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Two polymorphs of the title compound, (C8H20N)[W2S4(S4)(C15H22BN6)], have been obtained unexpectedly by attempted recrystallization of a mixed-metal–sulfur cluster complex from different solvents. The dinuclear complex anion contains WV in two different coordination environments, one of them distorted octa­hedral with a tris­(pyrazol­yl)borate anion, a terminal sulfide and two bridging sulfide ligands, the other distorted square-pyramidal with a terminal sulfide, two bridging sulfide and a chelating tetra­sulfide ligand. The three inde­pendent anions in the two polymorphs have essentially the same geometry. The central W2S2 ring is a slightly folded rhombus with acute angles at the S atoms, and the WS4 chelate ring is an envelope with one non­coordinating S atom as the flap. The second polymorph, with Z′ = 2 and pseudo-inversion symmetry relating the anions of the asymmetric unit, also displays pseudo-translation features in its layer structure, and all examined crystals were found to be twinned, possibly as a consequence of this structural feature.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270111013035/bi3009sup1.cif
Contains datablocks 1, 2, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270111013035/bi30091sup2.hkl
Contains datablock 1

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270111013035/bi30092sup3.hkl
Contains datablock 2

CCDC references: 829692; 829693

Comment top

In a long-term research project investigating mixed-metal cluster compounds with thiometallate cores (see, for example, Beheshti et al., 2007, 2008, 2011), we treated (Et4N)[Tp*WS3] [Tp*- = hydrogen tris(3,5-dimethylpyrazolyl)borate, an established tripodal ligand] with AgI in acetonitrile solution. Elemental analysis and electronic and vibrational spectroscopy of the crude product indicated a successful synthesis of the intended product (Et4N)[Tp*WS3(AgI)] in a type of reaction we have used many times previously; however, attempted recrystallization from acetonitrile solution by vapour diffusion of diethyl ether led to decomposition and the unexpected isolation of the title complex, (Et4N)[Tp*W2S22-S)2(S4)], (I), which was identified by crystal structure determination. A second polymorph of the same complex was obtained when recrystallization of the initial crude product was attempted from acetone solution. We report here the structures of both polymorphs, one of which (1) has Z' = 1 and the other (2) has Z' = 2 and pseudo-inversion symmetry relating the two anions in the asymmetric unit.

The asymmetric unit of polymorph (1), containing one cation and one anion, is shown in Fig. 1. Figs. 2 and 3 show the two cations and two anions in the asymmetric unit of polymorph (2), the complete asymmetric unit being too complex and congested for a single figure. Selected bond lengths and angles are presented in the tables. The structure of polymorph (2), as is often the case with structures having Z' > 1, is less precisely determined than that of polymorph (1), and PLATON (Spek, 2009) suggests several possible twin laws, though none of these applied individually leads to an improvement in the refinement. Discussion of the geometry is based, therefore, mainly on the more precise structure of polymorph (1).

Comparison of the two anions in polymorph (2) with each other, and with the single anion in polymorph (1), using the molecule overlay feature of Mercury (Macrae et al., 2008), shows that they are essentially identical, allowing for the chiral conformation of the WS4 chelate ring, both enantiomers of which are present in each case in these centrosymmetric crystal structures: the r.m.s. deviations for overlays of all non-H atoms of the anions are 0.116 Å for the two anions of polymorph (2) (one of them inverted), and 0.267 and 0.271 Å for the anion of polymorph (1) with each of the anions of polymorph (2); corresponding figures when the overlay is restricted to the five atoms of the WS4 ring are 0.087, 0.103 and 0.081 Å, respectively. The cations show no significant variations except in the flexible C—C—N—C torsion angles.

The anion contains two W atoms, which have the same +5 oxidation state but quite different ligand sets and coordination geometries. One (W1 or W3) is six-coordinate with a distorted octahedral geometry, being bonded to a tridentate Tp*- ligand in a necessarily facial configuration, one terminal sulfido ligand and two bridging sulfido ligands. The bite angles N—W—N of the Tp*- ligand are reduced below the ideal cis-octahedral value of 90° by the constraints of the ligand internal geometry, and the three S—W—S angles are all more than 10° greater than 90°. The strong trans influence of the terminal sulfido ligand causes the opposite W—N bond to be markedly longer than the other two.

The second tungsten atom (W2 or W4) is five-coordinate with a distorted square-based pyramidal geometry. The apical position is occupied by a terminal sulfido ligand, while two mutually cis-positions of the square base are taken by the bridging sulfido ligands and the other two by the chelating tetrasulfido ligand.

There are three different types of ligand containing only sulfur atoms: terminal sulfido, bridging sulfido and chelating tetrasulfido. Each of these has a formal 2- charge. The two sulfido bridges both link the two tungsten atoms, forming a central four-membered ring with essentially equal sides but markedly acute angles at the S atoms. The ring is slightly folded, with an r.m.s. deviation of 0.222 Å for the four atoms from their mean plane. The WS4 chelate ring has an envelope conformation, with one S atom [S6 in polymorph (1)] more than 1.0 Å out of the mean plane of the other four atoms; the central S—S bond of this ligand is significantly shorter than the other two.

A search of the Cambridge Structural Database (CSD, version 5.31; Allen, 2002) shows that all previously reported structures of ditungsten (and also dimolybdenum) complexes with two bridging sulfido ligands and a chelating tetrasulfido ligand [i.e. with an M(µ-S)2M(S4) structural unit] contain exclusively sulfido (and/or oxido), disulfido and tetrasulfido ligands in various combinations, the total number of such structures (including redeterminations) being 17 with the following CSD refcodes and references: BIZVUB (Draganjac et al., 1982); COZSIT (Huang et al., 1984); DOFZIH (Cohen & Stiefel, 1985); DOFZIH01 (Chakrabarty et al., 1996); DOFZIH02 (Mukherjee et al., 1997); DOYWAN, DOYWAP, DOYWET and DOYWIX (Müller et al., 1985); FAGVIS (Coucouvanis & Hadjikyriacou, 1986); FAGVIS10 (Hadjikyriacou & Coucouvanis, 1987); KADFAW and KADFEA (Coucouvanis & Koo, 1989); SULFMO (Clegg et al., 1981); VAKGAP (Zhang et al., 1987); VAKGAP01 (Bhattacharyya et al., 1991); VOCMAB (Coucouvanis et al., 1991). These complexes, all of them anionic, thus contain only Mo/W, S and (in some cases) O atoms, and the title complex is unprecedented in this respect. There are six previous examples of complexes in which a tris(pyrazolyl)borate ligand is coordinated to an M2-S)2M unit: FIBDAV (Young et al., 1987); FIBDAV10 and GIJFUA (Roberts et al., 1988); IMUPIP and IMUPOP (Seino et al., 2003); QOZZOU (Eagle et al., 1999). Only four reported structures contain both a tris(pyrazolyl)borate ligand and a tetrasulfido ligand bonded to metal atoms: two are indium complexes (NUXHUJ: Kuchta & Parkin, 1996; ZIPQAQ: Reger & Coan, 1995) and two are molybdenum complexes (QIXHOU and QIXHUA: Seino et al., 2001); and in every case the two ligands are coordinated to a single metal centre. Individual features of the polymorphs of the title complex are similar to these various known structures, including comparable bond lengths in general, but the combination of the features is novel.

