ag1178.1 (11)O14—C29—C30—F20102.8 (14)
Ag1—O1—C17—O25 (2)Ag9—O16—C31—O150 (3)
Ag1—O1—C17—C18171.3 (8)Ag9—O16—C31—C32174.3 (8)
Ag3—O2—C17—O125 (2)Ag8—O15—C31—O1618 (2)
Ag3—O2—C17—C18158.6 (8)Ag8—O15—C31—C32167.3 (8)
O1—C17—C18—F297.6 (14)O16—C31—C32—F2337.6 (16)
O2—C17—C18—F279.4 (14)O15—C31—C32—F23146.9 (13)
O1—C17—C18—F324.6 (17)O16—C31—C32—F24158.4 (12)
O2—C17—C18—F3158.4 (12)O15—C31—C32—F2426.1 (17)
O1—C17—C18—F1144.2 (13)O16—C31—C32—F2282.3 (15)
O2—C17—C18—F138.8 (16)O15—C31—C32—F2293.2 (14)
Symmetry codes: (i) x+3/2, y+1/2, z+1; (ii) x+1, y, z+1/2.
(II) top
Crystal data top
22(Ag+)·3(C11H102)·16(C2F3O2)·12(C2H6SO)Z = 4
Mr = 5545.56F(000) = 10584
Monoclinic, C2/cDx = 2.469 Mg m3
a = 21.9927 (13) ÅMo Kα radiation, λ = 0.71073 Å
b = 14.8488 (13) ŵ = 3.11 mm1
c = 45.797 (3) ÅT = 173 K
β = 93.937 (2)°Block, yellow
V = 14920.4 (19) Å30.50 × 0.50 × 0.40 mm
Data collection top
Bruker APEX-II CCD
diffractometer
12140 reflections with I > 2σ(I)
φ and ω scanRint = 0.131
Absorption correction: multi-scan
SADABS (Bruker, 2003)
θmax = 25.3°, θmin = 1.7°
Tmin = 0.305, Tmax = 0.369h = 2626
164822 measured reflectionsk = 1717
13506 independent reflectionsl = 5454
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.064Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.164H-atom parameters constrained
S = 1.14 w = 1/[σ2(Fo2) + (0.0621P)2 + 504.2735P]
where P = (Fo2 + 2Fc2)/3
13506 reflections(Δ/σ)max = 0.001
998 parametersΔρmax = 2.34 e Å3
508 restraintsΔρmin = 2.24 e Å3
Crystal data top
22(Ag+)·3(C11H102)·16(C2F3O2)·12(C2H6SO)V = 14920.4 (19) Å3
Mr = 5545.56Z = 4
Monoclinic, C2/cMo Kα radiation
a = 21.9927 (13) ŵ = 3.11 mm1
b = 14.8488 (13) ÅT = 173 K
c = 45.797 (3) Å0.50 × 0.50 × 0.40 mm
β = 93.937 (2)°
Data collection top
Bruker APEX-II CCD
diffractometer
13506 independent reflections
Absorption correction: multi-scan
SADABS (Bruker, 2003)
12140 reflections with I > 2σ(I)
Tmin = 0.305, Tmax = 0.369Rint = 0.131
164822 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.064508 restraints
wR(F2) = 0.164H-atom parameters constrained
S = 1.14 w = 1/[σ2(Fo2) + (0.0621P)2 + 504.2735P]
where P = (Fo2 + 2Fc2)/3
13506 reflectionsΔρmax = 2.34 e Å3
998 parametersΔρmin = 2.24 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.78934 (3)0.68328 (5)0.49160 (2)0.02263 (16)
Ag20.78734 (4)0.82858 (6)0.44754 (2)0.0398 (2)
Ag30.75820 (3)0.63562 (5)0.42987 (2)0.02748 (18)
Ag40.66586 (3)0.61903 (5)0.48612 (2)0.02833 (18)
Ag50.55050 (3)0.61107 (5)0.34015 (2)0.02221 (16)
Ag60.59408 (4)0.55934 (5)0.40930 (2)0.03211 (19)
Ag70.66991 (3)0.55186 (5)0.35906 (2)0.02186 (16)
Ag80.66011 (4)0.72902 (5)0.33473 (2)0.02775 (18)
Ag90.63728 (3)0.57202 (5)0.29451 (2)0.02596 (17)
Ag100.54797 (4)0.72234 (5)0.28909 (2)0.02852 (18)
Ag110.43225 (4)0.61153 (7)0.29338 (2)0.0451 (2)
C10.7103 (4)0.7344 (6)0.46118 (19)0.0215 (19)
C20.6709 (4)0.7559 (6)0.44217 (19)0.0168 (17)
C30.6234 (4)0.7759 (6)0.42031 (18)0.0196 (18)
C40.6203 (4)0.7146 (6)0.39587 (18)0.0155 (17)
C50.6209 (4)0.6668 (6)0.37422 (19)0.0195 (18)
C60.5850 (4)0.8460 (6)0.4211 (2)0.0240 (19)
C70.5346 (5)0.8637 (7)0.3981 (2)0.031 (2)
H7A0.49480.85960.40690.037*
H7B0.53550.81800.38250.037*
C80.5423 (5)0.9557 (8)0.3855 (2)0.038 (3)
H8A0.50780.96820.37110.046*
H8B0.58020.95720.37510.046*
C90.5450 (6)1.0280 (8)0.4085 (3)0.048 (3)
H9A0.50541.03140.41750.058*
H9B0.55261.08690.39930.058*
C100.5953 (6)1.0082 (8)0.4320 (3)0.042 (3)
H10A0.59411.05390.44770.050*
H10B0.63521.01320.42340.050*
C110.5894 (5)0.9149 (7)0.4452 (2)0.036 (2)
H11A0.62530.90210.45880.044*
H11B0.55250.91210.45640.044*
C120.5352 (4)0.5795 (6)0.29225 (19)0.0210 (18)
C130.5178 (4)0.5226 (6)0.2747 (2)0.0238 (19)
C140.50000.4662 (9)0.25000.024 (3)
C150.50000.3755 (12)0.25000.053 (4)0.5
C160.5015 (10)0.3245 (11)0.2799 (3)0.027 (4)0.5
H16A0.52120.36110.29600.032*0.5
H16B0.46010.30710.28500.032*0.5
C170.5396 (10)0.2429 (11)0.2733 (4)0.032 (5)0.5
H17A0.54910.20720.29130.038*0.5
H17B0.57830.26160.26530.038*0.5
C180.50000.1858 (13)0.25000.056 (5)0.5
H18A0.47240.14640.26050.068*0.25
H18B0.52760.14640.23950.068*0.25
C15'0.50000.3755 (12)0.25000.053 (4)0.5
C16'0.4605 (9)0.3228 (10)0.2262 (4)0.028 (4)0.5
H16C0.42100.30410.23350.033*0.5
H16D0.45290.35890.20820.033*0.5
C17'0.4993 (11)0.2424 (11)0.2789 (3)0.034 (5)0.5
H17C0.45740.26190.28240.041*0.5
H17D0.51590.20690.29600.041*0.5
C18'0.50000.1858 (13)0.25000.056 (5)0.5
H18C0.53640.14640.25140.068*0.25
H18D0.46360.14640.24860.068*0.25
S10.78487 (19)0.8805 (3)0.37164 (8)0.0651 (11)
O170.7667 (5)0.8145 (7)0.3937 (2)0.068 (3)
C350.8556 (7)0.9243 (11)0.3852 (4)0.074 (5)
H35A0.88690.87750.38450.111*
H35B0.85280.94410.40540.111*
H35C0.86640.97560.37310.111*
C360.7402 (8)0.9786 (12)0.3757 (4)0.073 (5)
H36A0.69780.96620.36880.110*
H36B0.75611.02760.36400.110*
H36C0.74200.99630.39630.110*
S20.82444 (12)0.5793 (2)0.36512 (6)0.0398 (7)
O180.7689 (3)0.5882 (5)0.38247 (15)0.0322 (16)
C370.8542 (7)0.4724 (10)0.3749 (4)0.062 (4)
H37A0.82810.42550.36570.093*
H37B0.85580.46550.39620.093*
H37C0.89540.46670.36820.093*
C380.8819 (6)0.6452 (10)0.3848 (3)0.058 (4)
H38A0.87300.70930.38190.087*
H38B0.92180.63140.37760.087*
H38C0.88250.63080.40570.087*
S30.70851 (12)0.41414 (18)0.44499 (6)0.0353 (6)
O190.6875 (3)0.5077 (5)0.4360 (2)0.0408 (19)
C390.6412 (5)0.3566 (8)0.4541 (3)0.038 (3)
H39A0.62780.38030.47260.057*
H39B0.64980.29210.45620.057*
H39C0.60890.36600.43850.057*
C400.7198 (8)0.3579 (10)0.4124 (3)0.062 (4)
H40A0.75630.38160.40390.092*
H40B0.68430.36700.39850.092*
H40C0.72510.29340.41630.092*
S40.50992 (12)0.58936 (19)0.47015 (6)0.0326 (6)
O200.5711 (3)0.5753 (5)0.45823 (15)0.0326 (16)
C410.4837 (6)0.6919 (8)0.4543 (3)0.049 (3)
H41A0.50680.74200.46350.073*
H41B0.44030.69950.45740.073*
H41C0.48930.69110.43330.073*
C420.4608 (6)0.5155 (9)0.4499 (3)0.052 (3)
H42A0.46930.45340.45620.077*
H42B0.46730.52130.42900.077*
H42C0.41840.53050.45320.077*
S50.30698 (15)0.4898 (2)0.26928 (6)0.0444 (7)
O210.3549 (4)0.5579 (6)0.26106 (16)0.045 (2)
C430.2612 (6)0.5447 (9)0.2933 (3)0.051 (3)
H43A0.23450.58760.28240.077*
H43B0.28710.57700.30810.077*
H43C0.23630.50030.30290.077*
C440.3463 (9)0.4194 (13)0.2956 (4)0.086 (6)
H44A0.37550.38170.28600.130*
H44B0.31690.38090.30490.130*
H44C0.36810.45680.31060.130*
S60.59192 (19)0.8495 (2)0.23326 (8)0.0426 (9)0.8
O220.5638 (3)0.7548 (5)0.23687 (17)0.0364 (17)0.8
C450.5982 (7)0.8621 (11)0.1948 (3)0.061 (4)0.8
H45A0.55800.87550.18520.092*0.8
H45B0.61380.80610.18680.092*0.8
H45C0.62630.91150.19130.092*0.8
C460.6716 (7)0.8270 (14)0.2433 (4)0.078 (5)0.8
H46A0.67730.81780.26450.117*0.8
H46B0.69630.87820.23770.117*0.8
H46C0.68420.77270.23320.117*0.8
S6'0.6140 (7)0.8004 (11)0.2195 (3)0.041 (3)0.2
O22'0.5638 (3)0.7548 (5)0.23687 (17)0.0364 (17)0.2
C45'0.5982 (7)0.8621 (11)0.1948 (3)0.061 (4)0.2
H45D0.56340.83780.18290.092*0.2
H45E0.63320.86800.18280.092*0.2
H45F0.58770.92140.20240.092*0.2
C46'0.6716 (7)0.8270 (14)0.2433 (4)0.078 (5)0.2
H46D0.67680.77960.25820.117*0.2
H46E0.66290.88430.25280.117*0.2
H46F0.70900.83260.23300.117*0.2
O10.8974 (4)0.7578 (6)0.49184 (18)0.045 (2)
O20.8873 (4)0.7930 (6)0.4443 (2)0.049 (2)
C190.9152 (5)0.7633 (7)0.4672 (2)0.027 (2)
C200.9780 (4)0.7220 (6)0.46322 (19)0.038 (3)
F10.9905 (5)0.7125 (9)0.43640 (18)0.132 (5)
F21.0199 (4)0.7694 (8)0.4765 (3)0.133 (5)
F30.9826 (5)0.6416 (7)0.4748 (3)0.141 (6)
O30.8332 (4)0.5483 (5)0.49281 (14)0.0355 (18)
O40.8401 (4)0.5427 (6)0.44397 (16)0.0396 (18)
C210.8495 (4)0.5157 (6)0.4696 (2)0.025 (2)
C220.8884 (4)0.4292 (6)0.47365 (19)0.042 (3)
F40.8742 (5)0.3781 (6)0.4951 (2)0.090 (3)
F50.9447 (4)0.4512 (7)0.4790 (3)0.133 (5)
F60.8847 (7)0.3806 (8)0.4503 (2)0.149 (6)
O50.7685 (4)0.9781 (5)0.44922 (17)0.045 (2)
O60.8220 (4)1.0117 (5)0.49086 (17)0.0387 (18)
C230.7898 (5)1.0291 (6)0.4684 (2)0.026 (2)
C240.7746 (4)1.1289 (7)0.46358 (19)0.040 (3)
F70.7487 (5)1.1624 (7)0.4857 (2)0.106 (4)
F80.7382 (5)1.1436 (6)0.4406 (2)0.117 (5)
F90.8235 (4)1.1746 (6)0.4608 (3)0.117 (4)
O70.5097 (5)0.4688 (7)0.3523 (3)0.075 (3)
O80.5608 (5)0.4239 (6)0.39316 (18)0.059 (3)
C250.5296 (6)0.4136 (8)0.3699 (2)0.038 (3)
C260.5147 (4)0.3148 (8)0.3618 (2)0.057 (3)
F100.4633 (4)0.3066 (7)0.3464 (2)0.085 (3)
F110.5575 (4)0.2834 (6)0.3466 (2)0.083 (3)
F120.5119 (6)0.2648 (7)0.38477 (17)0.122 (5)
O90.4657 (4)0.6813 (8)0.3609 (3)0.075 (4)
O100.3830 (4)0.6358 (7)0.33428 (18)0.047 (2)
C270.4115 (5)0.6686 (7)0.3560 (2)0.034 (2)
C280.3717 (4)0.6925 (6)0.3817 (2)0.040 (3)
F130.3141 (3)0.6898 (8)0.37499 (18)0.088 (3)
F140.3864 (4)0.7704 (5)0.3924 (2)0.102 (4)
F150.3823 (5)0.6342 (6)0.40308 (19)0.096 (3)
O110.7030 (4)0.4237 (5)0.34511 (16)0.0377 (18)
O120.6579 (4)0.4157 (5)0.29988 (18)0.046 (2)
C290.6873 (4)0.3861 (7)0.3217 (2)0.027 (2)
C300.7088 (4)0.2874 (6)0.32048 (18)0.040 (3)
F160.7684 (3)0.2844 (6)0.3206 (2)0.073 (3)
F170.6945 (4)0.2410 (5)0.34302 (18)0.071 (2)
F180.6872 (5)0.2470 (6)0.29714 (18)0.115 (5)
O130.7464 (4)0.7305 (5)0.3108 (2)0.046 (2)
O140.7368 (4)0.5905 (6)0.2931 (2)0.050 (2)
C310.7641 (5)0.6607 (7)0.2992 (2)0.032 (2)
C320.8312 (5)0.6627 (6)0.28966 (19)0.047 (3)
F190.8680 (3)0.7030 (5)0.30863 (15)0.059 (2)
F200.8316 (4)0.7065 (7)0.26516 (16)0.091 (3)
F210.8523 (4)0.5828 (5)0.2855 (3)0.105 (4)
O150.6420 (4)0.8787 (5)0.32315 (19)0.0419 (19)
O160.5514 (4)0.8659 (5)0.29905 (18)0.041 (2)
C330.5951 (4)0.9071 (6)0.3113 (2)0.024 (2)
C340.5868 (4)1.0114 (6)0.30942 (17)0.032 (2)
F220.5309 (3)1.0358 (4)0.31170 (17)0.056 (2)
F230.6211 (3)1.0534 (4)0.32930 (14)0.0502 (18)
F240.6036 (3)1.0383 (4)0.28404 (13)0.0528 (19)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0223 (3)0.0238 (4)0.0211 (3)0.0089 (3)0.0032 (3)0.0036 (3)
Ag20.0338 (4)0.0264 (4)0.0597 (6)0.0024 (3)0.0076 (4)0.0101 (4)
Ag30.0297 (4)0.0269 (4)0.0255 (4)0.0060 (3)0.0008 (3)0.0101 (3)
Ag40.0324 (4)0.0248 (4)0.0273 (4)0.0039 (3)0.0018 (3)0.0033 (3)
Ag50.0245 (3)0.0252 (4)0.0159 (3)0.0007 (3)0.0063 (3)0.0053 (3)
Ag60.0468 (5)0.0262 (4)0.0238 (4)0.0052 (3)0.0055 (3)0.0020 (3)
Ag70.0262 (4)0.0195 (3)0.0194 (3)0.0065 (3)0.0026 (3)0.0044 (3)
Ag80.0342 (4)0.0205 (4)0.0292 (4)0.0018 (3)0.0070 (3)0.0031 (3)
Ag90.0295 (4)0.0280 (4)0.0201 (3)0.0026 (3)0.0005 (3)0.0030 (3)
Ag100.0354 (4)0.0161 (3)0.0321 (4)0.0012 (3)0.0114 (3)0.0013 (3)
Ag110.0337 (5)0.0664 (6)0.0348 (5)0.0089 (4)0.0007 (4)0.0141 (4)
C10.021 (4)0.024 (4)0.019 (4)0.003 (3)0.001 (3)0.005 (3)
C20.016 (4)0.014 (4)0.019 (4)0.001 (3)0.005 (3)0.003 (3)
C30.020 (4)0.024 (4)0.014 (4)0.006 (3)0.007 (3)0.005 (3)
C40.017 (4)0.016 (4)0.012 (4)0.001 (3)0.006 (3)0.000 (3)
C50.024 (4)0.018 (4)0.016 (4)0.001 (3)0.005 (3)0.002 (3)
C60.028 (4)0.024 (4)0.019 (4)0.001 (4)0.005 (3)0.006 (3)
C70.030 (5)0.030 (5)0.031 (5)0.012 (4)0.006 (4)0.006 (4)
C80.040 (5)0.040 (5)0.032 (5)0.013 (5)0.011 (4)0.001 (4)
C90.060 (6)0.033 (5)0.051 (6)0.013 (5)0.003 (5)0.002 (5)
C100.047 (6)0.034 (5)0.044 (6)0.008 (5)0.001 (5)0.013 (5)
C110.046 (5)0.036 (5)0.025 (5)0.013 (4)0.010 (4)0.013 (4)
C120.028 (4)0.018 (4)0.016 (4)0.002 (3)0.008 (3)0.001 (3)
C130.035 (5)0.018 (4)0.017 (4)0.000 (4)0.007 (4)0.004 (3)
C140.040 (6)0.016 (5)0.015 (5)0.0000.011 (5)0.000
C150.073 (7)0.038 (6)0.044 (7)0.0000.017 (6)0.000
C160.030 (8)0.029 (8)0.020 (7)0.000 (7)0.007 (6)0.013 (6)
C170.036 (8)0.024 (8)0.035 (8)0.004 (7)0.004 (7)0.007 (7)
C180.070 (7)0.046 (7)0.053 (7)0.0000.001 (6)0.000
C15'0.073 (7)0.038 (6)0.044 (7)0.0000.017 (6)0.000
C16'0.027 (8)0.027 (8)0.028 (8)0.003 (7)0.004 (7)0.002 (6)
C17'0.039 (9)0.025 (8)0.038 (8)0.003 (7)0.003 (7)0.004 (7)
C18'0.070 (7)0.046 (7)0.053 (7)0.0000.001 (6)0.000
S10.073 (2)0.077 (3)0.047 (2)0.029 (2)0.0182 (17)0.0290 (18)
O170.072 (7)0.054 (6)0.081 (7)0.032 (5)0.029 (6)0.023 (5)
C350.065 (9)0.057 (8)0.104 (12)0.016 (7)0.030 (9)0.001 (8)
C360.068 (9)0.082 (10)0.065 (9)0.010 (8)0.030 (7)0.005 (8)
S20.0297 (14)0.0650 (19)0.0246 (13)0.0007 (13)0.0012 (10)0.0002 (13)
O180.024 (3)0.044 (4)0.028 (4)0.001 (3)0.000 (3)0.016 (3)
C370.050 (7)0.056 (8)0.081 (10)0.005 (6)0.013 (7)0.019 (7)
C380.041 (7)0.061 (8)0.072 (9)0.025 (6)0.004 (6)0.008 (7)
S30.0309 (13)0.0304 (13)0.0450 (16)0.0046 (11)0.0054 (11)0.0044 (12)
O190.021 (4)0.028 (4)0.073 (6)0.004 (3)0.004 (4)0.002 (4)
C390.034 (5)0.036 (6)0.045 (6)0.011 (5)0.002 (5)0.004 (5)
C400.087 (10)0.048 (7)0.053 (8)0.029 (7)0.024 (7)0.014 (6)
S40.0288 (13)0.0395 (14)0.0297 (13)0.0053 (11)0.0041 (10)0.0044 (11)
O200.022 (3)0.049 (5)0.027 (4)0.001 (3)0.004 (3)0.003 (3)
C410.039 (6)0.039 (6)0.066 (8)0.006 (5)0.008 (6)0.004 (6)
C420.038 (6)0.046 (7)0.070 (8)0.013 (5)0.002 (6)0.013 (6)
S50.0527 (18)0.0508 (18)0.0307 (14)0.0273 (15)0.0094 (13)0.0064 (13)
O210.052 (5)0.064 (6)0.019 (4)0.032 (4)0.004 (3)0.003 (4)
C430.055 (7)0.049 (7)0.050 (7)0.003 (6)0.003 (6)0.004 (6)
C440.094 (11)0.073 (10)0.094 (12)0.011 (9)0.020 (10)0.039 (9)
S60.061 (2)0.0316 (18)0.0368 (19)0.0136 (17)0.0128 (17)0.0066 (16)
O220.040 (4)0.030 (4)0.040 (4)0.003 (3)0.003 (3)0.004 (3)
C450.067 (8)0.067 (8)0.051 (7)0.010 (7)0.008 (6)0.008 (6)
C460.054 (8)0.114 (11)0.065 (8)0.028 (8)0.008 (7)0.009 (8)
S6'0.051 (8)0.052 (9)0.018 (6)0.018 (7)0.002 (6)0.001 (6)
O22'0.040 (4)0.030 (4)0.040 (4)0.003 (3)0.003 (3)0.004 (3)
C45'0.067 (8)0.067 (8)0.051 (7)0.010 (7)0.008 (6)0.008 (6)
C46'0.054 (8)0.114 (11)0.065 (8)0.028 (8)0.008 (7)0.009 (8)
O10.041 (5)0.059 (5)0.036 (4)0.013 (4)0.011 (4)0.003 (4)
O20.035 (4)0.060 (6)0.055 (5)0.009 (4)0.014 (4)0.016 (4)
C190.028 (5)0.024 (4)0.030 (5)0.005 (4)0.004 (4)0.003 (4)
C200.034 (5)0.043 (6)0.038 (5)0.004 (5)0.008 (4)0.003 (5)
F10.103 (8)0.218 (13)0.079 (7)0.103 (9)0.024 (6)0.018 (8)
F20.039 (5)0.164 (11)0.195 (12)0.004 (6)0.009 (6)0.109 (10)
F30.091 (8)0.121 (9)0.216 (13)0.060 (7)0.046 (8)0.071 (9)
O30.052 (5)0.035 (4)0.017 (3)0.023 (4)0.011 (3)0.007 (3)
O40.041 (4)0.049 (5)0.030 (4)0.016 (4)0.006 (3)0.002 (3)
C210.024 (4)0.024 (4)0.025 (5)0.004 (4)0.001 (4)0.001 (4)
C220.044 (6)0.038 (5)0.045 (6)0.016 (5)0.004 (5)0.004 (5)
F40.108 (7)0.055 (5)0.111 (8)0.040 (5)0.033 (6)0.036 (5)
F50.053 (6)0.090 (8)0.254 (14)0.033 (5)0.007 (7)0.052 (9)
F60.260 (15)0.103 (8)0.081 (7)0.111 (9)0.013 (9)0.032 (6)
O50.069 (6)0.028 (4)0.036 (4)0.010 (4)0.011 (4)0.001 (3)
O60.051 (5)0.022 (4)0.041 (4)0.001 (3)0.014 (4)0.004 (3)
C230.037 (5)0.019 (4)0.024 (4)0.003 (4)0.012 (4)0.005 (4)
C240.045 (6)0.032 (5)0.042 (6)0.009 (5)0.006 (5)0.006 (4)
F70.159 (10)0.063 (6)0.101 (8)0.048 (6)0.052 (7)0.005 (5)
F80.179 (11)0.051 (5)0.109 (8)0.034 (6)0.074 (8)0.004 (5)
F90.099 (8)0.045 (5)0.212 (13)0.004 (5)0.041 (8)0.031 (7)
O70.070 (7)0.050 (6)0.098 (8)0.026 (5)0.031 (6)0.031 (6)
O80.099 (8)0.040 (5)0.032 (5)0.015 (5)0.024 (5)0.001 (4)
C250.050 (6)0.037 (5)0.027 (5)0.016 (5)0.007 (4)0.004 (4)
C260.070 (7)0.062 (7)0.039 (6)0.016 (6)0.004 (6)0.002 (5)
F100.083 (6)0.089 (7)0.083 (6)0.039 (5)0.002 (5)0.030 (5)
F110.096 (7)0.069 (6)0.084 (6)0.010 (5)0.006 (5)0.034 (5)
F120.237 (13)0.065 (6)0.063 (6)0.070 (8)0.003 (7)0.010 (5)
O90.027 (5)0.097 (8)0.099 (8)0.005 (5)0.004 (5)0.069 (7)
O100.033 (4)0.071 (6)0.038 (4)0.001 (4)0.002 (3)0.016 (4)
C270.029 (5)0.032 (5)0.041 (5)0.004 (4)0.005 (4)0.004 (4)
C280.036 (5)0.046 (6)0.037 (5)0.004 (5)0.009 (4)0.004 (5)
F130.039 (4)0.173 (10)0.053 (5)0.016 (5)0.001 (4)0.013 (6)
F140.109 (8)0.068 (6)0.136 (9)0.007 (6)0.064 (7)0.048 (6)
F150.129 (9)0.110 (8)0.049 (5)0.032 (7)0.012 (5)0.017 (5)
O110.052 (5)0.031 (4)0.029 (4)0.012 (3)0.009 (3)0.012 (3)
O120.065 (6)0.028 (4)0.041 (5)0.011 (4)0.028 (4)0.006 (3)
C290.022 (4)0.024 (4)0.033 (5)0.003 (4)0.001 (4)0.003 (4)
C300.041 (5)0.035 (5)0.043 (6)0.020 (5)0.005 (5)0.014 (5)
F160.047 (4)0.077 (6)0.097 (7)0.035 (4)0.011 (4)0.008 (5)
F170.087 (6)0.033 (4)0.094 (6)0.001 (4)0.019 (5)0.009 (4)
F180.168 (10)0.068 (6)0.095 (7)0.065 (6)0.086 (7)0.064 (5)
O130.046 (5)0.037 (5)0.058 (5)0.006 (4)0.026 (4)0.008 (4)
O140.038 (5)0.049 (5)0.065 (6)0.005 (4)0.012 (4)0.018 (4)
C310.029 (5)0.036 (5)0.031 (5)0.001 (4)0.001 (4)0.002 (4)
C320.046 (6)0.056 (6)0.042 (6)0.003 (5)0.011 (5)0.007 (5)
F190.031 (4)0.088 (6)0.059 (5)0.014 (4)0.001 (3)0.006 (4)
F200.056 (5)0.166 (10)0.051 (5)0.022 (6)0.017 (4)0.024 (6)
F210.068 (6)0.086 (7)0.168 (11)0.010 (5)0.049 (7)0.036 (7)
O150.041 (4)0.022 (4)0.061 (5)0.003 (3)0.011 (4)0.003 (4)
O160.054 (5)0.014 (3)0.053 (5)0.005 (3)0.019 (4)0.001 (3)
C330.029 (5)0.017 (4)0.027 (4)0.002 (4)0.003 (4)0.001 (3)
C340.040 (5)0.017 (4)0.040 (5)0.003 (4)0.003 (4)0.005 (4)
F220.049 (4)0.024 (3)0.095 (6)0.011 (3)0.001 (4)0.007 (4)
F230.068 (5)0.020 (3)0.060 (4)0.009 (3)0.017 (4)0.005 (3)
F240.078 (5)0.032 (3)0.048 (4)0.005 (3)0.005 (4)0.019 (3)
Geometric parameters (Å, º) top
Ag1—O32.223 (7)C17'—H17C0.9900
Ag1—C12.281 (9)C17'—H17D0.9900
Ag1—C1i2.484 (9)S1—O171.483 (11)
Ag1—Ag1i2.7742 (13)S1—C351.758 (17)
Ag1—Ag42.8731 (11)S1—C361.774 (17)
Ag1—Ag32.9487 (10)C35—H35A0.9800
Ag1—Ag22.9522 (11)C35—H35B0.9800
Ag1—Ag4i3.2391 (10)C35—H35C0.9800
Ag1—Ag2i3.3600 (12)C36—H36A0.9800
Ag2—O52.261 (8)C36—H36B0.9800
Ag2—O22.276 (8)C36—H36C0.9800
Ag2—C12.315 (9)S2—O181.509 (7)
Ag2—O172.485 (11)S2—C371.764 (15)
Ag2—Ag33.0337 (12)S2—C381.792 (13)
Ag2—Ag4i3.2353 (13)C37—H37A0.9800
Ag2—Ag1i3.3601 (12)C37—H37B0.9800
Ag3—O182.310 (7)C37—H37C0.9800
Ag3—O42.324 (8)C38—H38A0.9800
Ag3—C12.350 (9)C38—H38B0.9800
Ag3—O192.482 (8)C38—H38C0.9800
Ag3—C22.709 (8)S3—O191.513 (8)
Ag4—O6i2.217 (7)S3—C401.744 (14)
Ag4—C12.313 (10)S3—C391.783 (11)
Ag4—O202.455 (7)C39—H39A0.9800
Ag4—O1i2.547 (8)C39—H39B0.9800
Ag4—Ag2i3.2353 (13)C39—H39C0.9800
Ag4—Ag1i3.2392 (10)C40—H40A0.9800
Ag5—C122.246 (8)C40—H40B0.9800
Ag5—C52.277 (9)C40—H40C0.9800
Ag5—O72.376 (9)S4—O201.502 (7)
Ag5—O92.391 (9)S4—C421.759 (12)
Ag5—Ag72.8474 (10)S4—C411.767 (12)
Ag5—Ag102.8606 (10)C41—H41A0.9800
Ag5—Ag92.9825 (10)C41—H41B0.9800
Ag5—Ag83.0038 (10)C41—H41C0.9800
Ag5—Ag113.2536 (11)C42—H42A0.9800
Ag5—Ag63.3347 (10)C42—H42B0.9800
Ag6—O82.248 (9)C42—H42C0.9800
Ag6—O202.342 (7)S5—O211.526 (8)
Ag6—C52.368 (9)S5—C431.743 (13)
Ag6—O192.442 (8)S5—C441.775 (17)
Ag6—C42.464 (8)O21—Ag9ii2.571 (7)
Ag6—Ag72.9349 (11)C43—H43A0.9800
Ag7—O112.151 (7)C43—H43B0.9800
Ag7—C52.159 (9)C43—H43C0.9800
Ag7—O182.420 (7)C44—H44A0.9800
Ag7—Ag82.8593 (10)C44—H44B0.9800
Ag7—Ag93.0087 (10)C44—H44C0.9800
Ag8—C52.254 (9)S6—O221.549 (8)
Ag8—O132.257 (8)S6—C451.785 (15)
Ag8—O152.314 (7)S6—C461.812 (17)
Ag8—Ag92.9921 (11)O22—Ag11ii2.544 (8)
Ag8—Ag103.1228 (11)C45—H45A0.9800
Ag9—O142.211 (8)C45—H45B0.9800
Ag9—C122.243 (9)C45—H45C0.9800
Ag9—O122.374 (8)C46—H46A0.9800
Ag9—O21ii2.571 (7)C46—H46B0.9800
Ag9—Ag102.9723 (11)C46—H46C0.9800
Ag10—C122.146 (9)O1—C191.223 (13)
Ag10—O162.180 (7)O1—Ag4i2.547 (8)
Ag10—O222.488 (8)O2—C191.256 (13)
Ag10—Ag113.0483 (12)C19—C201.533 (13)
Ag11—O102.256 (8)C20—F21.280 (8)
Ag11—C122.317 (9)C20—F11.285 (8)
Ag11—O212.318 (7)C20—F31.306 (9)
Ag11—C132.497 (10)O3—C211.242 (12)
Ag11—O22'ii2.544 (8)O4—C211.245 (12)
Ag11—O22ii2.544 (8)C21—C221.547 (13)
C1—C21.228 (13)C22—F61.289 (8)
C1—Ag1i2.484 (9)C22—F51.289 (9)
C2—C31.428 (12)C22—F41.295 (8)
C3—C61.343 (13)O5—C231.227 (13)
C3—C41.441 (12)O6—C231.236 (12)
C4—C51.220 (12)O6—Ag4i2.217 (7)
C6—C71.497 (13)C23—C241.531 (13)
C6—C111.504 (13)C24—F91.285 (9)
C7—C81.497 (16)C24—F81.296 (8)
C7—H7A0.9900C24—F71.298 (8)
C7—H7B0.9900O7—C251.211 (15)
C8—C91.501 (16)O8—C251.234 (14)
C8—H8A0.9900C25—C261.544 (16)
C8—H8B0.9900C26—F121.293 (9)
C9—C101.517 (17)C26—F111.295 (9)
C9—H9A0.9900C26—F101.297 (9)
C9—H9B0.9900O9—C271.213 (13)
C10—C111.522 (17)O10—C271.237 (13)
C10—H10A0.9900C27—C281.557 (15)
C10—H10B0.9900C28—F131.284 (8)
C11—H11A0.9900C28—F141.288 (8)
C11—H11B0.9900C28—F151.314 (8)
C12—C131.210 (13)O11—C291.238 (12)
C13—C141.440 (12)O12—C291.232 (12)
C14—C151.35 (2)C29—C301.543 (13)
C14—C13ii1.440 (12)C30—F181.288 (8)
C15—C16ii1.562 (15)C30—F171.298 (8)
C15—C161.562 (15)C30—F161.311 (8)
C16—C171.51 (3)O13—C311.239 (13)
C16—H16A0.9900O14—C311.226 (14)
C16—H16B0.9900C31—C321.566 (15)
C17—C181.577 (18)C32—F211.292 (8)
C17—H17A0.9900C32—F191.295 (8)
C17—H17B0.9900C32—F201.298 (8)
C18—C17ii1.577 (18)O15—C331.207 (12)
C18—H18A0.9900O16—C331.242 (12)
C18—H18B0.9900C33—C341.563 (12)
C16'—C17'ii1.51 (3)C34—F221.293 (8)
C16'—H16C0.9900C34—F231.301 (8)
C16'—H16D0.9900C34—F241.306 (8)
C17'—C16'ii1.51 (3)
O3—Ag1—C1128.8 (3)Ag1—C1—Ag379.1 (3)
O3—Ag1—C1i116.5 (3)Ag4—C1—Ag393.5 (3)
C1—Ag1—C1i108.9 (2)Ag2—C1—Ag381.1 (3)
O3—Ag1—Ag1i156.2 (2)C2—C1—Ag1i116.7 (7)
C1—Ag1—Ag1i57.9 (2)Ag1—C1—Ag1i71.1 (2)
C1i—Ag1—Ag1i51.1 (2)Ag4—C1—Ag1i84.9 (3)
O3—Ag1—Ag496.2 (2)Ag2—C1—Ag1i88.8 (3)
C1—Ag1—Ag451.8 (2)Ag3—C1—Ag1i149.8 (4)
C1i—Ag1—Ag4100.7 (2)C1—C2—C3176.6 (10)
Ag1i—Ag1—Ag469.98 (3)C1—C2—Ag360.0 (5)
O3—Ag1—Ag383.07 (17)C3—C2—Ag3119.1 (6)
C1—Ag1—Ag351.5 (2)C6—C3—C2125.1 (8)
C1i—Ag1—Ag3160.0 (2)C6—C3—C4120.9 (8)
Ag1i—Ag1—Ag3109.22 (4)C2—C3—C4114.0 (7)
Ag4—Ag1—Ag371.38 (3)C5—C4—C3175.0 (10)
O3—Ag1—Ag2131.4 (2)C5—C4—Ag671.0 (6)
C1—Ag1—Ag250.5 (2)C3—C4—Ag6113.4 (6)
C1i—Ag1—Ag2103.6 (2)C4—C5—Ag7139.0 (7)
Ag1i—Ag1—Ag271.78 (3)C4—C5—Ag8116.1 (7)
Ag4—Ag1—Ag2102.32 (3)Ag7—C5—Ag880.7 (3)
Ag3—Ag1—Ag261.88 (3)C4—C5—Ag5136.4 (7)
O3—Ag1—Ag4i133.4 (2)Ag7—C5—Ag579.8 (3)
C1—Ag1—Ag4i95.3 (2)Ag8—C5—Ag583.0 (3)
C1i—Ag1—Ag4i45.3 (2)C4—C5—Ag679.8 (6)
Ag1i—Ag1—Ag4i56.44 (3)Ag7—C5—Ag680.7 (3)
Ag4—Ag1—Ag4i126.42 (3)Ag8—C5—Ag6161.3 (4)
Ag3—Ag1—Ag4i124.42 (3)Ag5—C5—Ag691.8 (3)
Ag2—Ag1—Ag4i62.80 (3)C3—C6—C7123.8 (8)
O3—Ag1—Ag2i100.0 (2)C3—C6—C11122.5 (8)
C1—Ag1—Ag2i96.9 (2)C7—C6—C11113.7 (8)
C1i—Ag1—Ag2i43.5 (2)C6—C7—C8109.5 (9)
Ag1i—Ag1—Ag2i56.57 (3)C6—C7—H7A109.8
Ag4—Ag1—Ag2i61.96 (3)C8—C7—H7A109.8
Ag3—Ag1—Ag2i133.31 (3)C6—C7—H7B109.8
Ag2—Ag1—Ag2i128.35 (3)C8—C7—H7B109.8
Ag4i—Ag1—Ag2i86.86 (3)H7A—C7—H7B108.2
O5—Ag2—O2114.2 (3)C7—C8—C9112.5 (10)
O5—Ag2—C1116.4 (3)C7—C8—H8A109.1
O2—Ag2—C1127.2 (3)C9—C8—H8A109.1
O5—Ag2—O1795.5 (3)C7—C8—H8B109.1
O2—Ag2—O1791.6 (3)C9—C8—H8B109.1
C1—Ag2—O1797.4 (3)H8A—C8—H8B107.8
O5—Ag2—Ag1133.5 (2)C8—C9—C10110.5 (10)
O2—Ag2—Ag184.6 (2)C8—C9—H9A109.6
C1—Ag2—Ag149.5 (2)C10—C9—H9A109.6
O17—Ag2—Ag1127.6 (2)C8—C9—H9B109.6
O5—Ag2—Ag3154.2 (2)C10—C9—H9B109.6
O2—Ag2—Ag387.2 (3)H9A—C9—H9B108.1
C1—Ag2—Ag349.9 (2)C9—C10—C11112.3 (10)
O17—Ag2—Ag368.6 (2)C9—C10—H10A109.1
Ag1—Ag2—Ag359.01 (3)C11—C10—H10A109.1
O5—Ag2—Ag4i77.2 (2)C9—C10—H10B109.1
O2—Ag2—Ag4i82.5 (2)C11—C10—H10B109.1
C1—Ag2—Ag4i94.8 (2)H10A—C10—H10B107.9
O17—Ag2—Ag4i167.6 (2)C6—C11—C10109.3 (9)
Ag1—Ag2—Ag4i62.94 (3)C6—C11—H11A109.8
Ag3—Ag2—Ag4i121.69 (3)C10—C11—H11A109.8
O5—Ag2—Ag1i85.4 (2)C6—C11—H11B109.8
O2—Ag2—Ag1i125.7 (2)C10—C11—H11B109.8
C1—Ag2—Ag1i47.6 (2)H11A—C11—H11B108.3
O17—Ag2—Ag1i138.6 (2)C13—C12—Ag10133.0 (7)
Ag1—Ag2—Ag1i51.65 (3)C13—C12—Ag9105.4 (7)
Ag3—Ag2—Ag1i93.61 (3)Ag10—C12—Ag985.2 (3)
Ag4i—Ag2—Ag1i51.61 (2)C13—C12—Ag5144.5 (8)
O18—Ag3—O487.3 (3)Ag10—C12—Ag581.3 (3)
O18—Ag3—C1147.4 (3)Ag9—C12—Ag583.3 (3)
O4—Ag3—C1124.9 (3)C13—C12—Ag1183.9 (7)
O18—Ag3—O1988.7 (3)Ag10—C12—Ag1186.1 (3)
O4—Ag3—O1989.6 (3)Ag9—C12—Ag11170.2 (4)
C1—Ag3—O1995.6 (3)Ag5—C12—Ag1190.9 (3)
O18—Ag3—C2121.0 (3)C12—C13—C14170.0 (10)
O4—Ag3—C2151.6 (3)C12—C13—Ag1167.3 (6)
C1—Ag3—C226.9 (3)C14—C13—Ag11114.0 (5)
O19—Ag3—C291.3 (2)C15—C14—C13125.6 (5)
O18—Ag3—Ag1160.46 (17)C15—C14—C13ii125.6 (5)
O4—Ag3—Ag175.61 (19)C13—C14—C13ii108.8 (11)
C1—Ag3—Ag149.4 (2)C14—C15—C16ii119.0 (9)
O19—Ag3—Ag1100.4 (2)C14—C15—C16119.0 (9)
C2—Ag3—Ag176.33 (18)C16ii—C15—C16122.1 (17)
O18—Ag3—Ag2120.4 (2)C17—C16—C15101.1 (14)
O4—Ag3—Ag2109.9 (2)C17—C16—H16A111.6
C1—Ag3—Ag248.9 (2)C15—C16—H16A111.6
O19—Ag3—Ag2144.55 (19)C17—C16—H16B111.6
C2—Ag3—Ag257.42 (18)C15—C16—H16B111.6
Ag1—Ag3—Ag259.12 (3)H16A—C16—H16B109.4
O6i—Ag4—C1147.4 (3)C16—C17—C18106.2 (14)
O6i—Ag4—O2095.0 (3)C16—C17—H17A110.5
C1—Ag4—O20108.2 (3)C18—C17—H17A110.5
O6i—Ag4—O1i119.4 (3)C16—C17—H17B110.5
C1—Ag4—O1i85.7 (3)C18—C17—H17B110.5
O20—Ag4—O1i85.9 (3)H17A—C17—H17B108.7
O6i—Ag4—Ag199.6 (2)C17—C18—C17ii114.9 (17)
C1—Ag4—Ag150.8 (2)C17—C18—H18A108.5
O20—Ag4—Ag1153.69 (17)C17ii—C18—H18A108.5
O1i—Ag4—Ag1105.4 (2)C17—C18—H18B108.5
O6i—Ag4—Ag2i75.1 (2)C17ii—C18—H18B108.5
C1—Ag4—Ag2i99.6 (2)H18A—C18—H18B107.5
O20—Ag4—Ag2i139.12 (16)C17'ii—C16'—H16C111.4
O1i—Ag4—Ag2i66.56 (19)C17'ii—C16'—H16D111.4
Ag1—Ag4—Ag2i66.44 (3)H16C—C16'—H16D109.3
O6i—Ag4—Ag1i128.3 (2)C16'ii—C17'—H17C110.8
C1—Ag4—Ag1i49.8 (2)C16'ii—C17'—H17D110.8
O20—Ag4—Ag1i129.23 (19)H17C—C17'—H17D108.9
O1i—Ag4—Ag1i52.2 (2)O17—S1—C35106.1 (8)
Ag1—Ag4—Ag1i53.58 (3)O17—S1—C36107.2 (8)
Ag2i—Ag4—Ag1i54.25 (2)C35—S1—C3698.2 (8)
C12—Ag5—C5142.6 (3)S1—O17—Ag2125.5 (5)
C12—Ag5—O790.6 (4)S1—C35—H35A109.5
C5—Ag5—O7114.4 (3)S1—C35—H35B109.5
C12—Ag5—O9114.3 (4)H35A—C35—H35B109.5
C5—Ag5—O994.6 (3)S1—C35—H35C109.5
O7—Ag5—O988.7 (4)H35A—C35—H35C109.5
C12—Ag5—Ag7107.8 (2)H35B—C35—H35C109.5
C5—Ag5—Ag748.3 (2)S1—C36—H36A109.5
O7—Ag5—Ag790.5 (3)S1—C36—H36B109.5
O9—Ag5—Ag7137.9 (3)H36A—C36—H36B109.5
C12—Ag5—Ag1047.9 (2)S1—C36—H36C109.5
C5—Ag5—Ag10108.9 (2)H36A—C36—H36C109.5
O7—Ag5—Ag10136.0 (3)H36B—C36—H36C109.5
O9—Ag5—Ag1095.8 (3)O18—S2—C37104.2 (6)
Ag7—Ag5—Ag10113.12 (3)O18—S2—C38104.9 (6)
C12—Ag5—Ag948.3 (2)C37—S2—C3897.3 (7)
C5—Ag5—Ag996.5 (2)S2—O18—Ag3131.3 (4)
O7—Ag5—Ag9105.2 (3)S2—O18—Ag7118.9 (4)
O9—Ag5—Ag9156.6 (3)Ag3—O18—Ag7109.8 (3)
Ag7—Ag5—Ag962.09 (2)S2—C37—H37A109.5
Ag10—Ag5—Ag961.11 (3)S2—C37—H37B109.5
C12—Ag5—Ag896.2 (2)H37A—C37—H37B109.5
C5—Ag5—Ag848.2 (2)S2—C37—H37C109.5
O7—Ag5—Ag8148.8 (3)H37A—C37—H37C109.5
O9—Ag5—Ag8115.5 (3)H37B—C37—H37C109.5
Ag7—Ag5—Ag858.43 (2)S2—C38—H38A109.5
Ag10—Ag5—Ag864.30 (3)S2—C38—H38B109.5
Ag9—Ag5—Ag859.97 (2)H38A—C38—H38B109.5
C12—Ag5—Ag1145.4 (2)S2—C38—H38C109.5
C5—Ag5—Ag11157.7 (2)H38A—C38—H38C109.5
O7—Ag5—Ag1181.9 (2)H38B—C38—H38C109.5
O9—Ag5—Ag1169.6 (2)O19—S3—C40105.4 (6)
Ag7—Ag5—Ag11151.61 (3)O19—S3—C39105.1 (5)
Ag10—Ag5—Ag1159.40 (3)C40—S3—C3998.0 (7)
Ag9—Ag5—Ag1193.45 (3)S3—O19—Ag6130.9 (4)
Ag8—Ag5—Ag11123.65 (3)S3—O19—Ag3123.5 (4)
C12—Ag5—Ag6153.3 (2)Ag6—O19—Ag3102.4 (3)
C5—Ag5—Ag645.2 (2)S3—C39—H39A109.5
O7—Ag5—Ag670.2 (3)S3—C39—H39B109.5
O9—Ag5—Ag684.5 (3)H39A—C39—H39B109.5
Ag7—Ag5—Ag656.02 (2)S3—C39—H39C109.5
Ag10—Ag5—Ag6153.83 (3)H39A—C39—H39C109.5
Ag9—Ag5—Ag6117.69 (3)H39B—C39—H39C109.5
Ag8—Ag5—Ag691.88 (3)S3—C40—H40A109.5
Ag11—Ag5—Ag6142.21 (3)S3—C40—H40B109.5
O8—Ag6—O20108.6 (3)H40A—C40—H40B109.5
O8—Ag6—C5118.1 (3)S3—C40—H40C109.5
O20—Ag6—C5131.3 (3)H40A—C40—H40C109.5
O8—Ag6—O1997.4 (3)H40B—C40—H40C109.5
O20—Ag6—O1977.4 (3)O20—S4—C42104.8 (5)
C5—Ag6—O19108.2 (3)O20—S4—C41104.3 (6)
O8—Ag6—C4146.2 (3)C42—S4—C4198.6 (7)
O20—Ag6—C4102.3 (3)S4—O20—Ag6128.3 (4)
C5—Ag6—C429.2 (3)S4—O20—Ag4121.6 (4)
O19—Ag6—C4102.4 (3)Ag6—O20—Ag4107.1 (3)
O8—Ag6—Ag784.2 (3)S4—C41—H41A109.5
O20—Ag6—Ag7157.66 (17)S4—C41—H41B109.5
C5—Ag6—Ag746.6 (2)H41A—C41—H41B109.5
O19—Ag6—Ag782.9 (2)S4—C41—H41C109.5
C4—Ag6—Ag771.6 (2)H41A—C41—H41C109.5
O8—Ag6—Ag580.1 (2)H41B—C41—H41C109.5
O20—Ag6—Ag5144.92 (18)S4—C42—H42A109.5
C5—Ag6—Ag543.0 (2)S4—C42—H42B109.5
O19—Ag6—Ag5136.5 (2)H42A—C42—H42B109.5
C4—Ag6—Ag566.69 (18)S4—C42—H42C109.5
Ag7—Ag6—Ag553.56 (2)H42A—C42—H42C109.5
O11—Ag7—C5169.1 (3)H42B—C42—H42C109.5
O11—Ag7—O1890.9 (3)O21—S5—C43106.5 (6)
C5—Ag7—O1897.8 (3)O21—S5—C44104.2 (7)
O11—Ag7—Ag5120.5 (2)C43—S5—C4497.0 (8)
C5—Ag7—Ag551.9 (2)S5—O21—Ag11124.0 (4)
O18—Ag7—Ag5148.06 (18)S5—O21—Ag9ii113.1 (4)
O11—Ag7—Ag8135.8 (2)Ag11—O21—Ag9ii120.5 (3)
C5—Ag7—Ag851.1 (2)S5—C43—H43A109.5
O18—Ag7—Ag890.52 (19)S5—C43—H43B109.5
Ag5—Ag7—Ag863.52 (3)H43A—C43—H43B109.5
O11—Ag7—Ag6119.2 (2)S5—C43—H43C109.5
C5—Ag7—Ag652.8 (2)H43A—C43—H43C109.5
O18—Ag7—Ag6100.75 (17)H43B—C43—H43C109.5
Ag5—Ag7—Ag670.42 (3)S5—C44—H44A109.5
Ag8—Ag7—Ag6103.83 (3)S5—C44—H44B109.5
O11—Ag7—Ag981.9 (2)H44A—C44—H44B109.5
C5—Ag7—Ag998.4 (2)S5—C44—H44C109.5
O18—Ag7—Ag9124.03 (18)H44A—C44—H44C109.5
Ag5—Ag7—Ag961.16 (2)H44B—C44—H44C109.5
Ag8—Ag7—Ag961.25 (2)O22—S6—C45105.0 (6)
Ag6—Ag7—Ag9131.03 (3)O22—S6—C46101.0 (7)
C5—Ag8—O13140.8 (3)C45—S6—C4697.5 (8)
C5—Ag8—O15120.5 (3)S6—O22—Ag10111.2 (4)
O13—Ag8—O1590.9 (3)S6—O22—Ag11ii132.3 (4)
C5—Ag8—Ag748.2 (2)Ag10—O22—Ag11ii111.9 (3)
O13—Ag8—Ag798.9 (2)S6—C45—H45A109.5
O15—Ag8—Ag7168.7 (2)S6—C45—H45B109.5
C5—Ag8—Ag996.7 (2)H45A—C45—H45B109.5
O13—Ag8—Ag979.6 (2)S6—C45—H45C109.5
O15—Ag8—Ag9126.1 (2)H45A—C45—H45C109.5
Ag7—Ag8—Ag961.84 (2)H45B—C45—H45C109.5
C5—Ag8—Ag548.8 (2)S6—C46—H46A109.5
O13—Ag8—Ag5138.8 (2)S6—C46—H46B109.5
O15—Ag8—Ag5116.9 (2)H46A—C46—H46B109.5
Ag7—Ag8—Ag558.05 (2)S6—C46—H46C109.5
Ag9—Ag8—Ag559.66 (2)H46A—C46—H46C109.5
C5—Ag8—Ag10101.3 (2)H46B—C46—H46C109.5
O13—Ag8—Ag10109.1 (2)C19—O1—Ag4i122.5 (7)
O15—Ag8—Ag1076.2 (2)C19—O2—Ag2116.5 (7)
Ag7—Ag8—Ag10105.46 (3)O1—C19—O2128.6 (10)
Ag9—Ag8—Ag1058.12 (2)O1—C19—C20115.5 (9)
Ag5—Ag8—Ag1055.63 (2)O2—C19—C20115.7 (9)
O14—Ag9—C12169.2 (3)F2—C20—F1108.7 (8)
O14—Ag9—O1286.7 (3)F2—C20—F3106.0 (8)
C12—Ag9—O12103.7 (3)F1—C20—F3105.7 (8)
O14—Ag9—O21ii81.2 (3)F2—C20—C19110.5 (8)
C12—Ag9—O21ii95.3 (3)F1—C20—C19114.3 (8)
O12—Ag9—O21ii89.9 (3)F3—C20—C19111.3 (9)
O14—Ag9—Ag10123.7 (2)C21—O3—Ag1118.7 (6)
C12—Ag9—Ag1046.0 (2)C21—O4—Ag3121.9 (6)
O12—Ag9—Ag10149.7 (2)O3—C21—O4129.9 (9)
O21ii—Ag9—Ag1093.86 (17)O3—C21—C22114.3 (8)
O14—Ag9—Ag5132.8 (2)O4—C21—C22115.8 (8)
C12—Ag9—Ag548.4 (2)F6—C22—F5107.7 (8)
O12—Ag9—Ag5104.1 (2)F6—C22—F4107.2 (8)
O21ii—Ag9—Ag5143.04 (18)F5—C22—F4106.5 (8)
Ag10—Ag9—Ag557.42 (2)F6—C22—C21111.3 (8)
O14—Ag9—Ag878.3 (2)F5—C22—C21109.3 (8)
C12—Ag9—Ag896.6 (2)F4—C22—C21114.6 (8)
O12—Ag9—Ag8132.48 (18)C23—O5—Ag2124.6 (7)
O21ii—Ag9—Ag8130.8 (2)C23—O6—Ag4i128.5 (7)
Ag10—Ag9—Ag863.14 (3)O5—C23—O6129.5 (9)
Ag5—Ag9—Ag860.37 (2)O5—C23—C24115.2 (9)
O14—Ag9—Ag782.6 (3)O6—C23—C24115.4 (8)
C12—Ag9—Ag7102.8 (2)F9—C24—F8107.8 (8)
O12—Ag9—Ag776.71 (19)F9—C24—F7106.8 (8)
O21ii—Ag9—Ag7159.52 (17)F8—C24—F7106.8 (8)
Ag10—Ag9—Ag7105.57 (3)F9—C24—C23110.5 (8)
Ag5—Ag9—Ag756.75 (2)F8—C24—C23113.4 (8)
Ag8—Ag9—Ag756.91 (2)F7—C24—C23111.3 (8)
C12—Ag10—O16162.8 (3)C25—O7—Ag5129.3 (8)
C12—Ag10—O22106.5 (3)C25—O8—Ag6122.9 (8)
O16—Ag10—O2290.4 (3)O7—C25—O8130.1 (12)
C12—Ag10—Ag550.9 (2)O7—C25—C26114.9 (10)
O16—Ag10—Ag5113.3 (2)O8—C25—C26115.0 (10)
O22—Ag10—Ag5154.39 (18)F12—C26—F11108.0 (9)
C12—Ag10—Ag948.8 (2)F12—C26—F10107.4 (9)
O16—Ag10—Ag9134.7 (2)F11—C26—F10108.2 (8)
O22—Ag10—Ag995.19 (18)F12—C26—C25111.7 (9)
Ag5—Ag10—Ag961.47 (2)F11—C26—C25108.8 (9)
C12—Ag10—Ag1149.3 (3)F10—C26—C25112.6 (9)
O16—Ag10—Ag11122.1 (2)C27—O9—Ag5129.9 (8)
O22—Ag10—Ag11109.84 (18)C27—O10—Ag11118.9 (7)
Ag5—Ag10—Ag1166.73 (3)O9—C27—O10130.5 (11)
Ag9—Ag10—Ag1198.00 (3)O9—C27—C28114.7 (10)
C12—Ag10—Ag895.0 (2)O10—C27—C28114.7 (9)
O16—Ag10—Ag879.3 (2)F13—C28—F14109.7 (8)
O22—Ag10—Ag8118.74 (18)F13—C28—F15106.2 (8)
Ag5—Ag10—Ag860.08 (2)F14—C28—F15106.4 (8)
Ag9—Ag10—Ag858.74 (2)F13—C28—C27114.0 (8)
Ag11—Ag10—Ag8126.76 (3)F14—C28—C27110.7 (8)
O10—Ag11—C12125.2 (3)F15—C28—C27109.5 (8)
O10—Ag11—O21102.2 (3)C29—O11—Ag7125.2 (7)
C12—Ag11—O21126.2 (3)C29—O12—Ag9121.2 (7)
O10—Ag11—C13141.7 (3)O12—C29—O11130.0 (10)
C12—Ag11—C1328.8 (3)O12—C29—C30117.1 (8)
O21—Ag11—C1397.8 (3)O11—C29—C30113.0 (8)
O10—Ag11—O22'ii110.8 (3)F18—C30—F17108.4 (8)
C12—Ag11—O22'ii95.2 (3)F18—C30—F16107.3 (7)
O21—Ag11—O22'ii89.4 (3)F17—C30—F16106.0 (7)
C13—Ag11—O22'ii101.6 (3)F18—C30—C29112.1 (8)
O10—Ag11—O22ii110.8 (3)F17—C30—C29112.7 (8)
C12—Ag11—O22ii95.2 (3)F16—C30—C29110.0 (8)
O21—Ag11—O22ii89.4 (3)C31—O13—Ag8119.9 (7)
C13—Ag11—O22ii101.6 (3)C31—O14—Ag9124.7 (7)
O10—Ag11—Ag10114.7 (2)O14—C31—O13130.2 (10)
C12—Ag11—Ag1044.6 (2)O14—C31—C32114.1 (9)
O21—Ag11—Ag10136.36 (19)O13—C31—C32115.7 (9)
C13—Ag11—Ag1067.1 (2)F21—C32—F19108.0 (8)
O22'ii—Ag11—Ag1056.89 (18)F21—C32—F20108.0 (8)
O22ii—Ag11—Ag1056.89 (18)F19—C32—F20107.9 (8)
O10—Ag11—Ag582.0 (2)F21—C32—C31112.3 (9)
C12—Ag11—Ag543.6 (2)F19—C32—C31112.3 (8)
O21—Ag11—Ag5159.7 (2)F20—C32—C31108.3 (8)
C13—Ag11—Ag568.8 (2)C33—O15—Ag8124.4 (7)
O22'ii—Ag11—Ag5107.75 (18)C33—O16—Ag10126.2 (7)
O22ii—Ag11—Ag5107.75 (18)O15—C33—O16130.1 (9)
Ag10—Ag11—Ag553.87 (2)O15—C33—C34117.6 (8)
C2—C1—Ag1172.1 (7)O16—C33—C34112.3 (8)
C2—C1—Ag4103.9 (7)F22—C34—F23108.6 (7)
Ag1—C1—Ag477.4 (3)F22—C34—F24108.3 (7)
C2—C1—Ag298.4 (7)F23—C34—F24106.9 (7)
Ag1—C1—Ag279.9 (3)F22—C34—C33112.4 (7)
Ag4—C1—Ag2157.3 (4)F23—C34—C33112.1 (7)
C2—C1—Ag393.1 (6)F24—C34—C33108.3 (7)
Ag4—C1—C2—Ag394.4 (4)O2—C19—C20—F3128.3 (11)
Ag2—C1—C2—Ag381.5 (3)Ag1—O3—C21—O48.0 (15)
Ag1i—C1—C2—Ag3174.4 (7)Ag1—O3—C21—C22170.8 (6)
Ag3—C2—C3—C6165.8 (8)Ag3—O4—C21—O323.5 (16)
Ag3—C2—C3—C412.6 (10)Ag3—O4—C21—C22157.8 (6)
C6—C3—C4—Ag6116.9 (9)O3—C21—C22—F6155.6 (10)
C2—C3—C4—Ag664.6 (9)O4—C21—C22—F625.5 (13)
Ag6—C4—C5—Ag762.8 (9)O3—C21—C22—F585.6 (11)
Ag6—C4—C5—Ag8169.6 (6)O4—C21—C22—F593.3 (11)
Ag6—C4—C5—Ag581.8 (9)O3—C21—C22—F433.8 (13)
C2—C3—C6—C7178.4 (9)O4—C21—C22—F4147.3 (10)
C4—C3—C6—C73.3 (15)Ag2—O5—C23—O64.2 (17)
C2—C3—C6—C112.4 (16)Ag2—O5—C23—C24175.3 (6)
C4—C3—C6—C11175.9 (9)Ag4i—O6—C23—O519.8 (17)
C3—C6—C7—C8122.7 (11)Ag4i—O6—C23—C24160.6 (6)
C11—C6—C7—C856.6 (12)O5—C23—C24—F9117.3 (11)
C6—C7—C8—C956.2 (12)O6—C23—C24—F962.3 (12)
C7—C8—C9—C1055.7 (14)O5—C23—C24—F83.8 (13)
C8—C9—C10—C1154.3 (14)O6—C23—C24—F8176.5 (10)
C3—C6—C11—C10124.2 (11)O5—C23—C24—F7124.3 (10)
C7—C6—C11—C1055.1 (13)O6—C23—C24—F756.1 (12)
C9—C10—C11—C653.3 (13)Ag5—O7—C25—O830 (2)
Ag10—C12—C13—C1421 (6)Ag5—O7—C25—C26148.5 (9)
Ag9—C12—C13—C1477 (6)Ag6—O8—C25—O72 (2)
Ag5—C12—C13—C14177 (5)Ag6—O8—C25—C26176.3 (7)
Ag11—C12—C13—C14100 (6)O7—C25—C26—F12151.5 (12)
Ag10—C12—C13—Ag1178.8 (9)O8—C25—C26—F1229.7 (15)
Ag9—C12—C13—Ag11176.8 (5)O7—C25—C26—F1189.4 (13)
Ag5—C12—C13—Ag1183.0 (12)O8—C25—C26—F1189.4 (12)
C12—C13—C14—C15151 (5)O7—C25—C26—F1030.5 (14)
Ag11—C13—C14—C15113.1 (4)O8—C25—C26—F10150.7 (11)
C12—C13—C14—C13ii29 (5)Ag5—O9—C27—O1022 (2)
Ag11—C13—C14—C13ii66.9 (4)Ag5—O9—C27—C28154.1 (9)
C13—C14—C15—C16ii161.9 (11)Ag11—O10—C27—O910.4 (19)
C13ii—C14—C15—C16ii18.1 (11)Ag11—O10—C27—C28173.4 (6)
C13—C14—C15—C1618.1 (11)O9—C27—C28—F13171.5 (11)
C13ii—C14—C15—C16161.9 (11)O10—C27—C28—F1311.7 (14)
C14—C15—C16—C17145.4 (9)O9—C27—C28—F1447.3 (14)
C16ii—C15—C16—C1734.6 (9)O10—C27—C28—F14135.9 (11)
C15—C16—C17—C1867.3 (17)O9—C27—C28—F1569.7 (13)
C16—C17—C18—C17ii36.6 (9)O10—C27—C28—F15107.1 (11)
C35—S1—O17—Ag235.2 (10)Ag9—O12—C29—O1111.4 (17)
C36—S1—O17—Ag269.0 (9)Ag9—O12—C29—C30168.5 (6)
C37—S2—O18—Ag384.9 (8)Ag7—O11—C29—O1211.5 (17)
C38—S2—O18—Ag316.8 (9)Ag7—O11—C29—C30168.6 (6)
C37—S2—O18—Ag796.8 (7)O12—C29—C30—F186.2 (13)
C38—S2—O18—Ag7161.5 (6)O11—C29—C30—F18173.8 (9)
C40—S3—O19—Ag666.6 (9)O12—C29—C30—F17128.9 (10)
C39—S3—O19—Ag636.4 (8)O11—C29—C30—F1751.2 (11)
C40—S3—O19—Ag389.7 (8)O12—C29—C30—F16113.1 (10)
C39—S3—O19—Ag3167.3 (6)O11—C29—C30—F1666.9 (11)
C42—S4—O20—Ag642.4 (8)Ag9—O14—C31—O1310.8 (18)
C41—S4—O20—Ag660.7 (7)Ag9—O14—C31—C32166.8 (6)
C42—S4—O20—Ag4160.0 (6)Ag8—O13—C31—O1416.2 (17)
C41—S4—O20—Ag496.9 (6)Ag8—O13—C31—C32166.3 (6)
C43—S5—O21—Ag1168.5 (8)O14—C31—C32—F2120.2 (13)
C44—S5—O21—Ag1133.4 (10)O13—C31—C32—F21161.9 (10)
C43—S5—O21—Ag9ii129.1 (6)O14—C31—C32—F19142.1 (10)
C44—S5—O21—Ag9ii129.1 (8)O13—C31—C32—F1940.0 (13)
C45—S6—O22—Ag10178.6 (6)O14—C31—C32—F2098.9 (11)
C46—S6—O22—Ag1080.4 (7)O13—C31—C32—F2079.0 (11)
C45—S6—O22—Ag11ii28.0 (9)Ag8—O15—C33—O1611.9 (17)
C46—S6—O22—Ag11ii72.9 (8)Ag8—O15—C33—C34170.8 (6)
Ag4i—O1—C19—O240.0 (16)Ag10—O16—C33—O158.7 (17)
Ag4i—O1—C19—C20144.9 (7)Ag10—O16—C33—C34168.7 (6)
Ag2—O2—C19—O16.9 (16)O15—C33—C34—F22145.2 (9)
Ag2—O2—C19—C20168.1 (6)O16—C33—C34—F2237.1 (11)
O1—C19—C20—F270.1 (13)O15—C33—C34—F2322.5 (12)
O2—C19—C20—F2114.2 (11)O16—C33—C34—F23159.8 (8)
O1—C19—C20—F1167.0 (11)O15—C33—C34—F2495.1 (10)
O2—C19—C20—F18.7 (14)O16—C33—C34—F2482.6 (10)
O1—C19—C20—F347.4 (13)
Symmetry codes: (i) x+3/2, y+3/2, z+1; (ii) x+1, y, z+1/2.
(III) top
Crystal data top
7(Ag+)·(C12H122)·5(C2F3O2)·5(C2H6SO)Z = 4
Mr = 1867.04F(000) = 3592
Monoclinic, CcDx = 2.329 Mg m3
a = 17.8567 (17) ÅMo Kα radiation, λ = 0.71073 Å
b = 21.007 (2) ŵ = 2.83 mm1
c = 16.044 (3) ÅT = 173 K
β = 117.802 (1)°Block, yellow
V = 5323.6 (12) Å30.50 × 0.40 × 0.40 mm
Data collection top
Bruker APEX-II CCD
diffractometer
5135 reflections with I > 2σ(I)
φ and ω scanRint = 0.102
Absorption correction: multi-scan
SADABS (Bruker, 2003)
θmax = 25.3°, θmin = 2.4°
Tmin = 0.332, Tmax = 0.398h = 2021
19165 measured reflectionsk = 2525
6449 independent reflectionsl = 1919
Refinement top
Refinement on F2Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: fullH-atom parameters constrained
R[F2 > 2σ(F2)] = 0.066 w = 1/[σ2(Fo2) + (0.0867P)2]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.165(Δ/σ)max < 0.001
S = 1.05Δρmax = 1.67 e Å3
6449 reflectionsΔρmin = 1.38 e Å3
668 parametersAbsolute structure: Refined as an inversion twin.
184 restraintsAbsolute structure parameter: 0.48 (12)
Crystal data top
7(Ag+)·(C12H122)·5(C2F3O2)·5(C2H6SO)V = 5323.6 (12) Å3
Mr = 1867.04Z = 4
Monoclinic, CcMo Kα radiation
a = 17.8567 (17) ŵ = 2.83 mm1
b = 21.007 (2) ÅT = 173 K
c = 16.044 (3) Å0.50 × 0.40 × 0.40 mm
β = 117.802 (1)°
Data collection top
Bruker APEX-II CCD
diffractometer
6449 independent reflections
Absorption correction: multi-scan
SADABS (Bruker, 2003)
5135 reflections with I > 2σ(I)
Tmin = 0.332, Tmax = 0.398Rint = 0.102
19165 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.066H-atom parameters constrained
wR(F2) = 0.165Δρmax = 1.67 e Å3
S = 1.05Δρmin = 1.38 e Å3
6449 reflectionsAbsolute structure: Refined as an inversion twin.
668 parametersAbsolute structure parameter: 0.48 (12)
184 restraints
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refined as a 2-component inversion twin.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.05523 (11)0.21197 (9)0.41366 (11)0.0285 (4)
Ag20.11214 (12)0.33360 (9)0.38233 (13)0.0367 (5)
Ag30.04057 (10)0.24222 (8)0.22717 (11)0.0228 (4)
Ag40.14247 (13)0.12186 (9)0.34269 (15)0.0404 (5)
Ag50.40369 (11)0.32840 (8)0.72935 (12)0.0299 (4)
Ag60.42058 (11)0.19386 (9)0.76250 (12)0.0301 (4)
Ag70.25700 (11)0.23919 (10)0.61825 (13)0.0386 (5)
C10.1493 (14)0.2320 (11)0.3680 (15)0.029 (5)
C20.2257 (15)0.2297 (12)0.4068 (15)0.031 (5)
C30.3177 (14)0.2338 (14)0.4484 (14)0.037 (6)
C40.3576 (14)0.2431 (12)0.5497 (16)0.033 (6)
C50.3974 (13)0.2495 (12)0.6349 (15)0.032 (6)
C60.3601 (19)0.2232 (16)0.400 (2)0.060 (9)0.6667
C70.460 (2)0.220 (2)0.451 (3)0.053 (4)*0.6667
H7A0.48330.25360.49970.064*0.6667
H7B0.47840.17810.48420.064*0.6667
C80.496 (2)0.227 (2)0.386 (3)0.053 (4)*0.6667
H8A0.48310.18790.34690.064*0.6667
H8B0.55880.22930.42370.064*0.6667
C90.466 (3)0.283 (2)0.322 (3)0.053 (4)*0.6667
H9A0.46430.32010.35990.064*0.6667
H9B0.50980.29330.30220.064*0.6667
C100.384 (3)0.279 (2)0.238 (3)0.053 (4)*0.6667
H10A0.39230.24930.19490.064*0.6667
H10B0.37440.32170.20720.064*0.6667
C110.305 (3)0.261 (2)0.237 (3)0.053 (4)*0.6667
H11A0.28480.29670.26220.064*0.6667
H11B0.26100.25340.17110.064*0.6667
C120.314 (3)0.204 (2)0.293 (2)0.053 (4)*0.6667
H12A0.34760.17120.28050.064*0.6667
H12B0.25770.18530.27690.064*0.6667
C6'0.3601 (19)0.2232 (16)0.400 (2)0.060 (9)0.3333
C7'0.454 (3)0.249 (3)0.441 (4)0.053 (4)*0.3333
H7'10.45380.29150.41410.064*0.3333
H7'20.47890.25380.51030.064*0.3333
C8'0.508 (3)0.206 (4)0.420 (4)0.053 (4)*0.3333
H8'10.49460.16140.42880.064*0.3333
H8'20.56790.21380.46520.064*0.3333
C9'0.498 (4)0.212 (4)0.322 (4)0.053 (4)*0.3333
H9'10.53550.24680.32230.064*0.3333
H9'20.51920.17210.30710.064*0.3333
C10'0.413 (4)0.224 (4)0.244 (4)0.053 (4)*0.3333
H10C0.38570.18210.22420.064*0.3333
H10D0.42170.24050.19130.064*0.3333
C11'0.350 (5)0.266 (3)0.251 (4)0.053 (4)*0.3333
H11C0.37990.30370.29010.064*0.3333
H11D0.31080.28190.18710.064*0.3333
C12'0.302 (3)0.234 (4)0.292 (3)0.053 (4)*0.3333
H12C0.28040.19320.25970.064*0.3333
H12D0.25300.26110.28220.064*0.3333
S10.1405 (4)0.1037 (3)0.6040 (5)0.0442 (16)
O110.1697 (11)0.1449 (9)0.5468 (13)0.045 (4)
C230.0815 (19)0.0433 (14)0.5270 (18)0.060 (9)
H23A0.02330.05800.48780.091*
H23B0.08090.00590.56320.091*
H23C0.10690.03190.48650.091*
C240.2318 (17)0.0575 (15)0.674 (2)0.058 (8)
H24A0.25650.04180.63490.086*
H24B0.21590.02140.70120.086*
H24C0.27340.08400.72500.086*
S20.3256 (7)0.0485 (5)0.4307 (7)0.048 (3)0.6667
O120.2326 (14)0.0380 (10)0.4092 (17)0.108 (12)0.6667
C250.370 (2)0.0299 (15)0.448 (3)0.110 (18)0.6667
H25A0.37140.04880.50480.165*0.6667
H25B0.42820.02720.45660.165*0.6667
H25C0.33590.05640.39340.165*0.6667
C260.372 (3)0.0777 (19)0.542 (3)0.100 (15)0.6667
H26A0.33120.10250.55280.149*0.6667
H26B0.42000.10520.55100.149*0.6667
H26C0.39340.04240.58720.149*0.6667
S2'0.3112 (13)0.0132 (10)0.4949 (14)0.060 (6)0.3333
O12'0.2326 (14)0.0380 (10)0.4092 (17)0.108 (12)0.3333
C25'0.370 (2)0.0299 (15)0.448 (3)0.110 (18)0.3333
H25D0.34060.02780.37940.165*0.3333
H25E0.37600.07440.46860.165*0.3333
H25F0.42670.01080.47180.165*0.3333
C26'0.372 (3)0.0777 (19)0.542 (3)0.100 (15)0.3333
H26D0.41540.08020.52040.149*0.3333
H26E0.40050.07440.61110.149*0.3333
H26F0.33730.11610.52260.149*0.3333
S30.2714 (4)0.4024 (3)0.5144 (4)0.0405 (15)
O130.3128 (10)0.4037 (8)0.6203 (11)0.035 (4)
C270.2331 (19)0.4778 (11)0.477 (2)0.063 (9)
H27A0.19020.48810.49660.094*
H27B0.20770.47980.40810.094*
H27C0.27960.50850.50470.094*
C280.358 (3)0.4030 (17)0.487 (3)0.073 (10)
H28A0.37460.44710.48330.110*
H28B0.34120.38180.42630.110*
H28C0.40670.38040.53640.110*
S40.4745 (4)0.4813 (3)0.7282 (4)0.0389 (14)
O140.5033 (9)0.4228 (8)0.7893 (11)0.035 (4)
C290.5619 (17)0.5350 (14)0.778 (2)0.053 (7)
H29A0.58430.53630.84660.080*
H29B0.54310.57770.75190.080*
H29C0.60630.52050.76280.080*
C300.411 (2)0.5198 (14)0.766 (3)0.062 (8)
H30A0.35880.49510.74730.092*
H30B0.39620.56210.73700.092*
H30C0.44080.52400.83460.092*
S50.0839 (6)0.3477 (5)0.5827 (7)0.044 (2)0.6667
O150.1280 (12)0.2986 (9)0.5517 (11)0.049 (5)0.6667
C310.168 (3)0.385 (2)0.688 (3)0.061 (15)*0.6667
H31A0.20630.35210.72920.091*0.6667
H31B0.14300.40820.72190.091*0.6667
H31C0.20000.41470.66940.091*0.6667
C320.033 (3)0.294 (2)0.631 (3)0.061 (12)*0.6667
H32A0.00540.26510.58160.092*0.6667
H32B0.00170.31860.65600.092*0.6667
H32C0.07690.26850.68230.092*0.6667
S5'0.0961 (11)0.3024 (9)0.6267 (12)0.033 (4)0.3333
O15'0.1280 (12)0.2986 (9)0.5517 (11)0.049 (5)0.3333
C31'0.164 (3)0.365 (3)0.706 (4)0.027 (17)*0.3333
H31D0.22040.36220.70960.040*0.3333
H31E0.16950.35820.76920.040*0.3333
H31F0.13930.40640.68230.040*0.3333
C32'0.002 (3)0.347 (3)0.557 (4)0.024 (14)*0.3333
H32D0.00310.37190.50850.037*0.3333
H32E0.01330.37550.59830.037*0.3333
H32F0.04970.31690.52650.037*0.3333
O10.1682 (14)0.3887 (11)0.2927 (12)0.070 (7)
O20.0739 (13)0.3357 (10)0.1674 (12)0.059 (6)
C130.1275 (14)0.3779 (11)0.2075 (16)0.032 (5)
C140.1460 (12)0.4217 (10)0.1450 (13)0.055 (8)
F10.168 (2)0.3874 (12)0.094 (2)0.175 (14)
F20.2057 (15)0.4624 (13)0.1887 (17)0.149 (11)
F30.0804 (13)0.4543 (13)0.0890 (17)0.138 (11)
O30.0449 (12)0.4248 (9)0.3854 (14)0.058 (5)
O40.0666 (12)0.4133 (8)0.2481 (14)0.063 (6)
C150.0124 (16)0.4448 (13)0.3141 (18)0.041 (6)
C160.0154 (10)0.5179 (9)0.2985 (12)0.052 (7)
F40.0272 (12)0.5489 (9)0.3757 (12)0.109 (8)
F50.0922 (10)0.5377 (9)0.2602 (14)0.090 (6)
F60.0159 (14)0.5314 (11)0.2429 (16)0.115 (9)
O50.0744 (14)0.1829 (11)0.1306 (12)0.060 (6)
O60.1345 (17)0.0909 (9)0.1980 (15)0.068 (7)
C170.1162 (17)0.1374 (14)0.1374 (17)0.040 (6)
C180.1431 (10)0.1278 (7)0.0598 (12)0.046 (7)
F70.2067 (10)0.0910 (8)0.0838 (13)0.082 (6)
F80.0799 (10)0.1051 (7)0.0134 (11)0.073 (5)
F90.1611 (11)0.1827 (6)0.0373 (14)0.074 (5)
O70.3642 (11)0.3586 (9)0.8370 (12)0.042 (4)
O80.4700 (11)0.3179 (9)0.9668 (12)0.041 (4)
C190.4033 (16)0.3439 (11)0.9230 (18)0.033 (6)
C200.3588 (11)0.3657 (9)0.9832 (12)0.051 (8)
F100.2800 (9)0.3798 (9)0.9324 (12)0.082 (6)
F110.3631 (16)0.3225 (11)1.0419 (16)0.132 (10)
F120.3974 (12)0.4152 (11)1.0302 (15)0.119 (9)
O90.3629 (15)0.1800 (11)0.8611 (15)0.065 (6)
O100.2374 (12)0.2199 (12)0.7479 (13)0.061 (6)
C210.2898 (19)0.2016 (14)0.833 (2)0.048 (7)
C220.2478 (11)0.1923 (8)0.8957 (12)0.051 (7)
F130.2009 (12)0.2400 (8)0.8908 (13)0.080 (6)
F140.3049 (10)0.1852 (10)0.9817 (12)0.097 (7)
F150.2010 (12)0.1418 (8)0.8727 (14)0.090 (6)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0239 (8)0.0374 (10)0.0222 (7)0.0042 (7)0.0091 (7)0.0028 (7)
Ag20.0384 (10)0.0279 (9)0.0333 (9)0.0004 (8)0.0080 (8)0.0014 (8)
Ag30.0174 (7)0.0303 (9)0.0177 (7)0.0011 (7)0.0056 (6)0.0007 (7)
Ag40.0410 (11)0.0316 (10)0.0515 (11)0.0018 (9)0.0240 (9)0.0001 (9)
Ag50.0268 (8)0.0346 (10)0.0242 (8)0.0058 (7)0.0083 (7)0.0007 (7)
Ag60.0285 (9)0.0320 (10)0.0308 (8)0.0000 (8)0.0146 (7)0.0074 (7)
Ag70.0203 (9)0.0668 (14)0.0263 (8)0.0059 (9)0.0088 (7)0.0002 (9)
C10.033 (9)0.031 (10)0.028 (9)0.010 (8)0.018 (8)0.011 (7)
C20.029 (9)0.047 (10)0.020 (8)0.005 (8)0.015 (7)0.003 (8)
C30.016 (11)0.074 (19)0.016 (10)0.002 (11)0.002 (9)0.009 (11)
C40.019 (11)0.058 (17)0.027 (12)0.005 (11)0.015 (10)0.006 (11)
C50.013 (10)0.065 (17)0.014 (9)0.012 (10)0.002 (8)0.002 (10)
C60.046 (17)0.09 (3)0.039 (15)0.015 (17)0.017 (13)0.011 (16)
C6'0.046 (17)0.09 (3)0.039 (15)0.015 (17)0.017 (13)0.011 (16)
S10.044 (4)0.044 (4)0.037 (3)0.003 (3)0.013 (3)0.005 (3)
O110.039 (10)0.045 (11)0.041 (10)0.009 (8)0.009 (8)0.015 (9)
C230.063 (19)0.043 (17)0.032 (13)0.013 (14)0.013 (13)0.009 (12)
C240.030 (14)0.050 (19)0.07 (2)0.004 (12)0.007 (13)0.014 (15)
S20.058 (6)0.041 (6)0.032 (5)0.006 (5)0.010 (4)0.000 (4)
O120.063 (15)0.047 (14)0.13 (2)0.034 (12)0.022 (15)0.020 (15)
C250.07 (2)0.05 (2)0.17 (4)0.015 (19)0.02 (3)0.05 (3)
C260.17 (4)0.08 (3)0.09 (3)0.02 (3)0.09 (3)0.01 (2)
S2'0.072 (16)0.057 (15)0.046 (12)0.001 (12)0.021 (11)0.000 (11)
O12'0.063 (15)0.047 (14)0.13 (2)0.034 (12)0.022 (15)0.020 (15)
C25'0.07 (2)0.05 (2)0.17 (4)0.015 (19)0.02 (3)0.05 (3)
C26'0.17 (4)0.08 (3)0.09 (3)0.02 (3)0.09 (3)0.01 (2)
S30.042 (3)0.029 (3)0.034 (3)0.003 (3)0.003 (3)0.003 (3)
O130.037 (9)0.036 (10)0.033 (8)0.016 (8)0.016 (7)0.013 (7)
C270.054 (17)0.013 (12)0.08 (2)0.001 (12)0.006 (15)0.006 (13)
C280.11 (3)0.06 (2)0.07 (2)0.01 (2)0.05 (2)0.009 (17)
S40.040 (3)0.034 (3)0.037 (3)0.001 (3)0.013 (3)0.000 (3)
O140.025 (8)0.042 (10)0.039 (9)0.012 (7)0.017 (7)0.007 (8)
C290.040 (15)0.040 (16)0.068 (19)0.001 (13)0.014 (14)0.001 (14)
C300.059 (19)0.034 (16)0.08 (2)0.011 (14)0.026 (17)0.000 (15)
S50.040 (5)0.057 (7)0.039 (5)0.016 (5)0.022 (4)0.006 (5)
O150.047 (11)0.070 (13)0.025 (8)0.008 (10)0.013 (8)0.003 (8)
S5'0.034 (10)0.041 (12)0.033 (9)0.008 (8)0.022 (8)0.001 (8)
O15'0.047 (11)0.070 (13)0.025 (8)0.008 (10)0.013 (8)0.003 (8)
O10.080 (15)0.070 (15)0.026 (9)0.033 (12)0.004 (10)0.006 (9)
O20.058 (12)0.077 (15)0.026 (9)0.023 (11)0.007 (9)0.020 (9)
C130.028 (12)0.027 (13)0.034 (13)0.006 (10)0.008 (10)0.002 (10)
C140.051 (17)0.08 (2)0.019 (11)0.017 (16)0.006 (12)0.005 (13)
F10.22 (2)0.17 (2)0.19 (2)0.015 (18)0.145 (19)0.043 (18)
F20.151 (19)0.143 (18)0.131 (18)0.087 (15)0.048 (14)0.021 (15)
F30.128 (17)0.151 (19)0.114 (16)0.010 (15)0.041 (14)0.081 (15)
O30.044 (11)0.047 (12)0.057 (12)0.004 (9)0.001 (10)0.000 (10)
O40.041 (11)0.031 (10)0.066 (13)0.004 (9)0.017 (10)0.014 (10)
C150.039 (14)0.046 (17)0.037 (13)0.006 (13)0.018 (12)0.007 (12)
C160.052 (17)0.032 (16)0.055 (17)0.005 (13)0.010 (14)0.005 (14)
F40.128 (15)0.036 (10)0.092 (13)0.000 (10)0.010 (11)0.002 (10)
F50.074 (12)0.056 (11)0.109 (14)0.014 (9)0.018 (11)0.013 (10)
F60.137 (17)0.081 (14)0.163 (19)0.012 (12)0.099 (15)0.031 (13)
O50.076 (14)0.078 (15)0.031 (9)0.047 (12)0.029 (10)0.007 (9)
O60.14 (2)0.020 (10)0.058 (12)0.003 (11)0.052 (14)0.001 (9)
C170.041 (10)0.054 (11)0.036 (9)0.013 (9)0.026 (8)0.005 (8)
C180.057 (11)0.046 (11)0.052 (11)0.006 (9)0.039 (9)0.001 (9)
F70.096 (13)0.077 (12)0.082 (12)0.029 (10)0.048 (11)0.017 (10)
F80.123 (14)0.050 (10)0.061 (10)0.004 (10)0.055 (10)0.002 (8)
F90.089 (12)0.061 (11)0.108 (13)0.011 (9)0.075 (11)0.017 (10)
O70.036 (9)0.053 (12)0.034 (9)0.012 (8)0.015 (8)0.006 (8)
O80.044 (11)0.050 (11)0.033 (9)0.021 (9)0.020 (8)0.004 (8)
C190.038 (14)0.019 (12)0.051 (15)0.003 (10)0.029 (13)0.015 (11)
C200.047 (16)0.08 (2)0.025 (12)0.018 (15)0.019 (12)0.002 (14)
F100.059 (10)0.109 (14)0.102 (13)0.003 (10)0.057 (10)0.021 (11)
F110.150 (18)0.17 (2)0.117 (17)0.059 (15)0.098 (15)0.032 (15)
F120.102 (14)0.155 (18)0.113 (15)0.009 (13)0.061 (12)0.095 (14)
O90.079 (16)0.081 (16)0.060 (13)0.005 (13)0.054 (12)0.022 (11)
O100.039 (11)0.117 (18)0.040 (10)0.014 (11)0.029 (9)0.010 (11)
C210.049 (11)0.046 (12)0.060 (11)0.000 (9)0.034 (9)0.002 (9)
C220.061 (12)0.052 (12)0.040 (10)0.002 (10)0.025 (9)0.010 (9)
F130.097 (13)0.085 (12)0.085 (11)0.033 (10)0.064 (11)0.013 (10)
F140.105 (15)0.141 (17)0.077 (12)0.011 (12)0.068 (12)0.022 (12)
F150.104 (14)0.093 (13)0.098 (13)0.025 (12)0.069 (12)0.004 (11)
Geometric parameters (Å, º) top
Ag1—O8i2.156 (16)S1—O111.521 (19)
Ag1—C12.16 (2)S1—C231.74 (3)
Ag1—O112.580 (17)S1—C241.78 (3)
Ag1—Ag22.879 (3)C23—H23A0.9800
Ag1—Ag32.949 (2)C23—H23B0.9800
Ag1—Ag42.993 (3)C23—H23C0.9800
Ag1—Ag5i3.053 (2)C24—H24A0.9800
Ag1—Ag6i3.184 (2)C24—H24B0.9800
Ag2—O32.27 (2)C24—H24C0.9800
Ag2—C12.28 (2)S2—O121.55 (2)
Ag2—O12.40 (2)S2—C261.70 (4)
Ag2—Ag32.924 (2)S2—C251.79 (3)
Ag2—Ag6i3.097 (2)C25—H25A0.9800
Ag3—C12.20 (2)C25—H25B0.9800
Ag3—O52.279 (17)C25—H25C0.9800
Ag3—C5i2.29 (2)C26—H26A0.9800
Ag3—O22.380 (19)C26—H26B0.9800
Ag3—Ag6i2.801 (2)C26—H26C0.9800
Ag3—Ag5i2.873 (2)S3—O131.504 (17)
Ag3—Ag43.161 (3)S3—C271.72 (2)
Ag4—O122.287 (19)S3—C281.80 (4)
Ag4—C12.34 (2)C27—H27A0.9800
Ag4—O62.35 (2)C27—H27B0.9800
Ag4—O14i2.409 (16)C27—H27C0.9800
Ag4—C22.64 (2)C28—H28A0.9800
Ag5—C52.21 (3)C28—H28B0.9800
Ag5—O72.240 (17)C28—H28C0.9800
Ag5—O132.356 (15)S4—O141.506 (18)
Ag5—O142.535 (15)S4—C301.72 (3)
Ag5—Ag62.866 (2)S4—C291.78 (3)
Ag5—Ag3ii2.873 (2)O14—Ag4ii2.409 (16)
Ag5—Ag73.032 (3)C29—H29A0.9800
Ag5—Ag1ii3.053 (2)C29—H29B0.9800
Ag6—C52.22 (2)C29—H29C0.9800
Ag6—O92.274 (18)C30—H30A0.9800
Ag6—O4ii2.286 (18)C30—H30B0.9800
Ag6—Ag3ii2.801 (2)C30—H30C0.9800
Ag6—Ag72.914 (2)S5—O151.51 (2)
Ag6—Ag2ii3.098 (2)S5—C311.83 (4)
Ag6—Ag1ii3.184 (2)S5—C321.84 (4)
Ag7—O102.300 (17)C31—H31A0.9800
Ag7—O152.389 (18)C31—H31B0.9800
Ag7—C52.40 (2)C31—H31C0.9800
Ag7—O112.449 (18)C32—H32A0.9800
Ag7—C42.51 (2)C32—H32B0.9800
C1—C21.21 (3)C32—H32C0.9800
C2—C31.46 (3)S5'—C31'1.83 (4)
C3—C61.34 (4)S5'—C32'1.84 (4)
C3—C41.45 (3)C31'—H31D0.9800
C4—C51.22 (3)C31'—H31E0.9800
C5—Ag3ii2.29 (2)C31'—H31F0.9800
C6—C121.57 (4)C32'—H32D0.9800
C6—C71.59 (5)C32'—H32E0.9800
C7—C81.47 (5)C32'—H32F0.9800
C7—H7A0.9900O1—C131.23 (3)
C7—H7B0.9900O2—C131.24 (3)
C8—C91.50 (6)C13—C141.51 (3)
C8—H8A0.9900C14—F11.287 (13)
C8—H8B0.9900C14—F21.289 (13)
C9—C101.46 (5)C14—F31.291 (13)
C9—H9A0.9900O3—C151.20 (3)
C9—H9B0.9900O4—C151.24 (3)
C10—C111.47 (6)O4—Ag6i2.286 (18)
C10—H10A0.9900C15—C161.55 (3)
C10—H10B0.9900C16—F51.283 (13)
C11—C121.47 (5)C16—F61.286 (13)
C11—H11A0.9900C16—F41.288 (13)
C11—H11B0.9900O5—C171.19 (3)
C12—H12A0.9900O6—C171.31 (3)
C12—H12B0.9900C17—C181.54 (3)
C7'—C8'1.47 (5)C18—F71.276 (12)
C7'—H7'10.9900C18—F81.283 (13)
C7'—H7'20.9900C18—F91.293 (12)
C8'—C9'1.50 (6)O7—C191.26 (3)
C8'—H8'10.9900O8—C191.20 (3)
C8'—H8'20.9900O8—Ag1ii2.156 (16)
C9'—C10'1.46 (5)C19—C201.58 (3)
C9'—H9'10.9900C20—F121.281 (13)
C9'—H9'20.9900C20—F111.285 (13)
C10'—C11'1.47 (6)C20—F101.289 (13)
C10'—H10C0.9900O9—C211.25 (4)
C10'—H10D0.9900O10—C211.30 (4)
C11'—C12'1.47 (5)C21—C221.52 (3)
C11'—H11C0.9900C22—F131.283 (13)
C11'—H11D0.9900C22—F141.286 (13)
C12'—H12C0.9900C22—F151.293 (13)
C12'—H12D0.9900
O8i—Ag1—C1173.3 (8)H7A—C7—H7B107.8
O8i—Ag1—O1186.9 (6)C7—C8—C9116 (4)
C1—Ag1—O1186.9 (7)C7—C8—H8A108.4
O8i—Ag1—Ag2134.4 (5)C9—C8—H8A108.4
C1—Ag1—Ag251.3 (6)C7—C8—H8B108.4
O11—Ag1—Ag2114.9 (4)C9—C8—H8B108.4
O8i—Ag1—Ag3136.0 (5)H8A—C8—H8B107.4
C1—Ag1—Ag347.9 (6)C10—C9—C8118 (4)
O11—Ag1—Ag3128.2 (5)C10—C9—H9A107.8
Ag2—Ag1—Ag360.20 (6)C8—C9—H9A107.8
O8i—Ag1—Ag4123.7 (5)C10—C9—H9B107.8
C1—Ag1—Ag451.0 (6)C8—C9—H9B107.8
O11—Ag1—Ag467.5 (5)H9A—C9—H9B107.1
Ag2—Ag1—Ag4101.89 (7)C9—C10—C11125 (4)
Ag3—Ag1—Ag464.28 (6)C9—C10—H10A106.2
O8i—Ag1—Ag5i80.3 (5)C11—C10—H10A106.2