The two polymorphs differ primarily in their packing arrangements. While there is nothing remarkable about the packing in polymorph (1), the cations and anions in polymorph (2) are arranged in layers parallel to (001), as shown in Fig. 4. There are two layers in the unit-cell c-axis repeat. Each layer contains both independent cations and both independent anions. Anions in adjacent layers are related by pseudo-symmetry, alternating translations of about 10.2 and 11.3 Å relating individual symmetry-inequivalent anions in a zigzag fashion, these pseudo-translation vectors being inclined at approximately 106 and 72° to the b axis. It is possible that stacking faults in the sequence of these layers may be responsible in interaction terms for the occurrence of twinning in this polymorph, such twinning being geometrically facilitated by the fact that β is close to 90°. They do not, however, lead to any significant diffuse streaks in the diffraction pattern.

The polymorphism and features of interest in the anion geometry and packing of these crystal structures are unexpected results from an experiment originally designed to produce quite different chemical results.

Related literature top

For related literature, see: Allen (2002); Beheshti et al. (2007, 2008, 2011); Bhattacharyya et al. (1991); Chakrabarty et al. (1996); Clegg et al. (1981); Cohen & Stiefel (1985); Coucouvanis & Hadjikyriacou (1986); Coucouvanis & Koo (1989); Coucouvanis et al. (1991); Draganjac et al. (1982); Eagle et al. (1999); Hadjikyriacou & Coucouvanis (1987); Huang et al. (1984); Kuchta & Parkin (1996); Müller et al. (1985); Macrae et al. (2008); Mukherjee et al. (1997); Reger & Coan (1995); Roberts et al. (1988); Seino et al. (2001, 2003); Spek (2009); Young et al. (1987); Zhang et al. (1987); Zhao et al. (1999).

Experimental top

(Et4N)[Tp*WS3] (0.1 g, 0.14 mmol; Seino et al., 2001) was dissolved in dry acetonitrile (20 ml) and AgI (0.1 g, 0.42 mmol) was added. After stirring for ca 1 h at room temperature, the mixture was centrifuged and the supernatant was evaporated to dryness under vacuum. The product separated as a brown powder together with AgI. The precipitate was then leached with CH2Cl2 (2 x 5 ml) to separate the soluble complex from AgI. The brown supernatant liquid was evaporated to dryness. The residue was washed with diethyl ether (2 x 3 ml) and dried in vacuo to give a brown powder (66.6 mg, 50% yield based on W). Similar reactions of (Et4N)[Tp*WS3] with AgI in 1:4 molar ratio gave the same product. Analysis: calculated C 29.30, H 4.46, N 10.40%; found C 29.60, H 4.50, N 10.51%; 1H NMR (CDCl3, 400 MHz): δ 1.38–1.41 (t, 12H, CH3 in cation), 2.50 (s, 9H, CH3 in Tp*), 3.08 (s, 9H, CH3 in Tp*), 3.41–3.45 (q, 8H, CH2 in cation), 6.18 (s, 3H, CH in Tp*), B—H was not located; infrared spectrum (KBr disc): (W—S) 435 and 482 cm-1, (B—H) 2554 cm-1; UV-Vis spectrum (MeCN, λmax): 240, 302, 376 nm.

This product decomposed during crystallization attempts by slow diffusion of diethyl ether into a saturated solution in acetonitrile and acetone at room temperature. Two crystal types suitable for X-ray structure determination were obtained, subsequently found to be polymorphs, one of them from MeCN/diethyl ether and the other from acetone/diethyl ether. On leaving a solution in MeCN to stand for 24 h, air-stable pale-yellow needle-shaped crystals of the known compound (Et4N)5[Ag6I11] (Zhao et al., 1999) were obtained. After separation of these crystals by filtration, followed by slow diffusion of diethyl ether into the filtrate for 5 d at room temperature, deep-orange crystals of the title compound [polymorph (1)] were obtained. Analysis: calculated C 26.25, H 4.00, N 9.32%; found C 27.73, H 4.52, N 9.69%; 1H NMR (DMSO-d6, 400 MHz): δ 1.15–1.19 (m, 12H, CH3 of cation), 2.58 (s, 9H, CH3 in Tp*), 2.84 (s, 9H, CH3 in Tp*), 3.19–3.23 (q, 8H, CH2 of cation), 5.29 (B—H), 6.36 (s, 3H, CH in Tp*); infrared spectrum (KBr disc): (W—S) 434 and 490 cm-1, (S—S) 515 cm-1, B—H 2561 cm-1; UV-Vis spectrum (MeCN, λmax): 209, 242, 303 nm. Crystals of the second polymorph (giving essentially the same spectroscopic data) were obtained after 2 weeks by diffusion of diethyl ether into an acetone solution of the crude first product, no other compound being formed in this case.

The products of the two recrystallizations were not extensively examined to determine whether each was actually a pure single polymorph or whether a mixture was obtained in one or both cases, although several crystals from the acetone recrystallization were examined in an attempt to measure better data and the second polymorph was identified in every case.

Refinement top

H atoms were allocated in geometrically calculated positions and refined with a riding model (including free rotation about C—C bonds), and with Uiso constrained to be 1.2 (1.5 for methyl groups) times Ueq of the carrier atom; the single exception to this was the H atom attached to B in polymorph (1), the position of which was refined freely. For the lower-precision polymorph (2), which may be subject to unresolved multiple twinning, restraints (similarity and rigid-bond) were applied to all displacement parameters, and bond-length and -angle similarity restraints were applied to the tetraethylammonium cations. Several crystals of this polymorph were examined and two complete data sets were measured from different crystals. In each case the crystals were not single, with at least two components for which the same unit cell could be found in different orientations. Following a number of attempted approaches, the best result was obtained by extracting integrated intensity data for two dominant components of one crystal and then using one of these components and rejecting reflections that were overlapped with the second component. Significantly poorer refinement resulted from full multi-component data sets and other similar treatments of overlap of the component diffraction patterns.

More reflections than usual were rejected in the data integration and processing stages for polymorph (2) because of poor profile fitting and related problems; these are probably caused by twinning effects, which are suggested on the basis of unit-cell parameters and comparisons of observed and calculated structure factors by PLATON (Spek, 2009) and are likely to involve split reflection profiles.

Computing details top

For both compounds, data collection: CrysAlis PRO (Oxford Diffraction, 2009); cell refinement: CrysAlis PRO (Oxford Diffraction, 2009); data reduction: CrysAlis PRO (Oxford Diffraction, 2009); program(s) used to solve structure: SHELXTL (Sheldrick, 2008); program(s) used to refine structure: SHELXTL (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL and local programs.