C1—Ag1—Ag5i101.7 (6)C9—C10—H10B106.2
O11—Ag1—Ag5i130.7 (4)C11—C10—H10B106.2
Ag2—Ag1—Ag5i107.64 (7)H10A—C10—H10B106.3
Ag3—Ag1—Ag5i57.18 (5)C12—C11—C10112 (4)
Ag4—Ag1—Ag5i80.76 (7)C12—C11—H11A109.2
O8i—Ag1—Ag6i93.5 (5)C10—C11—H11A109.2
C1—Ag1—Ag6i92.9 (5)C12—C11—H11B109.2
O11—Ag1—Ag6i174.5 (4)C10—C11—H11B109.2
Ag2—Ag1—Ag6i61.20 (6)H11A—C11—H11B107.9
Ag3—Ag1—Ag6i54.20 (5)C11—C12—C6108 (3)
Ag4—Ag1—Ag6i116.44 (7)C11—C12—H12A110.1
Ag5i—Ag1—Ag6i54.66 (5)C6—C12—H12A110.1
O3—Ag2—C1166.7 (8)C11—C12—H12B110.1
O3—Ag2—O188.8 (9)C6—C12—H12B110.1
C1—Ag2—O199.7 (8)H12A—C12—H12B108.5
O3—Ag2—Ag1120.7 (6)C8'—C7'—H7'1109.3
C1—Ag2—Ag147.9 (6)C8'—C7'—H7'2109.3
O1—Ag2—Ag1144.4 (6)H7'1—C7'—H7'2108.0
O3—Ag2—Ag3123.1 (5)C7'—C8'—C9'115 (4)
C1—Ag2—Ag348.0 (5)C7'—C8'—H8'1108.6
O1—Ag2—Ag386.8 (5)C9'—C8'—H8'1108.6
Ag1—Ag2—Ag361.07 (6)C7'—C8'—H8'2108.6
O3—Ag2—Ag6i74.3 (5)C9'—C8'—H8'2108.6
C1—Ag2—Ag6i93.0 (6)H8'1—C8'—H8'2107.5
O1—Ag2—Ag6i111.5 (5)C10'—C9'—C8'118 (4)
Ag1—Ag2—Ag6i64.26 (6)C10'—C9'—H9'1107.7
Ag3—Ag2—Ag6i55.36 (5)C8'—C9'—H9'1107.7
C1—Ag3—O5105.0 (7)C10'—C9'—H9'2107.7
C1—Ag3—C5i149.1 (8)C8'—C9'—H9'2107.7
O5—Ag3—C5i100.0 (8)H9'1—C9'—H9'2107.1
C1—Ag3—O2103.1 (8)C9'—C10'—C11'124 (4)
O5—Ag3—O289.0 (8)C9'—C10'—H10C106.2
C5i—Ag3—O295.2 (8)C11'—C10'—H10C106.2
C1—Ag3—Ag6i103.4 (6)C9'—C10'—H10D106.2
O5—Ag3—Ag6i150.5 (5)C11'—C10'—H10D106.2
C5i—Ag3—Ag6i50.5 (6)H10C—C10'—H10D106.4
O2—Ag3—Ag6i92.5 (6)C12'—C11'—C10'113 (4)
C1—Ag3—Ag5i106.6 (6)C12'—C11'—H11C109.1
O5—Ag3—Ag5i102.9 (7)C10'—C11'—H11C109.1
C5i—Ag3—Ag5i49.2 (7)C12'—C11'—H11D109.1
O2—Ag3—Ag5i143.6 (5)C10'—C11'—H11D109.1
Ag6i—Ag3—Ag5i60.65 (6)H11C—C11'—H11D107.8
C1—Ag3—Ag250.4 (6)C11'—C12'—H12C109.7
O5—Ag3—Ag2142.1 (6)C11'—C12'—H12D109.7
C5i—Ag3—Ag2114.4 (6)H12C—C12'—H12D108.2
O2—Ag3—Ag273.1 (5)O11—S1—C23104.5 (13)
Ag6i—Ag3—Ag265.47 (6)O11—S1—C24102.7 (13)
Ag5i—Ag3—Ag2111.41 (7)C23—S1—C2497.2 (15)
C1—Ag3—Ag147.0 (6)S1—O11—Ag7120.0 (11)
O5—Ag3—Ag1130.2 (5)S1—O11—Ag1116.6 (10)
C5i—Ag3—Ag1102.5 (6)Ag7—O11—Ag191.8 (6)
O2—Ag3—Ag1131.8 (5)S1—C23—H23A109.5
Ag6i—Ag3—Ag167.19 (6)S1—C23—H23B109.5
Ag5i—Ag3—Ag163.24 (5)H23A—C23—H23B109.5
Ag2—Ag3—Ag158.72 (6)S1—C23—H23C109.5
C1—Ag3—Ag447.8 (6)H23A—C23—H23C109.5
O5—Ag3—Ag472.4 (5)H23B—C23—H23C109.5
C5i—Ag3—Ag4127.2 (7)S1—C24—H24A109.5
O2—Ag3—Ag4135.5 (5)S1—C24—H24B109.5
Ag6i—Ag3—Ag4123.38 (8)H24A—C24—H24B109.5
Ag5i—Ag3—Ag480.80 (6)S1—C24—H24C109.5
Ag2—Ag3—Ag497.03 (7)H24A—C24—H24C109.5
Ag1—Ag3—Ag458.55 (6)H24B—C24—H24C109.5
O12—Ag4—C1135.4 (8)O12—S2—C26103.7 (18)
O12—Ag4—O687.3 (8)O12—S2—C25104.9 (14)
C1—Ag4—O6114.8 (7)C26—S2—C25101.6 (18)
O12—Ag4—O14i104.5 (7)S2—O12—Ag4116.3 (12)
C1—Ag4—O14i114.1 (7)S2—C25—H25A109.5
O6—Ag4—O14i88.0 (7)S2—C25—H25B109.5
O12—Ag4—C2109.5 (8)H25A—C25—H25B109.5
C1—Ag4—C227.2 (7)S2—C25—H25C109.5
O6—Ag4—C2112.7 (7)H25A—C25—H25C109.5
O14i—Ag4—C2140.6 (6)H25B—C25—H25C109.5
O12—Ag4—Ag1133.4 (7)S2—C26—H26A109.5
C1—Ag4—Ag145.9 (5)S2—C26—H26B109.5
O6—Ag4—Ag1138.4 (6)H26A—C26—H26B109.5
O14i—Ag4—Ag175.4 (4)S2—C26—H26C109.5
C2—Ag4—Ag166.9 (5)H26A—C26—H26C109.5
O12—Ag4—Ag3167.7 (7)H26B—C26—H26C109.5
C1—Ag4—Ag344.0 (5)O13—S3—C27106.5 (14)
O6—Ag4—Ag383.6 (5)O13—S3—C28104.4 (14)
O14i—Ag4—Ag383.5 (4)C27—S3—C2898.9 (17)
C2—Ag4—Ag366.9 (5)S3—O13—Ag5129.2 (9)
Ag1—Ag4—Ag357.17 (5)S3—C27—H27A109.5
C5—Ag5—O7143.7 (8)S3—C27—H27B109.5
C5—Ag5—O13101.4 (7)H27A—C27—H27B109.5
O7—Ag5—O1391.6 (6)S3—C27—H27C109.5
C5—Ag5—O14130.4 (7)H27A—C27—H27C109.5
O7—Ag5—O1484.5 (6)H27B—C27—H27C109.5
O13—Ag5—O1482.8 (6)S3—C28—H28A109.5
C5—Ag5—Ag649.9 (6)S3—C28—H28B109.5
O7—Ag5—Ag6100.3 (5)H28A—C28—H28B109.5
O13—Ag5—Ag6141.0 (4)S3—C28—H28C109.5
O14—Ag5—Ag6135.0 (4)H28A—C28—H28C109.5
C5—Ag5—Ag3ii51.4 (6)H28B—C28—H28C109.5
O7—Ag5—Ag3ii137.0 (4)O14—S4—C30103.6 (13)
O13—Ag5—Ag3ii129.3 (4)O14—S4—C29105.3 (12)
O14—Ag5—Ag3ii87.6 (4)C30—S4—C2997.5 (15)
Ag6—Ag5—Ag3ii58.43 (6)S4—O14—Ag4ii122.1 (8)
C5—Ag5—Ag751.7 (6)S4—O14—Ag5115.2 (8)
O7—Ag5—Ag797.6 (5)Ag4ii—O14—Ag5104.8 (6)
O13—Ag5—Ag782.6 (4)S4—C29—H29A109.5
O14—Ag5—Ag7165.3 (4)S4—C29—H29B109.5
Ag6—Ag5—Ag759.13 (6)H29A—C29—H29B109.5
Ag3ii—Ag5—Ag7100.38 (7)S4—C29—H29C109.5
C5—Ag5—Ag1ii101.2 (6)H29A—C29—H29C109.5
O7—Ag5—Ag1ii77.7 (4)H29B—C29—H29C109.5
O13—Ag5—Ag1ii153.9 (4)S4—C30—H30A109.5
O14—Ag5—Ag1ii72.6 (4)S4—C30—H30B109.5
Ag6—Ag5—Ag1ii64.99 (6)H30A—C30—H30B109.5
Ag3ii—Ag5—Ag1ii59.58 (5)S4—C30—H30C109.5
Ag7—Ag5—Ag1ii122.01 (8)H30A—C30—H30C109.5
C5—Ag6—O9139.3 (9)H30B—C30—H30C109.5
C5—Ag6—O4ii114.2 (9)O15—S5—C31105.4 (17)
O9—Ag6—O4ii92.5 (9)O15—S5—C3298.8 (17)
C5—Ag6—Ag3ii52.6 (5)C31—S5—C32103 (2)
O9—Ag6—Ag3ii147.1 (6)S5—O15—Ag7138.6 (10)
O4ii—Ag6—Ag3ii109.3 (6)S5—C31—H31A109.5
C5—Ag6—Ag549.6 (7)S5—C31—H31B109.5
O9—Ag6—Ag5102.3 (6)H31A—C31—H31B109.5
O4ii—Ag6—Ag5163.7 (6)S5—C31—H31C109.5
Ag3ii—Ag6—Ag560.92 (6)H31A—C31—H31C109.5
C5—Ag6—Ag753.8 (6)H31B—C31—H31C109.5
O9—Ag6—Ag789.0 (6)S5—C32—H32A109.5
O4ii—Ag6—Ag7110.6 (4)S5—C32—H32B109.5
Ag3ii—Ag6—Ag7105.11 (7)H32A—C32—H32B109.5
Ag5—Ag6—Ag763.29 (6)S5—C32—H32C109.5
C5—Ag6—Ag2ii110.3 (6)H32A—C32—H32C109.5
O9—Ag6—Ag2ii105.8 (6)H32B—C32—H32C109.5
O4ii—Ag6—Ag2ii75.3 (4)C31'—S5'—C32'101 (2)
Ag3ii—Ag6—Ag2ii59.17 (6)S5'—C31'—H31D109.5
Ag5—Ag6—Ag2ii106.80 (7)S5'—C31'—H31E109.5
Ag7—Ag6—Ag2ii164.07 (8)H31D—C31'—H31E109.5
C5—Ag6—Ag1ii97.2 (6)S5'—C31'—H31F109.5
O9—Ag6—Ag1ii88.6 (6)H31D—C31'—H31F109.5
O4ii—Ag6—Ag1ii127.8 (4)H31E—C31'—H31F109.5
Ag3ii—Ag6—Ag1ii58.61 (6)S5'—C32'—H32D109.5
Ag5—Ag6—Ag1ii60.35 (6)S5'—C32'—H32E109.5
Ag7—Ag6—Ag1ii121.54 (8)H32D—C32'—H32E109.5
Ag2ii—Ag6—Ag1ii54.54 (5)S5'—C32'—H32F109.5
O10—Ag7—O1588.5 (7)H32D—C32'—H32F109.5
O10—Ag7—C5120.4 (7)H32E—C32'—H32F109.5
O15—Ag7—C5137.8 (8)C13—O1—Ag2112.5 (17)
O10—Ag7—O1187.1 (7)C13—O2—Ag3131.2 (15)
O15—Ag7—O1186.8 (7)O1—C13—O2128 (2)
C5—Ag7—O11121.8 (8)O1—C13—C14115 (2)
O10—Ag7—C4147.6 (7)O2—C13—C14116.6 (19)
O15—Ag7—C4121.7 (7)F1—C14—F2107.3 (13)
C5—Ag7—C428.6 (7)F1—C14—F3107.5 (12)
O11—Ag7—C4104.5 (8)F2—C14—F3106.2 (13)
O10—Ag7—Ag675.1 (5)F1—C14—C13108 (2)
O15—Ag7—Ag6157.8 (4)F2—C14—C13115.2 (18)
C5—Ag7—Ag648.2 (5)F3—C14—C13112.2 (18)
O11—Ag7—Ag6106.9 (4)C15—O3—Ag2119.8 (19)
C4—Ag7—Ag672.6 (5)C15—O4—Ag6i121.0 (16)
O10—Ag7—Ag591.8 (5)O3—C15—O4127 (3)
O15—Ag7—Ag5109.1 (5)O3—C15—C16117 (2)
C5—Ag7—Ag546.3 (6)O4—C15—C16116 (2)
O11—Ag7—Ag5164.0 (4)F5—C16—F6108.1 (13)
C4—Ag7—Ag568.8 (6)F5—C16—F4108.4 (12)
Ag6—Ag7—Ag557.59 (6)F6—C16—F4107.6 (12)
C2—C1—Ag1133.3 (17)F5—C16—C15110.3 (17)
C2—C1—Ag3141.0 (17)F6—C16—C15109.6 (18)
Ag1—C1—Ag385.1 (8)F4—C16—C15112.7 (17)
C2—C1—Ag2107.4 (19)C17—O5—Ag3137.2 (17)
Ag1—C1—Ag280.8 (7)C17—O6—Ag4114.0 (16)
Ag3—C1—Ag281.6 (7)O5—C17—O6127 (2)
C2—C1—Ag490.2 (17)O5—C17—C18117 (2)
Ag1—C1—Ag483.1 (8)O6—C17—C18116 (2)
Ag3—C1—Ag488.2 (8)F7—C18—F8109.2 (12)
Ag2—C1—Ag4161.6 (11)F7—C18—F9108.7 (12)
C1—C2—C3173 (3)F8—C18—F9107.6 (12)
C1—C2—Ag462.6 (15)F7—C18—C17113.9 (18)
C3—C2—Ag4122.6 (18)F8—C18—C17108.4 (16)
C6—C3—C4124 (2)F9—C18—C17108.7 (17)
C6—C3—C2123 (2)C19—O7—Ag5124.2 (15)
C4—C3—C2112.4 (19)C19—O8—Ag1ii126.5 (16)
C5—C4—C3175 (2)O8—C19—O7130 (2)
C5—C4—Ag770.9 (14)O8—C19—C20115 (2)
C3—C4—Ag7114.1 (15)O7—C19—C20115 (2)
C4—C5—Ag5132 (2)F12—C20—F11108.1 (12)
C4—C5—Ag6137 (2)F12—C20—F10108.4 (12)
Ag5—C5—Ag680.5 (8)F11—C20—F10107.4 (12)
C4—C5—Ag3ii128.6 (18)F12—C20—C19108.0 (16)
Ag5—C5—Ag3ii79.4 (7)F11—C20—C19111.6 (18)
Ag6—C5—Ag3ii76.8 (7)F10—C20—C19113.2 (16)
C4—C5—Ag780.4 (14)C21—O9—Ag6115.8 (19)
Ag5—C5—Ag782.0 (8)C21—O10—Ag7131.4 (18)
Ag6—C5—Ag778.0 (7)O9—C21—O10127 (3)
Ag3ii—C5—Ag7150.7 (10)O9—C21—C22118 (2)
C3—C6—C12122 (3)O10—C21—C22113 (2)
C3—C6—C7121 (3)F13—C22—F14108.9 (13)
C12—C6—C7117 (3)F13—C22—F15107.9 (13)
C8—C7—C6113 (3)F14—C22—F15107.1 (12)
C8—C7—H7A109.1F13—C22—C21111.6 (18)
C6—C7—H7A109.1F14—C22—C21109.6 (18)
C8—C7—H7B109.1F15—C22—C21111.6 (18)
C6—C7—H7B109.1
Ag1—C1—C2—Ag481 (2)O2—C13—C14—F156 (3)
Ag3—C1—C2—Ag487 (3)O1—C13—C14—F24 (3)
Ag2—C1—C2—Ag4174.4 (14)O2—C13—C14—F2176 (2)
Ag4—C2—C3—C665 (3)O1—C13—C14—F3118 (3)
Ag4—C2—C3—C4108 (2)O2—C13—C14—F363 (3)
C6—C3—C4—Ag7168 (3)Ag2—O3—C15—O436 (4)
C2—C3—C4—Ag75 (3)Ag2—O3—C15—C16139.0 (18)
Ag7—C4—C5—Ag570.1 (19)Ag6i—O4—C15—O310 (4)
Ag7—C4—C5—Ag660 (2)Ag6i—O4—C15—C16174.9 (15)
Ag7—C4—C5—Ag3ii176 (2)O3—C15—C16—F5142 (2)
C4—C3—C6—C12171 (3)O4—C15—C16—F543 (3)
C2—C3—C6—C121 (5)O3—C15—C16—F699 (3)
C4—C3—C6—C70 (5)O4—C15—C16—F676 (3)
C2—C3—C6—C7172 (3)O3—C15—C16—F421 (3)
C3—C6—C7—C8163 (4)O4—C15—C16—F4164 (2)
C12—C6—C7—C826 (5)Ag3—O5—C17—O628 (5)
C6—C7—C8—C951 (5)Ag3—O5—C17—C18160.2 (19)
C7—C8—C9—C1081 (5)Ag4—O6—C17—O531 (4)
C8—C9—C10—C1153 (6)Ag4—O6—C17—C18157.2 (15)
C9—C10—C11—C1248 (6)O5—C17—C18—F7160 (2)
C10—C11—C12—C676 (4)O6—C17—C18—F727 (3)
C3—C6—C12—C1199 (4)O5—C17—C18—F878 (3)
C7—C6—C12—C1190 (4)O6—C17—C18—F895 (2)
C7'—C8'—C9'—C10'37 (8)O5—C17—C18—F939 (3)
C8'—C9'—C10'—C11'38 (10)O6—C17—C18—F9148 (2)
C9'—C10'—C11'—C12'83 (7)Ag1ii—O8—C19—O73 (4)
C23—S1—O11—Ag7180.0 (13)Ag1ii—O8—C19—C20174.6 (13)
C24—S1—O11—Ag779.0 (15)Ag5—O7—C19—O88 (4)
C23—S1—O11—Ag170.7 (15)Ag5—O7—C19—C20174.9 (13)
C24—S1—O11—Ag1171.7 (14)O8—C19—C20—F1275 (2)
C26—S2—O12—Ag490.1 (17)O7—C19—C20—F12103 (2)
C25—S2—O12—Ag4163.7 (16)O8—C19—C20—F1144 (2)
C27—S3—O13—Ag5166.7 (15)O7—C19—C20—F11139 (2)
C28—S3—O13—Ag562.6 (17)O8—C19—C20—F10164.9 (19)
C30—S4—O14—Ag4ii145.1 (13)O7—C19—C20—F1017 (3)
C29—S4—O14—Ag4ii43.3 (15)Ag6—O9—C21—O1014 (4)
C30—S4—O14—Ag586.0 (14)Ag6—O9—C21—C22178.9 (16)
C29—S4—O14—Ag5172.2 (12)Ag7—O10—C21—O912 (5)
C31—S5—O15—Ag722 (3)Ag7—O10—C21—C22177.7 (16)
C32—S5—O15—Ag784 (2)O9—C21—C22—F13145 (2)
Ag2—O1—C13—O214 (4)O10—C21—C22—F1348 (3)
Ag2—O1—C13—C14166.6 (16)O9—C21—C22—F1424 (3)
Ag3—O2—C13—O114 (5)O10—C21—C22—F14169 (2)
Ag3—O2—C13—C14165.3 (17)O9—C21—C22—F1594 (3)
O1—C13—C14—F1124 (3)O10—C21—C22—F1573 (3)
Symmetry codes: (i) x1/2, y+1/2, z1/2; (ii) x+1/2, y+1/2, z+1/2.
(IV) top
Crystal data top
7(Ag+)·(C13H142)·5(C2F3O2)·4(C2H6SO)V = 2542.2 (5) Å3
Mr = 1802.94Z = 2
Triclinic, P1F(000) = 1728
a = 13.4350 (15) ÅDx = 2.355 Mg m3
b = 13.8806 (15) ÅMo Kα radiation, λ = 0.71073 Å
c = 16.3609 (18) ŵ = 2.92 mm1
α = 110.194 (2)°T = 173 K
β = 106.492 (2)°Block, yellow
γ = 104.003 (2)°0.50 × 0.40 × 0.40 mm
Data collection top
Bruker APEX-II CCD
diffractometer
15708 reflections with I > 2σ(I)
φ and ω scanRint = 0.075
Absorption correction: multi-scan
SADABS (Bruker, 2003)
θmax = 25.3°, θmin = 1.5°
Tmin = 0.324, Tmax = 0.389h = 1516
31854 measured reflectionsk = 1616
16780 independent reflectionsl = 1919
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.087H-atom parameters constrained
wR(F2) = 0.235 w = 1/[σ2(Fo2) + (0.1443P)2 + 44.008P]
where P = (Fo2 + 2Fc2)/3
S = 1.05(Δ/σ)max = 0.002
16780 reflectionsΔρmax = 3.89 e Å3
1276 parametersΔρmin = 1.66 e Å3
615 restraintsAbsolute structure: Refined as an inversion twin.
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.71 (8)
Crystal data top
7(Ag+)·(C13H142)·5(C2F3O2)·4(C2H6SO)γ = 104.003 (2)°
Mr = 1802.94V = 2542.2 (5) Å3
Triclinic, P1Z = 2
a = 13.4350 (15) ÅMo Kα radiation
b = 13.8806 (15) ŵ = 2.92 mm1
c = 16.3609 (18) ÅT = 173 K
α = 110.194 (2)°0.50 × 0.40 × 0.40 mm
β = 106.492 (2)°
Data collection top
Bruker APEX-II CCD
diffractometer
16780 independent reflections
Absorption correction: multi-scan
SADABS (Bruker, 2003)
15708 reflections with I > 2σ(I)
Tmin = 0.324, Tmax = 0.389Rint = 0.075
31854 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.087H-atom parameters constrained
wR(F2) = 0.235 w = 1/[σ2(Fo2) + (0.1443P)2 + 44.008P]
where P = (Fo2 + 2Fc2)/3
S = 1.05Δρmax = 3.89 e Å3
16780 reflectionsΔρmin = 1.66 e Å3
1276 parametersAbsolute structure: Refined as an inversion twin.
615 restraintsAbsolute structure parameter: 0.71 (8)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refined as a 2-component inversion twin.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.38356 (18)1.04880 (17)0.29993 (16)0.0296 (5)
Ag20.39957 (15)0.95877 (15)0.43389 (14)0.0227 (4)
Ag30.18377 (17)0.97454 (18)0.33388 (18)0.0345 (5)
Ag40.2679 (3)0.8511 (2)0.11866 (19)0.0525 (8)
Ag50.01505 (17)0.74041 (16)0.06564 (14)0.0246 (4)
Ag60.09451 (18)0.73854 (17)0.09833 (15)0.0295 (5)
Ag70.17573 (17)0.53556 (16)0.09545 (14)0.0251 (4)
Ag80.05579 (19)0.55442 (18)0.10487 (15)0.0308 (5)
Ag90.09364 (17)0.34284 (16)0.30561 (15)0.0267 (4)
Ag100.16204 (17)0.53232 (16)0.26833 (14)0.0243 (4)
Ag110.39091 (17)0.42528 (19)0.27721 (16)0.0332 (5)
Ag120.38647 (17)0.06238 (17)0.58175 (15)0.0270 (5)
Ag130.4225 (2)0.26637 (17)0.53787 (16)0.0313 (5)
Ag140.61891 (17)0.18002 (17)0.50427 (15)0.0272 (5)
C10.282 (2)0.882 (2)0.2728 (19)0.023 (5)
C20.213 (2)0.782 (2)0.2325 (16)0.017 (5)
C30.135 (2)0.6717 (19)0.1801 (17)0.018 (5)
C40.061 (2)0.652 (2)0.092 (2)0.023 (5)
C50.001 (2)0.636 (2)0.003 (2)0.026 (5)
C60.134 (2)0.587 (2)0.212 (2)0.027 (6)
C70.053 (2)0.470 (2)0.143 (2)0.030 (6)
H7A0.09470.43000.11400.035*
H7B0.00410.47400.09180.035*
C80.007 (3)0.404 (3)0.180 (2)0.042 (7)
H8A0.04490.32580.13050.050*
H8B0.04850.40580.23610.050*
C90.095 (4)0.447 (4)0.209 (4)0.071 (12)
H9A0.13270.39770.23160.085*
H9B0.15330.43710.14990.085*
C100.058 (4)0.566 (4)0.283 (3)0.058 (10)
H10A0.04070.61700.25470.070*
H10B0.11940.57470.30270.070*
C110.050 (4)0.595 (4)0.373 (3)0.064 (11)
H11A0.05610.52470.37130.077*
H11B0.03900.63310.43080.077*
C120.152 (4)0.662 (4)0.379 (3)0.064 (11)
H12A0.14220.72860.37430.077*
H12B0.20950.68760.44340.077*
C130.202 (3)0.614 (3)0.307 (3)0.050 (9)
H13A0.21150.54670.30950.060*
H13B0.27660.66910.32580.060*
C140.224 (2)0.395 (2)0.2382 (18)0.021 (5)
C150.265 (2)0.292 (2)0.270 (2)0.025 (5)
C160.326 (2)0.1780 (18)0.3168 (16)0.014 (4)
C170.408 (3)0.143 (2)0.411 (2)0.032 (6)
C180.465 (2)0.146 (2)0.4811 (19)0.021 (5)
C190.316 (3)0.104 (3)0.280 (2)0.032 (6)
C200.373 (3)0.015 (3)0.331 (2)0.039 (7)
H20A0.44030.03110.38640.046*
H20B0.32310.04500.35610.046*
C210.413 (3)0.081 (3)0.279 (3)0.045 (8)
H21A0.45520.16020.32570.053*
H21B0.34650.07630.22970.053*
C220.490 (4)0.035 (4)0.232 (4)0.072 (12)
H22A0.50930.08100.19990.086*
H22B0.56030.05490.28580.086*
C230.464 (5)0.080 (5)0.164 (4)0.076 (13)
H23A0.47210.12580.19850.091*
H23B0.51740.08040.13290.091*
C240.347 (4)0.130 (4)0.090 (3)0.065 (11)
H24A0.35010.17000.02780.078*
H24B0.32550.06730.08640.078*
C250.246 (4)0.212 (4)0.096 (3)0.067 (11)
H25A0.17860.24360.03620.080*
H25B0.26650.27380.10220.080*
C260.221 (3)0.155 (3)0.177 (2)0.042 (7)
H26A0.15470.20860.17340.050*
H26B0.20040.09460.16820.050*
S10.0743 (5)0.9081 (5)0.3241 (5)0.0257 (13)
O210.0129 (14)0.8547 (16)0.2695 (13)0.027 (4)
C470.163 (3)0.801 (3)0.338 (3)0.040 (7)
H47A0.11690.78010.38210.061*
H47B0.21380.82790.36410.061*
H47C0.20730.73590.27630.061*
C480.172 (3)0.935 (4)0.243 (3)0.046 (8)
H48A0.13160.99350.23090.069*
H48B0.21640.86730.18340.069*
H48C0.22260.95920.27150.069*
S20.2231 (7)0.8851 (7)0.0884 (6)0.0360 (17)
O220.1846 (19)0.875 (2)0.0112 (14)0.038 (5)
C490.337 (3)0.841 (3)0.076 (3)0.042 (8)
H49A0.30990.76100.09790.062*
H49B0.37630.86090.11350.062*
H49C0.38950.87840.00850.062*
C500.298 (5)1.030 (4)0.044 (4)0.073 (13)
H50A0.24481.06770.04660.110*
H50B0.35091.06010.02240.110*
H50C0.33881.04220.08250.110*
S30.3680 (7)0.6334 (7)0.0477 (6)0.0367 (17)
O230.2800 (17)0.6826 (19)0.0259 (15)0.036 (5)
C510.507 (3)0.758 (3)0.130 (2)0.047 (8)
H51A0.53140.79450.09400.070*
H51B0.49630.81030.18200.070*
H51C0.56410.73200.15720.070*
C520.341 (2)0.581 (3)0.126 (2)0.032 (6)
H52A0.27070.51590.09100.048*
H52B0.40260.55960.15190.048*
H52C0.33500.63800.17740.048*
S40.0300 (7)1.0024 (6)0.0916 (5)0.0335 (15)
O240.015 (2)0.8956 (18)0.0740 (15)0.040 (5)
C530.117 (4)0.989 (4)0.017 (3)0.061 (11)
H53A0.19290.93710.03680.092*
H53B0.11921.06180.00940.092*
H53C0.08790.96170.06490.092*
C540.094 (3)1.099 (3)0.107 (3)0.052 (9)
H54A0.15441.11680.16690.078*
H54B0.11481.06710.05390.078*
H54C0.08251.16650.10910.078*
S50.1171 (5)0.0987 (5)0.4906 (4)0.0219 (12)
O250.1783 (16)0.1792 (15)0.4562 (13)0.025 (4)
C550.109 (3)0.032 (3)0.417 (3)0.044 (8)
H55A0.18420.01880.43340.066*
H55B0.06060.00980.42580.066*
H55C0.07770.08750.35030.066*
C560.030 (2)0.181 (2)0.441 (2)0.026 (6)
H56A0.04350.22690.47410.039*
H56B0.05540.22890.37330.039*
H56C0.07210.13200.44960.039*
S60.1621 (6)0.4651 (6)0.4917 (5)0.0286 (14)
O260.2445 (18)0.4207 (17)0.4514 (14)0.035 (5)
C570.172 (4)0.345 (4)0.586 (3)0.056 (10)
H57A0.13630.30300.55900.084*
H57B0.25140.29900.62670.084*
H57C0.13460.36770.62310.084*
C580.232 (3)0.521 (3)0.561 (2)0.040 (7)
H58A0.23370.58980.51960.060*
H58B0.19190.53530.60010.060*
H58C0.30870.46730.60320.060*
S70.5048 (7)0.4923 (7)0.4683 (6)0.0392 (18)
O270.4769 (18)0.4092 (16)0.4351 (16)0.035 (5)
C590.605 (4)0.530 (4)0.424 (4)0.067 (12)
H59A0.67760.46760.45940.100*
H59B0.57890.54760.35630.100*
H59C0.61270.59460.43230.100*
C600.392 (3)0.617 (3)0.391 (3)0.056 (10)
H60A0.32620.61490.40460.084*
H60B0.41120.67800.40010.084*
H60C0.37640.62970.32530.084*
S80.6568 (8)0.2760 (7)0.2900 (7)0.045 (2)
O280.569 (2)0.282 (2)0.3294 (19)0.053 (7)
C610.702 (4)0.394 (4)0.283 (4)0.067 (12)
H61A0.74910.38070.34660.101*
H61B0.74520.40190.24290.101*
H61C0.63600.46280.25420.101*
C620.572 (4)0.327 (4)0.161 (3)0.067 (12)
H62A0.54120.27220.15220.100*
H62B0.51000.39740.13790.100*
H62C0.61910.33800.12590.100*
O10.3524 (17)1.1860 (17)0.2667 (15)0.032 (4)*
O20.5322 (18)1.313 (2)0.3373 (16)0.041 (6)
C270.437 (2)1.268 (2)0.2820 (19)0.024 (5)
C280.4005 (18)1.3323 (17)0.2239 (17)0.042 (8)
F10.4853 (19)1.4177 (19)0.243 (2)0.090 (10)
F20.325 (2)1.368 (3)0.243 (3)0.110 (12)
F30.359 (3)1.267 (2)0.1334 (17)0.141 (16)
O30.482 (2)1.022 (3)0.1882 (19)0.070 (11)
O40.6593 (19)1.077 (2)0.2961 (17)0.045 (6)
C290.585 (3)1.063 (2)0.222 (2)0.031 (6)
C300.6359 (18)1.0936 (18)0.1531 (16)0.042 (8)
F40.594 (3)1.159 (3)0.128 (3)0.127 (14)
F50.7440 (17)1.142 (2)0.1946 (18)0.089 (9)
F60.608 (2)1.003 (2)0.0784 (18)0.112 (13)
O50.4731 (17)0.8220 (16)0.4242 (15)0.030 (4)
O60.6226 (18)0.8911 (16)0.3978 (16)0.033 (5)
C310.560 (2)0.820 (2)0.4064 (19)0.022 (5)
C320.5856 (13)0.7147 (15)0.3985 (11)0.029 (6)
F70.5087 (14)0.6424 (15)0.4044 (14)0.050 (5)
F80.6817 (14)0.7421 (15)0.4661 (13)0.058 (6)
F90.5909 (17)0.6673 (15)0.3166 (11)0.053 (5)
O70.3209 (17)0.9409 (19)0.5395 (16)0.035 (5)
O80.203 (3)1.023 (3)0.4960 (18)0.066 (9)
C330.243 (3)0.973 (3)0.541 (2)0.037 (7)
C340.167 (2)0.934 (2)0.588 (2)0.081 (14)
F100.206 (3)0.881 (3)0.632 (3)0.113 (12)
F110.068 (3)0.867 (3)0.522 (2)0.137 (15)
F120.155 (3)1.016 (2)0.648 (2)0.115 (12)
O90.1194 (18)1.109 (2)0.326 (2)0.048 (6)
O100.2549 (18)1.2516 (16)0.4568 (15)0.037 (5)
C350.165 (2)1.206 (2)0.385 (2)0.029 (6)
C360.1062 (18)1.2819 (18)0.3635 (15)0.040 (7)
F130.008 (2)1.231 (2)0.2935 (18)0.109 (12)
F140.097 (2)1.344 (2)0.4391 (15)0.090 (10)
F150.171 (3)1.347 (3)0.342 (3)0.150 (18)
O110.1077 (19)0.6042 (17)0.2100 (14)0.034 (5)
O120.0333 (19)0.4442 (18)0.3394 (15)0.036 (5)
C370.095 (2)0.545 (3)0.289 (2)0.031 (6)
C380.1617 (16)0.6031 (17)0.3361 (14)0.046 (8)
F160.2671 (14)0.625 (2)0.2905 (16)0.076 (8)
F170.148 (2)0.6953 (16)0.3254 (18)0.076 (8)
F180.133 (2)0.5418 (18)0.4256 (12)0.077 (8)
O130.104 (2)0.4182 (18)0.0773 (17)0.049 (7)
O140.025 (2)0.275 (2)0.2222 (16)0.046 (6)
C390.080 (3)0.322 (2)0.137 (2)0.032 (6)
C400.1383 (19)0.2506 (19)0.0960 (16)0.043 (8)
F190.238 (2)0.313 (2)0.0287 (17)0.098 (10)
F200.150 (3)0.173 (2)0.1616 (17)0.112 (12)
F210.077 (2)0.204 (3)0.062 (3)0.129 (14)
O150.0417 (19)0.8175 (15)0.1631 (15)0.034 (5)
O160.124 (2)0.6664 (17)0.3067 (16)0.042 (6)
C410.077 (2)0.769 (2)0.250 (2)0.027 (6)
C420.0758 (16)0.8481 (16)0.2994 (13)0.036 (7)
F220.094 (2)0.7988 (16)0.3891 (12)0.066 (7)
F230.154 (2)0.887 (2)0.295 (2)0.096 (10)
F240.0196 (18)0.9311 (17)0.2564 (16)0.087 (9)
O170.256 (2)0.634 (2)0.0957 (19)0.054 (7)
O180.2842 (17)0.4720 (16)0.0230 (16)0.035 (5)
C430.298 (2)0.536 (3)0.048 (2)0.028 (6)
C440.3802 (17)0.4695 (16)0.0800 (13)0.042 (8)
F250.4730 (15)0.4860 (17)0.0541 (16)0.067 (7)
F260.3384 (18)0.5054 (19)0.1719 (11)0.065 (6)
F270.4050 (18)0.3626 (14)0.0412 (14)0.057 (6)
O190.260 (2)0.6802 (19)0.098 (2)0.058 (8)
O200.4398 (17)0.5637 (18)0.1967 (18)0.045 (6)
C450.3612 (19)0.651 (2)0.1285 (16)0.015 (5)
C460.4076 (16)0.7424 (17)0.0827 (13)0.038 (7)
F280.3365 (19)0.811 (2)0.0039 (13)0.083 (8)
F290.5039 (17)0.6974 (19)0.0825 (18)0.076 (8)
F300.419 (2)0.799 (2)0.1321 (18)0.088 (9)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0300 (11)0.0247 (10)0.0363 (12)0.0064 (8)0.0131 (9)0.0187 (9)
Ag20.0189 (9)0.0216 (9)0.0258 (10)0.0066 (7)0.0066 (8)0.0112 (8)
Ag30.0202 (10)0.0273 (11)0.0533 (14)0.0117 (8)0.0162 (10)0.0120 (10)
Ag40.091 (2)0.0387 (14)0.0287 (13)0.0187 (14)0.0292 (14)0.0160 (11)
Ag50.0298 (10)0.0211 (9)0.0224 (10)0.0092 (8)0.0074 (8)0.0119 (8)
Ag60.0313 (11)0.0231 (10)0.0303 (11)0.0076 (8)0.0185 (9)0.0049 (8)
Ag70.0241 (10)0.0245 (10)0.0189 (9)0.0048 (8)0.0071 (8)0.0055 (8)
Ag80.0409 (12)0.0333 (11)0.0285 (11)0.0216 (10)0.0209 (10)0.0143 (9)
Ag90.0278 (10)0.0244 (10)0.0326 (11)0.0136 (8)0.0163 (9)0.0119 (9)
Ag100.0324 (10)0.0224 (9)0.0251 (10)0.0119 (8)0.0148 (8)0.0148 (8)
Ag110.0222 (10)0.0391 (12)0.0306 (12)0.0126 (9)0.0078 (9)0.0087 (10)
Ag120.0281 (10)0.0260 (10)0.0357 (11)0.0143 (8)0.0186 (9)0.0159 (9)
Ag130.0459 (13)0.0202 (10)0.0365 (12)0.0137 (9)0.0236 (10)0.0156 (9)
Ag140.0234 (10)0.0293 (11)0.0245 (10)0.0130 (8)0.0062 (8)0.0079 (8)
C10.026 (10)0.019 (9)0.024 (10)0.002 (8)0.006 (8)0.016 (8)
C20.020 (9)0.016 (9)0.006 (8)0.007 (7)0.005 (7)0.004 (7)
C30.016 (9)0.013 (9)0.018 (9)0.005 (7)0.008 (7)0.000 (7)
C40.022 (10)0.025 (10)0.036 (11)0.010 (8)0.013 (8)0.025 (9)
C50.026 (10)0.024 (10)0.048 (12)0.015 (8)0.030 (9)0.022 (9)
C60.026 (10)0.028 (10)0.035 (11)0.009 (8)0.014 (8)0.022 (9)
C70.024 (10)0.023 (10)0.029 (11)0.001 (8)0.005 (8)0.008 (9)
C80.047 (13)0.036 (12)0.039 (12)0.009 (9)0.008 (9)0.027 (10)
C90.071 (17)0.075 (17)0.066 (16)0.017 (12)0.035 (13)0.031 (13)
C100.070 (16)0.055 (14)0.055 (14)0.020 (11)0.025 (11)0.032 (12)
C110.069 (16)0.064 (16)0.057 (15)0.015 (11)0.025 (12)0.031 (12)
C120.065 (16)0.069 (15)0.062 (15)0.018 (11)0.020 (11)0.043 (13)
C130.060 (14)0.039 (12)0.055 (14)0.014 (10)0.016 (10)0.035 (11)
C140.021 (5)0.021 (5)0.021 (5)0.008 (2)0.009 (2)0.009 (3)
C150.022 (10)0.020 (10)0.029 (11)0.002 (8)0.008 (8)0.013 (8)
C160.022 (9)0.011 (8)0.015 (9)0.008 (7)0.012 (7)0.009 (7)
C170.036 (11)0.023 (10)0.037 (12)0.009 (8)0.005 (9)0.021 (9)
C180.021 (10)0.014 (9)0.025 (10)0.004 (7)0.009 (8)0.008 (8)
C190.041 (12)0.039 (11)0.027 (11)0.015 (9)0.024 (9)0.020 (9)
C200.046 (12)0.031 (11)0.038 (12)0.021 (9)0.013 (9)0.013 (9)
C210.044 (13)0.047 (13)0.048 (13)0.015 (10)0.020 (10)0.027 (10)
C220.070 (17)0.072 (17)0.081 (17)0.032 (12)0.033 (12)0.037 (13)
C230.085 (18)0.079 (18)0.074 (17)0.027 (12)0.039 (13)0.042 (13)
C240.077 (16)0.071 (16)0.059 (15)0.027 (12)0.039 (12)0.032 (12)
C250.079 (17)0.067 (16)0.056 (15)0.022 (12)0.021 (11)0.037 (13)
C260.046 (13)0.034 (12)0.044 (13)0.012 (9)0.012 (9)0.024 (10)
S10.021 (3)0.023 (3)0.019 (3)0.004 (2)0.009 (3)0.003 (2)
O210.009 (8)0.028 (10)0.026 (10)0.002 (7)0.005 (7)0.003 (8)
C470.037 (14)0.032 (14)0.049 (16)0.002 (11)0.033 (13)0.009 (12)
C480.043 (16)0.08 (2)0.039 (15)0.040 (14)0.032 (13)0.025 (14)
S20.038 (4)0.046 (4)0.034 (4)0.016 (3)0.019 (3)0.025 (4)
O220.041 (12)0.056 (14)0.019 (10)0.017 (11)0.009 (9)0.022 (10)
C490.024 (13)0.049 (17)0.054 (17)0.018 (12)0.023 (12)0.016 (13)
C500.10 (3)0.049 (18)0.09 (2)0.033 (17)0.040 (19)0.040 (17)
S30.037 (4)0.038 (4)0.038 (4)0.016 (3)0.016 (3)0.017 (3)
O230.024 (10)0.046 (12)0.031 (11)0.021 (9)0.003 (8)0.011 (10)
C510.074 (19)0.049 (16)0.026 (14)0.047 (15)0.023 (13)0.007 (12)
C520.017 (11)0.036 (14)0.043 (15)0.012 (10)0.016 (11)0.013 (12)
S40.038 (4)0.026 (3)0.028 (4)0.010 (3)0.010 (3)0.008 (3)
O240.054 (14)0.033 (11)0.027 (11)0.006 (10)0.016 (10)0.015 (9)
C530.06 (2)0.07 (2)0.06 (2)0.026 (16)0.014 (15)0.031 (16)
C540.047 (17)0.040 (16)0.055 (18)0.006 (13)0.015 (14)0.018 (14)
S50.021 (3)0.022 (3)0.019 (3)0.009 (2)0.009 (2)0.005 (2)
O250.024 (9)0.016 (8)0.018 (9)0.004 (7)0.007 (7)0.002 (7)
C550.055 (17)0.024 (13)0.055 (17)0.005 (12)0.017 (14)0.030 (13)
C560.018 (11)0.015 (11)0.033 (13)0.001 (9)0.004 (10)0.008 (10)
S60.027 (3)0.030 (3)0.029 (3)0.010 (3)0.013 (3)0.011 (3)
O260.035 (11)0.032 (11)0.022 (10)0.000 (9)0.007 (9)0.009 (9)
C570.07 (2)0.07 (2)0.045 (17)0.032 (16)0.046 (16)0.024 (15)
C580.031 (13)0.046 (16)0.040 (15)0.008 (11)0.009 (11)0.025 (13)
S70.050 (5)0.037 (4)0.033 (4)0.025 (4)0.016 (4)0.014 (3)
O270.034 (11)0.021 (10)0.043 (12)0.010 (8)0.009 (10)0.012 (9)
C590.055 (19)0.07 (2)0.08 (2)0.049 (17)0.012 (15)0.030 (17)
C600.052 (18)0.045 (17)0.08 (2)0.021 (14)0.021 (15)0.040 (16)
S80.042 (4)0.039 (4)0.043 (5)0.003 (3)0.024 (4)0.009 (4)
O280.036 (13)0.055 (15)0.052 (15)0.001 (11)0.027 (12)0.012 (13)
C610.043 (17)0.08 (2)0.07 (2)0.023 (16)0.023 (16)0.023 (17)
C620.08 (2)0.08 (2)0.057 (19)0.019 (17)0.032 (16)0.043 (17)
O20.027 (11)0.056 (14)0.036 (12)0.003 (10)0.003 (9)0.032 (11)
C270.027 (11)0.022 (10)0.022 (10)0.004 (8)0.009 (8)0.013 (8)
C280.039 (12)0.041 (12)0.042 (13)0.009 (9)0.012 (9)0.023 (10)
F10.103 (18)0.053 (13)0.091 (17)0.005 (12)0.010 (13)0.054 (13)
F20.11 (2)0.12 (2)0.14 (2)0.070 (17)0.043 (16)0.089 (18)
F30.19 (3)0.12 (2)0.10 (2)0.05 (2)0.018 (17)0.08 (2)
O30.038 (14)0.11 (3)0.037 (14)0.020 (15)0.001 (11)0.050 (16)
O40.025 (11)0.059 (16)0.037 (12)0.012 (10)0.003 (10)0.017 (12)
C290.032 (11)0.031 (11)0.029 (11)0.013 (9)0.008 (9)0.014 (9)
C300.050 (13)0.043 (12)0.042 (12)0.010 (9)0.025 (10)0.029 (10)
F40.17 (3)0.15 (2)0.13 (2)0.061 (18)0.104 (19)0.108 (19)
F50.063 (14)0.11 (2)0.079 (16)0.001 (13)0.045 (13)0.043 (14)
F60.13 (2)0.12 (2)0.093 (18)0.012 (15)0.096 (18)0.034 (15)
O50.033 (10)0.021 (9)0.042 (12)0.018 (8)0.022 (9)0.010 (9)
O60.037 (11)0.023 (10)0.046 (12)0.009 (9)0.024 (10)0.019 (9)
C310.015 (9)0.026 (10)0.031 (10)0.015 (8)0.004 (7)0.018 (8)
C320.030 (11)0.021 (10)0.033 (11)0.014 (8)0.004 (8)0.013 (9)
F70.061 (12)0.033 (9)0.074 (13)0.026 (9)0.035 (10)0.030 (9)
F80.059 (12)0.041 (10)0.065 (13)0.028 (9)0.004 (10)0.026 (10)
F90.063 (12)0.035 (10)0.056 (12)0.023 (9)0.033 (10)0.004 (9)
O70.025 (10)0.044 (12)0.045 (13)0.014 (9)0.014 (9)0.029 (11)
O80.10 (2)0.10 (2)0.033 (13)0.09 (2)0.033 (14)0.032 (15)
C330.030 (11)0.037 (12)0.041 (12)0.008 (9)0.017 (9)0.015 (9)
C340.084 (19)0.079 (18)0.082 (18)0.022 (12)0.044 (14)0.037 (14)
F100.14 (2)0.14 (2)0.13 (2)0.062 (17)0.096 (18)0.088 (18)
F110.09 (2)0.14 (3)0.16 (3)0.019 (17)0.07 (2)0.05 (2)
F120.16 (2)0.09 (2)0.12 (2)0.036 (16)0.10 (2)0.045 (16)
O90.026 (11)0.042 (14)0.071 (17)0.014 (10)0.004 (11)0.030 (13)
O100.035 (11)0.021 (10)0.035 (12)0.017 (9)0.002 (9)0.004 (9)
C350.023 (10)0.023 (10)0.039 (12)0.006 (8)0.010 (9)0.018 (9)
C360.039 (12)0.039 (12)0.042 (12)0.025 (10)0.015 (9)0.013 (9)
F130.105 (19)0.076 (16)0.10 (2)0.063 (15)0.010 (14)0.017 (14)
F140.098 (17)0.084 (16)0.087 (17)0.079 (15)0.021 (13)0.019 (12)
F150.18 (3)0.14 (2)0.17 (3)0.064 (19)0.043 (18)0.13 (2)
O110.049 (13)0.033 (11)0.024 (10)0.006 (9)0.028 (10)0.011 (9)
O120.036 (11)0.030 (11)0.030 (11)0.001 (9)0.012 (9)0.010 (9)
C370.023 (10)0.037 (12)0.038 (12)0.013 (8)0.020 (9)0.014 (9)
C380.031 (12)0.044 (13)0.052 (14)0.012 (10)0.020 (10)0.009 (10)
F160.036 (11)0.106 (18)0.068 (14)0.006 (11)0.029 (10)0.028 (13)
F170.110 (18)0.059 (13)0.103 (17)0.030 (12)0.074 (15)0.060 (13)
F180.093 (17)0.088 (16)0.056 (13)0.014 (13)0.049 (12)0.037 (12)
O130.073 (17)0.022 (11)0.044 (13)0.027 (11)0.005 (12)0.015 (10)
O140.072 (17)0.043 (13)0.034 (13)0.038 (13)0.017 (12)0.021 (11)
C390.036 (11)0.025 (10)0.040 (12)0.009 (8)0.011 (9)0.024 (9)
C400.044 (13)0.042 (12)0.046 (13)0.017 (10)0.010 (9)0.028 (11)
F190.111 (19)0.085 (17)0.075 (16)0.053 (15)0.007 (13)0.036 (14)
F200.15 (2)0.097 (18)0.101 (19)0.093 (18)0.019 (15)0.046 (15)
F210.14 (2)0.15 (2)0.16 (3)0.087 (19)0.054 (17)0.12 (2)
O150.051 (12)0.017 (9)0.031 (11)0.016 (9)0.003 (9)0.018 (9)
O160.074 (17)0.022 (10)0.033 (12)0.018 (11)0.022 (11)0.016 (9)
C410.028 (10)0.026 (10)0.027 (11)0.009 (8)0.007 (8)0.015 (9)
C420.043 (12)0.033 (11)0.032 (12)0.012 (9)0.015 (9)0.017 (9)
F220.099 (16)0.058 (13)0.066 (13)0.027 (11)0.042 (12)0.050 (11)
F230.12 (2)0.096 (16)0.14 (2)0.078 (15)0.058 (15)0.093 (16)
F240.112 (19)0.056 (14)0.075 (16)0.002 (12)0.019 (13)0.045 (13)
O170.038 (13)0.060 (17)0.054 (16)0.004 (12)0.041 (13)0.008 (13)
O180.024 (10)0.018 (9)0.040 (12)0.003 (8)0.018 (9)0.013 (8)
C430.021 (10)0.038 (12)0.028 (11)0.011 (8)0.013 (8)0.013 (9)
C440.039 (12)0.038 (12)0.044 (13)0.016 (10)0.021 (10)0.009 (9)
F250.033 (10)0.067 (14)0.086 (16)0.011 (9)0.029 (11)0.021 (12)
F260.062 (13)0.091 (16)0.041 (11)0.020 (11)0.024 (10)0.030 (11)
F270.062 (13)0.048 (11)0.068 (13)0.017 (9)0.043 (11)0.023 (10)
O190.067 (18)0.023 (11)0.056 (16)0.029 (12)0.004 (13)0.004 (11)
O200.021 (10)0.026 (11)0.051 (14)0.001 (8)0.006 (10)0.011 (10)
C450.014 (9)0.020 (9)0.011 (9)0.009 (7)0.007 (7)0.002 (7)
C460.041 (12)0.039 (12)0.036 (12)0.017 (9)0.020 (9)0.013 (9)
F280.108 (18)0.077 (16)0.047 (13)0.056 (14)0.027 (12)0.003 (11)
F290.063 (13)0.080 (16)0.090 (17)0.034 (12)0.059 (13)0.017 (12)
F300.12 (2)0.090 (16)0.101 (18)0.080 (15)0.052 (14)0.064 (14)
Geometric parameters (Å, º) top
Ag1—C12.21 (2)C26—H26B0.9900
Ag1—O12.25 (2)S1—O211.51 (2)
Ag1—O32.53 (3)S1—C481.79 (3)
Ag1—Ag22.857 (3)S1—C471.80 (3)
Ag1—Ag42.906 (3)C47—H47A0.9800
Ag1—Ag32.912 (3)C47—H47B0.9800
Ag1—Ag12i3.066 (3)C47—H47C0.9800
Ag1—Ag14i3.105 (3)C48—H48A0.9800
Ag1—Ag13i3.112 (3)C48—H48B0.9800
Ag2—O72.32 (2)C48—H48C0.9800
Ag2—O52.323 (18)S2—O221.53 (2)
Ag2—C12.34 (3)S2—C491.77 (3)
Ag2—C18i2.40 (2)S2—C501.78 (5)
Ag2—Ag14i2.980 (3)C49—H49A0.9800
Ag2—Ag32.999 (3)C49—H49B0.9800
Ag2—Ag12i3.011 (3)C49—H49C0.9800
Ag3—C12.25 (3)C50—H50A0.9800
Ag3—O92.27 (2)C50—H50B0.9800
Ag3—O82.42 (2)C50—H50C0.9800
Ag3—O212.438 (17)S3—O231.52 (2)
Ag3—Ag14i3.052 (3)S3—C521.75 (3)
Ag4—O222.276 (19)S3—C511.92 (4)
Ag4—C12.35 (3)C51—H51A0.9800
Ag4—O232.38 (2)C51—H51B0.9800
Ag4—C22.57 (2)C51—H51C0.9800
Ag5—C52.13 (3)C52—H52A0.9800
Ag5—O152.203 (18)C52—H52B0.9800
Ag5—O242.54 (2)C52—H52C0.9800
Ag5—O222.56 (2)S4—O241.48 (2)
Ag5—Ag82.894 (3)S4—C531.74 (4)
Ag5—Ag72.908 (3)S4—C541.76 (4)
Ag5—Ag63.162 (3)C53—H53A0.9800
Ag5—Ag103.186 (3)C53—H53B0.9800
Ag6—O172.28 (2)C53—H53C0.9800
Ag6—O242.40 (2)C54—H54A0.9800
Ag6—O212.435 (19)C54—H54B0.9800
Ag6—C52.54 (3)C54—H54C0.9800
Ag6—C42.66 (3)S5—O251.59 (2)
Ag6—Ag73.092 (3)S5—C551.75 (3)
Ag7—C52.18 (3)S5—C561.80 (3)
Ag7—C142.25 (3)C55—H55A0.9800
Ag7—O182.32 (2)C55—H55B0.9800
Ag7—O192.54 (2)C55—H55C0.9800
Ag7—Ag102.872 (3)C56—H56A0.9800
Ag7—Ag113.062 (3)C56—H56B0.9800
Ag7—Ag83.110 (3)C56—H56C0.9800
Ag8—C52.19 (3)S6—O261.55 (2)
Ag8—O112.277 (18)S6—C581.77 (3)
Ag8—O132.28 (2)S6—C571.78 (4)
Ag8—Ag93.191 (3)C57—H57A0.9800
Ag8—Ag103.220 (3)C57—H57B0.9800
Ag9—O122.26 (2)C57—H57C0.9800
Ag9—O142.38 (2)C58—H58A0.9800
Ag9—O252.412 (18)C58—H58B0.9800
Ag9—C142.45 (3)C58—H58C0.9800
Ag9—C152.52 (3)S7—O271.51 (2)
Ag9—Ag102.918 (3)S7—C601.74 (4)
Ag10—O162.16 (2)S7—C591.80 (5)
Ag10—C142.16 (3)C59—H59A0.9800
Ag10—O262.58 (2)C59—H59B0.9800
Ag10—Ag113.012 (3)C59—H59C0.9800
Ag11—O202.28 (2)C60—H60A0.9800
Ag11—C142.33 (2)C60—H60B0.9800
Ag11—O282.41 (2)C60—H60C0.9800
Ag11—O272.42 (2)S8—O281.49 (3)
Ag12—O4ii2.31 (3)S8—C621.86 (5)
Ag12—O6ii2.322 (19)S8—C611.86 (5)
Ag12—C182.33 (3)C61—H61A0.9800
Ag12—Ag132.868 (3)C61—H61B0.9800
Ag12—Ag2ii3.011 (3)C61—H61C0.9800
Ag12—Ag1ii3.066 (3)C62—H62A0.9800
Ag13—C182.21 (2)C62—H62B0.9800
Ag13—O2ii2.32 (2)C62—H62C0.9800
Ag13—O262.41 (2)O1—C271.29 (3)
Ag13—O272.53 (2)O2—C271.19 (3)
Ag13—Ag142.907 (3)O2—Ag13i2.32 (2)
Ag13—Ag1ii3.112 (3)C27—C281.57 (3)
Ag14—C182.19 (3)C28—F11.299 (15)
Ag14—O10ii2.215 (19)C28—F31.300 (15)
Ag14—O282.51 (3)C28—F21.303 (15)
Ag14—Ag2ii2.980 (3)O3—C291.23 (4)
Ag14—Ag3ii3.052 (3)O4—C291.24 (4)
Ag14—Ag1ii3.105 (3)O4—Ag12i2.31 (3)
C1—C21.26 (4)C29—C301.60 (4)
C2—C31.41 (3)C30—F61.290 (15)
C3—C41.39 (4)C30—F51.294 (14)
C3—C61.44 (4)C30—F41.295 (14)
C4—C51.36 (4)O5—C311.29 (3)
C6—C131.42 (5)O6—C311.20 (3)
C6—C71.51 (4)O6—Ag12i2.323 (19)
C7—C81.46 (4)C31—C321.56 (3)
C7—H7A0.9900C32—F81.302 (14)
C7—H7B0.9900C32—F91.304 (14)
C8—C91.57 (7)C32—F71.305 (14)
C8—H8A0.9900O7—C331.23 (4)
C8—H8B0.9900O8—C331.27 (4)
C9—C101.52 (7)C33—C341.56 (4)
C9—H9A0.9900C34—F101.295 (15)
C9—H9B0.9900C34—F121.296 (15)
C10—C111.59 (6)C34—F111.305 (15)
C10—H10A0.9900O9—C351.21 (4)
C10—H10B0.9900O10—C351.25 (4)
C11—C121.42 (6)O10—Ag14i2.215 (19)
C11—H11A0.9900C35—C361.53 (3)
C11—H11B0.9900C36—F131.298 (15)
C12—C131.54 (7)C36—F141.301 (14)
C12—H12A0.9900C36—F151.307 (15)
C12—H12B0.9900O11—C371.20 (4)
C13—H13A0.9900O12—C371.26 (4)
C13—H13B0.9900C37—C381.59 (4)
C14—C151.25 (4)C38—F171.295 (15)
C15—C161.40 (3)C38—F181.297 (15)
C16—C191.37 (4)C38—F161.300 (15)
C16—C171.45 (4)O13—C391.25 (4)
C17—C181.20 (4)O14—C391.21 (4)
C18—Ag2ii2.40 (2)C39—C401.60 (3)
C19—C201.45 (4)C40—F211.297 (15)
C19—C261.58 (4)C40—F191.302 (15)
C20—C211.54 (5)C40—F201.305 (15)
C20—H20A0.9900O15—C411.22 (4)
C20—H20B0.9900O16—C411.27 (4)
C21—C221.59 (6)C41—C421.57 (3)
C21—H21A0.9900C42—F241.295 (14)
C21—H21B0.9900C42—F221.306 (14)
C22—C231.48 (7)C42—F231.307 (14)
C22—H22A0.9900O17—C431.19 (4)
C22—H22B0.9900O18—C431.29 (4)
C23—C241.49 (7)C43—C441.59 (4)
C23—H23A0.9900C44—F261.301 (15)
C23—H23B0.9900C44—F251.301 (15)
C24—C251.60 (7)C44—F271.307 (15)
C24—H24A0.9900O19—C451.21 (4)
C24—H24B0.9900O20—C451.27 (3)
C25—C261.46 (6)C45—C461.60 (3)
C25—H25A0.9900C46—F291.294 (14)
C25—H25B0.9900C46—F281.299 (15)
C26—H26A0.9900C46—F301.307 (15)
C1—Ag1—O1136.7 (9)H7A—C7—H7B107.1
C1—Ag1—O3106.5 (11)C7—C8—C9112 (3)
O1—Ag1—O388.1 (10)C7—C8—H8A109.2
C1—Ag1—Ag253.1 (7)C9—C8—H8A109.2
O1—Ag1—Ag2145.0 (6)C7—C8—H8B109.2
O3—Ag1—Ag2124.1 (8)C9—C8—H8B109.2
C1—Ag1—Ag452.7 (7)H8A—C8—H8B107.9
O1—Ag1—Ag4104.9 (5)C10—C9—C8120 (4)
O3—Ag1—Ag463.1 (6)C10—C9—H9A107.4
Ag2—Ag1—Ag4102.42 (9)C8—C9—H9A107.4
C1—Ag1—Ag349.8 (8)C10—C9—H9B107.4
O1—Ag1—Ag398.0 (6)C8—C9—H9B107.4
O3—Ag1—Ag3148.6 (6)H9A—C9—H9B106.9
Ag2—Ag1—Ag362.62 (7)C9—C10—C11110 (4)
Ag4—Ag1—Ag385.68 (10)C9—C10—H10A109.6
C1—Ag1—Ag12i98.6 (7)C11—C10—H10A109.6
O1—Ag1—Ag12i124.6 (5)C9—C10—H10B109.6
O3—Ag1—Ag12i75.4 (6)C11—C10—H10B109.6
Ag2—Ag1—Ag12i60.99 (7)H10A—C10—H10B108.1
Ag4—Ag1—Ag12i112.80 (11)C12—C11—C10115 (4)
Ag3—Ag1—Ag12i123.12 (9)C12—C11—H11A108.5
C1—Ag1—Ag14i97.8 (7)C10—C11—H11A108.5
O1—Ag1—Ag14i85.5 (6)C12—C11—H11B108.5
O3—Ag1—Ag14i150.5 (6)C10—C11—H11B108.5
Ag2—Ag1—Ag14i59.81 (7)H11A—C11—H11B107.5
Ag4—Ag1—Ag14i146.24 (11)C11—C12—C13120 (4)
Ag3—Ag1—Ag14i60.86 (7)C11—C12—H12A107.4
Ag12i—Ag1—Ag14i84.79 (8)C13—C12—H12A107.4
C1—Ag1—Ag13i141.1 (7)C11—C12—H12B107.4
O1—Ag1—Ag13i74.6 (5)C13—C12—H12B107.4
O3—Ag1—Ag13i94.8 (6)H12A—C12—H12B106.9
Ag2—Ag1—Ag13i88.00 (8)C6—C13—C12113 (3)
Ag4—Ag1—Ag13i157.77 (11)C6—C13—H13A108.9
Ag3—Ag1—Ag13i116.52 (10)C12—C13—H13A108.9
Ag12i—Ag1—Ag13i55.31 (7)C6—C13—H13B108.9
Ag14i—Ag1—Ag13i55.76 (7)C12—C13—H13B108.9
O7—Ag2—O597.3 (7)H13A—C13—H13B107.8
O7—Ag2—C1118.5 (9)C15—C14—Ag10145 (2)
O5—Ag2—C197.5 (9)C15—C14—Ag7133 (2)
O7—Ag2—C18i103.5 (9)Ag10—C14—Ag781.3 (9)
O5—Ag2—C18i115.3 (8)C15—C14—Ag1198.5 (19)
C1—Ag2—C18i122.3 (9)Ag10—C14—Ag1184.2 (8)
O7—Ag2—Ag1139.7 (5)Ag7—C14—Ag1184.0 (9)
O5—Ag2—Ag1120.8 (5)C15—C14—Ag978.8 (18)
C1—Ag2—Ag149.0 (6)Ag10—C14—Ag978.3 (8)
C18i—Ag2—Ag173.3 (6)Ag7—C14—Ag9125.5 (11)
O7—Ag2—Ag14i84.2 (6)Ag11—C14—Ag9141.9 (12)
O5—Ag2—Ag14i161.1 (5)C14—C15—C16170 (3)
C1—Ag2—Ag14i98.3 (6)C14—C15—Ag972.2 (17)
C18i—Ag2—Ag14i46.6 (6)C16—C15—Ag9112.1 (18)
Ag1—Ag2—Ag14i64.23 (7)C19—C16—C15126 (2)
O7—Ag2—Ag384.0 (5)C19—C16—C17121 (2)
O5—Ag2—Ag3137.5 (5)C15—C16—C17112 (2)
C1—Ag2—Ag347.9 (7)C18—C17—C16161 (3)
C18i—Ag2—Ag3105.4 (6)C17—C18—Ag14127 (2)
Ag1—Ag2—Ag359.57 (7)C17—C18—Ag13129 (2)
Ag14i—Ag2—Ag361.39 (7)Ag14—C18—Ag1382.6 (8)
O7—Ag2—Ag12i144.2 (5)C17—C18—Ag1298 (2)
O5—Ag2—Ag12i79.8 (5)Ag14—C18—Ag12133.9 (12)
C1—Ag2—Ag12i97.2 (7)Ag13—C18—Ag1278.3 (8)
C18i—Ag2—Ag12i49.3 (6)C17—C18—Ag2ii99.9 (19)
Ag1—Ag2—Ag12i62.92 (7)Ag14—C18—Ag2ii80.7 (8)
Ag14i—Ag2—Ag12i87.96 (7)Ag13—C18—Ag2ii128.1 (12)
Ag3—Ag2—Ag12i122.02 (9)Ag12—C18—Ag2ii79.0 (8)
C1—Ag3—O9139.8 (10)C16—C19—C20126 (3)
C1—Ag3—O8121.1 (8)C16—C19—C26115 (3)
O9—Ag3—O893.2 (10)C20—C19—C26118 (3)
C1—Ag3—O21111.0 (8)C19—C20—C21120 (3)
O9—Ag3—O2185.8 (8)C19—C20—H20A107.4
O8—Ag3—O2192.2 (10)C21—C20—H20A107.4
C1—Ag3—Ag148.5 (6)C19—C20—H20B107.4
O9—Ag3—Ag198.4 (7)C21—C20—H20B107.4
O8—Ag3—Ag1118.7 (9)H20A—C20—H20B106.9
O21—Ag3—Ag1148.3 (5)C20—C21—C22111 (3)
C1—Ag3—Ag250.5 (7)C20—C21—H21A109.4
O9—Ag3—Ag2137.8 (6)C22—C21—H21A109.4
O8—Ag3—Ag273.9 (6)C20—C21—H21B109.4
O21—Ag3—Ag2133.6 (5)C22—C21—H21B109.4
Ag1—Ag3—Ag257.80 (7)H21A—C21—H21B108.0
C1—Ag3—Ag14i98.3 (7)C23—C22—C21128 (5)
O9—Ag3—Ag14i79.5 (6)C23—C22—H22A105.3
O8—Ag3—Ag14i60.9 (9)C21—C22—H22A105.3
O21—Ag3—Ag14i148.0 (5)C23—C22—H22B105.3
Ag1—Ag3—Ag14i62.70 (7)C21—C22—H22B105.3
Ag2—Ag3—Ag14i59.01 (7)H22A—C22—H22B106.0
O22—Ag4—C1144.9 (9)C22—C23—C24111 (5)
O22—Ag4—O2393.2 (8)C22—C23—H23A109.5
C1—Ag4—O23116.3 (8)C24—C23—H23A109.5
O22—Ag4—C2139.0 (8)C22—C23—H23B109.5
C1—Ag4—C229.3 (8)C24—C23—H23B109.5
O23—Ag4—C294.6 (8)H23A—C23—H23B108.1
O22—Ag4—Ag1116.6 (6)C23—C24—C25122 (4)
C1—Ag4—Ag148.2 (6)C23—C24—H24A106.9
O23—Ag4—Ag1143.1 (5)C25—C24—H24A106.9
C2—Ag4—Ag177.5 (5)C23—C24—H24B106.9
C5—Ag5—O15168.4 (10)C25—C24—H24B106.9
C5—Ag5—O2495.0 (9)H24A—C24—H24B106.7
O15—Ag5—O2495.9 (7)C26—C25—C24112 (4)
C5—Ag5—O22106.3 (9)C26—C25—H25A109.3
O15—Ag5—O2278.9 (7)C24—C25—H25A109.3
O24—Ag5—O2283.1 (8)C26—C25—H25B109.3
C5—Ag5—Ag848.8 (7)C24—C25—H25B109.3
O15—Ag5—Ag8121.9 (6)H25A—C25—H25B107.9
O24—Ag5—Ag8139.9 (5)C25—C26—C19118 (3)
O22—Ag5—Ag891.0 (5)C25—C26—H26A107.9
C5—Ag5—Ag748.3 (8)C19—C26—H26A107.9
O15—Ag5—Ag7124.1 (6)C25—C26—H26B107.9
O24—Ag5—Ag7106.6 (5)C19—C26—H26B107.9
O22—Ag5—Ag7152.6 (5)H26A—C26—H26B107.2
Ag8—Ag5—Ag764.83 (7)O21—S1—C48105.9 (13)
C5—Ag5—Ag653.3 (7)O21—S1—C47106.2 (14)
O15—Ag5—Ag6134.3 (6)C48—S1—C47103.1 (19)
O24—Ag5—Ag648.3 (5)S1—O21—Ag6124.4 (10)
O22—Ag5—Ag6115.7 (5)S1—O21—Ag3111.5 (10)
Ag8—Ag5—Ag6101.77 (8)Ag6—O21—Ag3114.2 (8)
Ag7—Ag5—Ag661.08 (7)S1—C47—H47A109.5
C5—Ag5—Ag1091.7 (8)S1—C47—H47B109.5
O15—Ag5—Ag1077.1 (5)H47A—C47—H47B109.5
O24—Ag5—Ag10146.4 (6)S1—C47—H47C109.5
O22—Ag5—Ag10126.3 (5)H47A—C47—H47C109.5
Ag8—Ag5—Ag1063.75 (7)H47B—C47—H47C109.5
Ag7—Ag5—Ag1056.01 (6)S1—C48—H48A109.5
Ag6—Ag5—Ag10115.45 (8)S1—C48—H48B109.5
O17—Ag6—O24142.5 (10)H48A—C48—H48B109.5
O17—Ag6—O2194.6 (8)S1—C48—H48C109.5
O24—Ag6—O2190.3 (7)H48A—C48—H48C109.5
O17—Ag6—C5117.1 (9)H48B—C48—H48C109.5
O24—Ag6—C588.6 (8)O22—S2—C49105.2 (15)
O21—Ag6—C5126.3 (8)O22—S2—C50105 (2)
O17—Ag6—C4117.5 (9)C49—S2—C5099 (2)
O24—Ag6—C498.6 (8)S2—O22—Ag4131.5 (13)
O21—Ag6—C497.6 (8)S2—O22—Ag5117.4 (11)
C5—Ag6—C430.2 (9)Ag4—O22—Ag598.2 (8)
O17—Ag6—Ag780.8 (6)S2—C49—H49A109.5
O24—Ag6—Ag7104.9 (5)S2—C49—H49B109.5
O21—Ag6—Ag7160.6 (5)H49A—C49—H49B109.5
C5—Ag6—Ag744.2 (7)S2—C49—H49C109.5
C4—Ag6—Ag768.7 (6)H49A—C49—H49C109.5
O17—Ag6—Ag5132.1 (7)H49B—C49—H49C109.5
O24—Ag6—Ag552.3 (6)S2—C50—H50A109.5
O21—Ag6—Ag5133.2 (5)S2—C50—H50B109.5
C5—Ag6—Ag542.1 (6)H50A—C50—H50B109.5
C4—Ag6—Ag566.9 (6)S2—C50—H50C109.5
Ag7—Ag6—Ag555.40 (6)H50A—C50—H50C109.5
C5—Ag7—C14122.3 (10)H50B—C50—H50C109.5
C5—Ag7—O18112.7 (9)O23—S3—C52104.6 (14)
C14—Ag7—O18107.7 (8)O23—S3—C51105.6 (13)
C5—Ag7—O19102.9 (9)C52—S3—C51101.8 (15)
C14—Ag7—O19115.6 (9)S3—O23—Ag4130.8 (12)
O18—Ag7—O1991.6 (10)S3—C51—H51A109.5
C5—Ag7—Ag1099.5 (7)S3—C51—H51B109.5
C14—Ag7—Ag1048.1 (7)H51A—C51—H51B109.5
O18—Ag7—Ag10147.7 (5)S3—C51—H51C109.5
O19—Ag7—Ag1084.0 (7)H51A—C51—H51C109.5
C5—Ag7—Ag546.8 (7)H51B—C51—H51C109.5
C14—Ag7—Ag5112.3 (7)S3—C52—H52A109.5
O18—Ag7—Ag5139.8 (4)S3—C52—H52B109.5
O19—Ag7—Ag567.3 (7)H52A—C52—H52B109.5
Ag10—Ag7—Ag566.89 (7)S3—C52—H52C109.5
C5—Ag7—Ag11159.9 (7)H52A—C52—H52C109.5
C14—Ag7—Ag1149.1 (6)H52B—C52—H52C109.5
O18—Ag7—Ag1187.2 (5)O24—S4—C53107.6 (18)
O19—Ag7—Ag1172.4 (6)O24—S4—C54108.0 (17)
Ag10—Ag7—Ag1160.89 (7)C53—S4—C5498 (2)
Ag5—Ag7—Ag11115.66 (9)S4—O24—Ag6134.7 (15)
C5—Ag7—Ag654.5 (7)S4—O24—Ag5135.8 (12)
C14—Ag7—Ag6175.7 (7)Ag6—O24—Ag579.5 (7)
O18—Ag7—Ag676.6 (4)S4—C53—H53A109.5
O19—Ag7—Ag664.2 (6)S4—C53—H53B109.5
Ag10—Ag7—Ag6128.24 (9)H53A—C53—H53B109.5
Ag5—Ag7—Ag663.51 (7)S4—C53—H53C109.5
Ag11—Ag7—Ag6132.76 (9)H53A—C53—H53C109.5
C5—Ag7—Ag844.7 (7)H53B—C53—H53C109.5
C14—Ag7—Ag877.9 (7)S4—C54—H54A109.5
O18—Ag7—Ag8139.1 (6)S4—C54—H54B109.5
O19—Ag7—Ag8123.3 (8)H54A—C54—H54B109.5
Ag10—Ag7—Ag864.99 (7)S4—C54—H54C109.5
Ag5—Ag7—Ag857.37 (7)H54A—C54—H54C109.5
Ag11—Ag7—Ag8121.05 (9)H54B—C54—H54C109.5
Ag6—Ag7—Ag898.58 (8)O25—S5—C55104.2 (16)
C5—Ag8—O11131.8 (9)O25—S5—C56107.7 (11)
C5—Ag8—O13108.9 (10)C55—S5—C5696.8 (15)
O11—Ag8—O13117.8 (10)S5—O25—Ag9123.9 (10)
C5—Ag8—Ag547.0 (7)S5—C55—H55A109.5
O11—Ag8—Ag585.4 (6)S5—C55—H55B109.5
O13—Ag8—Ag5155.8 (7)H55A—C55—H55B109.5
C5—Ag8—Ag744.5 (8)S5—C55—H55C109.5
O11—Ag8—Ag7122.4 (6)H55A—C55—H55C109.5
O13—Ag8—Ag7109.0 (8)H55B—C55—H55C109.5
Ag5—Ag8—Ag757.81 (7)S5—C56—H56A109.5
C5—Ag8—Ag9127.1 (8)S5—C56—H56B109.5
O11—Ag8—Ag976.0 (5)H56A—C56—H56B109.5
O13—Ag8—Ag978.2 (6)S5—C56—H56C109.5
Ag5—Ag8—Ag9116.67 (9)H56A—C56—H56C109.5
Ag7—Ag8—Ag982.96 (8)H56B—C56—H56C109.5
C5—Ag8—Ag1089.7 (8)O26—S6—C58105.3 (14)
O11—Ag8—Ag1070.5 (6)O26—S6—C57104.9 (16)
O13—Ag8—Ag10129.2 (6)C58—S6—C5798.3 (19)
Ag5—Ag8—Ag1062.54 (7)S6—O26—Ag13127.8 (11)
Ag7—Ag8—Ag1053.93 (6)S6—O26—Ag10110.3 (10)
Ag9—Ag8—Ag1054.15 (6)Ag13—O26—Ag10121.8 (9)
O12—Ag9—O1498.2 (9)S6—C57—H57A109.5
O12—Ag9—O2597.1 (7)S6—C57—H57B109.5
O14—Ag9—O2596.0 (7)H57A—C57—H57B109.5
O12—Ag9—C14129.1 (9)S6—C57—H57C109.5
O14—Ag9—C14115.0 (9)H57A—C57—H57C109.5
O25—Ag9—C14115.4 (8)H57B—C57—H57C109.5
O12—Ag9—C15156.0 (9)S6—C58—H58A109.5
O14—Ag9—C15102.8 (9)S6—C58—H58B109.5
O25—Ag9—C1592.2 (8)H58A—C58—H58B109.5
C14—Ag9—C1529.0 (9)S6—C58—H58C109.5
O12—Ag9—Ag1083.1 (6)H58A—C58—H58C109.5
O14—Ag9—Ag10139.6 (6)H58B—C58—H58C109.5
O25—Ag9—Ag10124.1 (5)O27—S7—C60104.9 (15)
C14—Ag9—Ag1046.5 (6)O27—S7—C59107.4 (18)
C15—Ag9—Ag1073.4 (6)C60—S7—C5996 (2)
O12—Ag9—Ag877.7 (6)S7—O27—Ag11131.3 (13)
O14—Ag9—Ag877.3 (6)S7—O27—Ag13118.1 (13)
O25—Ag9—Ag8170.7 (5)Ag11—O27—Ag13104.4 (7)
C14—Ag9—Ag873.7 (6)S7—C59—H59A109.5
C15—Ag9—Ag895.6 (6)S7—C59—H59B109.5
Ag10—Ag9—Ag863.42 (7)H59A—C59—H59B109.5
O16—Ag10—C14172.1 (10)S7—C59—H59C109.5
O16—Ag10—O2680.2 (8)H59A—C59—H59C109.5
C14—Ag10—O2697.1 (8)H59B—C59—H59C109.5
O16—Ag10—Ag7129.8 (6)S7—C60—H60A109.5
C14—Ag10—Ag750.7 (7)S7—C60—H60B109.5
O26—Ag10—Ag7145.3 (5)H60A—C60—H60B109.5
O16—Ag10—Ag9130.1 (7)S7—C60—H60C109.5
C14—Ag10—Ag955.2 (7)H60A—C60—H60C109.5
O26—Ag10—Ag974.1 (5)H60B—C60—H60C109.5
Ag7—Ag10—Ag992.26 (8)O28—S8—C62102.0 (19)
O16—Ag10—Ag11122.0 (7)O28—S8—C61109 (2)
C14—Ag10—Ag1150.2 (7)C62—S8—C6199 (2)
O26—Ag10—Ag1187.7 (5)S8—O28—Ag11131.8 (16)
Ag7—Ag10—Ag1162.68 (7)S8—O28—Ag14121.6 (14)
Ag9—Ag10—Ag1199.13 (8)Ag11—O28—Ag14101.6 (9)
O16—Ag10—Ag578.0 (6)S8—C61—H61A109.5
C14—Ag10—Ag5105.3 (7)S8—C61—H61B109.5
O26—Ag10—Ag5157.3 (5)H61A—C61—H61B109.5
Ag7—Ag10—Ag557.10 (6)S8—C61—H61C109.5
Ag9—Ag10—Ag5116.13 (8)H61A—C61—H61C109.5
Ag11—Ag10—Ag5109.26 (8)H61B—C61—H61C109.5
O16—Ag10—Ag8111.0 (7)S8—C62—H62A109.5
C14—Ag10—Ag876.5 (7)S8—C62—H62B109.5
O26—Ag10—Ag8131.1 (5)H62A—C62—H62B109.5
Ag7—Ag10—Ag861.09 (7)S8—C62—H62C109.5
Ag9—Ag10—Ag862.43 (7)H62A—C62—H62C109.5
Ag11—Ag10—Ag8119.13 (8)H62B—C62—H62C109.5
Ag5—Ag10—Ag853.71 (6)C27—O1—Ag1119.0 (17)
O20—Ag11—C14131.0 (8)C27—O2—Ag13i115.7 (18)
O20—Ag11—O2893.8 (9)O2—C27—O1134 (3)
C14—Ag11—O28121.9 (10)O2—C27—C28113 (2)
O20—Ag11—O2798.4 (9)O1—C27—C28112 (2)
C14—Ag11—O27117.6 (8)F1—C28—F3108.3 (15)
O28—Ag11—O2781.5 (9)F1—C28—F2107.6 (14)
O20—Ag11—Ag10107.4 (6)F3—C28—F2108.3 (15)
C14—Ag11—Ag1045.6 (6)F1—C28—C27111.2 (19)
O28—Ag11—Ag10158.2 (7)F3—C28—C27109 (2)
O27—Ag11—Ag1090.3 (5)F2—C28—C27112 (2)
O20—Ag11—Ag784.5 (6)C29—O3—Ag1119 (2)
C14—Ag11—Ag746.9 (6)C29—O4—Ag12i120 (2)
O28—Ag11—Ag7132.9 (7)O3—C29—O4133 (3)
O27—Ag11—Ag7145.4 (5)O3—C29—C30114 (2)
Ag10—Ag11—Ag756.43 (7)O4—C29—C30112 (3)
O4ii—Ag12—O6ii99.4 (9)F6—C30—F5109.4 (15)
O4ii—Ag12—C18138.5 (9)F6—C30—F4109.5 (15)
O6ii—Ag12—C18120.5 (8)F5—C30—F4109.0 (14)
O4ii—Ag12—Ag1390.5 (7)F6—C30—C29108 (2)
O6ii—Ag12—Ag13169.5 (5)F5—C30—C29111 (2)
C18—Ag12—Ag1349.1 (6)F4—C30—C29110 (2)
O4ii—Ag12—Ag2ii134.8 (6)C31—O5—Ag2125.3 (16)
O6ii—Ag12—Ag2ii80.7 (5)C31—O6—Ag12i126.0 (18)
C18—Ag12—Ag2ii51.6 (6)O6—C31—O5127 (2)
Ag13—Ag12—Ag2ii89.80 (8)O6—C31—C32119 (2)
O4ii—Ag12—Ag1ii84.3 (6)O5—C31—C32114 (2)
O6ii—Ag12—Ag1ii114.0 (5)F8—C32—F9108.7 (14)
C18—Ag12—Ag1ii70.3 (6)F8—C32—F7108.6 (13)
Ag13—Ag12—Ag1ii63.17 (7)F9—C32—F7108.0 (13)
Ag2ii—Ag12—Ag1ii56.09 (6)F8—C32—C31109.8 (16)
C18—Ag13—O2ii148.1 (9)F9—C32—C31109.2 (17)
C18—Ag13—O26119.6 (8)F7—C32—C31112.6 (17)
O2ii—Ag13—O2691.9 (7)C33—O7—Ag2118 (2)
C18—Ag13—O2795.8 (9)C33—O8—Ag3121 (2)
O2ii—Ag13—O2794.0 (8)O7—C33—O8129 (3)
O26—Ag13—O2780.1 (7)O7—C33—C34120 (3)
C18—Ag13—Ag1252.6 (7)O8—C33—C34110 (3)
O2ii—Ag13—Ag12115.3 (7)F10—C34—F12109.2 (16)
O26—Ag13—Ag12109.7 (6)F10—C34—F11108.0 (16)
O27—Ag13—Ag12148.1 (5)F12—C34—F11107.7 (16)
C18—Ag13—Ag1448.5 (7)F10—C34—C33110 (3)
O2ii—Ag13—Ag14111.4 (6)F12—C34—C33113 (3)
O26—Ag13—Ag14137.6 (5)F11—C34—C33109 (3)
O27—Ag13—Ag1464.0 (5)C35—O9—Ag3124.8 (19)
Ag12—Ag13—Ag1492.19 (8)C35—O10—Ag14i127.6 (18)
C18—Ag13—Ag1ii70.6 (7)O9—C35—O10128 (3)
O2ii—Ag13—Ag1ii77.9 (6)O9—C35—C36115 (2)
O26—Ag13—Ag1ii160.4 (5)O10—C35—C36117 (2)
O27—Ag13—Ag1ii117.0 (5)F13—C36—F14108.7 (14)
Ag12—Ag13—Ag1ii61.53 (7)F13—C36—F15108.0 (15)
Ag14—Ag13—Ag1ii62.00 (7)F14—C36—F15107.4 (15)
C18—Ag14—O10ii161.0 (9)F13—C36—C35115 (2)
C18—Ag14—O2893.3 (10)F14—C36—C35110 (2)
O10ii—Ag14—O2893.0 (9)F15—C36—C35107 (2)
C18—Ag14—Ag1349.0 (6)C37—O11—Ag8128 (2)
O10ii—Ag14—Ag13112.0 (7)C37—O12—Ag9126 (2)
O28—Ag14—Ag13107.3 (5)O11—C37—O12128 (3)
C18—Ag14—Ag2ii52.7 (6)O11—C37—C38116 (2)
O10ii—Ag14—Ag2ii138.2 (5)O12—C37—C38116 (2)
O28—Ag14—Ag2ii114.9 (7)F17—C38—F18109.3 (15)
Ag13—Ag14—Ag2ii89.65 (8)F17—C38—F16108.8 (15)
C18—Ag14—Ag3ii109.5 (7)F18—C38—F16108.2 (15)
O10ii—Ag14—Ag3ii78.6 (5)F17—C38—C37109.9 (19)
O28—Ag14—Ag3ii133.2 (5)F18—C38—C37114 (2)
Ag13—Ag14—Ag3ii118.58 (10)F16—C38—C37106.6 (19)
Ag2ii—Ag14—Ag3ii59.60 (7)C39—O13—Ag8127.7 (19)
C18—Ag14—Ag1ii70.9 (7)C39—O14—Ag9124 (2)
O10ii—Ag14—Ag1ii101.9 (6)O14—C39—O13130 (3)
O28—Ag14—Ag1ii164.2 (6)O14—C39—C40114 (3)
Ag13—Ag14—Ag1ii62.24 (7)O13—C39—C40115 (2)
Ag2ii—Ag14—Ag1ii55.96 (6)F21—C40—F19108.6 (15)
Ag3ii—Ag14—Ag1ii56.44 (7)F21—C40—F20108.2 (15)
C2—C1—Ag1163 (2)F19—C40—F20107.2 (14)
C2—C1—Ag3102 (2)F21—C40—C39109 (2)
Ag1—C1—Ag381.6 (9)F19—C40—C39112 (2)
C2—C1—Ag2118.8 (18)F20—C40—C39112 (2)
Ag1—C1—Ag277.9 (8)C41—O15—Ag5125.8 (17)
Ag3—C1—Ag281.6 (9)C41—O16—Ag10126.4 (19)
C2—C1—Ag484.8 (17)O15—C41—O16131 (3)
Ag1—C1—Ag479.1 (8)O15—C41—C42114 (2)
Ag3—C1—Ag4118.5 (11)O16—C41—C42115 (2)
Ag2—C1—Ag4146.6 (13)F24—C42—F22108.0 (14)
C1—C2—C3175 (2)F24—C42—F23108.1 (14)
C1—C2—Ag465.9 (15)F22—C42—F23107.3 (14)
C3—C2—Ag4109.4 (16)F24—C42—C41110.5 (18)
C4—C3—C2112 (2)F22—C42—C41113.4 (18)
C4—C3—C6123 (2)F23—C42—C41109.4 (19)
C2—C3—C6124 (2)C43—O17—Ag6121 (2)
C5—C4—C3174 (3)C43—O18—Ag7123.9 (18)
C5—C4—Ag670.1 (15)O17—C43—O18132 (3)
C3—C4—Ag6114.3 (18)O17—C43—C44115 (2)
C4—C5—Ag5135 (2)O18—C43—C44113 (2)
C4—C5—Ag7133.1 (19)F26—C44—F25109.0 (14)
Ag5—C5—Ag784.9 (11)F26—C44—F27107.7 (14)
C4—C5—Ag8113.2 (18)F25—C44—F27107.7 (14)
Ag5—C5—Ag884.2 (10)F26—C44—C43111.1 (19)
Ag7—C5—Ag890.8 (12)F25—C44—C43107.0 (19)
C4—C5—Ag679.7 (17)F27—C44—C43114.1 (19)
Ag5—C5—Ag684.7 (8)C45—O19—Ag7118.4 (19)
Ag7—C5—Ag681.3 (8)C45—O20—Ag11117.4 (17)
Ag8—C5—Ag6166.9 (14)O19—C45—O20132 (2)
C13—C6—C3121 (3)O19—C45—C46116 (2)
C13—C6—C7121 (3)O20—C45—C46111.6 (19)
C3—C6—C7118 (2)F29—C46—F28109.5 (14)
C8—C7—C6118 (3)F29—C46—F30108.5 (14)
C8—C7—H7A107.8F28—C46—F30108.3 (14)
C6—C7—H7A107.8F29—C46—C45111.4 (18)
C8—C7—H7B107.8F28—C46—C45109.8 (18)
C6—C7—H7B107.8F30—C46—C45109.3 (18)
Ag1—C1—C2—Ag417 (8)Ag12i—O4—C29—O316 (6)
Ag3—C1—C2—Ag4118.1 (12)Ag12i—O4—C29—C30171.5 (16)
Ag2—C1—C2—Ag4155 (2)O3—C29—C30—F663 (4)
Ag4—C2—C3—C437 (3)O4—C29—C30—F6111 (3)
Ag4—C2—C3—C6142 (2)O3—C29—C30—F5176 (3)
C2—C3—C4—Ag674 (2)O4—C29—C30—F59 (3)
C6—C3—C4—Ag6108 (2)O3—C29—C30—F456 (4)
Ag6—C4—C5—Ag572 (2)O4—C29—C30—F4130 (3)
Ag6—C4—C5—Ag768 (2)Ag12i—O6—C31—O53 (4)
Ag6—C4—C5—Ag8177.4 (16)Ag12i—O6—C31—C32174.7 (14)
C4—C3—C6—C13172 (3)Ag2—O5—C31—O65 (4)
C2—C3—C6—C1310 (4)Ag2—O5—C31—C32176.6 (13)
C4—C3—C6—C74 (4)O6—C31—C32—F862 (3)
C2—C3—C6—C7174 (3)O5—C31—C32—F8116 (2)
C13—C6—C7—C837 (4)O6—C31—C32—F957 (3)
C3—C6—C7—C8140 (3)O5—C31—C32—F9125 (2)
C6—C7—C8—C970 (4)O6—C31—C32—F7177 (2)
C7—C8—C9—C1058 (5)O5—C31—C32—F75 (3)
C8—C9—C10—C1147 (5)Ag2—O7—C33—O86 (5)
C9—C10—C11—C12104 (5)Ag2—O7—C33—C34163 (2)
C10—C11—C12—C1369 (5)Ag3—O8—C33—O739 (5)
C3—C6—C13—C1280 (4)Ag3—O8—C33—C34131 (3)
C7—C6—C13—C1297 (4)O7—C33—C34—F107 (4)
C11—C12—C13—C665 (5)O8—C33—C34—F10179 (3)
Ag10—C14—C15—Ag949 (3)O7—C33—C34—F12130 (3)
Ag7—C14—C15—Ag9129 (2)O8—C33—C34—F1259 (3)
Ag11—C14—C15—Ag9141.4 (11)O7—C33—C34—F11111 (3)
Ag9—C15—C16—C1994 (3)O8—C33—C34—F1160 (3)
Ag9—C15—C16—C1788 (2)Ag3—O9—C35—O102 (5)
C19—C16—C17—C18175 (9)Ag3—O9—C35—C36179.3 (18)
C15—C16—C17—C183 (11)Ag14i—O10—C35—O910 (5)
C16—C17—C18—Ag1483 (10)Ag14i—O10—C35—C36166.5 (18)
C16—C17—C18—Ag1330 (12)O9—C35—C36—F139 (4)
C16—C17—C18—Ag12111 (10)O10—C35—C36—F13174 (3)
C16—C17—C18—Ag2ii168 (9)O9—C35—C36—F14132 (3)
C15—C16—C19—C20174 (3)O10—C35—C36—F1450 (3)
C17—C16—C19—C208 (5)O9—C35—C36—F15111 (3)
C15—C16—C19—C263 (4)O10—C35—C36—F1566 (3)
C17—C16—C19—C26179 (3)Ag8—O11—C37—O1214 (5)
C16—C19—C20—C21145 (3)Ag8—O11—C37—C38168.3 (16)
C26—C19—C20—C2145 (4)Ag9—O12—C37—O118 (5)
C19—C20—C21—C2255 (4)Ag9—O12—C37—C38169.5 (15)
C20—C21—C22—C2355 (6)O11—C37—C38—F1747 (3)
C21—C22—C23—C2443 (7)O12—C37—C38—F17131 (3)
C22—C23—C24—C25100 (6)O11—C37—C38—F18170 (2)
C23—C24—C25—C2667 (6)O12—C37—C38—F188 (3)
C24—C25—C26—C1962 (4)O11—C37—C38—F1671 (3)
C16—C19—C26—C2581 (4)O12—C37—C38—F16112 (3)
C20—C19—C26—C25107 (4)Ag9—O14—C39—O1314 (5)
C48—S1—O21—Ag631 (2)Ag9—O14—C39—C40171.4 (18)
C47—S1—O21—Ag678.3 (19)Ag8—O13—C39—O141 (6)
C48—S1—O21—Ag3112.7 (16)Ag8—O13—C39—C40173.2 (19)
C47—S1—O21—Ag3138.1 (15)O14—C39—C40—F2198 (3)
C49—S2—O22—Ag414 (2)O13—C39—C40—F2187 (3)
C50—S2—O22—Ag490 (3)O14—C39—C40—F19142 (3)
C49—S2—O22—Ag5118.3 (16)O13—C39—C40—F1933 (4)
C50—S2—O22—Ag5138 (2)O14—C39—C40—F2022 (4)
C52—S3—O23—Ag476 (2)O13—C39—C40—F20154 (3)
C51—S3—O23—Ag431 (2)Ag5—O15—C41—O1614 (5)
C53—S4—O24—Ag6101 (2)Ag5—O15—C41—C42174.4 (16)
C54—S4—O24—Ag6154 (2)Ag10—O16—C41—O150 (5)
C53—S4—O24—Ag529 (3)Ag10—O16—C41—C42171.4 (17)
C54—S4—O24—Ag576 (2)O15—C41—C42—F2447 (3)
C55—S5—O25—Ag970.3 (16)O16—C41—C42—F24140 (3)
C56—S5—O25—Ag931.7 (16)O15—C41—C42—F22169 (2)
C58—S6—O26—Ag1368 (2)O16—C41—C42—F2219 (3)
C57—S6—O26—Ag1336 (2)O15—C41—C42—F2372 (3)
C58—S6—O26—Ag10114.7 (15)O16—C41—C42—F23101 (3)
C57—S6—O26—Ag10142.1 (17)Ag6—O17—C43—O1817 (5)
C60—S7—O27—Ag1139 (2)Ag6—O17—C43—C44158.4 (17)
C59—S7—O27—Ag1162 (2)Ag7—O18—C43—O176 (5)
C60—S7—O27—Ag13108.4 (19)Ag7—O18—C43—C44177.7 (14)
C59—S7—O27—Ag13150.3 (18)O17—C43—C44—F2643 (3)
C62—S8—O28—Ag1147 (3)O18—C43—C44—F26133 (2)
C61—S8—O28—Ag1157 (3)O17—C43—C44—F2575 (3)
C62—S8—O28—Ag14163 (2)O18—C43—C44—F25108 (2)
C61—S8—O28—Ag1493 (2)O17—C43—C44—F27165 (2)
Ag13i—O2—C27—O111 (5)O18—C43—C44—F2711 (3)
Ag13i—O2—C27—C28158.2 (17)Ag7—O19—C45—O2037 (5)
Ag1—O1—C27—O230 (5)Ag7—O19—C45—C46149.5 (16)
Ag1—O1—C27—C28160.0 (16)Ag11—O20—C45—O194 (5)
O2—C27—C28—F15 (3)Ag11—O20—C45—C46177.1 (14)
O1—C27—C28—F1177 (2)O19—C45—C46—F29150 (3)
O2—C27—C28—F3125 (3)O20—C45—C46—F2936 (3)
O1—C27—C28—F363 (3)O19—C45—C46—F2828 (3)
O2—C27—C28—F2115 (3)O20—C45—C46—F28157 (2)
O1—C27—C28—F257 (3)O19—C45—C46—F3090 (3)
Ag1—O3—C29—O436 (6)O20—C45—C46—F3084 (3)
Ag1—O3—C29—C30151.5 (18)
Symmetry codes: (i) x1, y1, z1; (ii) x+1, y+1, z+1.