Figures top
[Figure 1] Fig. 1. The asymmetric unit of polymorph (1) with atom labels and 40% probability ellipsoids for non-H atoms.
[Figure 2] Fig. 2. One cation and one anion of polymorph (2) with atom labels and 40% probability ellipsoids for non-H atoms.
[Figure 3] Fig. 3. The other cation and anion of the asymmetric unit of polymorph (2) with atom labels and 40% probability ellipsoids for non-H atoms.
[Figure 4] Fig. 4. The packing of polymorph (2), viewed approximately along the a axis. H atoms are omitted for clarity.
(1) tetraethylammonium [hydrogen tris(3,5-dimethylpyrazolyl)borato]di-µ2-sulfido-disulfido(η2- tetrasulfido)ditungsten(V) top
Crystal data top
(C8H20N)[W2S4(S)4(C15H22BN6)]F(000) = 2040
Mr = 1051.63Dx = 2.008 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 11017 reflections
a = 10.5173 (2) Åθ = 2.8–28.5°
b = 17.5635 (3) ŵ = 7.12 mm1
c = 19.4889 (4) ÅT = 150 K
β = 104.878 (2)°Plate, intense orange
V = 3479.31 (11) Å30.32 × 0.24 × 0.08 mm
Z = 4
Data collection top
Oxford Diffraction Gemini A Ultra
diffractometer
7333 independent reflections
Radiation source: sealed tube with Enhance optics5814 reflections with I > 2σ(I)
None monochromatorRint = 0.025
Detector resolution: 10.3968 pixels mm-1θmax = 28.6°, θmin = 2.8°
ω scansh = 1414
Absorption correction: multi-scan
(CrysAlis PRO; Oxford Diffraction, 2009)
k = 1523
Tmin = 0.210, Tmax = 0.600l = 2025
17702 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.036Hydrogen site location: mixed
wR(F2) = 0.098Geom
S = 1.09 w = 1/[σ2(Fo2) + (0.0543P)2 + 6.0205P]
where P = (Fo2 + 2Fc2)/3
7333 reflections(Δ/σ)max = 0.002
383 parametersΔρmax = 2.98 e Å3
0 restraintsΔρmin = 1.86 e Å3
Crystal data top
(C8H20N)[W2S4(S)4(C15H22BN6)]V = 3479.31 (11) Å3
Mr = 1051.63Z = 4
Monoclinic, P21/nMo Kα radiation
a = 10.5173 (2) ŵ = 7.12 mm1
b = 17.5635 (3) ÅT = 150 K
c = 19.4889 (4) Å0.32 × 0.24 × 0.08 mm
β = 104.878 (2)°
Data collection top
Oxford Diffraction Gemini A Ultra
diffractometer
7333 independent reflections
Absorption correction: multi-scan
(CrysAlis PRO; Oxford Diffraction, 2009)
5814 reflections with I > 2σ(I)
Tmin = 0.210, Tmax = 0.600Rint = 0.025
17702 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0360 restraints
wR(F2) = 0.098Geom
S = 1.09Δρmax = 2.98 e Å3
7333 reflectionsΔρmin = 1.86 e Å3
383 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
W10.51632 (2)0.731946 (15)0.091792 (13)0.02064 (8)
W20.35462 (3)0.822902 (15)0.156258 (14)0.02412 (9)
S10.36663 (18)0.70837 (11)0.00279 (10)0.0329 (4)
S20.42433 (18)0.69878 (10)0.18395 (9)0.0282 (4)
S30.51514 (16)0.86402 (9)0.10102 (9)0.0256 (4)
S40.1724 (2)0.81905 (13)0.08127 (12)0.0472 (5)
S50.3068 (2)0.79876 (15)0.26935 (11)0.0487 (5)
S60.1976 (2)0.88776 (14)0.28670 (13)0.0553 (6)
S70.3292 (2)0.97015 (16)0.28946 (13)0.0591 (6)
S80.3931 (2)0.95092 (11)0.19903 (11)0.0401 (5)
N10.7002 (5)0.5867 (3)0.0950 (3)0.0233 (11)
N20.5764 (5)0.6097 (3)0.0973 (3)0.0242 (12)
N30.7669 (5)0.7002 (3)0.0342 (3)0.0228 (11)
N40.6612 (5)0.7486 (3)0.0270 (3)0.0231 (12)
N50.8220 (5)0.6928 (3)0.1665 (3)0.0238 (12)
N60.7185 (5)0.7352 (3)0.1775 (3)0.0220 (11)
N70.6066 (7)0.5338 (4)0.3631 (3)0.0379 (15)
B10.8068 (8)0.6463 (4)0.0989 (4)0.0248 (16)
H00.894 (8)0.621 (4)0.107 (4)0.037*
C10.5047 (7)0.5427 (4)0.0945 (3)0.0279 (15)
C20.5848 (7)0.4816 (4)0.0913 (3)0.0290 (15)
H20.56040.42940.08910.035*
C30.7078 (7)0.5105 (4)0.0919 (3)0.0271 (15)
C40.3630 (7)0.5414 (4)0.0934 (4)0.0355 (17)
H4A0.32660.49080.07860.053*
H4B0.31580.57970.05990.053*
H4C0.35300.55270.14100.053*
C50.8316 (7)0.4689 (4)0.0909 (4)0.0349 (17)
H5A0.86880.49060.05400.052*
H5B0.81180.41490.08090.052*
H5C0.89530.47410.13720.052*
C60.6556 (7)0.7898 (4)0.0321 (3)0.0260 (14)
C70.7560 (7)0.7679 (4)0.0614 (4)0.0333 (16)
H70.77420.78780.10320.040*
C80.8248 (7)0.7117 (4)0.0185 (3)0.0274 (15)
C90.5527 (8)0.8497 (5)0.0610 (4)0.0405 (19)
H9A0.46640.83120.05810.061*
H9B0.55070.86040.11060.061*
H9C0.57450.89640.03290.061*
C100.9432 (8)0.6671 (5)0.0258 (4)0.0398 (19)
H10A1.02030.68210.01190.060*
H10B0.95950.67770.07220.060*