(V) top
Crystal data top
7(Ag+)·(C10H82)·5(C2F3O2)·2(H2O)Z = 4
Mr = 1484.39F(000) = 2768
Monoclinic, C2/cDx = 2.864 Mg m3
a = 23.394 (2) ÅMo Kα radiation, λ = 0.71073 Å
b = 13.9512 (12) ŵ = 4.03 mm1
c = 10.7920 (9) ÅT = 173 K
β = 102.214 (1)°Block, colourless
V = 3442.5 (5) Å30.50 × 0.50 × 0.40 mm
Data collection top
Bruker APEX-II CCD
diffractometer
2897 reflections with I > 2σ(I)
φ and ω scanRint = 0.087
Absorption correction: multi-scan
SADABS (Bruker, 2003)
θmax = 25.3°, θmin = 1.7°
Tmin = 0.238, Tmax = 0.295h = 2828
30572 measured reflectionsk = 1616
3109 independent reflectionsl = 1212
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.047Hydrogen site location: mixed
wR(F2) = 0.125H-atom parameters constrained
S = 1.07 w = 1/[σ2(Fo2) + (0.0768P)2 + 33.6886P]
where P = (Fo2 + 2Fc2)/3
3109 reflections(Δ/σ)max = 0.001
264 parametersΔρmax = 1.26 e Å3
78 restraintsΔρmin = 1.77 e Å3
Crystal data top
7(Ag+)·(C10H82)·5(C2F3O2)·2(H2O)V = 3442.5 (5) Å3
Mr = 1484.39Z = 4
Monoclinic, C2/cMo Kα radiation
a = 23.394 (2) ŵ = 4.03 mm1
b = 13.9512 (12) ÅT = 173 K
c = 10.7920 (9) Å0.50 × 0.50 × 0.40 mm
β = 102.214 (1)°
Data collection top
Bruker APEX-II CCD
diffractometer
3109 independent reflections
Absorption correction: multi-scan
SADABS (Bruker, 2003)
2897 reflections with I > 2σ(I)
Tmin = 0.238, Tmax = 0.295Rint = 0.087
30572 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.04778 restraints
wR(F2) = 0.125H-atom parameters constrained
S = 1.07 w = 1/[σ2(Fo2) + (0.0768P)2 + 33.6886P]
where P = (Fo2 + 2Fc2)/3
3109 reflectionsΔρmax = 1.26 e Å3
264 parametersΔρmin = 1.77 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.37163 (2)0.07147 (3)0.68599 (5)0.03003 (18)
Ag20.32516 (2)0.20816 (4)0.50198 (5)0.03480 (19)
Ag30.42235 (2)0.07770 (3)0.47735 (5)0.02865 (18)
Ag40.49357 (9)0.11845 (6)0.77319 (16)0.0284 (4)0.5
C10.4190 (3)0.1923 (4)0.6088 (6)0.0232 (12)
C20.4473 (2)0.2606 (4)0.6565 (5)0.0192 (11)
C30.4754 (2)0.3485 (4)0.7045 (5)0.0191 (11)
C40.4452 (3)0.4398 (5)0.6504 (8)0.0366 (16)
H4A0.43800.43730.55660.044*
H4B0.40690.44470.67490.044*
C50.4808 (6)0.5258 (7)0.6961 (14)0.095 (4)
H5A0.50210.54340.62930.114*
H5B0.45300.57860.70060.114*
O10.2769 (2)0.0418 (4)0.6968 (5)0.0379 (12)
O20.23691 (18)0.1606 (3)0.5673 (4)0.0264 (9)
C60.2363 (3)0.0940 (4)0.6448 (6)0.0235 (12)
C70.1773 (3)0.0700 (4)0.6810 (6)0.0347 (16)
F10.13862 (18)0.1399 (3)0.6533 (5)0.0562 (13)
F20.1845 (2)0.0524 (5)0.8030 (5)0.0684 (16)
F30.1536 (2)0.0062 (3)0.6191 (5)0.0598 (13)
O30.3679 (2)0.0952 (3)0.6017 (4)0.0337 (11)
O40.3928 (2)0.0740 (3)0.4154 (4)0.0306 (10)
C80.3726 (3)0.1204 (5)0.4959 (6)0.0277 (14)
C90.3527 (3)0.2236 (5)0.4548 (6)0.049 (2)
F40.3091 (4)0.2224 (5)0.3602 (8)0.159 (5)
F50.3406 (3)0.2758 (4)0.5456 (5)0.0707 (17)
F60.3951 (4)0.2703 (5)0.4163 (9)0.137 (4)
O50.4813 (2)0.0444 (3)0.3346 (4)0.0289 (10)
C100.50000.0852 (6)0.25000.0236 (18)
C110.50000.1974 (6)0.25000.046 (3)
F70.5495 (3)0.2353 (7)0.2783 (12)0.061 (3)0.5
F80.4800 (4)0.2240 (6)0.1214 (6)0.050 (2)0.5
F90.4600 (4)0.2350 (7)0.2986 (9)0.048 (3)0.5
O1W0.3089 (3)0.1396 (4)0.2956 (6)0.0619 (19)
H1W0.29900.08120.29930.093*
H2W0.34000.14340.26710.093*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0342 (3)0.0305 (3)0.0279 (3)0.00341 (19)0.0121 (2)0.01018 (18)
Ag20.0205 (3)0.0332 (3)0.0470 (4)0.00385 (19)0.0012 (2)0.0172 (2)
Ag30.0362 (3)0.0239 (3)0.0296 (3)0.00335 (18)0.0155 (2)0.00848 (18)
Ag40.0236 (9)0.0121 (4)0.0417 (13)0.0021 (4)0.0106 (6)0.0028 (4)
C10.026 (3)0.015 (3)0.026 (3)0.004 (2)0.001 (2)0.001 (2)
C20.019 (3)0.017 (3)0.020 (3)0.008 (2)0.001 (2)0.002 (2)
C30.024 (3)0.012 (3)0.022 (3)0.001 (2)0.006 (2)0.000 (2)
C40.038 (4)0.017 (3)0.050 (4)0.011 (3)0.004 (3)0.004 (3)
C50.105 (7)0.030 (4)0.122 (8)0.005 (5)0.042 (6)0.010 (5)
O10.027 (2)0.033 (3)0.054 (3)0.007 (2)0.008 (2)0.024 (2)
O20.023 (2)0.024 (2)0.033 (2)0.0064 (17)0.0060 (17)0.0121 (18)
C60.022 (3)0.021 (3)0.027 (3)0.000 (2)0.006 (2)0.002 (2)
C70.028 (3)0.035 (4)0.043 (4)0.001 (3)0.012 (3)0.011 (3)
F10.031 (2)0.051 (3)0.094 (4)0.015 (2)0.031 (2)0.023 (3)
F20.051 (3)0.106 (4)0.055 (3)0.001 (3)0.025 (2)0.030 (3)
F30.041 (3)0.045 (3)0.093 (4)0.014 (2)0.013 (2)0.007 (3)
O30.057 (3)0.021 (2)0.028 (2)0.003 (2)0.020 (2)0.0012 (19)
O40.049 (3)0.021 (2)0.023 (2)0.0114 (19)0.010 (2)0.0026 (16)
C80.034 (3)0.022 (3)0.027 (3)0.006 (3)0.007 (3)0.001 (2)
C90.089 (7)0.034 (4)0.026 (4)0.030 (4)0.017 (4)0.007 (3)
F40.233 (10)0.070 (5)0.121 (6)0.096 (6)0.085 (7)0.025 (4)
F50.118 (5)0.038 (3)0.062 (3)0.035 (3)0.034 (3)0.005 (2)
F60.237 (10)0.047 (4)0.174 (8)0.040 (5)0.150 (8)0.046 (4)
O50.035 (2)0.022 (2)0.036 (2)0.0009 (19)0.021 (2)0.0015 (19)
C100.023 (4)0.013 (4)0.038 (5)0.0000.015 (4)0.000
C110.047 (7)0.018 (5)0.079 (9)0.0000.028 (6)0.000
F70.052 (5)0.027 (4)0.093 (7)0.011 (4)0.011 (6)0.001 (6)
F80.074 (6)0.024 (4)0.056 (5)0.000 (4)0.026 (5)0.016 (4)
F90.071 (6)0.027 (4)0.056 (5)0.021 (4)0.036 (5)0.002 (4)
O1W0.106 (5)0.045 (3)0.047 (3)0.030 (3)0.045 (4)0.026 (3)
Geometric parameters (Å, º) top
Ag1—C12.270 (6)C5—C5ii1.31 (2)
Ag1—O12.282 (5)C5—H5A0.9900
Ag1—O4i2.420 (5)C5—H5B0.9900
Ag1—O32.491 (5)O1—C61.234 (8)
Ag1—Ag32.7597 (7)O2—C61.251 (7)
Ag1—Ag22.8015 (7)O2—Ag2iii2.359 (4)
Ag1—Ag42.884 (2)C6—C71.548 (8)
Ag1—Ag4ii3.1592 (19)C7—F21.315 (7)
Ag2—C12.264 (6)C7—F31.315 (7)
Ag2—O2iii2.359 (4)C7—F11.320 (6)
Ag2—O1W2.379 (5)O3—C81.222 (8)
Ag2—O22.412 (4)O4—C81.254 (8)
Ag2—Ag32.9680 (7)O4—Ag1iv2.420 (5)
Ag3—C12.150 (6)C8—C91.549 (9)
Ag3—O42.281 (4)C9—F41.282 (8)
Ag3—O52.321 (4)C9—F51.299 (7)
Ag3—Ag4ii3.033 (2)C9—F61.325 (8)
Ag3—Ag43.323 (2)O5—C101.233 (6)
Ag4—Ag4ii0.636 (2)O5—Ag4iv2.401 (5)
Ag4—O5i2.401 (5)C10—O5v1.233 (6)
Ag4—C1ii2.401 (6)C10—C111.566 (11)
Ag4—C12.438 (6)C11—F7v1.250 (7)
Ag4—C2ii2.445 (5)C11—F71.250 (7)
Ag4—C22.473 (6)C11—F9v1.278 (7)
Ag4—Ag3ii3.033 (2)C11—F91.278 (7)
Ag4—Ag1ii3.1592 (19)C11—F8v1.417 (7)
C1—C21.212 (9)C11—F81.417 (7)
C1—Ag4ii2.401 (6)F7—F9v0.812 (12)
C2—C31.435 (8)F7—F8v1.412 (14)
C2—Ag4ii2.445 (5)F8—F7v1.412 (14)
C3—C3ii1.345 (12)F8—F9v1.491 (13)
C3—C41.513 (8)F9—F7v0.812 (12)
C4—C51.484 (13)F9—F8v1.491 (13)
C4—H4A0.9900O1W—H1W0.8503
C4—H4B0.9900O1W—H2W0.8493
C1—Ag1—O1135.09 (19)C2—Ag4—Ag364.63 (14)
C1—Ag1—O4i110.76 (19)Ag1—Ag4—Ag352.22 (4)
O1—Ag1—O4i86.65 (18)Ag3ii—Ag4—Ag3156.91 (4)
C1—Ag1—O3122.78 (18)Ag1ii—Ag4—Ag3112.41 (3)
O1—Ag1—O383.65 (19)C2—C1—Ag3140.5 (5)
O4i—Ag1—O3111.76 (15)C2—C1—Ag2121.6 (4)
C1—Ag1—Ag349.45 (15)Ag3—C1—Ag284.5 (2)
O1—Ag1—Ag3129.58 (14)C2—C1—Ag1134.0 (5)
O4i—Ag1—Ag3143.50 (13)Ag3—C1—Ag177.22 (19)
O3—Ag1—Ag373.71 (10)Ag2—C1—Ag176.33 (19)
C1—Ag1—Ag251.74 (15)C2—C1—Ag4ii77.6 (4)
O1—Ag1—Ag285.65 (11)Ag3—C1—Ag4ii83.38 (19)
O4i—Ag1—Ag2132.86 (10)Ag2—C1—Ag4ii159.6 (3)
O3—Ag1—Ag2113.45 (11)Ag1—C1—Ag4ii85.07 (19)
Ag3—Ag1—Ag264.505 (19)C2—C1—Ag477.3 (4)
C1—Ag1—Ag454.91 (15)Ag3—C1—Ag492.6 (2)
O1—Ag1—Ag4158.29 (14)Ag2—C1—Ag4151.6 (3)
O4i—Ag1—Ag471.85 (13)Ag1—C1—Ag475.46 (18)
O3—Ag1—Ag4106.70 (13)Ag4ii—C1—Ag415.09 (6)
Ag3—Ag1—Ag472.11 (3)C1—C2—C3173.2 (6)
Ag2—Ag1—Ag4106.58 (3)C1—C2—Ag4ii73.5 (4)
C1—Ag1—Ag4ii49.22 (15)C3—C2—Ag4ii113.2 (4)
O1—Ag1—Ag4ii169.20 (14)C1—C2—Ag474.1 (4)
O4i—Ag1—Ag4ii82.65 (13)C3—C2—Ag4112.5 (4)
O3—Ag1—Ag4ii101.64 (13)Ag4ii—C2—Ag414.85 (6)
Ag3—Ag1—Ag4ii61.21 (3)C3ii—C3—C2121.3 (3)
Ag2—Ag1—Ag4ii100.59 (3)C3ii—C3—C4122.6 (4)
Ag4—Ag1—Ag4ii10.91 (5)C2—C3—C4116.0 (5)
C1—Ag2—O2iii134.67 (18)C5—C4—C3111.7 (7)
C1—Ag2—O1W112.5 (2)C5—C4—H4A109.3
O2iii—Ag2—O1W92.8 (2)C3—C4—H4A109.3
C1—Ag2—O2128.44 (19)C5—C4—H4B109.3
O2iii—Ag2—O278.39 (16)C3—C4—H4B109.3
O1W—Ag2—O2100.7 (2)H4A—C4—H4B107.9
C1—Ag2—Ag151.93 (15)C5ii—C5—C4121.7 (9)
O2iii—Ag2—Ag1150.92 (11)C5ii—C5—H5A106.9
O1W—Ag2—Ag1110.54 (17)C4—C5—H5A106.9
O2—Ag2—Ag180.39 (10)C5ii—C5—H5B106.9
C1—Ag2—Ag346.15 (15)C4—C5—H5B106.9
O2iii—Ag2—Ag3151.61 (11)H5A—C5—H5B106.7
O1W—Ag2—Ag369.10 (19)C6—O1—Ag1122.2 (4)
O2—Ag2—Ag3125.22 (10)C6—O2—Ag2iii134.0 (4)
Ag1—Ag2—Ag357.066 (17)C6—O2—Ag2122.1 (4)
C1—Ag3—O4146.3 (2)Ag2iii—O2—Ag2101.61 (16)
C1—Ag3—O5134.2 (2)O1—C6—O2128.7 (6)
O4—Ag3—O578.78 (17)O1—C6—C7113.5 (5)
C1—Ag3—Ag153.33 (17)O2—C6—C7117.8 (5)
O4—Ag3—Ag193.11 (12)F2—C7—F3107.9 (5)
O5—Ag3—Ag1162.44 (12)F2—C7—F1107.5 (5)
C1—Ag3—Ag249.39 (16)F3—C7—F1106.7 (5)
O4—Ag3—Ag2113.87 (13)F2—C7—C6111.2 (5)
O5—Ag3—Ag2139.11 (12)F3—C7—C6110.4 (5)
Ag1—Ag3—Ag258.429 (17)F1—C7—C6112.8 (5)
C1—Ag3—Ag4ii51.85 (16)C8—O3—Ag1127.4 (4)
O4—Ag3—Ag4ii122.23 (12)C8—O4—Ag3114.3 (4)
O5—Ag3—Ag4ii105.18 (12)C8—O4—Ag1iv133.7 (4)
Ag1—Ag3—Ag4ii65.90 (3)Ag3—O4—Ag1iv105.69 (17)
Ag2—Ag3—Ag4ii99.83 (3)O3—C8—O4128.4 (6)
C1—Ag3—Ag447.12 (15)O3—C8—C9117.0 (6)
O4—Ag3—Ag4119.97 (12)O4—C8—C9114.6 (5)
O5—Ag3—Ag4115.12 (12)F4—C9—F5110.1 (6)
Ag1—Ag3—Ag455.68 (3)F4—C9—F6106.2 (7)
Ag2—Ag3—Ag492.68 (3)F5—C9—F6105.0 (6)
Ag4ii—Ag3—Ag410.24 (5)F4—C9—C8110.8 (6)
Ag4ii—Ag4—O5i108.75 (11)F5—C9—C8113.9 (5)
Ag4ii—Ag4—C1ii85.7 (4)F6—C9—C8110.4 (6)
O5i—Ag4—C1ii113.45 (19)C10—O5—Ag3138.9 (4)
Ag4ii—Ag4—C179.2 (4)C10—O5—Ag4iv98.7 (4)
O5i—Ag4—C1119.5 (2)Ag3—O5—Ag4iv119.69 (19)
C1ii—Ag4—C1127.1 (3)O5v—C10—O5125.0 (8)
Ag4ii—Ag4—C2ii85.0 (3)O5v—C10—C11117.5 (4)
O5i—Ag4—C2ii140.8 (2)O5—C10—C11117.5 (4)
C1ii—Ag4—C2ii28.9 (2)F7v—C11—F7130.1 (12)
C1—Ag4—C2ii98.85 (19)F7v—C11—F9v116.6 (7)
Ag4ii—Ag4—C280.1 (3)F7—C11—F9v37.5 (5)
O5i—Ag4—C2146.6 (2)F7v—C11—F937.5 (5)
C1ii—Ag4—C299.08 (19)F7—C11—F9116.6 (7)
C1—Ag4—C228.6 (2)F9v—C11—F9131.6 (11)
C2ii—Ag4—C270.4 (3)F7v—C11—F8v103.0 (6)
Ag4ii—Ag4—Ag1110.1 (4)F7—C11—F8v63.5 (6)
O5i—Ag4—Ag172.97 (12)F9v—C11—F8v100.2 (6)
C1ii—Ag4—Ag1160.66 (15)F9—C11—F8v67.0 (6)
C1—Ag4—Ag149.63 (15)F7v—C11—F863.5 (6)
C2ii—Ag4—Ag1137.83 (15)F7—C11—F8103.0 (6)
C2—Ag4—Ag173.74 (15)F9v—C11—F867.0 (6)
Ag4ii—Ag4—Ag3ii111.9 (4)F9—C11—F8100.2 (6)
O5i—Ag4—Ag3ii70.77 (12)F8v—C11—F8149.7 (9)
C1ii—Ag4—Ag3ii44.77 (14)F7v—C11—C10115.0 (6)
C1—Ag4—Ag3ii162.75 (14)F7—C11—C10115.0 (6)
C2ii—Ag4—Ag3ii70.04 (14)F9v—C11—C10114.2 (6)
C2—Ag4—Ag3ii137.24 (14)F9—C11—C10114.2 (6)
Ag1—Ag4—Ag3ii131.15 (4)F8v—C11—C10105.1 (5)
Ag4ii—Ag4—Ag1ii59.0 (4)F8—C11—C10105.2 (5)
O5i—Ag4—Ag1ii86.53 (12)F9v—F7—C1173.1 (8)
C1ii—Ag4—Ag1ii45.71 (15)F9v—F7—F8v135.2 (12)
C1—Ag4—Ag1ii136.79 (15)C11—F7—F8v64.0 (5)
C2ii—Ag4—Ag1ii69.06 (15)F7v—F8—C1152.5 (4)
C2—Ag4—Ag1ii123.63 (14)F7v—F8—F9v95.6 (6)
Ag1—Ag4—Ag1ii152.58 (4)C11—F8—F9v52.0 (4)
Ag3ii—Ag4—Ag1ii52.88 (4)F7v—F9—C1169.5 (8)
Ag4ii—Ag4—Ag357.9 (4)F7v—F9—F8v127.8 (12)
O5i—Ag4—Ag392.20 (12)C11—F9—F8v61.0 (5)
C1ii—Ag4—Ag3141.31 (15)Ag2—O1W—H1W109.4
C1—Ag4—Ag340.27 (14)Ag2—O1W—H2W109.5
C2ii—Ag4—Ag3124.94 (14)H1W—O1W—H2W109.8
Ag3—C1—C2—Ag4ii63.0 (6)O5v—C10—C11—F7v110.0 (7)
Ag2—C1—C2—Ag4ii172.4 (5)O5—C10—C11—F7v70.0 (7)
Ag1—C1—C2—Ag4ii70.4 (5)O5v—C10—C11—F770.0 (7)
Ag4—C1—C2—Ag4ii15.46 (6)O5—C10—C11—F7110.0 (7)
Ag3—C1—C2—Ag478.5 (6)O5v—C10—C11—F9v28.6 (6)
Ag2—C1—C2—Ag4156.9 (5)O5—C10—C11—F9v151.4 (6)
Ag1—C1—C2—Ag455.0 (5)O5v—C10—C11—F9151.4 (6)
Ag4ii—C1—C2—Ag415.46 (6)O5—C10—C11—F928.6 (6)
Ag4ii—C2—C3—C3ii10.5 (9)O5v—C10—C11—F8v137.5 (5)
Ag4—C2—C3—C3ii5.6 (9)O5—C10—C11—F8v42.5 (5)
Ag4ii—C2—C3—C4171.7 (5)O5v—C10—C11—F842.5 (5)
Ag4—C2—C3—C4172.2 (5)O5—C10—C11—F8137.5 (5)
C3ii—C3—C4—C58.1 (13)F7v—C11—F7—F9v82.2 (12)
C2—C3—C4—C5174.1 (9)F9—C11—F7—F9v124.6 (15)
C3—C4—C5—C5ii25 (3)F8v—C11—F7—F9v167.0 (15)
Ag1—O1—C6—O210.3 (10)F8—C11—F7—F9v16.0 (14)
Ag1—O1—C6—C7171.1 (4)C10—C11—F7—F9v97.8 (12)
Ag2iii—O2—C6—O1161.3 (5)F7v—C11—F7—F8v84.8 (5)
Ag2—O2—C6—O11.9 (10)F9v—C11—F7—F8v167.0 (15)
Ag2iii—O2—C6—C720.2 (9)F9—C11—F7—F8v42.5 (7)
Ag2—O2—C6—C7179.5 (4)F8—C11—F7—F8v151.0 (9)
O1—C6—C7—F242.2 (8)C10—C11—F7—F8v95.2 (5)
O2—C6—C7—F2139.0 (6)F7—C11—F8—F7v128.5 (12)
O1—C6—C7—F377.5 (7)F9v—C11—F8—F7v139.0 (8)
O2—C6—C7—F3101.3 (7)F9—C11—F8—F7v8.0 (9)
O1—C6—C7—F1163.2 (6)F8v—C11—F8—F7v69.3 (6)
O2—C6—C7—F118.1 (8)C10—C11—F8—F7v110.7 (6)
Ag1—O3—C8—O417.3 (11)F7v—C11—F8—F9v139.0 (8)
Ag1—O3—C8—C9164.3 (5)F7—C11—F8—F9v10.5 (9)
Ag3—O4—C8—O31.3 (10)F9—C11—F8—F9v131.0 (11)
Ag1iv—O4—C8—O3148.5 (6)F8v—C11—F8—F9v69.7 (6)
Ag3—O4—C8—C9179.7 (4)C10—C11—F8—F9v110.3 (6)
Ag1iv—O4—C8—C933.1 (9)F7—C11—F9—F7v122.0 (15)
O3—C8—C9—F4116.0 (8)F9v—C11—F9—F7v80.0 (12)
O4—C8—C9—F465.4 (9)F8v—C11—F9—F7v163.1 (15)
O3—C8—C9—F58.8 (10)F8—C11—F9—F7v11.8 (14)
O4—C8—C9—F5169.8 (7)C10—C11—F9—F7v100.0 (12)
O3—C8—C9—F6126.7 (8)F7v—C11—F9—F8v163.1 (15)
O4—C8—C9—F651.9 (9)F7—C11—F9—F8v41.0 (7)
Ag3—O5—C10—O5v160.0 (6)F9v—C11—F9—F8v83.1 (5)
Ag4iv—O5—C10—O5v0.60 (6)F8—C11—F9—F8v151.3 (9)
Ag3—O5—C10—C1120.0 (6)C10—C11—F9—F8v96.9 (5)
Ag4iv—O5—C10—C11179.40 (6)
Symmetry codes: (i) x, y, z+1/2; (ii) x+1, y, z+3/2; (iii) x+1/2, y+1/2, z+1; (iv) x, y, z1/2; (v) x+1, y, z+1/2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1W—H1W···O1iv0.852.052.786 (7)144.8
O1W—H2W···O3iv0.852.132.808 (7)136.0
Symmetry code: (iv) x, y, z1/2.
(VI) top
Crystal data top
9(Ag+)·C10H82·9(C2F3O2)·C5H5N·2(C5H6N+)Z = 2
Mr = 2355.49F(000) = 2224
Monoclinic, P21Dx = 2.518 Mg m3
a = 8.9453 (9) ÅMo Kα radiation, λ = 0.71073 Å
b = 24.902 (3) ŵ = 2.93 mm1
c = 14.4248 (16) ÅT = 173 K
β = 105.016 (2)°Block, yellow
V = 3103.5 (6) Å30.50 × 0.50 × 0.40 mm
Data collection top
Bruker APEX-II CCD
diffractometer
10668 reflections with I > 2σ(I)
φ and ω scanRint = 0.077
Absorption correction: multi-scan
SADABS (Bruker, 2003)
θmax = 25.3°, θmin = 1.7°
Tmin = 0.323, Tmax = 0.388h = 1010
68475 measured reflectionsk = 2929
11211 independent reflectionsl = 1717
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: mixed
R[F2 > 2σ(F2)] = 0.036H-atom parameters constrained
wR(F2) = 0.098 w = 1/[σ2(Fo2) + (0.0648P)2 + 2.1022P]
where P = (Fo2 + 2Fc2)/3
S = 1.03(Δ/σ)max = 0.001
11211 reflectionsΔρmax = 1.39 e Å3
873 parametersΔρmin = 0.71 e Å3
283 restraintsAbsolute structure: Refined as an inversion twin.
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.48 (4)
Crystal data top
9(Ag+)·C10H82·9(C2F3O2)·C5H5N·2(C5H6N+)V = 3103.5 (6) Å3
Mr = 2355.49Z = 2
Monoclinic, P21Mo Kα radiation
a = 8.9453 (9) ŵ = 2.93 mm1
b = 24.902 (3) ÅT = 173 K
c = 14.4248 (16) Å0.50 × 0.50 × 0.40 mm
β = 105.016 (2)°
Data collection top
Bruker APEX-II CCD
diffractometer
11211 independent reflections
Absorption correction: multi-scan
SADABS (Bruker, 2003)
10668 reflections with I > 2σ(I)
Tmin = 0.323, Tmax = 0.388Rint = 0.077
68475 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.036H-atom parameters constrained
wR(F2) = 0.098Δρmax = 1.39 e Å3
S = 1.03Δρmin = 0.71 e Å3
11211 reflectionsAbsolute structure: Refined as an inversion twin.
873 parametersAbsolute structure parameter: 0.48 (4)
283 restraints
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refined as a 2-component inversion twin.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.26306 (8)0.51006 (3)0.29525 (5)0.02586 (16)
Ag20.08014 (8)0.41637 (3)0.32873 (5)0.02328 (16)
Ag30.32482 (8)0.46660 (4)0.48591 (5)0.03095 (18)
Ag40.59817 (8)0.47469 (3)0.37339 (5)0.02662 (17)
Ag50.31599 (9)0.41789 (4)0.17934 (5)0.03128 (19)
Ag60.66712 (10)0.43281 (3)0.18543 (6)0.03162 (19)
Ag70.88279 (9)0.51015 (3)0.30338 (6)0.03278 (19)
Ag80.98831 (9)0.46345 (3)0.49325 (5)0.02847 (18)
Ag90.7961 (3)0.56467 (19)0.56632 (13)0.0576 (10)0.699 (11)
N10.8037 (14)0.6264 (5)0.6766 (7)0.037 (3)*0.699 (11)
C290.7333 (16)0.6171 (5)0.7505 (9)0.050 (5)*0.699 (11)
H290.67520.58520.75080.060*0.699 (11)
C300.748 (2)0.6545 (6)0.8239 (9)0.071 (7)*0.699 (11)
H300.69980.64810.87430.085*0.699 (11)
C310.833 (2)0.7012 (6)0.8234 (10)0.077 (7)*0.699 (11)
H310.84300.72670.87360.093*0.699 (11)
C320.9034 (19)0.7105 (5)0.7496 (11)0.070 (6)*0.699 (11)
H320.96150.74240.74930.084*0.699 (11)
C330.8888 (16)0.6731 (6)0.6762 (9)0.064 (6)*0.699 (11)
H330.93690.67950.62570.076*0.699 (11)
Ag9'0.8395 (8)0.5950 (4)0.5745 (4)0.057 (2)0.301 (11)
N1'0.857 (3)0.6561 (10)0.6927 (14)0.038 (8)*0.301 (11)
C29'0.798 (3)0.6385 (9)0.7676 (17)0.038 (9)*0.301 (11)
H29'0.75470.60360.76550.046*0.301 (11)
C30'0.804 (3)0.6719 (11)0.8455 (15)0.032 (8)*0.301 (11)
H30'0.76330.65990.89670.038*0.301 (11)
C31'0.868 (4)0.7230 (11)0.8485 (18)0.073 (16)*0.301 (11)
H31'0.87100.74580.90180.087*0.301 (11)
C32'0.926 (4)0.7406 (9)0.774 (2)0.057 (12)*0.301 (11)
H32'0.97010.77550.77570.069*0.301 (11)
C33'0.921 (3)0.7072 (11)0.6957 (17)0.038 (9)*0.301 (11)
H33'0.96150.71920.64450.046*0.301 (11)
O10.0746 (8)0.5761 (3)0.3373 (5)0.0266 (15)
O20.0314 (11)0.5810 (4)0.4587 (7)0.051 (2)
C110.0579 (12)0.5957 (4)0.4133 (7)0.027 (2)
C120.1602 (12)0.6451 (4)0.4505 (7)0.038 (3)
F10.1227 (12)0.6687 (4)0.5227 (6)0.079 (3)
F20.3054 (8)0.6311 (4)0.4778 (7)0.071 (3)
F30.1468 (13)0.6816 (3)0.3835 (5)0.081 (3)
O30.4124 (9)0.5863 (3)0.2861 (6)0.0349 (17)
O40.6178 (9)0.5615 (3)0.4048 (6)0.0350 (17)
C130.5287 (12)0.5947 (4)0.3494 (8)0.030 (2)
C140.5852 (11)0.6548 (4)0.3662 (7)0.038 (3)
F40.6157 (10)0.6668 (3)0.4573 (5)0.055 (2)
F50.4818 (9)0.6877 (3)0.3193 (7)0.071 (3)
F60.7134 (9)0.6615 (3)0.3393 (6)0.061 (2)
O50.0985 (9)0.5370 (3)0.1518 (5)0.0328 (17)
O60.1723 (8)0.4737 (3)0.0632 (5)0.0307 (15)
C150.0958 (11)0.5129 (5)0.0771 (7)0.028 (2)
C160.0235 (12)0.5347 (4)0.0121 (8)0.043 (3)
F70.1569 (9)0.5482 (4)0.0039 (6)0.072 (3)
F80.0587 (11)0.5009 (4)0.0842 (6)0.087 (4)
F90.0313 (10)0.5786 (4)0.0411 (8)0.095 (4)
O70.1234 (9)0.3402 (3)0.4288 (5)0.0319 (16)
O80.1889 (10)0.3929 (3)0.5593 (6)0.0378 (18)
C170.1676 (12)0.3491 (4)0.5164 (8)0.029 (2)
C180.2079 (13)0.2984 (4)0.5799 (8)0.046 (3)
F100.1291 (16)0.2565 (4)0.5444 (8)0.116 (6)
F110.1964 (18)0.3064 (4)0.6669 (6)0.122 (6)
F120.3542 (12)0.2865 (5)0.5896 (11)0.134 (6)
O90.3176 (12)0.5258 (4)0.5968 (7)0.051 (2)
O100.0871 (10)0.5094 (4)0.6282 (6)0.0443 (19)
C190.2194 (16)0.5309 (4)0.6422 (8)0.039 (3)
C200.2604 (13)0.5673 (4)0.7318 (7)0.044 (3)
F130.253 (2)0.6160 (4)0.7092 (7)0.191 (12)
F140.1732 (17)0.5596 (7)0.7926 (9)0.160 (8)
F150.3977 (14)0.5557 (6)0.7840 (9)0.146 (7)
O110.0437 (9)0.3753 (3)0.1802 (5)0.0342 (17)
O120.1369 (9)0.4324 (4)0.0999 (6)0.0414 (19)
C210.0549 (12)0.3909 (5)0.1083 (7)0.029 (2)
C220.0739 (11)0.3550 (5)0.0190 (7)0.043 (3)
F160.0321 (11)0.3654 (5)0.0255 (8)0.097 (4)
F170.0629 (17)0.3041 (4)0.0417 (7)0.108 (5)
F180.2087 (10)0.3599 (5)0.0426 (6)0.090 (4)
O130.3643 (13)0.3544 (6)0.0817 (10)0.080 (4)
O140.6198 (12)0.3490 (4)0.1223 (8)0.057 (3)
C230.4862 (15)0.3354 (5)0.0806 (9)0.038 (3)
C240.4756 (12)0.2843 (5)0.0166 (8)0.047 (3)
F190.4424 (15)0.2979 (4)0.0737 (6)0.097 (4)
F200.3681 (12)0.2510 (4)0.0270 (9)0.092 (4)
F210.6043 (11)0.2563 (4)0.0333 (9)0.099 (4)
O150.5360 (9)0.5063 (3)0.1190 (6)0.0369 (17)
O160.7191 (8)0.5649 (3)0.1932 (5)0.0320 (16)
C250.5966 (12)0.5522 (5)0.1358 (8)0.032 (2)
C260.5095 (11)0.5982 (4)0.0722 (7)0.035 (2)
F220.3589 (7)0.5906 (3)0.0480 (7)0.065 (2)
F230.5335 (10)0.6450 (3)0.1135 (6)0.062 (2)
F240.5541 (12)0.6000 (5)0.0073 (6)0.090 (4)
O170.5447 (14)0.4270 (5)0.5933 (9)0.074 (3)*
O180.7438 (12)0.4657 (7)0.5522 (6)0.073 (3)
C270.6832 (14)0.4330 (7)0.5936 (9)0.054 (4)
C280.7894 (19)0.3919 (7)0.6523 (12)0.093 (6)*
F250.7201 (16)0.3529 (7)0.6863 (13)0.197 (12)
F260.8809 (18)0.4142 (9)0.7292 (11)0.222 (13)
F270.8815 (16)0.3686 (8)0.6069 (10)0.208 (13)
C10.3506 (10)0.4309 (4)0.3512 (7)0.0225 (19)
C20.4353 (11)0.3925 (4)0.3448 (7)0.026 (2)
C30.5172 (11)0.3432 (4)0.3492 (7)0.023 (2)
C40.4246 (13)0.2919 (4)0.3431 (9)0.035 (2)
H4A0.35660.28790.27740.042*
H4B0.35810.29390.38820.042*
C50.5300 (15)0.2428 (4)0.3675 (9)0.038 (3)
H5A0.57910.24190.43740.045*
H5B0.46790.20960.35000.045*
C60.6532 (14)0.2451 (4)0.3133 (9)0.036 (2)
H6A0.60360.24770.24370.043*
H6B0.71500.21160.32480.043*
C70.7587 (13)0.2928 (4)0.3449 (9)0.035 (2)
H7A0.82170.29840.29850.042*
H7B0.83020.28500.40830.042*
C80.6694 (11)0.3438 (4)0.3518 (7)0.0229 (19)
C90.7474 (11)0.3925 (4)0.3508 (7)0.024 (2)
C100.8375 (11)0.4312 (4)0.3554 (7)0.0232 (19)
N20.0533 (15)0.6496 (4)0.1685 (7)0.046 (3)
H20.06570.61460.16620.056*
C340.1674 (18)0.6803 (7)0.1632 (10)0.058 (4)
H34A0.26320.66510.15970.070*
C350.148 (2)0.7362 (7)0.1625 (11)0.062 (4)
H35A0.22890.75980.15690.075*
C360.014 (2)0.7545 (6)0.1700 (11)0.058 (4)
H36A0.00180.79220.17010.070*
C370.0983 (17)0.7218 (7)0.1775 (11)0.056 (4)
H37A0.19380.73640.18320.067*
C380.0792 (16)0.6677 (6)0.1773 (10)0.048 (3)
H38A0.15930.64400.18320.058*
N30.4065 (15)0.4149 (6)0.7639 (8)0.052 (3)0.5
H30.41200.40250.70770.062*0.5
C420.3911 (13)0.4539 (5)0.9361 (7)0.038 (2)0.5
H42A0.38410.46700.99670.045*0.5
N3'0.3911 (13)0.4539 (5)0.9361 (7)0.038 (2)0.5
H3'0.38460.46610.99220.045*0.5
C42'0.4065 (15)0.4149 (6)0.7639 (8)0.052 (3)0.5
H42B0.41240.40240.70290.062*0.5
C390.2704 (14)0.4167 (6)0.7868 (8)0.043 (3)
H390.17980.40380.74230.051*
C400.5387 (16)0.4333 (7)0.8304 (10)0.054 (3)
H40A0.63600.43170.81550.064*
C410.5298 (16)0.4532 (6)0.9168 (9)0.050 (3)
H41A0.61920.46630.96210.060*
C430.2598 (15)0.4365 (6)0.8724 (9)0.044 (3)
H43A0.16280.43820.88750.053*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0254 (4)0.0218 (3)0.0285 (4)0.0007 (3)0.0037 (3)0.0018 (3)
Ag20.0182 (3)0.0268 (4)0.0254 (3)0.0000 (3)0.0065 (3)0.0009 (3)
Ag30.0253 (4)0.0437 (5)0.0234 (3)0.0007 (3)0.0056 (3)0.0023 (4)
Ag40.0210 (3)0.0213 (4)0.0373 (4)0.0011 (3)0.0071 (3)0.0011 (3)
Ag50.0292 (4)0.0388 (4)0.0259 (4)0.0091 (3)0.0071 (3)0.0000 (3)
Ag60.0377 (4)0.0282 (4)0.0284 (4)0.0030 (3)0.0075 (3)0.0041 (3)
Ag70.0265 (4)0.0235 (4)0.0436 (5)0.0036 (3)0.0007 (3)0.0059 (3)
Ag80.0271 (4)0.0313 (4)0.0251 (3)0.0006 (3)0.0034 (3)0.0046 (3)
Ag90.0605 (12)0.062 (2)0.0485 (9)0.0069 (13)0.0102 (8)0.0233 (9)
Ag9'0.065 (3)0.061 (5)0.056 (3)0.006 (3)0.033 (2)0.005 (3)
O10.024 (4)0.031 (4)0.025 (4)0.001 (3)0.007 (3)0.003 (3)
O20.048 (5)0.063 (6)0.050 (5)0.005 (4)0.029 (4)0.000 (5)
C110.024 (5)0.026 (5)0.027 (5)0.003 (4)0.002 (4)0.001 (4)
C120.047 (6)0.028 (5)0.035 (5)0.007 (5)0.004 (5)0.001 (4)
F10.110 (8)0.071 (6)0.064 (6)0.022 (6)0.038 (6)0.039 (5)
F20.041 (5)0.062 (6)0.100 (7)0.019 (4)0.002 (4)0.005 (5)
F30.140 (9)0.044 (5)0.046 (5)0.045 (6)0.001 (5)0.009 (4)
O30.037 (4)0.027 (4)0.037 (4)0.007 (3)0.003 (4)0.004 (3)
O40.032 (4)0.025 (4)0.043 (4)0.001 (3)0.002 (3)0.001 (3)
C130.027 (5)0.025 (5)0.036 (5)0.001 (4)0.005 (4)0.002 (4)
C140.032 (5)0.023 (5)0.054 (7)0.000 (4)0.001 (5)0.003 (5)
F40.078 (6)0.041 (4)0.050 (4)0.014 (4)0.024 (4)0.021 (3)
F50.061 (5)0.023 (4)0.104 (7)0.001 (4)0.026 (5)0.006 (4)
F60.072 (6)0.038 (4)0.088 (6)0.027 (4)0.047 (5)0.015 (4)
O50.033 (4)0.031 (4)0.030 (4)0.007 (3)0.001 (3)0.002 (3)
O60.029 (4)0.035 (4)0.026 (3)0.006 (3)0.004 (3)0.002 (3)
C150.022 (4)0.037 (5)0.024 (5)0.000 (4)0.007 (4)0.006 (4)
C160.041 (6)0.051 (7)0.037 (6)0.012 (5)0.008 (5)0.003 (5)
F70.051 (5)0.110 (8)0.050 (5)0.039 (5)0.003 (4)0.013 (5)
F80.084 (7)0.109 (9)0.045 (5)0.040 (6)0.026 (4)0.029 (5)
F90.065 (6)0.114 (9)0.086 (7)0.002 (6)0.014 (5)0.068 (7)
O70.034 (4)0.031 (4)0.029 (4)0.001 (3)0.006 (3)0.003 (3)
O80.044 (5)0.030 (4)0.041 (5)0.006 (3)0.015 (4)0.005 (3)
C170.027 (5)0.029 (5)0.032 (5)0.004 (4)0.011 (4)0.006 (4)
C180.058 (7)0.037 (6)0.041 (6)0.014 (6)0.010 (5)0.010 (5)
F100.166 (13)0.043 (6)0.097 (9)0.032 (7)0.040 (8)0.035 (6)
F110.249 (18)0.066 (7)0.059 (6)0.037 (9)0.054 (9)0.037 (6)
F120.101 (9)0.109 (11)0.196 (16)0.073 (9)0.048 (10)0.094 (11)
O90.061 (6)0.049 (6)0.042 (5)0.012 (4)0.012 (4)0.014 (4)
O100.056 (5)0.045 (5)0.031 (4)0.003 (4)0.010 (4)0.008 (4)
C190.059 (7)0.020 (5)0.033 (5)0.010 (5)0.004 (5)0.004 (4)
C200.059 (7)0.036 (6)0.029 (5)0.017 (5)0.001 (5)0.005 (5)
F130.45 (4)0.030 (5)0.050 (6)0.004 (10)0.017 (11)0.013 (5)
F140.209 (19)0.191 (18)0.096 (10)0.075 (15)0.067 (11)0.104 (12)
F150.137 (12)0.164 (14)0.089 (8)0.053 (11)0.054 (8)0.084 (9)
O110.030 (4)0.041 (5)0.032 (4)0.000 (3)0.010 (3)0.009 (3)
O120.029 (4)0.042 (5)0.057 (5)0.003 (4)0.018 (4)0.006 (4)
C210.024 (5)0.037 (6)0.027 (5)0.004 (4)0.009 (4)0.008 (4)
C220.038 (6)0.055 (7)0.033 (6)0.001 (5)0.005 (5)0.007 (5)
F160.089 (7)0.129 (10)0.098 (8)0.053 (7)0.068 (6)0.077 (8)
F170.188 (14)0.059 (7)0.063 (6)0.007 (8)0.006 (7)0.026 (5)
F180.063 (6)0.147 (11)0.049 (5)0.002 (6)0.007 (4)0.038 (6)
O130.051 (6)0.096 (9)0.086 (8)0.023 (6)0.007 (6)0.053 (7)
O140.061 (6)0.044 (5)0.074 (7)0.017 (5)0.033 (5)0.031 (5)
C230.044 (7)0.034 (6)0.037 (6)0.001 (5)0.014 (5)0.005 (5)
C240.051 (7)0.045 (7)0.050 (7)0.012 (6)0.019 (5)0.015 (5)
F190.180 (13)0.073 (7)0.043 (5)0.029 (8)0.037 (7)0.021 (5)
F200.099 (8)0.077 (7)0.111 (9)0.049 (6)0.049 (7)0.034 (6)
F210.084 (8)0.068 (7)0.143 (11)0.007 (6)0.028 (7)0.060 (7)
O150.034 (4)0.029 (4)0.041 (4)0.001 (3)0.003 (3)0.003 (4)
O160.026 (4)0.032 (4)0.034 (4)0.002 (3)0.000 (3)0.002 (3)
C250.027 (5)0.034 (6)0.033 (5)0.003 (4)0.005 (4)0.003 (4)
C260.038 (6)0.035 (6)0.031 (5)0.010 (5)0.004 (4)0.007 (4)
F220.030 (4)0.060 (5)0.094 (7)0.011 (3)0.004 (4)0.022 (5)
F230.068 (6)0.035 (4)0.072 (5)0.009 (4)0.002 (4)0.008 (4)
F240.102 (8)0.130 (10)0.052 (5)0.059 (7)0.043 (5)0.040 (6)
O180.053 (6)0.134 (11)0.031 (4)0.012 (7)0.010 (4)0.004 (6)
C270.028 (5)0.098 (10)0.038 (6)0.006 (6)0.012 (5)0.012 (6)
F250.101 (11)0.24 (2)0.27 (2)0.076 (13)0.097 (14)0.20 (2)
F260.094 (11)0.43 (4)0.110 (12)0.031 (18)0.035 (9)0.07 (2)
F270.136 (13)0.36 (3)0.175 (16)0.168 (18)0.121 (13)0.18 (2)
C10.016 (4)0.025 (5)0.026 (4)0.003 (4)0.004 (3)0.004 (4)
C20.018 (4)0.037 (5)0.023 (4)0.001 (4)0.007 (4)0.000 (4)
C30.016 (4)0.026 (5)0.026 (5)0.003 (4)0.003 (4)0.001 (4)
C40.027 (5)0.025 (5)0.054 (6)0.005 (4)0.014 (5)0.004 (5)
C50.045 (6)0.020 (5)0.048 (6)0.007 (4)0.012 (5)0.004 (4)
C60.034 (5)0.025 (5)0.049 (6)0.000 (4)0.010 (5)0.002 (5)
C70.031 (5)0.021 (5)0.053 (6)0.004 (4)0.009 (5)0.001 (5)
C80.023 (5)0.022 (5)0.023 (4)0.002 (4)0.005 (4)0.000 (4)
C90.023 (5)0.028 (5)0.021 (4)0.006 (4)0.005 (4)0.005 (4)
C100.019 (4)0.022 (5)0.029 (5)0.001 (4)0.007 (4)0.001 (4)
N20.078 (8)0.025 (5)0.033 (5)0.013 (5)0.009 (5)0.001 (4)
C340.052 (8)0.076 (9)0.048 (7)0.014 (7)0.015 (6)0.001 (7)
C350.074 (9)0.056 (8)0.059 (8)0.028 (7)0.021 (7)0.009 (7)
C360.087 (10)0.033 (6)0.051 (7)0.010 (6)0.011 (7)0.010 (5)
C370.047 (7)0.061 (8)0.053 (7)0.014 (6)0.003 (6)0.007 (6)
C380.047 (7)0.054 (7)0.045 (6)0.012 (6)0.014 (5)0.008 (6)
N30.054 (6)0.064 (7)0.040 (5)0.002 (6)0.017 (5)0.013 (6)
C420.043 (5)0.048 (6)0.021 (4)0.002 (5)0.008 (4)0.005 (4)
N3'0.043 (5)0.048 (6)0.021 (4)0.002 (5)0.008 (4)0.005 (4)
C42'0.054 (6)0.064 (7)0.040 (5)0.002 (6)0.017 (5)0.013 (6)
C390.045 (6)0.045 (6)0.036 (5)0.002 (5)0.006 (5)0.003 (5)
C400.040 (6)0.067 (8)0.055 (7)0.002 (6)0.014 (6)0.008 (6)
C410.043 (6)0.070 (8)0.032 (5)0.005 (6)0.003 (5)0.003 (6)
C430.040 (6)0.055 (7)0.038 (6)0.004 (5)0.009 (5)0.009 (5)
Geometric parameters (Å, º) top
Ag1—C12.196 (10)C14—F51.289 (10)
Ag1—O52.306 (7)C14—F41.306 (10)
Ag1—O32.345 (7)C14—F61.313 (10)
Ag1—O12.538 (7)O5—C151.229 (13)
Ag1—Ag32.8728 (11)O6—C151.237 (14)
Ag1—Ag52.9494 (12)C15—C161.542 (14)
Ag1—Ag22.9603 (11)C16—F91.309 (11)
Ag1—Ag43.0466 (10)C16—F81.311 (11)
Ag2—O112.319 (7)C16—F71.315 (11)
Ag2—C10i2.330 (9)O7—C171.242 (14)
Ag2—O72.355 (8)O8—C171.244 (14)
Ag2—C12.384 (9)O8—Ag8i2.516 (8)
Ag2—Ag7i2.8929 (11)C17—C181.547 (15)
Ag2—Ag8i2.9481 (10)C18—F101.289 (11)
Ag2—Ag32.9874 (10)C18—F111.300 (11)
Ag3—O92.189 (9)C18—F121.313 (11)
Ag3—C12.202 (10)O9—C191.231 (16)
Ag3—O172.379 (13)O10—C191.266 (17)
Ag3—O82.577 (8)O10—Ag8i2.233 (8)
Ag3—Ag8i3.0405 (11)C19—C201.544 (15)
Ag3—Ag43.2727 (10)C20—F131.251 (11)
Ag4—O42.206 (8)C20—F151.297 (11)
Ag4—C12.414 (9)C20—F141.330 (11)
Ag4—C102.472 (9)O11—C211.237 (14)
Ag4—C22.484 (11)O12—C211.255 (14)
Ag4—C92.511 (10)O12—Ag6i2.391 (7)
Ag4—O182.581 (9)C21—C221.541 (15)
Ag4—Ag73.1006 (11)C22—F161.302 (10)
Ag4—Ag63.1120 (11)C22—F181.304 (11)
Ag5—O132.233 (10)C22—F171.306 (11)
Ag5—O62.297 (7)O13—C231.192 (16)
Ag5—C22.432 (10)O14—C231.238 (16)
Ag5—C12.439 (9)C23—C241.560 (16)
Ag5—Ag63.1414 (11)C24—F191.303 (11)
Ag6—O152.249 (8)C24—F201.308 (11)
Ag6—O142.274 (9)C24—F211.314 (11)
Ag6—O12ii2.391 (7)O15—C251.261 (14)
Ag6—C92.515 (10)O16—C251.232 (13)
Ag6—C102.530 (10)C25—C261.547 (15)
Ag6—Ag72.9368 (12)C26—F231.300 (10)
Ag7—C102.180 (10)C26—F241.309 (10)
Ag7—O162.308 (7)C26—F221.315 (10)
Ag7—O1ii2.333 (7)O17—C271.247 (17)
Ag7—Ag2ii2.8929 (11)O18—C271.22 (2)
Ag7—Ag82.8992 (12)C27—C281.50 (2)
Ag8—O10ii2.233 (8)C28—F271.312 (13)
Ag8—C102.242 (10)C28—F251.313 (13)
Ag8—O8ii2.516 (8)C28—F261.318 (13)
Ag8—O182.544 (10)C1—C21.239 (14)
Ag8—Ag2ii2.9480 (10)C2—C31.421 (15)
Ag8—Ag3ii3.0404 (11)C3—C81.353 (14)
Ag8—Ag93.371 (3)C3—C41.513 (14)
Ag9—N12.201 (10)C4—C51.528 (16)
Ag9—O42.460 (8)C4—H4A0.9900
Ag9—O2ii2.490 (9)C4—H4B0.9900
Ag9—O182.508 (17)C5—C61.508 (17)
N1—C291.3900C5—H5A0.9900
N1—C331.3900C5—H5B0.9900
C29—C301.3900C6—C71.513 (15)
C29—H290.9500C6—H6A0.9900
C30—C311.3900C6—H6B0.9900
C30—H300.9500C7—C81.517 (14)
C31—C321.3900C7—H7A0.9900
C31—H310.9500C7—H7B0.9900
C32—C331.3900C8—C91.400 (15)
C32—H320.9500C9—C101.247 (14)
C33—H330.9500C10—Ag2ii2.330 (9)
Ag9'—N1'2.26 (2)N2—C341.29 (2)
Ag9'—O2ii2.291 (9)N2—C381.304 (19)
N1'—C29'1.3900N2—H20.8800
N1'—C33'1.3900C34—C351.40 (2)
C29'—C30'1.3900C34—H34A0.9500
C29'—H29'0.9500C35—C361.31 (2)
C30'—C31'1.3900C35—H35A0.9500
C30'—H30'0.9500C36—C371.32 (2)
C31'—C32'1.3900C36—H36A0.9500
C31'—H31'0.9500C37—C381.36 (2)
C32'—C33'1.3900C37—H37A0.9500
C32'—H32'0.9500C38—H38A0.9500
C33'—H33'0.9500N3—C391.343 (17)
O1—C111.244 (13)N3—C401.393 (19)
O1—Ag7i2.333 (7)N3—H30.8799
O2—C111.213 (14)C42—C411.340 (18)
O2—Ag9'i2.291 (9)C42—C431.361 (17)
O2—Ag9i2.490 (9)C42—H42A0.9500
C11—C121.545 (15)C39—C431.354 (18)
C12—F21.304 (11)C39—H390.9500
C12—F31.309 (10)C40—C411.364 (19)
C12—F11.312 (10)C40—H40A0.9500
O3—C131.212 (14)C41—H41A0.9501
O4—C131.276 (14)C43—H43A0.9487
C13—C141.577 (15)
C1—Ag1—O5132.4 (3)C33—C32—H32120.0
C1—Ag1—O3126.4 (3)C31—C32—H32120.0
O5—Ag1—O387.4 (3)C32—C33—N1120.0
C1—Ag1—O1133.6 (3)C32—C33—H33120.0
O5—Ag1—O173.5 (2)N1—C33—H33120.0
O3—Ag1—O185.0 (3)N1'—Ag9'—O2ii134.6 (8)
C1—Ag1—Ag349.3 (2)C29'—N1'—C33'120.0
O5—Ag1—Ag3152.6 (2)C29'—N1'—Ag9'114.0 (13)
O3—Ag1—Ag3112.82 (19)C33'—N1'—Ag9'126.0 (13)
O1—Ag1—Ag389.44 (16)N1'—C29'—C30'120.0
C1—Ag1—Ag554.2 (2)N1'—C29'—H29'120.0
O5—Ag1—Ag582.93 (19)C30'—C29'—H29'120.0
O3—Ag1—Ag5114.9 (2)C31'—C30'—C29'120.0
O1—Ag1—Ag5148.60 (16)C31'—C30'—H30'120.0
Ag3—Ag1—Ag5103.31 (3)C29'—C30'—H30'120.0
C1—Ag1—Ag252.6 (2)C30'—C31'—C32'120.0
O5—Ag1—Ag297.1 (2)C30'—C31'—H31'120.0
O3—Ag1—Ag2173.9 (2)C32'—C31'—H31'120.0
O1—Ag1—Ag292.41 (16)C31'—C32'—C33'120.0
Ag3—Ag1—Ag261.59 (3)C31'—C32'—H32'120.0
Ag5—Ag1—Ag269.87 (3)C33'—C32'—H32'120.0
C1—Ag1—Ag451.8 (2)C32'—C33'—N1'120.0
O5—Ag1—Ag4139.0 (2)C32'—C33'—H33'120.0
O3—Ag1—Ag474.6 (2)N1'—C33'—H33'120.0
O1—Ag1—Ag4138.57 (16)C11—O1—Ag7i102.2 (6)
Ag3—Ag1—Ag467.06 (3)C11—O1—Ag1134.7 (6)
Ag5—Ag1—Ag472.40 (3)Ag7i—O1—Ag189.6 (2)
Ag2—Ag1—Ag4104.14 (3)C11—O2—Ag9'i151.1 (10)
O11—Ag2—C10i108.0 (3)C11—O2—Ag9i170.8 (9)
O11—Ag2—O7100.0 (3)O2—C11—O1127.2 (10)
C10i—Ag2—O792.2 (3)O2—C11—C12117.7 (10)
O11—Ag2—C195.0 (3)O1—C11—C12115.1 (9)
C10i—Ag2—C1155.4 (3)F2—C12—F3107.6 (9)
O7—Ag2—C192.2 (3)F2—C12—F1108.7 (9)
O11—Ag2—Ag7i107.7 (2)F3—C12—F1106.3 (9)
C10i—Ag2—Ag7i47.9 (2)F2—C12—C11110.2 (8)
O7—Ag2—Ag7i136.55 (18)F3—C12—C11111.3 (8)
C1—Ag2—Ag7i117.3 (2)F1—C12—C11112.5 (9)
O11—Ag2—Ag8i156.49 (19)C13—O3—Ag1119.2 (7)
C10i—Ag2—Ag8i48.6 (2)C13—O4—Ag4120.2 (7)
O7—Ag2—Ag8i82.11 (18)C13—O4—Ag9136.0 (7)
C1—Ag2—Ag8i108.3 (2)Ag4—O4—Ag9102.9 (3)
Ag7i—Ag2—Ag8i59.51 (3)O3—C13—O4129.5 (10)
O11—Ag2—Ag198.5 (2)O3—C13—C14117.2 (9)
C10i—Ag2—Ag1118.7 (2)O4—C13—C14113.3 (9)
O7—Ag2—Ag1136.48 (19)F5—C14—F4108.5 (9)
C1—Ag2—Ag147.0 (2)F5—C14—F6109.0 (9)
Ag7i—Ag2—Ag171.83 (3)F4—C14—F6107.2 (8)
Ag8i—Ag2—Ag195.68 (3)F5—C14—C13111.5 (8)
O11—Ag2—Ag3141.78 (19)F4—C14—C13110.4 (8)
C10i—Ag2—Ag3109.8 (2)F6—C14—C13110.2 (8)
O7—Ag2—Ag384.28 (19)C15—O5—Ag1120.5 (7)
C1—Ag2—Ag346.8 (2)C15—O6—Ag5126.0 (6)
Ag7i—Ag2—Ag393.50 (3)O5—C15—O6129.9 (9)
Ag8i—Ag2—Ag361.62 (3)O5—C15—C16114.3 (9)
Ag1—Ag2—Ag357.76 (3)O6—C15—C16115.8 (9)
O9—Ag3—C1161.1 (4)F9—C16—F8108.4 (10)
O9—Ag3—O1788.8 (4)F9—C16—F7106.0 (9)
C1—Ag3—O1798.6 (4)F8—C16—F7105.1 (9)
O9—Ag3—O894.2 (3)F9—C16—C15108.9 (9)
C1—Ag3—O8104.1 (3)F8—C16—C15114.0 (9)
O17—Ag3—O880.5 (4)F7—C16—C15114.0 (9)
O9—Ag3—Ag1114.3 (3)C17—O7—Ag2116.0 (7)
C1—Ag3—Ag149.1 (2)C17—O8—Ag8i114.9 (7)
O17—Ag3—Ag1134.5 (3)C17—O8—Ag3116.6 (7)
O8—Ag3—Ag1131.90 (19)Ag8i—O8—Ag373.3 (2)
O9—Ag3—Ag2133.0 (3)O7—C17—O8129.1 (10)
C1—Ag3—Ag252.0 (2)O7—C17—C18114.9 (9)
O17—Ag3—Ag2129.8 (3)O8—C17—C18116.0 (9)
O8—Ag3—Ag271.49 (19)F10—C18—F11109.7 (11)
Ag1—Ag3—Ag260.65 (3)F10—C18—F12106.7 (10)
O9—Ag3—Ag8i77.0 (3)F11—C18—F12105.0 (10)
C1—Ag3—Ag8i110.6 (2)F10—C18—C17113.9 (9)
O17—Ag3—Ag8i128.7 (3)F11—C18—C17112.4 (9)
O8—Ag3—Ag8i52.43 (18)F12—C18—C17108.6 (9)
Ag1—Ag3—Ag8i95.54 (3)C19—O9—Ag3128.2 (8)
Ag2—Ag3—Ag8i58.55 (2)C19—O10—Ag8i119.9 (7)
O9—Ag3—Ag4119.2 (3)O9—C19—O10129.6 (11)
C1—Ag3—Ag447.5 (2)O9—C19—C20117.3 (12)
O17—Ag3—Ag475.6 (3)O10—C19—C20113.1 (10)
O8—Ag3—Ag4137.77 (18)F13—C20—F15110.5 (12)
Ag1—Ag3—Ag459.01 (2)F13—C20—F14108.1 (11)
Ag2—Ag3—Ag498.28 (3)F15—C20—F14102.3 (10)
Ag8i—Ag3—Ag4153.20 (3)F13—C20—C19111.5 (9)
O4—Ag4—C1119.4 (3)F15—C20—C19109.8 (9)
O4—Ag4—C10115.2 (3)F14—C20—C19114.4 (10)
C1—Ag4—C10125.3 (3)C21—O11—Ag2122.4 (7)
O4—Ag4—C2148.6 (3)C21—O12—Ag6i116.2 (7)
C1—Ag4—C229.3 (3)O11—C21—O12127.7 (10)
C10—Ag4—C296.2 (3)O11—C21—C22114.8 (9)
O4—Ag4—C9144.0 (3)O12—C21—C22117.5 (10)
C1—Ag4—C996.6 (3)F16—C22—F18108.0 (9)
C10—Ag4—C929.0 (3)F16—C22—F17107.4 (10)
C2—Ag4—C967.3 (3)F18—C22—F17104.9 (10)
O4—Ag4—O1883.5 (4)F16—C22—C21111.1 (9)
C1—Ag4—O18107.5 (4)F18—C22—C21113.5 (9)
C10—Ag4—O1880.8 (3)F17—C22—C21111.6 (9)
C2—Ag4—O18102.5 (4)C23—O13—Ag5128.1 (10)
C9—Ag4—O1884.9 (4)C23—O14—Ag6120.1 (9)
O4—Ag4—Ag179.1 (2)O13—C23—O14131.0 (12)
C1—Ag4—Ag145.6 (2)O13—C23—C24114.6 (12)
C10—Ag4—Ag1152.1 (2)O14—C23—C24114.4 (10)
C2—Ag4—Ag172.4 (2)F19—C24—F20107.2 (10)
C9—Ag4—Ag1133.8 (2)F19—C24—F21106.5 (10)
O18—Ag4—Ag1126.0 (2)F20—C24—F21106.1 (10)
O4—Ag4—Ag776.1 (2)F19—C24—C23110.1 (10)
C1—Ag4—Ag7152.6 (2)F20—C24—C23112.5 (10)
C10—Ag4—Ag744.3 (2)F21—C24—C23114.1 (9)
C2—Ag4—Ag7132.5 (2)C25—O15—Ag6120.3 (7)
C9—Ag4—Ag771.4 (2)C25—O16—Ag7127.3 (7)
O18—Ag4—Ag796.1 (3)O16—C25—O15128.7 (11)
Ag1—Ag4—Ag7127.55 (3)O16—C25—C26115.6 (10)
O4—Ag4—Ag6119.0 (2)O15—C25—C26115.6 (9)
C1—Ag4—Ag696.6 (2)F23—C26—F24108.6 (9)
C10—Ag4—Ag652.4 (2)F23—C26—F22106.6 (8)
C2—Ag4—Ag679.6 (2)F24—C26—F22107.2 (9)
C9—Ag4—Ag651.8 (2)F23—C26—C25113.2 (8)
O18—Ag4—Ag6132.8 (3)F24—C26—C25108.9 (9)
Ag1—Ag4—Ag699.94 (3)F22—C26—C25112.0 (9)
Ag7—Ag4—Ag656.42 (3)C27—O17—Ag3127.3 (11)
O4—Ag4—Ag389.3 (2)C27—O18—Ag9135.6 (11)
C1—Ag4—Ag342.3 (2)C27—O18—Ag8132.9 (12)
C10—Ag4—Ag3143.5 (2)Ag9—O18—Ag883.7 (4)
C2—Ag4—Ag363.3 (2)C27—O18—Ag4112.0 (10)
C9—Ag4—Ag3120.3 (2)Ag9—O18—Ag491.8 (5)
O18—Ag4—Ag375.4 (2)Ag8—O18—Ag485.6 (3)
Ag1—Ag4—Ag353.93 (2)O18—C27—O17130.3 (15)
Ag7—Ag4—Ag3163.97 (3)O18—C27—C28115.9 (12)
Ag6—Ag4—Ag3138.91 (3)O17—C27—C28113.8 (14)
O13—Ag5—O697.6 (4)F27—C28—F25106.2 (13)
O13—Ag5—C2109.1 (4)F27—C28—F26105.8 (13)
O6—Ag5—C2153.3 (3)F25—C28—F26104.3 (13)
O13—Ag5—C1137.8 (4)F27—C28—C27114.0 (13)
O6—Ag5—C1124.1 (3)F25—C28—C27115.1 (14)
C2—Ag5—C129.5 (3)F26—C28—C27110.6 (14)
O13—Ag5—Ag1174.0 (4)C2—C1—Ag1146.3 (8)
O6—Ag5—Ag178.49 (19)C2—C1—Ag3125.7 (8)
C2—Ag5—Ag175.0 (3)Ag1—C1—Ag381.6 (3)
C1—Ag5—Ag146.9 (2)C2—C1—Ag2119.4 (7)
O13—Ag5—Ag675.3 (3)Ag1—C1—Ag280.4 (3)
O6—Ag5—Ag6108.38 (19)Ag3—C1—Ag281.2 (3)
C2—Ag5—Ag679.7 (2)C2—C1—Ag478.5 (6)
C1—Ag5—Ag695.3 (2)Ag1—C1—Ag482.6 (3)
Ag1—Ag5—Ag6101.44 (3)Ag3—C1—Ag490.2 (3)
O15—Ag6—O14123.6 (4)Ag2—C1—Ag4161.9 (5)
O15—Ag6—O12ii98.9 (3)C2—C1—Ag574.9 (6)
O14—Ag6—O12ii82.8 (3)Ag1—C1—Ag578.8 (3)
O15—Ag6—C9135.9 (3)Ag3—C1—Ag5159.3 (5)
O14—Ag6—C989.5 (4)Ag2—C1—Ag589.1 (3)
O12ii—Ag6—C9114.9 (3)Ag4—C1—Ag593.7 (3)
O15—Ag6—C10122.9 (3)C1—C2—C3168.8 (10)
O14—Ag6—C10112.1 (4)C1—C2—Ag575.6 (6)
O12ii—Ag6—C1099.3 (3)C3—C2—Ag5111.0 (7)
C9—Ag6—C1028.6 (3)C1—C2—Ag472.2 (6)
O15—Ag6—Ag784.6 (2)C3—C2—Ag4115.5 (6)
O14—Ag6—Ag7149.4 (3)Ag5—C2—Ag492.2 (4)
O12ii—Ag6—Ag780.9 (2)C8—C3—C2119.7 (9)
C9—Ag6—Ag774.3 (2)C8—C3—C4122.8 (9)
C10—Ag6—Ag746.3 (2)C2—C3—C4117.3 (8)
O15—Ag6—Ag484.2 (2)C3—C4—C5111.6 (9)
O14—Ag6—Ag4126.8 (3)C3—C4—H4A109.3
O12ii—Ag6—Ag4142.0 (2)C5—C4—H4A109.3
C9—Ag6—Ag451.7 (2)C3—C4—H4B109.3
C10—Ag6—Ag450.7 (2)C5—C4—H4B109.3
Ag7—Ag6—Ag461.59 (3)H4A—C4—H4B108.0
O15—Ag6—Ag571.2 (2)C6—C5—C4109.9 (9)
O14—Ag6—Ag578.4 (3)C6—C5—H5A109.7
O12ii—Ag6—Ag5147.8 (2)C4—C5—H5A109.7
C9—Ag6—Ag591.0 (2)C6—C5—H5B109.7
C10—Ag6—Ag5111.8 (2)C4—C5—H5B109.7
Ag7—Ag6—Ag5126.57 (4)H5A—C5—H5B108.2
Ag4—Ag6—Ag569.00 (3)C5—C6—C7110.9 (10)
C10—Ag7—O16129.0 (3)C5—C6—H6A109.5
C10—Ag7—O1ii139.0 (3)C7—C6—H6A109.5
O16—Ag7—O1ii91.7 (3)C5—C6—H6B109.5
C10—Ag7—Ag2ii52.4 (2)C7—C6—H6B109.5
O16—Ag7—Ag2ii145.3 (2)H6A—C6—H6B108.0
O1ii—Ag7—Ag2ii98.62 (18)C6—C7—C8112.3 (9)
C10—Ag7—Ag850.0 (3)C6—C7—H7A109.1
O16—Ag7—Ag8151.77 (19)C8—C7—H7A109.1
O1ii—Ag7—Ag892.44 (17)C6—C7—H7B109.1
Ag2ii—Ag7—Ag861.19 (3)C8—C7—H7B109.1
C10—Ag7—Ag657.0 (3)H7A—C7—H7B107.9
O16—Ag7—Ag677.5 (2)C3—C8—C9120.6 (9)
O1ii—Ag7—Ag6156.91 (17)C3—C8—C7122.2 (9)
Ag2ii—Ag7—Ag680.31 (3)C9—C8—C7116.8 (9)
Ag8—Ag7—Ag6106.77 (3)C10—C9—C8170.1 (10)
C10—Ag7—Ag452.4 (2)C10—C9—Ag473.8 (6)
O16—Ag7—Ag487.98 (19)C8—C9—Ag4114.9 (7)
O1ii—Ag7—Ag4138.90 (17)C10—C9—Ag676.4 (6)
Ag2ii—Ag7—Ag4104.75 (3)C8—C9—Ag6109.6 (6)
Ag8—Ag7—Ag470.85 (3)Ag4—C9—Ag676.5 (3)
Ag6—Ag7—Ag461.99 (3)C9—C10—Ag7148.6 (8)
O10ii—Ag8—C10165.4 (3)C9—C10—Ag8123.9 (8)
O10ii—Ag8—O8ii86.9 (3)Ag7—C10—Ag881.9 (3)
C10—Ag8—O8ii107.0 (3)C9—C10—Ag2ii119.1 (7)
O10ii—Ag8—O1883.0 (3)Ag7—C10—Ag2ii79.7 (3)
C10—Ag8—O1886.1 (3)Ag8—C10—Ag2ii80.3 (3)
O8ii—Ag8—O18118.6 (4)C9—C10—Ag477.2 (6)
O10ii—Ag8—Ag7125.2 (2)Ag7—C10—Ag483.3 (3)
C10—Ag8—Ag748.1 (2)Ag8—C10—Ag495.1 (3)
O8ii—Ag8—Ag7131.59 (18)Ag2ii—C10—Ag4162.9 (5)
O18—Ag8—Ag7102.1 (2)C9—C10—Ag675.0 (6)
O10ii—Ag8—Ag2ii140.9 (2)Ag7—C10—Ag676.7 (3)
C10—Ag8—Ag2ii51.2 (2)Ag8—C10—Ag6157.9 (5)
O8ii—Ag8—Ag2ii72.97 (18)Ag2ii—C10—Ag6101.3 (3)
O18—Ag8—Ag2ii136.1 (3)Ag4—C10—Ag676.9 (3)
Ag7—Ag8—Ag2ii59.30 (3)C34—N2—C38123.5 (12)
O10ii—Ag8—Ag3ii81.1 (2)C34—N2—H2118.2
C10—Ag8—Ag3ii110.6 (2)C38—N2—H2118.2
O8ii—Ag8—Ag3ii54.27 (19)N2—C34—C35119.4 (14)
O18—Ag8—Ag3ii162.9 (2)N2—C34—H34A120.3
Ag7—Ag8—Ag3ii92.27 (3)C35—C34—H34A120.3
Ag2ii—Ag8—Ag3ii59.83 (2)C36—C35—C34117.1 (14)
O10ii—Ag8—Ag957.5 (2)C36—C35—H35A121.4
C10—Ag8—Ag9107.9 (2)C34—C35—H35A121.4
O8ii—Ag8—Ag9140.84 (19)C35—C36—C37121.7 (14)
O18—Ag8—Ag947.7 (4)C35—C36—H36A119.2
Ag7—Ag8—Ag985.86 (5)C37—C36—H36A119.2
Ag2ii—Ag8—Ag9145.11 (6)C36—C37—C38120.7 (14)
Ag3ii—Ag8—Ag9125.56 (9)C36—C37—H37A119.6
N1—Ag9—O4126.7 (4)C38—C37—H37A119.6
N1—Ag9—O2ii115.3 (4)N2—C38—C37117.5 (13)
O4—Ag9—O2ii76.7 (3)N2—C38—H38A121.2
N1—Ag9—O18135.7 (4)C37—C38—H38A121.2
O4—Ag9—O1880.2 (3)C39—N3—C40118.8 (11)
O2ii—Ag9—O18104.1 (3)C39—N3—H3120.6
N1—Ag9—Ag8145.7 (3)C40—N3—H3120.6
O4—Ag9—Ag886.43 (19)C41—C42—C43122.6 (11)
O2ii—Ag9—Ag858.6 (3)C41—C42—H42A118.7
O18—Ag9—Ag848.6 (2)C43—C42—H42A118.7
C29—N1—C33120.0N3—C39—C43121.2 (12)
C29—N1—Ag9120.1 (6)N3—C39—H39119.4
C33—N1—Ag9119.7 (6)C43—C39—H39119.3
N1—C29—C30120.0C41—C40—N3120.6 (12)
N1—C29—H29120.0C41—C40—H40A119.7
C30—C29—H29120.0N3—C40—H40A119.7
C29—C30—C31120.0C42—C41—C40118.1 (13)
C29—C30—H30120.0C42—C41—H41A120.9
C31—C30—H30120.0C40—C41—H41A121.0
C32—C31—C30120.0C39—C43—C42118.7 (11)
C32—C31—H31120.0C39—C43—H43A120.6
C30—C31—H31120.0C42—C43—H43A120.7
C33—C32—C31120.0
C33—N1—C29—C300.0Ag6—O14—C23—C24163.4 (7)
Ag9—N1—C29—C30175.3 (9)O13—C23—C24—F1976.1 (15)
N1—C29—C30—C310.0O14—C23—C24—F19104.4 (13)
C29—C30—C31—C320.0O13—C23—C24—F2043.4 (17)
C30—C31—C32—C330.0O14—C23—C24—F20136.1 (12)
C31—C32—C33—N10.0O13—C23—C24—F21164.2 (14)
C29—N1—C33—C320.0O14—C23—C24—F2115.2 (15)
Ag9—N1—C33—C32175.3 (9)Ag7—O16—C25—O154.8 (17)
C33'—N1'—C29'—C30'0.0Ag7—O16—C25—C26178.6 (6)
Ag9'—N1'—C29'—C30'179.3 (18)Ag6—O15—C25—O167.5 (16)
N1'—C29'—C30'—C31'0.0Ag6—O15—C25—C26169.0 (6)
C29'—C30'—C31'—C32'0.0O16—C25—C26—F2329.6 (13)
C30'—C31'—C32'—C33'0.0O15—C25—C26—F23153.4 (10)
C31'—C32'—C33'—N1'0.0O16—C25—C26—F2491.4 (11)
C29'—N1'—C33'—C32'0.0O15—C25—C26—F2485.7 (12)
Ag9'—N1'—C33'—C32'179 (2)O16—C25—C26—F22150.2 (9)
Ag9'i—O2—C11—O1164.9 (12)O15—C25—C26—F2232.8 (13)
Ag9'i—O2—C11—C1213 (2)Ag9—O18—C27—O1770 (2)
Ag7i—O1—C11—O23.5 (13)Ag8—O18—C27—O17152.5 (14)
Ag1—O1—C11—O298.2 (13)Ag4—O18—C27—O1747 (2)
Ag7i—O1—C11—C12174.5 (7)Ag9—O18—C27—C28112.0 (15)
Ag1—O1—C11—C1283.8 (11)Ag8—O18—C27—C2825 (2)
O2—C11—C12—F2114.1 (11)Ag4—O18—C27—C28130.5 (11)
O1—C11—C12—F267.6 (11)Ag3—O17—C27—O1813 (3)
O2—C11—C12—F3126.5 (11)Ag3—O17—C27—C28164.4 (10)
O1—C11—C12—F351.7 (12)O18—C27—C28—F2748 (2)
O2—C11—C12—F17.3 (14)O17—C27—C28—F27129.6 (16)
O1—C11—C12—F1170.9 (9)O18—C27—C28—F25171.6 (15)
Ag1—O3—C13—O427.6 (16)O17—C27—C28—F257 (2)
Ag1—O3—C13—C14154.5 (7)O18—C27—C28—F2670.6 (18)
Ag4—O4—C13—O312.9 (16)O17—C27—C28—F26111.3 (17)
Ag9—O4—C13—O3153.9 (9)Ag1—C1—C2—C3168 (4)
Ag4—O4—C13—C14165.1 (6)Ag3—C1—C2—C353 (6)
Ag9—O4—C13—C1428.1 (14)Ag2—C1—C2—C347 (6)
O3—C13—C14—F511.1 (14)Ag4—C1—C2—C3135 (5)
O4—C13—C14—F5170.7 (10)Ag5—C1—C2—C3128 (5)
O3—C13—C14—F4131.7 (10)Ag1—C1—C2—Ag540.0 (13)
O4—C13—C14—F450.1 (12)Ag3—C1—C2—Ag5178.9 (7)
O3—C13—C14—F6110.1 (11)Ag2—C1—C2—Ag580.2 (6)
O4—C13—C14—F668.2 (12)Ag4—C1—C2—Ag597.1 (2)
Ag1—O5—C15—O60.6 (16)Ag1—C1—C2—Ag457.1 (13)
Ag1—O5—C15—C16178.3 (6)Ag3—C1—C2—Ag481.8 (7)
Ag5—O6—C15—O514.5 (16)Ag2—C1—C2—Ag4177.3 (7)
Ag5—O6—C15—C16164.4 (6)Ag5—C1—C2—Ag497.1 (2)
O5—C15—C16—F977.7 (12)C1—C2—C3—C8143 (5)
O6—C15—C16—F9103.3 (11)Ag5—C2—C3—C892.1 (9)
O5—C15—C16—F8161.2 (10)Ag4—C2—C3—C811.2 (12)
O6—C15—C16—F817.8 (13)C1—C2—C3—C441 (6)
O5—C15—C16—F740.5 (13)Ag5—C2—C3—C483.3 (10)
O6—C15—C16—F7138.5 (10)Ag4—C2—C3—C4173.5 (7)
Ag2—O7—C17—O82.0 (15)C8—C3—C4—C515.4 (15)
Ag2—O7—C17—C18175.3 (6)C2—C3—C4—C5169.3 (10)
Ag8i—O8—C17—O740.6 (14)C3—C4—C5—C647.7 (13)
Ag3—O8—C17—O742.4 (14)C4—C5—C6—C764.2 (13)
Ag8i—O8—C17—C18142.2 (7)C5—C6—C7—C845.5 (14)
Ag3—O8—C17—C18134.8 (7)C2—C3—C8—C90.4 (14)
O7—C17—C18—F1030.2 (14)C4—C3—C8—C9175.5 (10)
O8—C17—C18—F10152.2 (11)C2—C3—C8—C7172.7 (10)
O7—C17—C18—F11155.7 (11)C4—C3—C8—C72.5 (16)
O8—C17—C18—F1126.7 (14)C6—C7—C8—C312.6 (15)
O7—C17—C18—F1288.6 (13)C6—C7—C8—C9160.7 (10)
O8—C17—C18—F1289.0 (13)C3—C8—C9—Ag410.4 (12)
Ag3—O9—C19—O1012 (2)C7—C8—C9—Ag4176.2 (7)
Ag3—O9—C19—C20166.4 (7)C3—C8—C9—Ag673.4 (10)
Ag8i—O10—C19—O99.6 (18)C7—C8—C9—Ag6100.0 (9)
Ag8i—O10—C19—C20172.1 (7)Ag4—C9—C10—Ag753.2 (13)
O9—C19—C20—F1375.4 (16)Ag6—C9—C10—Ag726.5 (13)
O10—C19—C20—F13106.1 (14)Ag4—C9—C10—Ag887.6 (6)
O9—C19—C20—F1547.3 (15)Ag6—C9—C10—Ag8167.2 (7)
O10—C19—C20—F15131.2 (13)Ag4—C9—C10—Ag2ii174.4 (7)
O9—C19—C20—F14161.6 (13)Ag6—C9—C10—Ag2ii94.7 (6)
O10—C19—C20—F1416.9 (15)Ag6—C9—C10—Ag479.7 (2)
Ag2—O11—C21—O127.9 (16)Ag4—C9—C10—Ag679.7 (2)
Ag2—O11—C21—C22173.7 (6)C38—N2—C34—C353 (2)
Ag6i—O12—C21—O1170.0 (13)N2—C34—C35—C362 (2)
Ag6i—O12—C21—C22111.6 (9)C34—C35—C36—C370 (2)
O11—C21—C22—F1681.3 (13)C35—C36—C37—C380 (3)
O12—C21—C22—F1697.2 (12)C34—N2—C38—C372 (2)
O11—C21—C22—F18156.8 (10)C36—C37—C38—N21 (2)
O12—C21—C22—F1824.7 (14)C40—N3—C39—C431 (2)
O11—C21—C22—F1738.5 (13)C39—N3—C40—C411 (2)
O12—C21—C22—F17142.9 (11)C43—C42—C41—C401 (2)
Ag5—O13—C23—O1411 (3)N3—C40—C41—C421 (2)
Ag5—O13—C23—C24168.8 (10)N3—C39—C43—C421 (2)
Ag6—O14—C23—O1317 (2)C41—C42—C43—C391 (2)
Symmetry codes: (i) x1, y, z; (ii) x+1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N2—H2···O10.882.633.013 (12)107
N2—H2···O50.881.972.852 (12)176
N3—H3···O80.882.533.133 (15)126.3
N3—H3···O170.882.353.041 (17)135.6
N3—H3···O6iii0.882.393.049 (12)132.2
N3—H3···O15iii0.882.212.927 (13)138.1
Symmetry code: (iii) x, y, z+1.