H10C0.92680.61260.02190.060*
C110.7656 (7)0.7696 (4)0.2410 (4)0.0285 (15)
C120.8954 (7)0.7506 (4)0.2695 (4)0.0332 (17)
H120.95050.76770.31340.040*
C130.9301 (7)0.7015 (4)0.2211 (4)0.0295 (15)
C140.6887 (8)0.8246 (4)0.2740 (4)0.0378 (18)
H14A0.67010.87080.24490.057*
H14B0.74030.83790.32190.057*
H14C0.60570.80100.27670.057*
C151.0570 (7)0.6618 (5)0.2252 (4)0.0412 (19)
H15A1.04410.60670.22710.062*
H15B1.12270.67830.26800.062*
H15C1.08770.67440.18310.062*
C160.6608 (9)0.4640 (5)0.4023 (5)0.053 (2)
H16A0.64270.46620.44960.063*
H16B0.75760.46500.40990.063*
C170.6107 (10)0.3876 (5)0.3684 (6)0.064 (3)
H17A0.51690.38240.36610.096*
H17B0.65970.34620.39710.096*
H17C0.62320.38530.32030.096*
C180.6651 (8)0.6005 (5)0.4059 (4)0.046 (2)
H18A0.76130.59950.41150.056*
H18B0.65010.59530.45370.056*
C190.6139 (12)0.6769 (5)0.3764 (5)0.064 (3)
H19A0.63260.68430.33010.096*
H19B0.65710.71710.40910.096*
H19C0.51870.67910.37090.096*
C200.4573 (8)0.5372 (5)0.3473 (5)0.047 (2)
H20A0.42640.58340.31890.057*
H20B0.42030.49260.31780.057*
C210.4031 (9)0.5382 (6)0.4124 (5)0.059 (3)
H21A0.42960.49150.43990.088*
H21B0.30690.54120.39750.088*
H21C0.43800.58250.44180.088*
C220.6342 (9)0.5368 (5)0.2892 (4)0.046 (2)
H22A0.59560.49070.26260.055*
H22B0.58730.58140.26350.055*
C230.7734 (9)0.5417 (5)0.2873 (5)0.053 (2)
H23A0.81220.58860.31090.080*
H23B0.77880.54200.23790.080*
H23C0.82150.49760.31200.080*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
W10.02621 (14)0.01919 (14)0.01782 (13)0.00071 (10)0.00801 (11)0.00217 (10)
W20.02558 (14)0.02424 (15)0.02436 (15)0.00190 (11)0.00971 (12)0.00499 (11)
S10.0360 (10)0.0329 (10)0.0279 (9)0.0038 (8)0.0049 (8)0.0060 (8)
S20.0402 (10)0.0239 (9)0.0235 (8)0.0038 (7)0.0137 (8)0.0019 (7)
S30.0318 (8)0.0211 (8)0.0272 (8)0.0004 (7)0.0135 (7)0.0018 (7)
S40.0486 (12)0.0546 (14)0.0385 (11)0.0026 (10)0.0113 (10)0.0023 (10)
S50.0499 (12)0.0691 (15)0.0317 (10)0.0025 (11)0.0189 (10)0.0040 (10)
S60.0605 (14)0.0539 (14)0.0579 (14)0.0019 (11)0.0266 (12)0.0052 (11)
S70.0563 (14)0.0701 (17)0.0588 (15)0.0020 (12)0.0293 (12)0.0122 (12)
S80.0437 (11)0.0303 (10)0.0489 (12)0.0048 (8)0.0167 (10)0.0128 (9)
N10.027 (3)0.023 (3)0.019 (3)0.002 (2)0.004 (2)0.003 (2)
N20.033 (3)0.020 (3)0.022 (3)0.003 (2)0.011 (2)0.000 (2)
N30.026 (3)0.019 (3)0.025 (3)0.003 (2)0.010 (2)0.001 (2)
N40.029 (3)0.020 (3)0.024 (3)0.005 (2)0.013 (2)0.000 (2)
N50.026 (3)0.023 (3)0.022 (3)0.001 (2)0.006 (2)0.002 (2)
N60.031 (3)0.018 (3)0.017 (3)0.003 (2)0.006 (2)0.004 (2)
N70.051 (4)0.039 (4)0.027 (3)0.010 (3)0.016 (3)0.008 (3)
B10.029 (4)0.019 (4)0.025 (4)0.001 (3)0.005 (3)0.001 (3)
C10.043 (4)0.019 (3)0.023 (3)0.009 (3)0.011 (3)0.000 (3)
C20.045 (4)0.021 (4)0.023 (3)0.004 (3)0.012 (3)0.001 (3)
C30.040 (4)0.020 (3)0.020 (3)0.003 (3)0.005 (3)0.005 (3)
C40.042 (4)0.030 (4)0.038 (4)0.007 (3)0.016 (4)0.004 (3)
C50.044 (4)0.021 (4)0.042 (4)0.003 (3)0.014 (4)0.003 (3)
C60.033 (4)0.028 (4)0.019 (3)0.008 (3)0.011 (3)0.002 (3)
C70.041 (4)0.041 (4)0.024 (3)0.001 (3)0.019 (3)0.003 (3)
C80.033 (4)0.033 (4)0.022 (3)0.003 (3)0.016 (3)0.001 (3)
C90.050 (5)0.045 (5)0.030 (4)0.012 (4)0.015 (4)0.014 (3)
C100.042 (4)0.045 (5)0.042 (4)0.011 (4)0.028 (4)0.001 (4)
C110.031 (4)0.027 (4)0.027 (4)0.004 (3)0.006 (3)0.001 (3)
C120.044 (4)0.030 (4)0.022 (3)0.008 (3)0.002 (3)0.004 (3)
C130.038 (4)0.018 (3)0.029 (4)0.000 (3)0.001 (3)0.008 (3)
C140.054 (5)0.035 (4)0.024 (4)0.003 (4)0.010 (4)0.013 (3)
C150.033 (4)0.044 (5)0.042 (4)0.003 (4)0.001 (4)0.001 (4)
C160.057 (5)0.060 (6)0.048 (5)0.015 (5)0.027 (5)0.015 (4)
C170.068 (6)0.033 (5)0.089 (7)0.011 (4)0.018 (6)0.003 (5)
C180.043 (5)0.060 (6)0.037 (4)0.005 (4)0.012 (4)0.008 (4)
C190.091 (8)0.044 (6)0.057 (6)0.007 (5)0.017 (6)0.011 (5)
C200.043 (5)0.042 (5)0.054 (5)0.008 (4)0.007 (4)0.006 (4)
C210.047 (5)0.058 (6)0.078 (7)0.006 (4)0.029 (5)0.016 (5)
C220.062 (5)0.045 (5)0.030 (4)0.005 (4)0.010 (4)0.003 (4)
C230.067 (6)0.049 (5)0.056 (6)0.014 (5)0.037 (5)0.010 (4)
Geometric parameters (Å, º) top
W1—S12.1348 (18)C7—H70.950
W1—S22.3224 (16)C7—C81.374 (10)
W1—S32.3269 (17)C8—C101.509 (9)