(VII) top
Crystal data top
7(Ag+)·(C10H82)·5(C2F3O2)·2(C10H8N2)V = 2353.5 (12) Å3
Mr = 1760.72Z = 2
Triclinic, P1F(000) = 1672
a = 12.427 (3) ÅDx = 2.485 Mg m3
b = 14.132 (3) ÅMo Kα radiation, λ = 0.71073 Å
c = 16.384 (6) ŵ = 2.97 mm1
α = 96.481 (5)°T = 173 K
β = 108.935 (5)°Block, yellow
γ = 115.229 (4)°0.50 × 0.50 × 0.40 mm
Data collection top
Bruker APEX-II CCD
diffractometer
6185 reflections with I > 2σ(I)
φ and ω scanRint = 0.093
Absorption correction: multi-scan
SADABS (Bruker, 2003)
θmax = 25.3°, θmin = 1.9°
Tmin = 0.318, Tmax = 0.383h = 1414
18969 measured reflectionsk = 1616
8486 independent reflectionsl = 1819
Refinement top
Refinement on F2360 restraints
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.083H-atom parameters constrained
wR(F2) = 0.214 w = 1/[σ2(Fo2) + (0.1152P)2]
where P = (Fo2 + 2Fc2)/3
S = 1.04(Δ/σ)max = 0.001
8486 reflectionsΔρmax = 1.74 e Å3
686 parametersΔρmin = 1.62 e Å3
Crystal data top
7(Ag+)·(C10H82)·5(C2F3O2)·2(C10H8N2)γ = 115.229 (4)°
Mr = 1760.72V = 2353.5 (12) Å3
Triclinic, P1Z = 2
a = 12.427 (3) ÅMo Kα radiation
b = 14.132 (3) ŵ = 2.97 mm1
c = 16.384 (6) ÅT = 173 K
α = 96.481 (5)°0.50 × 0.50 × 0.40 mm
β = 108.935 (5)°
Data collection top
Bruker APEX-II CCD
diffractometer
8486 independent reflections
Absorption correction: multi-scan
SADABS (Bruker, 2003)
6185 reflections with I > 2σ(I)
Tmin = 0.318, Tmax = 0.383Rint = 0.093
18969 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.083360 restraints
wR(F2) = 0.214H-atom parameters constrained
S = 1.04Δρmax = 1.74 e Å3
8486 reflectionsΔρmin = 1.62 e Å3
686 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.13419 (9)0.17284 (7)0.86522 (6)0.0225 (2)
Ag20.11776 (9)0.01035 (7)0.99309 (6)0.0279 (2)
Ag30.31333 (9)0.09425 (8)0.81438 (6)0.0318 (3)
Ag40.00614 (9)0.04568 (7)0.76277 (6)0.0275 (3)
Ag50.10595 (10)0.07953 (8)0.62362 (6)0.0288 (3)
Ag60.00832 (13)0.08219 (10)0.56938 (7)0.0476 (3)
Ag70.34071 (10)0.10803 (9)0.71064 (7)0.0381 (3)
C10.0985 (12)0.0032 (10)0.8633 (8)0.027 (3)
C20.0267 (10)0.0829 (9)0.8529 (7)0.019 (2)
C30.0449 (11)0.1927 (9)0.8504 (7)0.020 (2)
C40.0347 (12)0.2798 (10)0.9067 (8)0.028 (3)
H4A0.05170.27230.96830.034*
H4B0.05470.26920.87910.034*
C50.1341 (17)0.3947 (12)0.9119 (10)0.049 (4)
H5A0.11030.44780.93390.059*
H5B0.22140.41380.95680.059*
C60.1428 (17)0.4064 (13)0.8278 (11)0.052 (4)
H6A0.20690.48280.83640.062*
H6B0.05670.38940.78240.062*
C70.1861 (12)0.3274 (9)0.7937 (8)0.024 (2)
H7A0.17160.32280.73000.029*
H7B0.28100.35790.82950.029*
C80.1149 (11)0.2158 (9)0.8005 (7)0.023 (2)
C90.1273 (11)0.1321 (9)0.7528 (7)0.021 (2)
C100.1523 (11)0.0726 (9)0.7105 (7)0.022 (2)
O10.0243 (9)0.2680 (7)0.8918 (6)0.032 (2)
O20.1736 (9)0.1263 (8)0.9792 (7)0.043 (2)
C110.0934 (13)0.2243 (11)0.9393 (8)0.032 (3)
C120.1486 (10)0.3053 (9)0.9464 (7)0.042 (3)
F10.1156 (10)0.3652 (7)0.8671 (5)0.074 (3)
F20.0999 (12)0.3721 (9)0.9893 (7)0.088 (4)
F30.2750 (9)0.2553 (8)0.9876 (9)0.139 (6)
O30.2147 (8)0.3026 (7)0.7196 (6)0.035 (2)
O40.0326 (9)0.2047 (7)0.7009 (6)0.038 (2)
C130.1338 (11)0.2917 (10)0.6884 (7)0.023 (2)
C140.1502 (9)0.3944 (9)0.6293 (6)0.040 (3)
F40.2616 (8)0.4807 (7)0.6103 (6)0.069 (3)
F50.1423 (10)0.3824 (7)0.5537 (5)0.077 (3)
F60.0578 (9)0.4140 (8)0.6741 (6)0.083 (4)
O50.2935 (8)0.1492 (7)0.9886 (6)0.033 (2)
O60.2839 (9)0.2761 (7)1.0775 (6)0.036 (2)
C150.3342 (12)0.2446 (10)1.0328 (7)0.025 (3)
C160.4615 (10)0.3320 (8)1.0347 (6)0.032 (3)
F70.5575 (8)0.3128 (8)1.0716 (7)0.077 (3)
F80.4985 (11)0.4308 (7)1.0790 (9)0.118 (5)
F90.4514 (10)0.3321 (10)0.9533 (6)0.104 (4)
O70.1336 (9)0.2041 (7)0.5610 (5)0.036 (2)
O80.0646 (12)0.2072 (10)0.4161 (7)0.058 (3)
C170.1097 (13)0.2369 (10)0.4786 (9)0.033 (3)
C180.1445 (9)0.3275 (8)0.4584 (6)0.032 (3)
F100.1105 (10)0.3642 (7)0.3725 (5)0.073 (3)
F110.2710 (7)0.2884 (7)0.4992 (7)0.073 (3)
F120.0892 (8)0.4107 (6)0.4867 (6)0.057 (2)
O90.1711 (19)0.1868 (11)0.5330 (12)0.113 (7)
O100.1802 (15)0.0650 (15)0.4466 (14)0.139 (9)
C190.2280 (18)0.1602 (15)0.4964 (12)0.057 (4)
C200.3574 (14)0.2430 (12)0.4947 (8)0.080 (6)
F130.4504 (10)0.2302 (10)0.5477 (6)0.085 (3)
F140.3799 (15)0.3410 (10)0.5210 (11)0.150 (6)
F150.3563 (13)0.2264 (11)0.4143 (7)0.108 (4)
N10.5031 (10)0.2574 (8)0.7370 (7)0.029 (2)
N20.4807 (11)0.0742 (10)0.8302 (8)0.043 (3)
C210.5081 (14)0.3501 (12)0.6973 (9)0.040 (3)
H21A0.43000.34620.69690.048*
C220.6236 (14)0.4508 (12)0.6572 (9)0.043 (3)
H22A0.62360.51370.62980.052*
C230.7360 (16)0.4579 (14)0.6579 (9)0.049 (4)
H23A0.81560.52550.63120.059*
C240.7310 (14)0.3625 (13)0.6990 (9)0.045 (3)
H24A0.80780.36490.70070.054*
C250.6147 (12)0.2658 (11)0.7368 (7)0.027 (3)
C260.6013 (12)0.1634 (11)0.7861 (8)0.030 (3)
C270.7104 (14)0.1563 (13)0.7899 (9)0.040 (3)
H27A0.79650.21640.75760.048*
C280.6886 (15)0.0602 (14)0.8416 (10)0.047 (4)
H28A0.76100.05590.84550.056*
C290.5704 (16)0.0258 (14)0.8856 (10)0.049 (4)
H29A0.55630.09120.92150.059*
C300.4659 (15)0.0157 (13)0.8767 (9)0.048 (4)
H30A0.38050.07740.90600.057*
N30.4862 (10)0.0771 (8)0.6771 (7)0.029 (2)
N40.5290 (11)0.2720 (9)0.7629 (7)0.036 (3)
C310.4617 (14)0.0226 (11)0.6327 (9)0.038 (3)
H31A0.37600.08310.61140.045*
C320.5560 (14)0.0391 (12)0.6177 (9)0.041 (3)
H32A0.53610.11020.58850.049*
C330.6784 (14)0.0481 (12)0.6453 (9)0.041 (3)
H33A0.74420.03830.63460.049*
C340.7058 (13)0.1504 (12)0.6887 (9)0.037 (3)
H34A0.79100.21090.70800.045*
C350.6104 (12)0.1661 (11)0.7047 (8)0.030 (3)
C360.6321 (13)0.2746 (10)0.7498 (8)0.031 (3)
C370.7444 (14)0.3679 (12)0.7735 (10)0.044 (4)
H37A0.81530.36510.76510.053*
C380.7586 (15)0.4671 (13)0.8094 (10)0.048 (4)
H38A0.83720.53340.82470.057*
C390.6544 (15)0.4671 (12)0.8227 (9)0.045 (3)
H39A0.66010.53340.84920.053*
C400.5423 (16)0.3686 (12)0.7964 (10)0.049 (4)
H40A0.46920.36950.80240.058*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0264 (5)0.0142 (5)0.0293 (5)0.0100 (4)0.0148 (4)0.0046 (3)
Ag20.0267 (5)0.0175 (5)0.0383 (5)0.0083 (4)0.0179 (4)0.0014 (4)
Ag30.0234 (5)0.0329 (6)0.0395 (5)0.0143 (5)0.0131 (4)0.0097 (4)
Ag40.0384 (6)0.0158 (5)0.0385 (5)0.0132 (4)0.0282 (4)0.0074 (4)
Ag50.0398 (6)0.0221 (5)0.0320 (5)0.0172 (5)0.0220 (4)0.0042 (4)
Ag60.0730 (9)0.0555 (8)0.0382 (6)0.0527 (7)0.0218 (6)0.0130 (5)
Ag70.0344 (6)0.0301 (6)0.0570 (6)0.0134 (5)0.0318 (5)0.0086 (5)
C10.033 (6)0.023 (6)0.036 (6)0.019 (5)0.019 (5)0.009 (4)
C20.017 (5)0.018 (5)0.020 (5)0.009 (4)0.007 (4)0.001 (4)
C30.027 (5)0.014 (5)0.023 (5)0.012 (4)0.013 (4)0.004 (4)
C40.035 (6)0.022 (6)0.033 (5)0.016 (5)0.017 (5)0.007 (4)
C50.070 (8)0.031 (7)0.045 (6)0.021 (6)0.032 (6)0.001 (5)
C60.057 (8)0.045 (7)0.061 (7)0.021 (6)0.039 (6)0.015 (6)
C70.031 (6)0.014 (5)0.034 (5)0.012 (4)0.016 (4)0.010 (4)
C80.023 (5)0.015 (5)0.025 (5)0.008 (4)0.008 (4)0.005 (4)
C90.021 (5)0.021 (5)0.024 (5)0.012 (4)0.012 (4)0.007 (4)
C100.027 (5)0.015 (5)0.028 (5)0.010 (4)0.016 (4)0.009 (4)
O10.044 (6)0.024 (5)0.034 (4)0.022 (4)0.018 (4)0.005 (4)
O20.029 (5)0.027 (5)0.069 (6)0.016 (5)0.017 (5)0.001 (5)
C110.035 (6)0.030 (6)0.035 (6)0.017 (5)0.017 (5)0.006 (5)
C120.039 (6)0.038 (7)0.060 (7)0.029 (6)0.021 (5)0.008 (5)
F10.130 (9)0.062 (6)0.074 (6)0.075 (7)0.054 (6)0.020 (5)
F20.160 (10)0.096 (8)0.105 (8)0.107 (8)0.093 (7)0.067 (6)
F30.081 (8)0.074 (8)0.221 (14)0.061 (7)0.005 (8)0.020 (8)
O30.023 (5)0.031 (5)0.044 (5)0.011 (4)0.012 (4)0.001 (4)
O40.051 (6)0.018 (5)0.045 (5)0.013 (5)0.029 (5)0.002 (4)
C130.026 (6)0.022 (6)0.022 (5)0.012 (5)0.011 (4)0.007 (4)
C140.045 (7)0.033 (7)0.038 (6)0.014 (5)0.022 (5)0.003 (5)
F40.063 (6)0.039 (5)0.083 (6)0.009 (5)0.038 (5)0.008 (5)
F50.112 (8)0.053 (6)0.052 (5)0.020 (6)0.055 (5)0.007 (4)
F60.079 (7)0.056 (6)0.104 (8)0.051 (6)0.012 (6)0.009 (5)
O50.036 (5)0.020 (5)0.047 (5)0.008 (4)0.029 (4)0.005 (4)
O60.037 (5)0.024 (5)0.048 (5)0.010 (4)0.026 (4)0.010 (4)
C150.028 (5)0.021 (6)0.029 (5)0.015 (5)0.014 (4)0.001 (4)
C160.034 (6)0.028 (6)0.038 (6)0.017 (5)0.017 (5)0.006 (5)
F70.034 (5)0.075 (7)0.128 (9)0.026 (5)0.034 (5)0.054 (6)
F80.104 (9)0.037 (6)0.211 (13)0.006 (6)0.111 (9)0.012 (7)
F90.067 (7)0.123 (10)0.066 (6)0.004 (6)0.027 (5)0.050 (6)
O70.048 (6)0.037 (5)0.030 (4)0.030 (5)0.014 (4)0.001 (4)
O80.092 (9)0.083 (9)0.036 (5)0.073 (8)0.027 (5)0.018 (5)
C170.039 (6)0.022 (6)0.040 (6)0.016 (5)0.021 (5)0.005 (5)
C180.048 (7)0.022 (6)0.030 (5)0.017 (5)0.021 (5)0.003 (4)
F100.154 (9)0.058 (6)0.047 (5)0.077 (7)0.052 (5)0.023 (4)
F110.050 (6)0.050 (6)0.127 (8)0.034 (5)0.038 (6)0.009 (5)
F120.081 (6)0.034 (5)0.077 (6)0.034 (5)0.047 (5)0.027 (4)
O90.205 (18)0.054 (9)0.185 (16)0.082 (11)0.169 (16)0.058 (10)
O100.066 (10)0.103 (13)0.197 (19)0.022 (10)0.056 (11)0.061 (13)
C190.066 (8)0.056 (8)0.066 (8)0.048 (7)0.023 (6)0.017 (6)
C200.080 (9)0.079 (10)0.092 (10)0.058 (8)0.028 (7)0.006 (7)
F130.064 (7)0.118 (9)0.061 (6)0.042 (7)0.016 (5)0.030 (6)
F140.142 (12)0.090 (10)0.250 (16)0.060 (9)0.123 (11)0.020 (9)
F150.112 (9)0.157 (12)0.108 (9)0.084 (9)0.064 (7)0.087 (8)
N10.023 (5)0.019 (6)0.038 (6)0.006 (5)0.011 (4)0.004 (4)
N20.038 (7)0.048 (8)0.049 (7)0.031 (6)0.015 (6)0.002 (6)
C210.042 (7)0.046 (7)0.037 (6)0.027 (6)0.017 (5)0.005 (5)
C220.040 (7)0.035 (7)0.043 (6)0.016 (6)0.010 (5)0.002 (5)
C230.047 (7)0.052 (8)0.038 (6)0.017 (6)0.017 (5)0.008 (5)
C240.036 (6)0.048 (7)0.046 (7)0.019 (6)0.013 (5)0.013 (5)
C250.025 (6)0.034 (6)0.024 (5)0.018 (5)0.007 (4)0.011 (4)
C260.030 (6)0.044 (7)0.024 (5)0.021 (5)0.013 (4)0.013 (5)
C270.038 (6)0.050 (7)0.048 (6)0.030 (6)0.020 (5)0.023 (5)
C280.048 (7)0.065 (8)0.047 (7)0.044 (6)0.019 (5)0.017 (6)
C290.061 (8)0.055 (8)0.044 (7)0.042 (6)0.021 (6)0.008 (5)
C300.046 (7)0.051 (7)0.042 (6)0.032 (6)0.007 (5)0.001 (5)
N30.024 (5)0.015 (5)0.046 (6)0.008 (5)0.018 (5)0.001 (4)
N40.041 (7)0.032 (7)0.048 (6)0.024 (6)0.024 (5)0.009 (5)
C310.038 (6)0.025 (6)0.050 (6)0.015 (5)0.021 (5)0.001 (5)
C320.045 (7)0.032 (7)0.048 (6)0.019 (5)0.023 (5)0.004 (5)
C330.039 (6)0.047 (7)0.050 (7)0.027 (6)0.026 (5)0.014 (5)
C340.034 (6)0.035 (7)0.048 (6)0.016 (5)0.024 (5)0.008 (5)
C350.031 (6)0.031 (6)0.031 (5)0.012 (5)0.021 (5)0.008 (4)
C360.036 (6)0.027 (6)0.029 (5)0.013 (5)0.015 (5)0.011 (4)
C370.040 (7)0.039 (7)0.054 (7)0.017 (6)0.026 (5)0.003 (5)
C380.049 (7)0.035 (7)0.047 (7)0.011 (6)0.020 (6)0.006 (5)
C390.048 (7)0.032 (7)0.046 (6)0.015 (6)0.022 (6)0.002 (5)
C400.052 (7)0.041 (7)0.059 (7)0.024 (6)0.034 (6)0.002 (5)
Geometric parameters (Å, º) top
Ag1—C12.251 (12)C14—F51.298 (9)
Ag1—O12.274 (8)C14—F41.303 (9)
Ag1—O6i2.366 (9)C14—F61.305 (9)
Ag1—O32.441 (9)O5—C151.248 (14)
Ag1—Ag32.8278 (13)O6—C151.260 (13)
Ag1—Ag22.9159 (14)O6—Ag1i2.366 (9)
Ag1—Ag42.9250 (13)C15—C161.525 (16)
Ag1—Ag2i2.9653 (13)C16—F91.299 (9)
Ag2—O52.261 (9)C16—F81.302 (9)
Ag2—O22.326 (9)C16—F71.306 (9)
Ag2—C1i2.450 (12)O7—C171.267 (14)
Ag2—Ag2i2.9013 (19)O8—C171.210 (16)
Ag2—Ag1i2.9653 (13)O8—Ag6ii2.325 (9)
Ag2—Ag3i2.9977 (16)C17—C181.551 (15)
Ag3—C12.208 (13)C18—F101.300 (8)
Ag3—N12.291 (10)C18—F121.307 (9)
Ag3—N22.305 (10)C18—F111.310 (9)
Ag3—Ag2i2.9978 (16)O9—C191.206 (19)
Ag4—O42.196 (8)O10—C191.26 (2)
Ag4—C22.362 (10)O10—Ag6ii2.283 (18)
Ag4—C92.410 (12)C19—C201.55 (2)
Ag4—C12.446 (11)C20—F141.280 (10)
Ag4—C102.453 (11)C20—F131.297 (10)
Ag4—Ag53.1223 (14)C20—F151.306 (10)
Ag5—O72.147 (8)N1—C251.340 (15)
Ag5—C102.168 (11)N1—C211.362 (16)
Ag5—Ag72.7249 (15)N2—C301.312 (18)
Ag5—Ag6ii3.0051 (17)N2—C261.355 (17)
Ag5—Ag63.0996 (15)C21—C221.40 (2)
Ag6—O92.250 (14)C21—H21A0.9500
Ag6—O10ii2.283 (18)C22—C231.36 (2)
Ag6—O8ii2.325 (9)C22—H22A0.9500
Ag6—C102.482 (11)C23—C241.40 (2)
Ag6—Ag6ii2.950 (2)C23—H23A0.9500
Ag6—Ag5ii3.0051 (17)C24—C251.372 (19)
Ag7—C102.174 (11)C24—H24A0.9500
Ag7—N32.242 (9)C25—C261.489 (17)
Ag7—N42.282 (12)C26—C271.421 (17)
C1—C21.235 (17)C27—C281.38 (2)
C1—Ag2i2.450 (12)C27—H27A0.9500
C2—C31.436 (16)C28—C291.32 (2)
C3—C81.346 (15)C28—H28A0.9500
C3—C41.527 (15)C29—C301.41 (2)
C4—C51.54 (2)C29—H29A0.9500
C4—H4A0.9900C30—H30A0.9500
C4—H4B0.9900N3—C311.366 (15)
C5—C61.44 (2)N3—C351.390 (16)
C5—H5A0.9900N4—C401.331 (17)
C5—H5B0.9900N4—C361.354 (16)
C6—C71.554 (18)C31—C321.376 (18)
C6—H6A0.9900C31—H31A0.9500
C6—H6B0.9900C32—C331.37 (2)
C7—C81.482 (16)C32—H32A0.9500
C7—H7A0.9900C33—C341.380 (19)
C7—H7B0.9900C33—H33A0.9500
C8—C91.434 (15)C34—C351.392 (17)
C9—C101.231 (15)C34—H34A0.9500
O1—C111.229 (15)C35—C361.494 (17)
O2—C111.239 (16)C36—C371.342 (19)
C11—C121.563 (16)C37—C381.37 (2)
C12—F31.296 (9)C37—H37A0.9500
C12—F11.298 (9)C38—C391.38 (2)
C12—F21.301 (9)C38—H38A0.9500
O3—C131.231 (14)C39—C401.37 (2)
O4—C131.262 (14)C39—H39A0.9500
C13—C141.546 (15)C40—H40A0.9500
C1—Ag1—O1140.4 (4)C5—C6—H6B109.7
C1—Ag1—O6i119.1 (4)C7—C6—H6B109.7
O1—Ag1—O6i93.4 (3)H6A—C6—H6B108.2
C1—Ag1—O3116.2 (4)C8—C7—C6112.9 (10)
O1—Ag1—O374.5 (3)C8—C7—H7A109.0
O6i—Ag1—O3101.1 (3)C6—C7—H7A109.0
C1—Ag1—Ag350.0 (3)C8—C7—H7B109.0
O1—Ag1—Ag3169.1 (2)C6—C7—H7B109.0
O6i—Ag1—Ag380.1 (2)H7A—C7—H7B107.8
O3—Ag1—Ag398.0 (2)C3—C8—C9120.7 (10)
C1—Ag1—Ag262.7 (3)C3—C8—C7122.9 (10)
O1—Ag1—Ag283.0 (2)C9—C8—C7116.4 (10)
O6i—Ag1—Ag2118.2 (2)C10—C9—C8170.7 (12)
O3—Ag1—Ag2135.7 (2)C10—C9—Ag477.3 (8)
Ag3—Ag1—Ag2107.83 (4)C8—C9—Ag4111.9 (7)
C1—Ag1—Ag454.5 (3)C9—C10—Ag5154.3 (10)
O1—Ag1—Ag498.1 (2)C9—C10—Ag7127.9 (9)
O6i—Ag1—Ag4165.7 (2)Ag5—C10—Ag777.7 (4)
O3—Ag1—Ag474.1 (2)C9—C10—Ag473.4 (7)
Ag3—Ag1—Ag487.23 (4)Ag5—C10—Ag484.8 (4)
Ag2—Ag1—Ag471.88 (4)Ag7—C10—Ag4139.5 (5)
C1—Ag1—Ag2i53.9 (3)C9—C10—Ag688.0 (8)
O1—Ag1—Ag2i124.7 (2)Ag5—C10—Ag683.3 (4)
O6i—Ag1—Ag2i74.5 (2)Ag7—C10—Ag6111.7 (4)
O3—Ag1—Ag2i160.1 (2)Ag4—C10—Ag6102.1 (4)
Ag3—Ag1—Ag2i62.27 (3)C11—O1—Ag1123.0 (8)
Ag2—Ag1—Ag2i59.11 (4)C11—O2—Ag2124.1 (8)
Ag4—Ag1—Ag2i105.26 (4)O1—C11—O2129.4 (12)
O5—Ag2—O299.1 (3)O1—C11—C12114.1 (11)
O5—Ag2—C1i120.3 (4)O2—C11—C12116.4 (11)
O2—Ag2—C1i97.1 (4)F3—C12—F1107.6 (8)
O5—Ag2—Ag2i133.9 (2)F3—C12—F2108.6 (9)
O2—Ag2—Ag2i127.0 (2)F1—C12—F2106.6 (8)
C1i—Ag2—Ag2i61.1 (3)F3—C12—C11112.5 (10)
O5—Ag2—Ag1137.8 (2)F1—C12—C11111.2 (9)
O2—Ag2—Ag179.7 (2)F2—C12—C11110.1 (9)
C1i—Ag2—Ag1101.5 (3)C13—O3—Ag1116.3 (7)
Ag2i—Ag2—Ag161.29 (4)C13—O4—Ag4119.8 (7)
O5—Ag2—Ag1i87.1 (2)O3—C13—O4127.7 (11)
O2—Ag2—Ag1i139.9 (3)O3—C13—C14118.8 (10)
C1i—Ag2—Ag1i48.0 (3)O4—C13—C14113.5 (9)
Ag2i—Ag2—Ag1i59.60 (3)F5—C14—F4107.8 (8)
Ag1—Ag2—Ag1i120.89 (4)F5—C14—F6108.2 (8)
O5—Ag2—Ag3i78.1 (2)F4—C14—F6107.5 (8)
O2—Ag2—Ag3i85.7 (2)F5—C14—C13112.6 (9)
C1i—Ag2—Ag3i46.5 (3)F4—C14—C13111.9 (9)
Ag2i—Ag2—Ag3i103.79 (5)F6—C14—C13108.7 (8)
Ag1—Ag2—Ag3i142.82 (4)C15—O5—Ag2119.0 (7)
Ag1i—Ag2—Ag3i56.61 (3)C15—O6—Ag1i128.8 (8)
C1—Ag3—N1147.3 (4)O5—C15—O6127.5 (12)
C1—Ag3—N2140.2 (4)O5—C15—C16115.8 (9)
N1—Ag3—N272.2 (4)O6—C15—C16116.6 (10)
C1—Ag3—Ag151.3 (3)F9—C16—F8107.6 (9)
N1—Ag3—Ag199.4 (2)F9—C16—F7106.2 (8)
N2—Ag3—Ag1149.3 (3)F8—C16—F7106.9 (8)
C1—Ag3—Ag2i53.6 (3)F9—C16—C15110.7 (9)
N1—Ag3—Ag2i130.7 (3)F8—C16—C15114.0 (9)
N2—Ag3—Ag2i101.3 (3)F7—C16—C15111.2 (9)
Ag1—Ag3—Ag2i61.11 (3)C17—O7—Ag5127.9 (8)
O4—Ag4—C2158.5 (4)C17—O8—Ag6ii122.8 (8)
O4—Ag4—C9128.7 (3)O8—C17—O7128.9 (12)
C2—Ag4—C972.7 (4)O8—C17—C18117.7 (10)
O4—Ag4—C1128.9 (4)O7—C17—C18113.4 (10)
C2—Ag4—C129.7 (4)F10—C18—F12108.0 (8)
C9—Ag4—C1102.4 (4)F10—C18—F11107.4 (8)
O4—Ag4—C1099.5 (3)F12—C18—F11106.9 (8)
C2—Ag4—C10101.8 (4)F10—C18—C17111.5 (9)
C9—Ag4—C1029.3 (4)F12—C18—C17112.6 (9)
C1—Ag4—C10131.5 (4)F11—C18—C17110.1 (9)
O4—Ag4—Ag181.4 (2)C19—O9—Ag6129.3 (13)
C2—Ag4—Ag177.4 (3)C19—O10—Ag6ii124.6 (13)
C9—Ag4—Ag1147.6 (2)O9—C19—O10123 (2)
C1—Ag4—Ag148.6 (3)O9—C19—C20123.1 (16)
C10—Ag4—Ag1165.2 (3)O10—C19—C20113.2 (15)
O4—Ag4—Ag556.6 (2)F14—C20—F13110.5 (10)
C2—Ag4—Ag5144.8 (3)F14—C20—F15108.2 (10)
C9—Ag4—Ag572.5 (2)F13—C20—F15107.4 (9)
C1—Ag4—Ag5173.1 (3)F14—C20—C19110.5 (12)
C10—Ag4—Ag543.8 (3)F13—C20—C19107.8 (12)
Ag1—Ag4—Ag5137.65 (4)F15—C20—C19112.4 (13)
O7—Ag5—C10159.7 (4)C25—N1—C21117.3 (11)
O7—Ag5—Ag7109.2 (3)C25—N1—Ag3118.7 (8)
C10—Ag5—Ag751.2 (3)C21—N1—Ag3123.7 (9)
O7—Ag5—Ag6ii81.0 (2)C30—N2—C26120.1 (12)
C10—Ag5—Ag6ii108.5 (3)C30—N2—Ag3124.6 (10)
Ag7—Ag5—Ag6ii107.75 (5)C26—N2—Ag3115.3 (8)
O7—Ag5—Ag6138.6 (2)N1—C21—C22122.5 (13)
C10—Ag5—Ag652.7 (3)N1—C21—H21A118.7
Ag7—Ag5—Ag682.65 (5)C22—C21—H21A118.7
Ag6ii—Ag5—Ag657.77 (4)C23—C22—C21119.4 (14)
O7—Ag5—Ag4138.0 (3)C23—C22—H22A120.3
C10—Ag5—Ag451.5 (3)C21—C22—H22A120.3
Ag7—Ag5—Ag495.66 (4)C22—C23—C24118.2 (15)
Ag6ii—Ag5—Ag4123.51 (5)C22—C23—H23A120.9
Ag6—Ag5—Ag476.15 (4)C24—C23—H23A120.9
O9—Ag6—O10ii158.1 (6)C25—C24—C23119.7 (14)
O9—Ag6—O8ii96.2 (5)C25—C24—H24A120.1
O10ii—Ag6—O8ii94.8 (5)C23—C24—H24A120.1
O9—Ag6—C1095.5 (6)N1—C25—C24122.8 (12)
O10ii—Ag6—C1096.3 (7)N1—C25—C26114.7 (11)
O8ii—Ag6—C10117.1 (3)C24—C25—C26122.4 (11)
O9—Ag6—Ag6ii78.6 (3)N2—C26—C27118.7 (12)
O10ii—Ag6—Ag6ii80.9 (4)N2—C26—C25119.0 (10)
O8ii—Ag6—Ag6ii141.1 (2)C27—C26—C25122.2 (12)
C10—Ag6—Ag6ii101.9 (3)C28—C27—C26118.6 (14)
O9—Ag6—Ag5ii70.9 (5)C28—C27—H27A120.7
O10ii—Ag6—Ag5ii92.8 (6)C26—C27—H27A120.7
O8ii—Ag6—Ag5ii79.0 (2)C29—C28—C27122.2 (13)
C10—Ag6—Ag5ii160.7 (3)C29—C28—H28A118.9
Ag6ii—Ag6—Ag5ii62.73 (4)C27—C28—H28A118.9
O9—Ag6—Ag597.4 (4)C28—C29—C30116.7 (14)
O10ii—Ag6—Ag578.6 (5)C28—C29—H29A121.6
O8ii—Ag6—Ag5157.7 (2)C30—C29—H29A121.6
C10—Ag6—Ag544.0 (2)N2—C30—C29123.5 (15)
Ag6ii—Ag6—Ag559.51 (4)N2—C30—H30A118.2
Ag5ii—Ag6—Ag5122.24 (4)C29—C30—H30A118.2
C10—Ag7—N3157.7 (4)C31—N3—C35118.2 (10)
C10—Ag7—N4129.0 (4)C31—N3—Ag7124.7 (8)
N3—Ag7—N473.0 (4)C35—N3—Ag7117.1 (7)
C10—Ag7—Ag551.0 (3)C40—N4—C36116.0 (12)
N3—Ag7—Ag5106.7 (3)C40—N4—Ag7125.4 (9)
N4—Ag7—Ag5171.0 (3)C36—N4—Ag7118.1 (8)
C2—C1—Ag3130.4 (9)N3—C31—C32122.8 (13)
C2—C1—Ag1144.4 (9)N3—C31—H31A118.6
Ag3—C1—Ag178.7 (4)C32—C31—H31A118.6
C2—C1—Ag471.4 (7)C33—C32—C31119.1 (13)
Ag3—C1—Ag4117.0 (5)C33—C32—H32A120.5
Ag1—C1—Ag476.9 (3)C31—C32—H32A120.5
C2—C1—Ag2i121.8 (9)C32—C33—C34119.6 (12)
Ag3—C1—Ag2i79.9 (4)C32—C33—H33A120.2
Ag1—C1—Ag2i78.1 (4)C34—C33—H33A120.2
Ag4—C1—Ag2i145.9 (5)C33—C34—C35120.9 (13)
C1—C2—C3167.7 (11)C33—C34—H34A119.6
C1—C2—Ag478.9 (7)C35—C34—H34A119.6
C3—C2—Ag4113.1 (7)N3—C35—C34119.4 (11)
C8—C3—C2121.4 (10)N3—C35—C36116.7 (10)
C8—C3—C4122.8 (10)C34—C35—C36123.9 (12)
C2—C3—C4115.8 (9)C37—C36—N4122.6 (12)
C3—C4—C5110.3 (10)C37—C36—C35122.5 (12)
C3—C4—H4A109.6N4—C36—C35115.0 (11)
C5—C4—H4A109.6C36—C37—C38121.2 (14)
C3—C4—H4B109.6C36—C37—H37A119.4
C5—C4—H4B109.6C38—C37—H37A119.4
H4A—C4—H4B108.1C37—C38—C39117.5 (14)
C6—C5—C4114.7 (12)C37—C38—H38A121.2
C6—C5—H5A108.6C39—C38—H38A121.2
C4—C5—H5A108.6C40—C39—C38118.1 (13)
C6—C5—H5B108.6C40—C39—H39A121.0
C4—C5—H5B108.6C38—C39—H39A121.0
H5A—C5—H5B107.6N4—C40—C39124.5 (14)
C5—C6—C7109.7 (13)N4—C40—H40A117.7
C5—C6—H6A109.7C39—C40—H40A117.7
C7—C6—H6A109.7
Ag3—C1—C2—C360 (6)O8—C17—C18—F11114.8 (13)
Ag1—C1—C2—C3161 (4)O7—C17—C18—F1165.3 (13)
Ag4—C1—C2—C3170 (5)Ag6—O9—C19—O1023 (3)
Ag2i—C1—C2—C345 (6)Ag6—O9—C19—C20165.9 (12)
Ag3—C1—C2—Ag4110.0 (10)Ag6ii—O10—C19—O99 (3)
Ag1—C1—C2—Ag428.4 (15)Ag6ii—O10—C19—C20179.3 (12)
Ag2i—C1—C2—Ag4145.0 (8)O9—C19—C20—F1412 (2)
C1—C2—C3—C8169 (5)O10—C19—C20—F14159.2 (17)
Ag4—C2—C3—C80.2 (13)O9—C19—C20—F13108.5 (19)
C1—C2—C3—C410 (6)O10—C19—C20—F1380.0 (19)
Ag4—C2—C3—C4179.5 (8)O9—C19—C20—F15133.4 (18)
C8—C3—C4—C510.9 (16)O10—C19—C20—F1538 (2)
C2—C3—C4—C5169.8 (11)C25—N1—C21—C220.3 (19)
C3—C4—C5—C643.4 (17)Ag3—N1—C21—C22174.4 (10)
C4—C5—C6—C760.9 (18)N1—C21—C22—C230 (2)
C5—C6—C7—C845.3 (17)C21—C22—C23—C240 (2)
C2—C3—C8—C94.2 (17)C22—C23—C24—C250 (2)
C4—C3—C8—C9176.5 (10)C21—N1—C25—C240.1 (18)
C2—C3—C8—C7177.8 (10)Ag3—N1—C25—C24174.3 (10)
C4—C3—C8—C71.5 (17)C21—N1—C25—C26176.4 (11)
C6—C7—C8—C315.3 (17)Ag3—N1—C25—C262.0 (13)
C6—C7—C8—C9166.7 (11)C23—C24—C25—N10 (2)
C3—C8—C9—Ag45.8 (13)C23—C24—C25—C26176.4 (12)
C7—C8—C9—Ag4176.1 (8)C30—N2—C26—C271 (2)
Ag4—C9—C10—Ag533 (2)Ag3—N2—C26—C27177.8 (9)
Ag4—C9—C10—Ag7140.6 (9)C30—N2—C26—C25177.6 (13)
Ag4—C9—C10—Ag6103.2 (3)Ag3—N2—C26—C253.3 (15)
Ag1—O1—C11—O21.3 (19)N1—C25—C26—N23.5 (16)
Ag1—O1—C11—C12178.7 (6)C24—C25—C26—N2172.8 (12)
Ag2—O2—C11—O19 (2)N1—C25—C26—C27177.6 (11)
Ag2—O2—C11—C12173.5 (7)C24—C25—C26—C276.1 (19)
O1—C11—C12—F3172.1 (11)N2—C26—C27—C282.7 (19)
O2—C11—C12—F35.7 (15)C25—C26—C27—C28176.2 (12)
O1—C11—C12—F151.3 (14)C26—C27—C28—C292 (2)
O2—C11—C12—F1126.5 (12)C27—C28—C29—C301 (2)
O1—C11—C12—F266.6 (13)C26—N2—C30—C291 (2)
O2—C11—C12—F2115.6 (12)Ag3—N2—C30—C29179.8 (11)
Ag1—O3—C13—O428.8 (16)C28—C29—C30—N22 (2)
Ag1—O3—C13—C14148.6 (7)C35—N3—C31—C323 (2)
Ag4—O4—C13—O312.9 (16)Ag7—N3—C31—C32176.5 (10)
Ag4—O4—C13—C14169.6 (6)N3—C31—C32—C332 (2)
O3—C13—C14—F5130.2 (11)C31—C32—C33—C341 (2)
O4—C13—C14—F552.1 (12)C32—C33—C34—C350 (2)
O3—C13—C14—F48.6 (14)C31—N3—C35—C341.7 (18)
O4—C13—C14—F4173.7 (9)Ag7—N3—C35—C34177.5 (9)
O3—C13—C14—F6109.9 (11)C31—N3—C35—C36177.7 (11)
O4—C13—C14—F667.8 (12)Ag7—N3—C35—C363.2 (14)
Ag2—O5—C15—O64.6 (17)C33—C34—C35—N30 (2)
Ag2—O5—C15—C16173.5 (6)C33—C34—C35—C36178.8 (12)
Ag1i—O6—C15—O520.1 (19)C40—N4—C36—C373.6 (19)
Ag1i—O6—C15—C16158.0 (7)Ag7—N4—C36—C37176.1 (10)
O5—C15—C16—F956.5 (13)C40—N4—C36—C35174.8 (12)
O6—C15—C16—F9125.2 (11)Ag7—N4—C36—C352.3 (14)
O5—C15—C16—F8177.9 (11)N3—C35—C36—C37174.9 (12)
O6—C15—C16—F83.8 (14)C34—C35—C36—C374 (2)
O5—C15—C16—F761.2 (13)N3—C35—C36—N43.6 (16)
O6—C15—C16—F7117.1 (11)C34—C35—C36—N4177.1 (12)
Ag6ii—O8—C17—O75 (2)N4—C36—C37—C383 (2)
Ag6ii—O8—C17—C18175.2 (8)C35—C36—C37—C38175.7 (13)
Ag5—O7—C17—O81 (2)C36—C37—C38—C392 (2)
Ag5—O7—C17—C18179.0 (7)C37—C38—C39—C402 (2)
O8—C17—C18—F104.3 (16)C36—N4—C40—C394 (2)
O7—C17—C18—F10175.7 (10)Ag7—N4—C40—C39176.0 (12)
O8—C17—C18—F12126.0 (13)C38—C39—C40—N44 (2)
O7—C17—C18—F1254.0 (14)
Symmetry codes: (i) x, y, z+2; (ii) x, y, z+1.
(VIII) top
Crystal data top
11(Ag+)·(C6Br22)·9(C2F3O2)·C2H3N·3(H2O)F(000) = 9360
Mr = 2530.73Dx = 3.054 Mg m3
Orthorhombic, PbcaMo Kα radiation, λ = 0.71073 Å
a = 16.861 (6) ŵ = 5.43 mm1
b = 24.431 (9) ÅT = 173 K
c = 26.723 (10) ÅBlock, yellow
V = 11008 (7) Å30.50 × 0.50 × 0.50 mm
Z = 8
Data collection top
Bruker APEX-II CCD
diffractometer
7690 reflections with I > 2σ(I)
φ and ω scanRint = 0.135
Absorption correction: multi-scan
SADABS (Bruker, 2003)
θmax = 25.3°, θmin = 1.7°
Tmin = 0.172, Tmax = 0.172h = 2020
179417 measured reflectionsk = 2929
9961 independent reflectionsl = 3232
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.055Hydrogen site location: mixed
wR(F2) = 0.154H-atom parameters constrained
S = 1.08 w = 1/[σ2(Fo2) + (0.0723P)2 + 137.2121P]
where P = (Fo2 + 2Fc2)/3
9961 reflections(Δ/σ)max = 0.001
794 parametersΔρmax = 1.77 e Å3
216 restraintsΔρmin = 1.33 e Å3
Crystal data top
11(Ag+)·(C6Br22)·9(C2F3O2)·C2H3N·3(H2O)V = 11008 (7) Å3
Mr = 2530.73Z = 8
Orthorhombic, PbcaMo Kα radiation
a = 16.861 (6) ŵ = 5.43 mm1
b = 24.431 (9) ÅT = 173 K
c = 26.723 (10) Å0.50 × 0.50 × 0.50 mm
Data collection top
Bruker APEX-II CCD
diffractometer
9961 independent reflections
Absorption correction: multi-scan
SADABS (Bruker, 2003)
7690 reflections with I > 2σ(I)
Tmin = 0.172, Tmax = 0.172Rint = 0.135
179417 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.055216 restraints
wR(F2) = 0.154H-atom parameters constrained
S = 1.08 w = 1/[σ2(Fo2) + (0.0723P)2 + 137.2121P]
where P = (Fo2 + 2Fc2)/3
9961 reflectionsΔρmax = 1.77 e Å3
794 parametersΔρmin = 1.33 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.32376 (5)0.47119 (3)0.46985 (3)0.0398 (2)
Ag20.46852 (5)0.31308 (3)0.44930 (3)0.0386 (2)
Ag30.45057 (5)0.40470 (3)0.38494 (3)0.03210 (19)
Ag40.04632 (5)0.39233 (4)0.39154 (3)0.0381 (2)
Ag50.49165 (5)0.42136 (3)0.48859 (3)0.0329 (2)
Ag60.02865 (6)0.30072 (3)0.46609 (4)0.0438 (2)
Ag70.01120 (5)0.40942 (3)0.49546 (3)0.0363 (2)
Ag80.12831 (5)0.47403 (3)0.45809 (4)0.0400 (2)
Ag90.01148 (6)0.38375 (4)0.25786 (3)0.0463 (2)
Ag100.12776 (6)0.44062 (4)0.19143 (3)0.0491 (3)
Ag110.08649 (7)0.51336 (5)0.30636 (4)0.0566 (3)
Br10.16484 (7)0.28225 (5)0.56301 (5)0.0456 (3)
Br20.34978 (7)0.28691 (5)0.55508 (5)0.0452 (3)
C10.1052 (6)0.3822 (4)0.4638 (4)0.026 (2)
C20.1709 (6)0.3692 (4)0.4775 (3)0.024 (2)
C30.2472 (5)0.3500 (4)0.4943 (4)0.024 (2)
C40.3172 (5)0.3728 (4)0.4709 (4)0.026 (2)
C50.3799 (5)0.3860 (4)0.4521 (4)0.026 (2)
C60.2529 (6)0.3124 (4)0.5311 (4)0.029 (2)
O10.5543 (5)0.2961 (3)0.5185 (3)0.0400 (18)
O20.5853 (5)0.3825 (3)0.5397 (3)0.0421 (19)
C70.5924 (6)0.3314 (4)0.5408 (4)0.033 (2)
C80.6628 (6)0.3116 (4)0.5732 (4)0.054 (3)
F10.6701 (6)0.2589 (3)0.5739 (4)0.105 (4)
F20.6561 (7)0.3279 (4)0.6184 (3)0.119 (4)
F30.7295 (5)0.3312 (5)0.5565 (4)0.131 (5)
O30.5584 (5)0.2952 (4)0.3830 (3)0.051 (2)
O40.5249 (4)0.3563 (3)0.3245 (3)0.0381 (18)
C90.5608 (6)0.3149 (5)0.3417 (4)0.035 (2)
C100.6220 (6)0.2869 (4)0.3057 (4)0.059 (4)
F40.6139 (5)0.3011 (3)0.2593 (3)0.076 (3)
F50.6174 (6)0.2343 (3)0.3084 (3)0.102 (4)
F60.6934 (5)0.2998 (5)0.3193 (4)0.109 (4)
O50.5561 (4)0.5024 (3)0.4569 (3)0.0346 (17)
O60.5847 (5)0.4572 (3)0.3876 (3)0.0424 (19)
C110.5845 (6)0.4985 (4)0.4139 (4)0.030 (2)
C120.6238 (6)0.5503 (5)0.3926 (3)0.048 (3)
F70.6729 (6)0.5731 (4)0.4233 (3)0.091 (3)
F80.6624 (8)0.5415 (5)0.3519 (3)0.140 (5)
F90.5697 (6)0.5861 (5)0.3829 (5)0.164 (6)
O70.2713 (5)0.5349 (4)0.5202 (4)0.056 (2)
O80.1406 (4)0.5471 (3)0.5131 (3)0.0421 (19)
C130.2080 (6)0.5580 (4)0.5287 (4)0.033 (2)
C140.2146 (5)0.6058 (4)0.5675 (4)0.052 (3)
F100.2774 (6)0.6352 (5)0.5609 (5)0.131 (5)
F110.1542 (6)0.6373 (5)0.5672 (5)0.154 (6)
F120.2217 (9)0.5866 (5)0.6128 (4)0.149 (6)
O90.0447 (5)0.2845 (3)0.5426 (3)0.0380 (18)
O100.0786 (5)0.3700 (3)0.5638 (3)0.046 (2)
C150.0748 (6)0.3201 (4)0.5704 (4)0.033 (2)
C160.1064 (5)0.2998 (4)0.6220 (4)0.046 (3)
F130.1606 (5)0.3321 (3)0.6395 (3)0.072 (2)
F140.1365 (6)0.2511 (3)0.6193 (4)0.106 (4)
F150.0493 (5)0.2979 (5)0.6541 (3)0.105 (4)
O110.0216 (6)0.2661 (4)0.3905 (3)0.055 (2)
O120.0082 (6)0.3344 (4)0.3361 (3)0.052 (2)
C170.0266 (8)0.2876 (6)0.3487 (4)0.047 (3)
C180.0694 (8)0.2530 (5)0.3093 (4)0.091 (7)
F160.0519 (12)0.2021 (5)0.3146 (5)0.192 (7)
F170.0567 (9)0.2664 (5)0.2640 (3)0.144 (5)
F180.1460 (8)0.2556 (8)0.3162 (7)0.235 (10)
O130.0053 (4)0.5167 (3)0.4407 (3)0.0375 (17)
O140.0149 (5)0.4787 (3)0.3639 (3)0.045 (2)
C190.0328 (6)0.5116 (4)0.3982 (4)0.029 (2)
C200.1017 (6)0.5526 (4)0.3844 (3)0.051 (3)
F190.1394 (5)0.5699 (4)0.4231 (3)0.093 (3)
F200.1522 (5)0.5306 (4)0.3541 (4)0.105 (4)
F210.0714 (7)0.5943 (4)0.3619 (4)0.116 (4)
O150.1215 (5)0.4153 (3)0.3085 (3)0.0421 (19)
O160.2136 (5)0.4135 (4)0.2482 (3)0.051 (2)
C210.1878 (6)0.4039 (5)0.2912 (4)0.035 (2)
C220.2451 (6)0.3783 (5)0.3285 (4)0.072 (5)
F220.3115 (5)0.3637 (5)0.3095 (4)0.121 (4)
F230.2139 (6)0.3373 (4)0.3514 (4)0.123 (5)
F240.2612 (7)0.4143 (5)0.3636 (4)0.146 (6)
O170.0087 (5)0.4827 (4)0.2269 (3)0.050 (2)
O180.0772 (5)0.4840 (3)0.1631 (3)0.045 (2)
C230.0445 (7)0.5026 (5)0.2009 (4)0.036 (2)
C240.0781 (7)0.5591 (5)0.2179 (4)0.066 (4)
F250.0811 (10)0.5934 (4)0.1817 (4)0.144 (5)
F260.0389 (8)0.5812 (5)0.2536 (4)0.139 (5)
F270.1503 (7)0.5528 (6)0.2335 (6)0.198 (8)
N10.1583 (9)0.5764 (7)0.2670 (5)0.080 (4)
C250.1953 (10)0.6082 (8)0.2542 (8)0.084 (6)
C260.2451 (13)0.6508 (11)0.2299 (14)0.180 (17)
H26A0.29940.63900.22950.270*
H26B0.24090.68440.24840.270*
H26C0.22710.65650.19630.270*
O1W0.3311 (5)0.5379 (3)0.4077 (3)0.0419 (19)
H1W0.35840.52580.38330.063*
H2W0.35270.56660.41950.063*
O2W0.1637 (5)0.5390 (3)0.3941 (3)0.0407 (18)
H3W0.21380.54290.39360.061*
H4W0.14170.56960.40010.061*
O3W0.1267 (6)0.4242 (6)0.2854 (4)0.094 (4)
H5W0.16560.41230.26830.141*
H6W0.12280.45870.28180.141*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0443 (5)0.0291 (4)0.0460 (5)0.0071 (3)0.0011 (4)0.0017 (4)
Ag20.0498 (5)0.0258 (4)0.0402 (5)0.0089 (3)0.0042 (4)0.0012 (4)
Ag30.0339 (4)0.0381 (5)0.0244 (4)0.0031 (3)0.0058 (3)0.0049 (3)
Ag40.0441 (5)0.0455 (5)0.0247 (4)0.0005 (4)0.0072 (3)0.0003 (4)
Ag50.0346 (4)0.0294 (4)0.0347 (4)0.0001 (3)0.0058 (3)0.0054 (3)
Ag60.0620 (6)0.0262 (4)0.0432 (5)0.0058 (4)0.0062 (4)0.0001 (4)
Ag70.0315 (4)0.0354 (5)0.0419 (5)0.0047 (3)0.0098 (3)0.0052 (4)
Ag80.0401 (5)0.0268 (4)0.0530 (6)0.0037 (3)0.0035 (4)0.0039 (4)
Ag90.0505 (5)0.0602 (6)0.0281 (5)0.0073 (4)0.0037 (4)0.0055 (4)
Ag100.0451 (5)0.0688 (7)0.0334 (5)0.0052 (4)0.0113 (4)0.0153 (4)
Ag110.0690 (7)0.0538 (6)0.0471 (6)0.0057 (5)0.0031 (5)0.0023 (5)
Br10.0393 (6)0.0501 (7)0.0475 (7)0.0119 (5)0.0056 (5)0.0169 (6)
Br20.0369 (6)0.0452 (7)0.0535 (7)0.0077 (5)0.0084 (5)0.0162 (6)
C10.036 (6)0.021 (5)0.020 (5)0.000 (4)0.000 (4)0.004 (4)
C20.028 (5)0.022 (5)0.022 (5)0.003 (4)0.001 (4)0.001 (4)
C30.018 (4)0.030 (5)0.025 (5)0.003 (4)0.003 (4)0.001 (4)
C40.025 (5)0.024 (5)0.028 (5)0.001 (4)0.007 (4)0.004 (4)
C50.021 (5)0.029 (5)0.028 (5)0.002 (4)0.002 (4)0.002 (4)
C60.027 (5)0.027 (5)0.032 (5)0.002 (4)0.001 (4)0.005 (4)
O10.046 (4)0.023 (4)0.051 (5)0.001 (3)0.014 (4)0.004 (3)
O20.045 (5)0.030 (4)0.052 (5)0.001 (3)0.017 (4)0.001 (4)
C70.036 (6)0.032 (6)0.032 (6)0.003 (5)0.005 (4)0.001 (5)
C80.060 (8)0.047 (8)0.055 (9)0.014 (6)0.025 (7)0.001 (6)
F10.118 (8)0.048 (5)0.148 (9)0.026 (5)0.083 (7)0.008 (5)
F20.150 (10)0.151 (10)0.056 (6)0.072 (8)0.052 (6)0.021 (6)
F30.047 (5)0.184 (12)0.162 (11)0.009 (6)0.032 (6)0.063 (9)
O30.058 (5)0.061 (6)0.035 (5)0.022 (4)0.009 (4)0.014 (4)
O40.046 (4)0.041 (4)0.028 (4)0.017 (4)0.003 (3)0.001 (3)
C90.029 (5)0.036 (6)0.039 (7)0.005 (4)0.003 (5)0.002 (5)
C100.073 (10)0.061 (9)0.044 (8)0.023 (7)0.020 (7)0.006 (7)
F40.100 (6)0.086 (6)0.043 (5)0.036 (5)0.025 (4)0.000 (4)
F50.160 (9)0.053 (5)0.094 (7)0.042 (6)0.058 (7)0.004 (5)
F60.053 (5)0.176 (11)0.099 (8)0.031 (6)0.017 (5)0.002 (7)
O50.047 (4)0.031 (4)0.026 (4)0.008 (3)0.012 (3)0.005 (3)
O60.041 (4)0.050 (5)0.037 (4)0.011 (4)0.012 (3)0.018 (4)
C110.028 (5)0.041 (6)0.022 (5)0.010 (4)0.002 (4)0.000 (5)
C120.055 (8)0.062 (8)0.027 (6)0.012 (6)0.013 (5)0.009 (6)
F70.120 (8)0.087 (6)0.067 (6)0.067 (6)0.010 (5)0.001 (5)
F80.216 (12)0.122 (9)0.084 (7)0.100 (9)0.073 (8)0.027 (6)
F90.132 (10)0.117 (9)0.243 (15)0.015 (8)0.029 (10)0.101 (10)
O70.039 (5)0.060 (6)0.069 (6)0.013 (4)0.000 (4)0.029 (5)
O80.035 (4)0.036 (4)0.055 (5)0.004 (3)0.007 (4)0.009 (4)
C130.037 (6)0.029 (6)0.034 (6)0.001 (4)0.001 (5)0.002 (5)
C140.046 (7)0.049 (8)0.061 (9)0.007 (6)0.008 (6)0.024 (7)
F100.121 (9)0.107 (8)0.165 (11)0.054 (7)0.033 (8)0.073 (8)
F110.112 (8)0.127 (9)0.222 (13)0.062 (7)0.070 (9)0.132 (9)
F120.237 (14)0.143 (11)0.067 (7)0.003 (10)0.003 (8)0.039 (7)
O90.049 (4)0.031 (4)0.034 (4)0.003 (3)0.013 (3)0.002 (3)
O100.055 (5)0.024 (4)0.058 (5)0.003 (3)0.020 (4)0.002 (4)
C150.031 (5)0.028 (6)0.041 (6)0.001 (4)0.005 (5)0.005 (5)
C160.056 (7)0.042 (7)0.039 (7)0.013 (6)0.009 (6)0.001 (5)
F130.076 (5)0.075 (6)0.065 (5)0.024 (4)0.030 (4)0.006 (4)
F140.158 (9)0.057 (5)0.102 (7)0.026 (6)0.067 (7)0.002 (5)
F150.099 (7)0.165 (10)0.051 (5)0.033 (7)0.003 (5)0.037 (6)
O110.072 (6)0.063 (6)0.032 (5)0.027 (5)0.001 (4)0.009 (4)
O120.073 (6)0.053 (5)0.031 (4)0.032 (5)0.009 (4)0.002 (4)
C170.058 (8)0.056 (8)0.028 (6)0.023 (6)0.001 (5)0.003 (6)
C180.129 (16)0.086 (13)0.058 (11)0.068 (13)0.020 (10)0.014 (9)
F160.311 (17)0.108 (10)0.156 (12)0.004 (11)0.104 (12)0.056 (9)
F170.223 (13)0.154 (10)0.056 (6)0.098 (10)0.021 (7)0.022 (7)
F180.171 (13)0.290 (18)0.243 (16)0.103 (13)0.045 (13)0.075 (14)
O130.042 (4)0.041 (4)0.029 (4)0.001 (3)0.002 (3)0.010 (3)
O140.056 (5)0.046 (5)0.033 (4)0.009 (4)0.002 (4)0.005 (4)
C190.039 (6)0.036 (6)0.014 (5)0.004 (4)0.005 (4)0.004 (4)
C200.075 (9)0.056 (8)0.023 (6)0.019 (7)0.006 (6)0.012 (6)
F190.104 (7)0.122 (8)0.054 (5)0.071 (6)0.007 (5)0.017 (5)
F200.074 (6)0.132 (9)0.110 (8)0.036 (6)0.047 (6)0.052 (7)
F210.133 (9)0.085 (7)0.129 (9)0.022 (7)0.010 (8)0.049 (7)
O150.041 (4)0.054 (5)0.031 (4)0.005 (4)0.005 (3)0.004 (4)
O160.033 (4)0.084 (7)0.037 (5)0.003 (4)0.004 (4)0.018 (4)
C210.035 (6)0.045 (6)0.025 (6)0.007 (5)0.006 (5)0.004 (5)
C220.039 (7)0.136 (16)0.042 (8)0.021 (8)0.003 (6)0.035 (10)
F220.073 (6)0.193 (11)0.099 (8)0.061 (7)0.018 (6)0.057 (8)
F230.098 (7)0.134 (9)0.135 (9)0.043 (7)0.017 (7)0.091 (8)
F240.128 (10)0.229 (14)0.081 (8)0.009 (9)0.058 (7)0.014 (9)
O170.051 (5)0.048 (5)0.052 (5)0.012 (4)0.010 (4)0.001 (4)
O180.052 (5)0.045 (5)0.039 (5)0.013 (4)0.006 (4)0.009 (4)
C230.043 (6)0.039 (6)0.026 (6)0.008 (5)0.006 (5)0.005 (5)
C240.088 (11)0.074 (10)0.036 (7)0.040 (9)0.021 (7)0.022 (7)
F250.268 (15)0.069 (7)0.095 (8)0.059 (8)0.035 (9)0.008 (6)
F260.185 (12)0.101 (8)0.132 (10)0.056 (8)0.073 (9)0.062 (7)
F270.143 (11)0.185 (13)0.266 (16)0.084 (10)0.044 (11)0.075 (12)
N10.088 (10)0.099 (11)0.053 (8)0.041 (9)0.002 (7)0.004 (7)
C250.049 (9)0.084 (12)0.118 (16)0.008 (8)0.003 (9)0.038 (11)
C260.085 (16)0.13 (2)0.33 (5)0.015 (14)0.03 (2)0.13 (3)
O1W0.046 (4)0.032 (4)0.048 (5)0.005 (3)0.009 (4)0.001 (4)
O2W0.043 (4)0.036 (4)0.044 (5)0.004 (3)0.011 (4)0.004 (4)
O3W0.046 (6)0.156 (12)0.081 (8)0.010 (7)0.005 (5)0.061 (8)
Geometric parameters (Å, º) top
Ag1—O72.241 (8)O3—C91.205 (13)
Ag1—O1W2.330 (8)O4—C91.265 (13)
Ag1—C52.335 (10)O4—Ag9ii2.381 (7)
Ag1—C42.407 (10)C9—C101.568 (15)
Ag1—Ag53.1220 (15)C10—F51.288 (9)
Ag1—Ag83.3111 (17)C10—F41.294 (9)
Ag2—C52.326 (9)C10—F61.297 (9)
Ag2—O32.371 (8)O5—C111.249 (12)
Ag2—O12.384 (8)O5—Ag5iii2.496 (7)
Ag2—O9i2.405 (7)O6—C111.231 (13)
Ag2—Ag32.8390 (14)O6—Ag10ii2.269 (7)
Ag2—Ag52.8728 (15)C11—C121.538 (14)
Ag3—C52.203 (10)C12—F81.285 (8)
Ag3—O42.362 (7)C12—F91.289 (9)
Ag3—O18ii2.371 (8)C12—F71.292 (8)
Ag3—O62.600 (8)O7—C131.227 (13)
Ag3—Ag52.8842 (15)O8—C131.240 (13)
Ag4—C12.185 (10)O8—Ag7v2.437 (8)
Ag4—O122.246 (8)C13—C141.566 (14)
Ag4—O142.462 (8)C14—F111.276 (9)
Ag4—Ag72.9711 (15)C14—F101.291 (9)
Ag4—Ag83.0097 (14)C14—F121.304 (9)
Ag4—Ag63.0112 (15)O9—C151.250 (13)
Ag5—C52.291 (9)O9—Ag2iv2.405 (7)
Ag5—O22.294 (7)O10—C151.232 (13)
Ag5—O52.412 (7)C15—C161.560 (15)
Ag5—O5iii2.496 (7)C16—F151.290 (9)
Ag6—O112.348 (9)C16—F131.294 (8)
Ag6—C12.374 (10)C16—F141.296 (9)
Ag6—O92.424 (7)O11—C171.237 (15)
Ag6—O1iv2.441 (7)O12—C171.231 (15)
Ag6—Ag72.8494 (15)C17—C181.531 (17)
Ag7—C12.238 (10)C18—F171.274 (9)
Ag7—O102.356 (8)C18—F161.287 (9)
Ag7—O8v2.437 (8)C18—F181.307 (10)
Ag7—O13v2.499 (7)O13—C191.234 (12)
Ag7—Ag83.0039 (14)O13—Ag7v2.499 (7)
Ag8—C12.281 (10)O14—C191.256 (13)
Ag8—O82.322 (8)C19—C201.578 (15)
Ag8—O2W2.408 (7)C20—F211.286 (9)
Ag8—O132.525 (8)C20—F191.287 (8)
Ag8—C22.710 (10)C20—F201.292 (9)
Ag9—O3W2.300 (10)O15—C211.240 (13)
Ag9—O4vi2.381 (7)O16—C211.253 (13)
Ag9—O122.415 (8)C21—C221.523 (15)
Ag9—O172.577 (9)C22—F221.279 (9)
Ag9—Ag103.2547 (16)C22—F231.287 (9)
Ag10—O162.198 (8)C22—F241.312 (9)
Ag10—O6vi2.269 (7)O17—C231.234 (14)
Ag10—O172.446 (9)O18—C231.238 (13)
Ag11—N12.224 (14)O18—Ag3vi2.371 (8)
Ag11—O142.450 (9)C23—C241.558 (15)
Ag11—O152.468 (8)C24—F251.282 (9)
Br1—C61.864 (10)C24—F261.282 (9)
Br2—C61.863 (10)C24—F271.295 (9)
C1—C21.209 (14)N1—C251.05 (2)
C2—C31.442 (13)C25—C261.49 (3)
C3—C61.350 (14)C26—H26A0.9600
C3—C41.446 (13)C26—H26B0.9600
C4—C51.213 (14)C26—H26C0.9600
O1—C71.229 (13)O1W—H1W0.8511
O1—Ag6i2.441 (7)O1W—H2W0.8507
O2—C71.254 (13)O2W—H3W0.8502
C7—C81.547 (14)O2W—H4W0.8498
C8—F21.278 (9)O3W—H5W0.8506
C8—F11.292 (8)O3W—H6W0.8509
C8—F31.302 (9)
O7—Ag1—O1W87.9 (3)Ag4—C1—Ag784.4 (4)
O7—Ag1—C5154.3 (4)C2—C1—Ag897.0 (7)
O1W—Ag1—C5117.2 (3)Ag4—C1—Ag884.7 (3)
O7—Ag1—C4132.0 (4)Ag7—C1—Ag883.3 (3)
O1W—Ag1—C4135.1 (3)C2—C1—Ag6105.6 (7)
C5—Ag1—C429.6 (3)Ag4—C1—Ag682.6 (3)
O7—Ag1—Ag5122.2 (2)Ag7—C1—Ag676.3 (3)
O1W—Ag1—Ag5109.8 (2)Ag8—C1—Ag6156.8 (5)
C5—Ag1—Ag547.0 (2)C1—C2—C3176.2 (10)
C4—Ag1—Ag569.5 (2)C1—C2—Ag856.7 (6)
O7—Ag1—Ag869.5 (2)C3—C2—Ag8127.1 (6)
O1W—Ag1—Ag888.3 (2)C6—C3—C2120.7 (8)
C5—Ag1—Ag8113.8 (2)C6—C3—C4121.3 (8)
C4—Ag1—Ag888.7 (2)C2—C3—C4118.0 (8)
Ag5—Ag1—Ag8157.80 (4)C5—C4—C3172.5 (10)
C5—Ag2—O3125.2 (3)C5—C4—Ag171.9 (6)
C5—Ag2—O1119.8 (3)C3—C4—Ag1115.2 (7)
O3—Ag2—O199.2 (3)C4—C5—Ag3149.6 (8)
C5—Ag2—O9i134.2 (3)C4—C5—Ag5129.9 (8)
O3—Ag2—O9i86.8 (3)Ag3—C5—Ag579.8 (3)
O1—Ag2—O9i79.3 (2)C4—C5—Ag2111.7 (8)
C5—Ag2—Ag349.3 (2)Ag3—C5—Ag277.6 (3)
O3—Ag2—Ag376.2 (2)Ag5—C5—Ag277.0 (3)
O1—Ag2—Ag3132.19 (18)C4—C5—Ag178.5 (7)
O9i—Ag2—Ag3145.70 (18)Ag3—C5—Ag1101.5 (4)
C5—Ag2—Ag551.0 (2)Ag5—C5—Ag184.9 (3)
O3—Ag2—Ag5110.9 (2)Ag2—C5—Ag1161.7 (5)
O1—Ag2—Ag578.11 (17)C3—C6—Br2122.7 (7)
O9i—Ag2—Ag5153.26 (18)C3—C6—Br1123.2 (7)
Ag3—Ag2—Ag560.65 (4)Br2—C6—Br1114.1 (5)
C5—Ag3—O4137.8 (3)C7—O1—Ag2124.8 (7)
C5—Ag3—O18ii120.3 (3)C7—O1—Ag6i133.7 (7)
O4—Ag3—O18ii98.3 (3)Ag2—O1—Ag6i101.1 (3)
C5—Ag3—O6123.4 (3)C7—O2—Ag5119.4 (7)
O4—Ag3—O678.7 (3)O1—C7—O2129.6 (10)
O18ii—Ag3—O677.5 (3)O1—C7—C8116.9 (9)
C5—Ag3—Ag253.1 (2)O2—C7—C8113.4 (9)
O4—Ag3—Ag287.86 (19)F2—C8—F1107.8 (8)
O18ii—Ag3—Ag2173.4 (2)F2—C8—F3106.7 (9)
O6—Ag3—Ag2106.2 (2)F1—C8—F3106.8 (8)
C5—Ag3—Ag551.4 (2)F2—C8—C7111.4 (9)
O4—Ag3—Ag5126.87 (18)F1—C8—C7113.1 (9)
O18ii—Ag3—Ag5116.9 (2)F3—C8—C7110.8 (9)
O6—Ag3—Ag572.27 (17)C9—O3—Ag2129.2 (7)
Ag2—Ag3—Ag560.25 (3)C9—O4—Ag3113.9 (7)
C1—Ag4—O12134.2 (3)C9—O4—Ag9ii133.2 (7)
C1—Ag4—O14123.5 (3)Ag3—O4—Ag9ii110.7 (3)
O12—Ag4—O1499.8 (3)O3—C9—O4129.5 (10)
C1—Ag4—Ag748.6 (3)O3—C9—C10114.2 (9)
O12—Ag4—Ag7124.8 (2)O4—C9—C10116.1 (9)
O14—Ag4—Ag791.33 (19)F5—C10—F4108.3 (8)
C1—Ag4—Ag849.0 (3)F5—C10—F6106.5 (8)
O12—Ag4—Ag8174.8 (2)F4—C10—F6107.4 (8)
O14—Ag4—Ag878.6 (2)F5—C10—C9111.2 (9)
Ag7—Ag4—Ag860.29 (3)F4—C10—C9113.7 (8)
C1—Ag4—Ag651.4 (3)F6—C10—C9109.4 (9)
O12—Ag4—Ag685.8 (2)C11—O5—Ag5115.6 (6)
O14—Ag4—Ag6142.6 (2)C11—O5—Ag5iii135.9 (7)
Ag7—Ag4—Ag656.88 (3)Ag5—O5—Ag5iii105.2 (3)
Ag8—Ag4—Ag698.48 (4)C11—O6—Ag10ii132.7 (7)
C5—Ag5—O2131.6 (3)C11—O6—Ag3114.7 (6)
C5—Ag5—O5122.1 (3)Ag10ii—O6—Ag399.5 (3)
O2—Ag5—O5103.8 (3)O6—C11—O5126.2 (10)
C5—Ag5—O5iii105.3 (3)O6—C11—C12117.6 (9)
O2—Ag5—O5iii100.6 (3)O5—C11—C12116.2 (9)
O5—Ag5—O5iii74.8 (3)F8—C12—F9107.5 (9)
C5—Ag5—Ag252.1 (2)F8—C12—F7106.5 (8)
O2—Ag5—Ag286.00 (19)F9—C12—F7106.8 (9)
O5—Ag5—Ag2133.56 (17)F8—C12—C11113.2 (9)
O5iii—Ag5—Ag2148.87 (17)F9—C12—C11109.1 (9)
C5—Ag5—Ag348.8 (2)F7—C12—C11113.3 (8)
O2—Ag5—Ag3132.8 (2)C13—O7—Ag1140.7 (8)
O5—Ag5—Ag383.53 (17)C13—O8—Ag8117.4 (7)
O5iii—Ag5—Ag3126.00 (18)C13—O8—Ag7v139.3 (7)
Ag2—Ag5—Ag359.09 (3)Ag8—O8—Ag7v101.3 (3)
C5—Ag5—Ag148.2 (2)O7—C13—O8129.5 (10)
O2—Ag5—Ag1151.8 (2)O7—C13—C14113.8 (9)
O5—Ag5—Ag191.84 (19)O8—C13—C14116.6 (9)
O5iii—Ag5—Ag160.68 (18)F11—C14—F10108.5 (9)
Ag2—Ag5—Ag1100.21 (4)F11—C14—F12107.3 (9)
Ag3—Ag5—Ag171.53 (3)F10—C14—F12104.6 (8)
O11—Ag6—C1118.5 (3)F11—C14—C13112.9 (9)
O11—Ag6—O9118.9 (3)F10—C14—C13112.5 (9)
C1—Ag6—O9115.9 (3)F12—C14—C13110.7 (9)
O11—Ag6—O1iv81.9 (3)C15—O9—Ag2iv132.4 (7)
C1—Ag6—O1iv136.2 (3)C15—O9—Ag6126.4 (7)
O9—Ag6—O1iv77.9 (3)Ag2iv—O9—Ag6101.0 (3)
O11—Ag6—Ag7119.2 (3)C15—O10—Ag7119.3 (7)
C1—Ag6—Ag749.7 (2)O10—C15—O9128.6 (10)
O9—Ag6—Ag778.42 (18)O10—C15—C16115.0 (9)
O1iv—Ag6—Ag7154.01 (19)O9—C15—C16116.2 (9)
O11—Ag6—Ag474.6 (2)F15—C16—F13108.0 (8)
C1—Ag6—Ag446.0 (2)F15—C16—F14107.3 (8)
O9—Ag6—Ag4136.92 (18)F13—C16—F14107.6 (8)
O1iv—Ag6—Ag4144.57 (19)F15—C16—C15110.2 (8)
Ag7—Ag6—Ag460.85 (4)F13—C16—C15111.5 (8)
C1—Ag7—O10126.5 (3)F14—C16—C15112.1 (8)
C1—Ag7—O8v151.5 (3)C17—O11—Ag6130.4 (8)
O10—Ag7—O8v79.5 (3)C17—O12—Ag4120.5 (8)
C1—Ag7—O13v112.0 (3)C17—O12—Ag9134.1 (8)
O10—Ag7—O13v79.6 (3)Ag4—O12—Ag9105.4 (3)
O8v—Ag7—O13v81.3 (3)O12—C17—O11128.7 (11)
C1—Ag7—Ag654.0 (2)O12—C17—C18116.2 (11)
O10—Ag7—Ag686.91 (18)O11—C17—C18114.7 (11)
O8v—Ag7—Ag6126.26 (18)F17—C18—F16108.2 (10)
O13v—Ag7—Ag6146.61 (19)F17—C18—F18106.6 (10)
C1—Ag7—Ag447.1 (2)F16—C18—F18105.0 (9)
O10—Ag7—Ag4145.5 (2)F17—C18—C17115.7 (10)
O8v—Ag7—Ag4105.4 (2)F16—C18—C17110.6 (12)
O13v—Ag7—Ag4134.68 (18)F18—C18—C17110.1 (12)
Ag6—Ag7—Ag462.27 (3)C19—O13—Ag7v138.0 (7)
C1—Ag7—Ag849.0 (2)C19—O13—Ag8117.6 (7)
O10—Ag7—Ag8148.2 (2)Ag7v—O13—Ag894.2 (3)
O8v—Ag7—Ag8116.2 (2)C19—O14—Ag11113.8 (7)
O13v—Ag7—Ag876.12 (18)C19—O14—Ag4115.5 (7)
Ag6—Ag7—Ag8102.33 (4)Ag11—O14—Ag4101.1 (3)
Ag4—Ag7—Ag860.49 (3)O13—C19—O14130.2 (10)
C1—Ag8—O8136.8 (3)O13—C19—C20115.3 (8)
C1—Ag8—O2W137.6 (3)O14—C19—C20114.4 (8)
O8—Ag8—O2W85.4 (3)F21—C20—F19108.2 (8)
C1—Ag8—O13105.4 (3)F21—C20—F20107.3 (8)
O8—Ag8—O1383.0 (2)F19—C20—F20108.3 (8)
O2W—Ag8—O1379.5 (3)F21—C20—C19108.6 (9)
C1—Ag8—C226.3 (3)F19—C20—C19112.6 (8)
O8—Ag8—C2125.6 (3)F20—C20—C19111.5 (8)
O2W—Ag8—C2133.9 (3)C21—O15—Ag11115.2 (7)
O13—Ag8—C2131.4 (3)C21—O16—Ag10117.5 (7)
C1—Ag8—Ag747.7 (3)O15—C21—O16127.8 (10)
O8—Ag8—Ag7105.3 (2)O15—C21—C22114.9 (9)
O2W—Ag8—Ag7140.9 (2)O16—C21—C22117.2 (9)
O13—Ag8—Ag765.13 (18)F22—C22—F23109.3 (9)
C2—Ag8—Ag769.3 (2)F22—C22—F24106.8 (9)
C1—Ag8—Ag446.3 (2)F23—C22—F24105.4 (8)
O8—Ag8—Ag4157.67 (19)F22—C22—C21114.2 (9)
O2W—Ag8—Ag497.6 (2)F23—C22—C21111.7 (9)
O13—Ag8—Ag475.84 (17)F24—C22—C21108.9 (10)
C2—Ag8—Ag466.9 (2)C23—O17—Ag10123.0 (8)
Ag7—Ag8—Ag459.22 (3)C23—O17—Ag9117.1 (8)
C1—Ag8—Ag198.2 (3)Ag10—O17—Ag980.7 (3)
O8—Ag8—Ag182.38 (19)C23—O18—Ag3vi130.8 (7)
O2W—Ag8—Ag180.48 (19)O17—C23—O18129.6 (11)
O13—Ag8—Ag1156.06 (18)O17—C23—C24116.7 (10)
C2—Ag8—Ag172.4 (2)O18—C23—C24113.6 (9)
Ag7—Ag8—Ag1137.46 (4)F25—C24—F26107.8 (9)
Ag4—Ag8—Ag1119.95 (4)F25—C24—F27106.5 (9)
O3W—Ag9—O4vi129.4 (3)F26—C24—F27107.2 (9)
O3W—Ag9—O1287.5 (4)F25—C24—C23111.8 (9)
O4vi—Ag9—O12130.8 (3)F26—C24—C23113.8 (10)
O3W—Ag9—O1779.1 (4)F27—C24—C23109.3 (10)
O4vi—Ag9—O1786.2 (3)C25—N1—Ag11170.8 (17)
O12—Ag9—O17138.1 (3)N1—C25—C26173 (3)
O3W—Ag9—Ag10126.9 (4)C25—C26—H26A109.5
O4vi—Ag9—Ag1055.3 (2)C25—C26—H26B109.5
O12—Ag9—Ag10132.0 (2)H26A—C26—H26B109.5
O17—Ag9—Ag1047.9 (2)C25—C26—H26C109.5
O16—Ag10—O6vi155.0 (3)H26A—C26—H26C109.5
O16—Ag10—O17113.6 (3)H26B—C26—H26C109.5
O6vi—Ag10—O1791.3 (3)Ag1—O1W—H1W109.4
O16—Ag10—Ag988.3 (2)Ag1—O1W—H2W109.6
O6vi—Ag10—Ag9110.6 (2)H1W—O1W—H2W109.8
O17—Ag10—Ag951.4 (2)Ag8—O2W—H3W109.3
N1—Ag11—O14156.4 (5)Ag8—O2W—H4W109.7
N1—Ag11—O15123.6 (5)H3W—O2W—H4W109.8
O14—Ag11—O1579.5 (3)Ag9—O3W—H5W109.4
C2—C1—Ag4135.4 (8)Ag9—O3W—H6W108.9
C2—C1—Ag7140.1 (8)H5W—O3W—H6W109.7
Ag4—C1—C2—Ag889.6 (10)O7—C13—C14—F1275.4 (13)
Ag7—C1—C2—Ag888.0 (11)O8—C13—C14—F12101.2 (12)
Ag6—C1—C2—Ag8175.1 (7)Ag7—O10—C15—O97.2 (16)
Ag8—C2—C3—C6136.0 (9)Ag7—O10—C15—C16168.0 (6)
Ag8—C2—C3—C443.3 (12)Ag2iv—O9—C15—O10179.2 (8)
C6—C3—C4—Ag1126.9 (9)Ag6—O9—C15—O105.3 (17)
C2—C3—C4—Ag152.4 (11)Ag2iv—O9—C15—C164.0 (14)
Ag1—C4—C5—Ag393.2 (15)Ag6—O9—C15—C16169.9 (6)
Ag1—C4—C5—Ag573.2 (8)O10—C15—C16—F1591.6 (11)
Ag1—C4—C5—Ag2164.1 (6)O9—C15—C16—F1584.3 (11)
C2—C3—C6—Br2178.9 (7)O10—C15—C16—F1328.3 (13)
C4—C3—C6—Br20.4 (14)O9—C15—C16—F13155.9 (9)
C2—C3—C6—Br10.0 (14)O10—C15—C16—F14149.0 (10)
C4—C3—C6—Br1179.3 (8)O9—C15—C16—F1435.2 (12)
Ag2—O1—C7—O214.7 (18)Ag4—O12—C17—O112 (2)
Ag6i—O1—C7—O2156.6 (9)Ag9—O12—C17—O11179.2 (10)
Ag2—O1—C7—C8161.9 (7)Ag4—O12—C17—C18175.2 (9)
Ag6i—O1—C7—C826.9 (15)Ag9—O12—C17—C188.0 (19)
Ag5—O2—C7—O11.9 (17)Ag6—O11—C17—O123 (2)
Ag5—O2—C7—C8174.7 (6)Ag6—O11—C17—C18175.4 (9)
O1—C7—C8—F2124.1 (11)O12—C17—C18—F1724.9 (18)
O2—C7—C8—F258.8 (13)O11—C17—C18—F17161.3 (13)
O1—C7—C8—F12.5 (14)O12—C17—C18—F16148.3 (14)
O2—C7—C8—F1179.6 (10)O11—C17—C18—F1637.9 (16)
O1—C7—C8—F3117.3 (11)O12—C17—C18—F1896.1 (15)
O2—C7—C8—F359.7 (12)O11—C17—C18—F1877.6 (16)
Ag2—O3—C9—O412.4 (19)Ag7v—O13—C19—O14152.6 (9)
Ag2—O3—C9—C10172.1 (7)Ag8—O13—C19—O1417.8 (15)
Ag3—O4—C9—O35.2 (16)Ag7v—O13—C19—C2027.6 (14)
Ag9ii—O4—C9—O3156.3 (10)Ag8—O13—C19—C20162.4 (6)
Ag3—O4—C9—C10170.2 (7)Ag11—O14—C19—O1391.6 (12)
Ag9ii—O4—C9—C1028.3 (15)Ag4—O14—C19—O1324.7 (15)
O3—C9—C10—F545.2 (13)Ag11—O14—C19—C2088.6 (9)
O4—C9—C10—F5138.7 (10)Ag4—O14—C19—C20155.0 (6)
O3—C9—C10—F4167.7 (10)O13—C19—C20—F2194.3 (11)
O4—C9—C10—F416.1 (14)O14—C19—C20—F2185.9 (11)
O3—C9—C10—F672.2 (12)O13—C19—C20—F1925.5 (13)
O4—C9—C10—F6104.0 (11)O14—C19—C20—F19154.3 (10)
Ag10ii—O6—C11—O5177.5 (8)O13—C19—C20—F20147.6 (10)
Ag3—O6—C11—O545.2 (14)O14—C19—C20—F2032.2 (12)
Ag10ii—O6—C11—C123.4 (15)Ag11—O15—C21—O1658.0 (15)
Ag3—O6—C11—C12135.8 (7)Ag11—O15—C21—C22118.0 (9)
Ag5—O5—C11—O62.5 (14)Ag10—O16—C21—O1511.6 (17)
Ag5iii—O5—C11—O6158.3 (8)Ag10—O16—C21—C22172.5 (8)
Ag5—O5—C11—C12178.4 (6)O15—C21—C22—F22176.0 (10)
Ag5iii—O5—C11—C1222.6 (14)O16—C21—C22—F227.6 (15)
O6—C11—C12—F89.4 (14)O15—C21—C22—F2351.3 (14)
O5—C11—C12—F8169.8 (10)O16—C21—C22—F23132.2 (11)
O6—C11—C12—F9110.3 (11)O15—C21—C22—F2464.7 (13)
O5—C11—C12—F970.5 (12)O16—C21—C22—F24111.7 (12)
O6—C11—C12—F7130.8 (10)Ag10—O17—C23—O1845.7 (17)
O5—C11—C12—F748.4 (13)Ag9—O17—C23—O1851.0 (16)
Ag1—O7—C13—O811 (2)Ag10—O17—C23—C24136.0 (8)
Ag1—O7—C13—C14173.5 (9)Ag9—O17—C23—C24127.4 (9)
Ag8—O8—C13—O71.6 (17)Ag3vi—O18—C23—O176.4 (19)
Ag7v—O8—C13—O7162.1 (10)Ag3vi—O18—C23—C24175.2 (7)
Ag8—O8—C13—C14177.4 (7)O17—C23—C24—F25131.0 (12)
Ag7v—O8—C13—C1422.0 (17)O18—C23—C24—F2550.3 (14)
O7—C13—C14—F11164.4 (11)O17—C23—C24—F268.5 (15)
O8—C13—C14—F1119.1 (14)O18—C23—C24—F26172.8 (11)
O7—C13—C14—F1041.2 (14)O17—C23—C24—F27111.2 (13)
O8—C13—C14—F10142.3 (11)O18—C23—C24—F2767.4 (13)
Symmetry codes: (i) x+1/2, y+1/2, z+1; (ii) x+1/2, y, z+1/2; (iii) x+1, y+1, z+1; (iv) x1/2, y+1/2, z+1; (v) x, y+1, z+1; (vi) x1/2, y, z+1/2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1W—H2W···O2iii0.851.962.783 (11)163.6
O1W—H1W···O18ii0.851.942.774 (11)167.4
O2W—H4W···O10v0.852.062.875 (11)160.8
O2W—H3W···O1W0.852.022.846 (12)164.7
O3W—H5W···O16vi0.852.082.851 (13)149.6
O3W—H6W···F200.852.663.212 (14)123.9
Symmetry codes: (ii) x+1/2, y, z+1/2; (iii) x+1, y+1, z+1; (v) x, y+1, z+1; (vi) x1/2, y, z+1/2.

Experimental details

(I)(II)(III)(IV)
Crystal data
Chemical formula22(Ag+)·3(C10H82)·16(C2F3O2)·12(C2H6SO)22(Ag+)·3(C11H102)·16(C2F3O2)·12(C2H6SO)7(Ag+)·(C12H122)·5(C2F3O2)·5(C2H6SO)7(Ag+)·(C13H142)·5(C2F3O2)·4(C2H6SO)
Mr5503.485545.561867.041802.94
Crystal system, space groupMonoclinic, C2/cMonoclinic, C2/cMonoclinic, CcTriclinic, P1
Temperature (K)173173173173
a, b, c (Å)22.076 (3), 14.7930 (18), 45.863 (6)21.9927 (13), 14.8488 (13), 45.797 (3)17.8567 (17), 21.007 (2), 16.044 (3)13.4350 (15), 13.8806 (15), 16.3609 (18)
α, β, γ (°)90, 93.501 (3), 9090, 93.937 (2), 9090, 117.802 (1), 90110.194 (2), 106.492 (2), 104.003 (2)
V3)14950 (3)14920.4 (19)5323.6 (12)2542.2 (5)
Z4442
Radiation typeMo KαMo KαMo KαMo Kα
µ (mm1)3.113.112.832.92
Crystal size (mm)0.50 × 0.50 × 0.400.50 × 0.50 × 0.400.50 × 0.40 × 0.400.50 × 0.40 × 0.40
Data collection
DiffractometerBruker APEX-II CCD
diffractometer
Bruker APEX-II CCD
diffractometer
Bruker APEX-II CCD
diffractometer
Bruker APEX-II CCD
diffractometer
Absorption correctionMulti-scan
SADABS (Bruker, 2003)
Multi-scan
SADABS (Bruker, 2003)
Multi-scan
SADABS (Bruker, 2003)
Multi-scan
SADABS (Bruker, 2003)
Tmin, Tmax0.306, 0.3700.305, 0.3690.332, 0.3980.324, 0.389
No. of measured, independent and
observed [I > 2σ(I)] reflections
102163, 13534, 9700 164822, 13506, 12140 19165, 6449, 5135 31854, 16780, 15708
Rint0.1580.1310.1020.075
(sin θ/λ)max1)0.6000.6000.6000.600
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.076, 0.200, 1.08 0.064, 0.164, 1.14 0.066, 0.165, 1.05 0.087, 0.235, 1.05
No. of reflections1353413506644916780
No. of parameters9679986681276
No. of restraints606508184615
H-atom treatmentH-atom parameters constrainedH-atom parameters constrainedH-atom parameters constrainedH-atom parameters constrained
w = 1/[σ2(Fo2) + (0.096P)2 + 292.8881P]
where P = (Fo2 + 2Fc2)/3
w = 1/[σ2(Fo2) + (0.0621P)2 + 504.2735P]
where P = (Fo2 + 2Fc2)/3
w = 1/[σ2(Fo2) + (0.0867P)2]
where P = (Fo2 + 2Fc2)/3
w = 1/[σ2(Fo2) + (0.1443P)2 + 44.008P]
where P = (Fo2 + 2Fc2)/3
Δρmax, Δρmin (e Å3)3.61, 1.642.34, 2.241.67, 1.383.89, 1.66
Absolute structure??Refined as an inversion twin.Refined as an inversion twin.
Absolute structure parameter??0.48 (12)0.71 (8)


(V)(VI)(VII)(VIII)
Crystal data
Chemical formula7(Ag+)·(C10H82)·5(C2F3O2)·2(H2O)9(Ag+)·C10H82·9(C2F3O2)·C5H5N·2(C5H6N+)7(Ag+)·(C10H82)·5(C2F3O2)·2(C10H8N2)11(Ag+)·(C6Br22)·9(C2F3O2)·C2H3N·3(H2O)
Mr1484.392355.491760.722530.73
Crystal system, space groupMonoclinic, C2/cMonoclinic, P21Triclinic, P1Orthorhombic, Pbca
Temperature (K)173173173173
a, b, c (Å)23.394 (2), 13.9512 (12), 10.7920 (9)8.9453 (9), 24.902 (3), 14.4248 (16)12.427 (3), 14.132 (3), 16.384 (6)16.861 (6), 24.431 (9), 26.723 (10)
α, β, γ (°)90, 102.214 (1), 9090, 105.016 (2), 9096.481 (5), 108.935 (5), 115.229 (4)90, 90, 90
V3)3442.5 (5)3103.5 (6)2353.5 (12)11008 (7)
Z4228
Radiation typeMo KαMo KαMo KαMo Kα
µ (mm1)4.032.932.975.43
Crystal size (mm)0.50 × 0.50 × 0.400.50 × 0.50 × 0.400.50 × 0.50 × 0.400.50 × 0.50 × 0.50
Data collection
DiffractometerBruker APEX-II CCD
diffractometer
Bruker APEX-II CCD
diffractometer
Bruker APEX-II CCD
diffractometer
Bruker APEX-II CCD
diffractometer
Absorption correctionMulti-scan
SADABS (Bruker, 2003)
Multi-scan
SADABS (Bruker, 2003)
Multi-scan
SADABS (Bruker, 2003)
Multi-scan
SADABS (Bruker, 2003)
Tmin, Tmax0.238, 0.2950.323, 0.3880.318, 0.3830.172, 0.172
No. of measured, independent and
observed [I > 2σ(I)] reflections
30572, 3109, 2897 68475, 11211, 10668 18969, 8486, 6185 179417, 9961, 7690
Rint0.0870.0770.0930.135
(sin θ/λ)max1)0.6000.6000.6000.600
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.047, 0.125, 1.07 0.036, 0.098, 1.03 0.083, 0.214, 1.04 0.055, 0.154, 1.08
No. of reflections31091121184869961
No. of parameters264873686794
No. of restraints78283360216
H-atom treatmentH-atom parameters constrainedH-atom parameters constrainedH-atom parameters constrainedH-atom parameters constrained
w = 1/[σ2(Fo2) + (0.0768P)2 + 33.6886P]
where P = (Fo2 + 2Fc2)/3
w = 1/[σ2(Fo2) + (0.0648P)2 + 2.1022P]
where P = (Fo2 + 2Fc2)/3
w = 1/[σ2(Fo2) + (0.1152P)2]
where P = (Fo2 + 2Fc2)/3
w = 1/[σ2(Fo2) + (0.0723P)2 + 137.2121P]
where P = (Fo2 + 2Fc2)/3
Δρmax, Δρmin (e Å3)1.26, 1.771.39, 0.711.74, 1.621.77, 1.33
Absolute structure?Refined as an inversion twin.??
Absolute structure parameter?0.48 (4)??

Computer programs: APEX2 (Bruker, 2003), SAINT (Bruker, 2003), SAINT, SHELXS97 (Sheldrick, 2008), SHELXL2013 (Sheldrick, 2008), DIAMOND (Brandenburg, 2009), SHELXL2013.

Hydrogen-bond geometry (Å, º) for (V) top
D—H···AD—HH···AD···AD—H···A
O1W—H1W···O1i0.852.052.786 (7)144.8
O1W—H2W···O3i0.852.132.808 (7)136.0
Symmetry code: (i) x, y, z1/2.
Hydrogen-bond geometry (Å, º) for (VI) top
D—H···AD—HH···AD···AD—H···A
N2—H2···O10.882.633.013 (12)107.4
N2—H2···O50.881.972.852 (12)175.7
N3—H3···O80.882.533.133 (15)126.3
N3—H3···O170.882.353.041 (17)135.6
N3'—H3'···O6i0.882.393.049 (12)132.2
N3'—H3'···O15i0.882.212.927 (13)138.1
Symmetry code: (i) x, y, z+1.
Hydrogen-bond geometry (Å, º) for (VIII) top
D—H···AD—HH···AD···AD—H···A
O1W—H2W···O2i0.851.962.783 (11)163.6
O1W—H1W···O18ii0.851.942.774 (11)167.4
O2W—H4W···O10iii0.852.062.875 (11)160.8
O2W—H3W···O1W0.852.022.846 (12)164.7
O3W—H5W···O16iv0.852.082.851 (13)149.6
O3W—H6W···F200.852.663.212 (14)123.9
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+1/2, y, z+1/2; (iii) x, y+1, z+1; (iv) x1/2, y, z+1/2.
 

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