W1—N22.232 (5)C9—H9A0.980
W1—N42.235 (5)C9—H9B0.980
W1—N62.343 (5)C9—H9C0.980
W2—S22.3190 (18)C10—H10A0.980
W2—S32.3374 (16)C10—H10B0.980
W2—S42.091 (2)C10—H10C0.980
W2—S52.421 (2)C11—C121.376 (10)
W2—S82.3960 (19)C11—C141.506 (10)
S5—S62.019 (3)C12—H120.950
S6—S71.994 (4)C12—C131.393 (10)
S7—S82.069 (3)C13—C151.490 (10)
N1—N21.375 (7)C14—H14A0.980
N1—B11.522 (9)C14—H14B0.980
N1—C31.342 (9)C14—H14C0.980
N2—C11.391 (8)C15—H15A0.980
N3—N41.377 (7)C15—H15B0.980
N3—B11.547 (9)C15—H15C0.980
N3—C81.336 (8)C16—H16A0.990
N4—C61.348 (8)C16—H16B0.990
N5—N61.380 (7)C16—C171.528 (13)
N5—B11.523 (9)C17—H17A0.980
N5—C131.352 (9)C17—H17B0.980
N6—C111.352 (8)C17—H17C0.980
N7—C161.478 (11)C18—H18A0.990
N7—C181.478 (10)C18—H18B0.990
N7—C201.522 (10)C18—C191.503 (13)
N7—C221.542 (9)C19—H19A0.980
B1—H00.99 (8)C19—H19B0.980
C1—C21.376 (10)C19—H19C0.980
C1—C41.486 (10)C20—H20A0.990
C2—H20.950C20—H20B0.990
C2—C31.388 (10)C20—C211.519 (12)
C3—C51.498 (10)C21—H21A0.980
C4—H4A0.980C21—H21B0.980
C4—H4B0.980C21—H21C0.980
C4—H4C0.980C22—H22A0.990
C5—H5A0.980C22—H22B0.990
C5—H5B0.980C22—C231.476 (12)
C5—H5C0.980C23—H23A0.980
C6—C71.377 (9)C23—H23B0.980
C6—C91.511 (10)C23—H23C0.980
S1—W1—S2104.94 (7)C6—C7—C8106.8 (6)
S1—W1—S3104.05 (7)H7—C7—C8126.6
S1—W1—N289.53 (15)N3—C8—C7107.7 (6)
S1—W1—N489.77 (15)N3—C8—C10123.0 (6)
S1—W1—N6162.42 (14)C7—C8—C10129.3 (6)
S2—W1—S3100.29 (6)C6—C9—H9A109.5
S2—W1—N283.74 (13)C6—C9—H9B109.5
S2—W1—N4161.83 (15)C6—C9—H9C109.5
S2—W1—N686.39 (13)H9A—C9—H9B109.5
S3—W1—N2164.13 (15)H9A—C9—H9C109.5
S3—W1—N486.05 (14)H9B—C9—H9C109.5
S3—W1—N686.69 (13)C8—C10—H10A109.5
N2—W1—N485.82 (19)C8—C10—H10B109.5
N2—W1—N678.20 (19)C8—C10—H10C109.5
N4—W1—N676.93 (19)H10A—C10—H10B109.5
S2—W2—S3100.08 (6)H10A—C10—H10C109.5
S2—W2—S4108.08 (8)H10B—C10—H10C109.5
S2—W2—S575.55 (7)N6—C11—C12110.7 (6)
S2—W2—S8141.82 (7)N6—C11—C14124.6 (6)
S3—W2—S4109.19 (7)C12—C11—C14124.7 (6)
S3—W2—S5144.77 (7)C11—C12—H12126.8
S3—W2—S878.04 (6)C11—C12—C13106.4 (6)
S4—W2—S5105.28 (8)H12—C12—C13126.8
S4—W2—S8108.43 (8)N5—C13—C12106.8 (6)
S5—W2—S884.47 (8)N5—C13—C15123.3 (7)
W1—S2—W275.75 (5)C12—C13—C15129.8 (7)
W1—S3—W275.31 (5)C11—C14—H14A109.5
W2—S5—S6106.08 (12)C11—C14—H14B109.5
S5—S6—S798.36 (14)C11—C14—H14C109.5
S6—S7—S8103.51 (14)H14A—C14—H14B109.5
W2—S8—S7112.75 (12)H14A—C14—H14C109.5
N2—N1—B1119.2 (5)H14B—C14—H14C109.5
N2—N1—C3111.3 (5)C13—C15—H15A109.5
B1—N1—C3129.5 (6)C13—C15—H15B109.5
W1—N2—N1122.7 (4)C13—C15—H15C109.5
W1—N2—C1131.9 (4)H15A—C15—H15B109.5
N1—N2—C1104.9 (5)H15A—C15—H15C109.5
N4—N3—B1120.3 (5)H15B—C15—H15C109.5
N4—N3—C8110.0 (5)N7—C16—H16A108.0
B1—N3—C8129.5 (6)N7—C16—H16B108.0
W1—N4—N3120.7 (4)N7—C16—C17117.4 (8)
W1—N4—C6131.8 (4)H16A—C16—H16B107.2
N3—N4—C6106.0 (5)H16A—C16—C17108.0
N6—N5—B1120.8 (5)H16B—C16—C17108.0
N6—N5—C13110.7 (5)C16—C17—H17A109.5
B1—N5—C13128.5 (6)C16—C17—H17B109.5
W1—N6—N5118.9 (4)C16—C17—H17C109.5
W1—N6—C11135.7 (4)H17A—C17—H17B109.5
N5—N6—C11105.4 (5)H17A—C17—H17C109.5
C16—N7—C18108.5 (7)H17B—C17—H17C109.5
C16—N7—C20112.2 (6)N7—C18—H18A108.3
C16—N7—C22111.7 (6)N7—C18—H18B108.3
C18—N7—C20110.0 (6)N7—C18—C19115.9 (7)
C18—N7—C22110.4 (6)H18A—C18—H18B107.4
C20—N7—C22104.0 (6)H18A—C18—C19108.3
N1—B1—N3109.7 (6)H18B—C18—C19108.3
N1—B1—N5109.0 (5)C18—C19—H19A109.5
N1—B1—H0110 (4)C18—C19—H19B109.5
N3—B1—N5108.8 (5)C18—C19—H19C109.5
N3—B1—H0117 (4)H19A—C19—H19B109.5
N5—B1—H0102 (4)H19A—C19—H19C109.5
N2—C1—C2109.3 (6)H19B—C19—H19C109.5
N2—C1—C4123.1 (6)N7—C20—H20A108.6
C2—C1—C4127.6 (6)N7—C20—H20B108.6
C1—C2—H2126.5N7—C20—C21114.8 (7)
C1—C2—C3107.1 (6)H20A—C20—H20B107.5
H2—C2—C3126.5H20A—C20—C21108.6
N1—C3—C2107.4 (6)H20B—C20—C21108.6
N1—C3—C5123.3 (6)C20—C21—H21A109.5
C2—C3—C5129.3 (6)C20—C21—H21B109.5
C1—C4—H4A109.5C20—C21—H21C109.5
C1—C4—H4B109.5H21A—C21—H21B109.5
C1—C4—H4C109.5H21A—C21—H21C109.5
H4A—C4—H4B109.5H21B—C21—H21C109.5
H4A—C4—H4C109.5N7—C22—H22A108.1
H4B—C4—H4C109.5N7—C22—H22B108.1
C3—C5—H5A109.5N7—C22—C23116.8 (7)
C3—C5—H5B109.5H22A—C22—H22B107.3
C3—C5—H5C109.5H22A—C22—C23108.1
H5A—C5—H5B109.5H22B—C22—C23108.1
H5A—C5—H5C109.5C22—C23—H23A109.5
H5B—C5—H5C109.5C22—C23—H23B109.5
N4—C6—C7109.5 (6)C22—C23—H23C109.5
N4—C6—C9124.2 (6)H23A—C23—H23B109.5
C7—C6—C9126.3 (6)H23A—C23—H23C109.5
C6—C7—H7126.6H23B—C23—H23C109.5
S3—W2—S2—W122.11 (6)S3—W1—N6—C1148.0 (6)
S4—W2—S2—W192.05 (7)N2—W1—N6—N541.9 (4)
S5—W2—S2—W1166.29 (7)N2—W1—N6—C11136.9 (6)
S8—W2—S2—W1105.53 (9)N4—W1—N6—N546.5 (4)
S1—W1—S2—W285.46 (7)N4—W1—N6—C11134.7 (6)
S3—W1—S2—W222.23 (6)N2—N1—B1—N362.5 (7)
N2—W1—S2—W2173.29 (15)N2—N1—B1—N556.6 (7)
N4—W1—S2—W2131.4 (5)C3—N1—B1—N3120.3 (7)
N6—W1—S2—W2108.20 (13)C3—N1—B1—N5120.6 (7)
S1—W1—S3—W286.30 (6)N6—N5—B1—N161.5 (7)
S2—W1—S3—W222.09 (6)N6—N5—B1—N358.1 (7)
N2—W1—S3—W2125.6 (5)C13—N5—B1—N1120.4 (7)
N4—W1—S3—W2175.08 (15)C13—N5—B1—N3119.9 (7)
N6—W1—S3—W2107.81 (13)N4—N3—B1—N167.1 (7)
S2—W2—S3—W122.11 (6)N4—N3—B1—N552.0 (8)
S4—W2—S3—W191.20 (8)C8—N3—B1—N1116.7 (7)
S5—W2—S3—W1101.30 (12)C8—N3—B1—N5124.2 (7)
S8—W2—S3—W1163.23 (7)W1—N2—C1—C2172.6 (4)
S2—W2—S5—S6170.33 (13)W1—N2—C1—C45.9 (9)
S3—W2—S5—S6102.61 (15)N1—N2—C1—C20.5 (7)
S4—W2—S5—S665.15 (14)N1—N2—C1—C4177.9 (6)
S8—W2—S5—S642.48 (12)N2—C1—C2—C30.1 (7)
W2—S5—S6—S761.89 (15)C4—C1—C2—C3178.3 (7)
S5—S6—S7—S849.38 (17)N2—N1—C3—C20.7 (7)
S6—S7—S8—W221.36 (18)N2—N1—C3—C5178.3 (6)
S2—W2—S8—S769.86 (15)B1—N1—C3—C2178.1 (6)
S3—W2—S8—S7161.01 (13)B1—N1—C3—C50.9 (10)
S4—W2—S8—S792.52 (13)C1—C2—C3—N10.4 (7)
S5—W2—S8—S711.77 (13)C1—C2—C3—C5178.6 (7)
B1—N1—N2—W18.5 (7)W1—N4—C6—C7165.9 (5)
B1—N1—N2—C1178.5 (5)W1—N4—C6—C913.4 (11)
C3—N1—N2—W1173.8 (4)N3—N4—C6—C70.2 (8)
C3—N1—N2—C10.8 (7)N3—N4—C6—C9179.1 (7)
S1—W1—N2—N1119.4 (4)N4—C6—C7—C80.1 (9)
S1—W1—N2—C151.5 (5)C9—C6—C7—C8179.4 (7)
S2—W1—N2—N1135.5 (4)N4—N3—C8—C70.6 (8)
S2—W1—N2—C153.6 (5)N4—N3—C8—C10179.6 (7)
S3—W1—N2—N129.8 (8)B1—N3—C8—C7177.0 (7)
S3—W1—N2—C1159.4 (4)B1—N3—C8—C103.9 (11)
N4—W1—N2—N129.6 (4)C6—C7—C8—N30.4 (8)
N4—W1—N2—C1141.3 (6)C6—C7—C8—C10179.4 (8)
N6—W1—N2—N147.9 (4)W1—N6—C11—C12179.6 (5)
N6—W1—N2—C1141.2 (6)W1—N6—C11—C143.6 (11)
B1—N3—N4—W115.0 (8)N5—N6—C11—C120.7 (7)
B1—N3—N4—C6177.3 (6)N5—N6—C11—C14177.4 (6)
C8—N3—N4—W1168.1 (4)N6—C11—C12—C130.4 (8)
C8—N3—N4—C60.5 (7)C14—C11—C12—C13177.1 (7)
S1—W1—N4—N3115.3 (4)N6—N5—C13—C120.5 (7)
S1—W1—N4—C648.7 (6)N6—N5—C13—C15178.9 (6)
S2—W1—N4—N329.3 (8)B1—N5—C13—C12178.7 (6)
S2—W1—N4—C6166.7 (4)B1—N5—C13—C152.9 (11)
S3—W1—N4—N3140.6 (5)C11—C12—C13—N50.1 (8)
S3—W1—N4—C655.4 (6)C11—C12—C13—C15178.3 (7)
N2—W1—N4—N325.7 (5)C18—N7—C16—C17178.4 (7)
N2—W1—N4—C6138.3 (6)C20—N7—C16—C1756.7 (9)
N6—W1—N4—N353.1 (5)C22—N7—C16—C1759.7 (9)
N6—W1—N4—C6142.9 (6)C16—N7—C18—C19175.9 (7)
B1—N5—N6—W11.7 (7)C20—N7—C18—C1952.8 (9)
B1—N5—N6—C11179.1 (6)C22—N7—C18—C1961.4 (9)
C13—N5—N6—W1179.9 (4)C16—N7—C20—C2161.3 (9)
C13—N5—N6—C110.7 (7)C18—N7—C20—C2159.5 (9)
S1—W1—N6—N54.7 (8)C22—N7—C20—C21177.7 (7)
S1—W1—N6—C11176.4 (5)C16—N7—C22—C2364.2 (10)
S2—W1—N6—N5126.3 (4)C18—N7—C22—C2356.6 (10)
S2—W1—N6—C1152.6 (6)C20—N7—C22—C23174.5 (8)
S3—W1—N6—N5133.2 (4)
(2) tetraethylammonium [hydrogen tris(3,5-dimethylpyrazolyl)borato]di-µ2-sulfido-disulfido(η2- tetrasulfido)ditungsten(V) top
Crystal data top
(C8H20N)[W2S4(S)4(C15H22BN6)]F(000) = 4080
Mr = 1051.63Dx = 2.010 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 6724 reflections
a = 17.8602 (10) Åθ = 3.0–26.9°
b = 18.8742 (10) ŵ = 7.12 mm1
c = 20.6188 (10) ÅT = 150 K
β = 90.343 (5)°Plate, orange
V = 6950.4 (6) Å30.52 × 0.38 × 0.04 mm
Z = 8
Data collection top
Oxford Diffraction Gemini A Ultra
diffractometer
11129 independent reflections
Radiation source: sealed tube with Enhance optics6168 reflections with I > 2σ(I)
None monochromatorRint = 0.119
Detector resolution: 10.3968 pixels mm-1θmax = 27.0°, θmin = 3.1°
ω scansh = 2218
Absorption correction: multi-scan
(CrysAlis PRO; Oxford Diffraction, 2009)
k = 2123
Tmin = 0.120, Tmax = 0.765l = 2225
23985 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.066Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.171H-atom parameters constrained
S = 0.97 w = 1/[σ2(Fo2) + (0.0768P)2]
where P = (Fo2 + 2Fc2)/3
11129 reflections(Δ/σ)max = 0.001
759 parametersΔρmax = 3.82 e Å3
760 restraintsΔρmin = 2.26 e Å3
Crystal data top
(C8H20N)[W2S4(S)4(C15H22BN6)]V = 6950.4 (6) Å3
Mr = 1051.63Z = 8
Monoclinic, P21/nMo Kα radiation
a = 17.8602 (10) ŵ = 7.12 mm1
b = 18.8742 (10) ÅT = 150 K
c = 20.6188 (10) Å0.52 × 0.38 × 0.04 mm
β = 90.343 (5)°
Data collection top
Oxford Diffraction Gemini A Ultra
diffractometer
11129 independent reflections
Absorption correction: multi-scan
(CrysAlis PRO; Oxford Diffraction, 2009)
6168 reflections with I > 2σ(I)
Tmin = 0.120, Tmax = 0.765Rint = 0.119
23985 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.066760 restraints
wR(F2) = 0.171H-atom parameters constrained
S = 0.97Δρmax = 3.82 e Å3
11129 reflectionsΔρmin = 2.26 e Å3
759 parameters
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
W10.66878 (4)0.28456 (4)0.13733 (3)0.0239 (2)
W20.77677 (4)0.32135 (4)0.23453 (4)0.0306 (2)
W30.33782 (4)0.52581 (4)0.32667 (4)0.0287 (2)
W40.22327 (4)0.50403 (4)0.23227 (4)0.0313 (2)
S10.7460 (3)0.2757 (3)0.0585 (2)0.0412 (12)
S20.6959 (3)0.3959 (2)0.1783 (2)0.0349 (11)
S30.7190 (2)0.2122 (2)0.2173 (2)0.0302 (10)
S40.8674 (5)0.3205 (6)0.1907 (5)0.115 (3)
S50.7959 (3)0.2581 (3)0.3370 (3)0.0593 (16)
S60.8058 (5)0.3261 (4)0.4147 (4)0.095 (3)
S70.8588 (4)0.4066 (4)0.3743 (4)0.092 (3)
S80.7864 (3)0.4285 (3)0.2988 (3)0.0526 (15)
S110.2636 (3)0.5353 (3)0.4063 (2)0.0423 (12)
S120.2993 (3)0.4189 (3)0.2809 (2)0.0345 (11)
S130.2932 (3)0.6058 (3)0.2505 (2)0.0377 (12)
S140.1332 (4)0.5152 (5)0.2832 (4)0.098 (2)
S150.1999 (3)0.5653 (4)0.1318 (3)0.0679 (17)
S160.1681 (6)0.5085 (7)0.0574 (5)0.135 (4)
S170.1225 (8)0.4349 (5)0.1019 (4)0.134 (4)
S180.2022 (4)0.4028 (4)0.1652 (3)0.0741 (19)
N10.5333 (8)0.1852 (7)0.0934 (7)0.029 (3)
N20.6082 (8)0.1845 (8)0.1067 (7)0.035 (3)
N30.5108 (9)0.3109 (8)0.0658 (8)0.038 (3)
N40.5851 (8)0.3387 (8)0.0724 (7)0.035 (3)
N50.4918 (7)0.2689 (8)0.1753 (7)0.029 (3)
N60.5608 (7)0.2895 (8)0.2000 (7)0.027 (3)
N110.4797 (8)0.6187 (8)0.3695 (7)0.033 (3)
N120.4032 (8)0.6189 (8)0.3637 (8)0.038 (3)
N130.4933 (7)0.4875 (7)0.3930 (7)0.027 (3)
N140.4195 (8)0.4647 (8)0.3835 (7)0.034 (3)
N150.5132 (7)0.5352 (7)0.2829 (7)0.027 (3)
N160.4440 (8)0.5161 (8)0.2588 (7)0.034 (3)
C10.6374 (10)0.1205 (10)0.0929 (8)0.032 (4)
C20.5735 (11)0.0777 (10)0.0764 (9)0.039 (4)
H20.57440.02820.06810.047*
C30.5108 (10)0.1201 (10)0.0747 (8)0.033 (4)
C40.7157 (10)0.0981 (10)0.0975 (9)0.037 (4)
H4A0.74850.13910.09110.055*
H4B0.72590.06250.06400.055*
H4C0.72530.07760.14040.055*
C50.4336 (11)0.0987 (11)0.0613 (10)0.049 (5)
H5A0.41140.13090.02930.073*
H5B0.40460.10070.10150.073*
H5C0.43300.05030.04430.073*
C60.5911 (11)0.3956 (10)0.0321 (9)0.040 (4)
C70.5252 (11)0.4035 (10)0.0001 (9)0.043 (4)
H70.51550.43770.03290.051*
C80.4751 (11)0.3548 (10)0.0220 (9)0.036 (4)
C90.6593 (11)0.4352 (11)0.0235 (9)0.045 (5)
H9A0.66940.46350.06250.067*
H9B0.65390.46680.01400.067*
H9C0.70090.40240.01620.067*
C100.3969 (12)0.3401 (12)0.0040 (11)0.056 (6)
H10A0.37980.37530.02770.085*
H10B0.36550.34250.04270.085*
H10C0.39340.29260.01510.085*
C110.5467 (10)0.3105 (10)0.2634 (9)0.033 (4)
C120.4721 (11)0.3000 (10)0.2775 (10)0.042 (4)
H120.44870.31020.31760.051*
C130.4377 (10)0.2726 (11)0.2240 (10)0.041 (4)
C140.6020 (11)0.3401 (11)0.3111 (9)0.041 (5)
H14A0.64320.30640.31710.062*
H14B0.57720.34820.35270.062*
H14C0.62180.38500.29470.062*
C150.3595 (9)0.2510 (11)0.2095 (10)0.045 (5)
H15A0.33290.24230.25020.068*
H15B0.35970.20760.18350.068*
H15C0.33420.28880.18540.068*
N70.5696 (9)0.1014 (10)0.3791 (7)0.099 (6)
C160.5197 (14)0.0889 (19)0.3212 (10)0.140 (10)
H16A0.49540.04220.32740.169*
H16B0.47950.12490.32250.169*
C170.5506 (19)0.0896 (19)0.2548 (11)0.124 (12)
H17A0.55240.13850.23880.186*
H17B0.51850.06120.22610.186*
H17C0.60120.06970.25540.186*
C180.6062 (17)0.1733 (13)0.3769 (12)0.119 (9)
H18A0.63980.17440.33890.143*
H18B0.56660.20910.36930.143*
C190.651 (2)0.1959 (19)0.4354 (17)0.154 (16)
H19A0.61680.20650.47120.231*
H19B0.68010.23820.42480.231*
H19C0.68490.15750.44830.231*
C200.5181 (13)0.0984 (14)0.4380 (11)0.103 (8)
H20A0.48890.05390.43590.124*
H20B0.54960.09640.47770.124*
C210.4644 (16)0.1593 (16)0.4444 (18)0.140 (13)
H21A0.48910.19860.46710.211*
H21B0.42050.14410.46910.211*
H21C0.44840.17500.40120.211*
C220.6279 (13)0.0444 (13)0.3820 (13)0.113 (8)
H22A0.66380.05670.41700.136*
H22B0.65580.04520.34070.136*
C230.6016 (19)0.0304 (14)0.393 (2)0.152 (14)
H23A0.57050.03190.43240.228*
H23B0.64510.06150.39930.228*
H23C0.57220.04650.35590.228*
C310.3805 (11)0.6862 (11)0.3814 (10)0.044 (4)
C320.4435 (10)0.7245 (10)0.4001 (9)0.037 (4)
H320.44460.77180.41590.044*
C330.5031 (11)0.6813 (10)0.3915 (10)0.041 (4)
C340.3005 (10)0.7070 (11)0.3869 (12)0.056 (6)
H34A0.28590.73530.34900.083*
H34B0.29350.73510.42640.083*
H34C0.26930.66430.38900.083*
C350.5847 (10)0.6981 (11)0.4031 (9)0.042 (5)
H35A0.60380.66900.43900.062*
H35B0.59010.74830.41410.062*
H35C0.61320.68780.36370.062*
C360.4137 (9)0.4047 (9)0.4219 (8)0.028 (3)
C370.4810 (9)0.3928 (9)0.4527 (8)0.027 (3)
H370.49200.35510.48170.033*
C380.5291 (9)0.4446 (9)0.4340 (9)0.028 (4)
C390.3423 (10)0.3652 (12)0.4299 (10)0.047 (5)
H39A0.30510.39600.45020.071*
H39B0.35100.32360.45750.071*
H39C0.32390.34980.38740.071*
C400.6113 (10)0.4544 (11)0.4525 (9)0.041 (5)
H40A0.62630.41720.48310.061*
H40B0.61820.50090.47290.061*
H40C0.64230.45140.41350.061*
C410.4538 (9)0.5006 (10)0.1951 (8)0.033 (4)
C420.5302 (9)0.5104 (9)0.1788 (9)0.031 (4)
H420.55320.50190.13810.038*
C430.5637 (9)0.5347 (10)0.2344 (9)0.031 (4)
C440.3949 (9)0.4754 (11)0.1485 (8)0.038 (5)
H44A0.38220.42600.15820.057*
H44B0.41400.47860.10410.057*
H44C0.35020.50500.15260.057*
C450.6446 (8)0.5564 (9)0.2456 (9)0.032 (4)
H45A0.64660.60630.25860.048*
H45B0.67290.54990.20540.048*
H45C0.66660.52690.27990.048*
N170.0750 (7)0.2969 (7)0.3417 (6)0.048 (4)
C460.1438 (10)0.2517 (11)0.3479 (9)0.062 (5)
H46A0.14700.22160.30870.075*
H46B0.18790.28340.34780.075*
C470.150 (2)0.2046 (17)0.4056 (15)0.143 (15)
H47A0.10290.20580.42970.215*
H47B0.19090.22110.43360.215*
H47C0.16020.15600.39140.215*
C480.0802 (12)0.3372 (12)0.2786 (9)0.075 (6)
H48A0.12780.36410.27980.090*
H48B0.08470.30180.24350.090*
C490.0201 (13)0.3876 (15)0.2592 (14)0.113 (12)
H49A0.02170.36130.23960.169*
H49B0.03990.42150.22760.169*
H49C0.00240.41330.29750.169*
C500.0049 (11)0.2515 (11)0.3396 (10)0.070 (6)
H50A0.00180.22460.38070.084*
H50B0.03920.28320.33750.084*
C510.0001 (15)0.2001 (12)0.2844 (12)0.081 (8)
H51A0.01010.22480.24360.122*
H51B0.05050.17950.28280.122*
H51C0.03680.16220.29080.122*
C520.0679 (10)0.3474 (11)0.3990 (10)0.065 (6)
H52A0.02550.37990.39030.077*
H52B0.05490.31920.43790.077*
C530.1358 (13)0.3914 (13)0.4148 (12)0.084 (9)
H53A0.17540.36080.43230.126*
H53B0.12270.42740.44710.126*
H53C0.15360.41470.37530.126*
B10.4864 (11)0.2490 (11)0.1043 (10)0.031 (3)
H10.43320.23770.09330.047*
B110.5230 (11)0.5518 (11)0.3533 (10)0.032 (3)
H110.57740.55910.36310.047*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
W10.0194 (4)0.0273 (4)0.0249 (4)0.0008 (3)0.0033 (3)0.0008 (3)
W20.0204 (4)0.0309 (5)0.0404 (5)0.0016 (3)0.0085 (3)0.0074 (4)
W30.0193 (4)0.0350 (5)0.0316 (4)0.0005 (3)0.0068 (3)0.0037 (3)
W40.0210 (4)0.0419 (5)0.0311 (4)0.0027 (3)0.0045 (3)0.0032 (4)
S10.038 (3)0.048 (3)0.037 (3)0.009 (2)0.008 (2)0.002 (2)
S20.033 (3)0.024 (2)0.048 (3)0.0014 (19)0.009 (2)0.001 (2)
S30.032 (2)0.029 (2)0.029 (2)0.009 (2)0.007 (2)0.002 (2)
S40.082 (5)0.113 (7)0.151 (8)0.002 (4)0.023 (5)0.024 (6)
S50.064 (4)0.060 (4)0.054 (3)0.024 (3)0.032 (3)0.011 (3)
S60.126 (7)0.078 (5)0.079 (4)0.023 (4)0.043 (5)0.027 (4)
S70.098 (6)0.067 (4)0.109 (6)0.025 (4)0.059 (5)0.026 (4)
S80.040 (3)0.042 (3)0.075 (4)0.003 (2)0.022 (3)0.015 (3)
S110.028 (2)0.057 (3)0.042 (3)0.004 (2)0.009 (2)0.012 (2)
S120.031 (2)0.037 (3)0.036 (3)0.001 (2)0.004 (2)0.001 (2)
S130.032 (3)0.035 (3)0.046 (3)0.002 (2)0.014 (2)0.001 (2)
S140.072 (4)0.137 (8)0.084 (5)0.010 (4)0.006 (4)0.011 (5)
S150.045 (3)0.108 (5)0.051 (3)0.008 (3)0.009 (3)0.022 (3)
S160.134 (8)0.190 (10)0.081 (5)0.016 (7)0.023 (6)0.007 (5)
S170.263 (13)0.089 (6)0.050 (4)0.033 (6)0.021 (6)0.015 (4)
S180.070 (4)0.089 (4)0.062 (4)0.026 (4)0.007 (3)0.021 (3)
N10.031 (6)0.030 (6)0.025 (7)0.003 (5)0.014 (6)0.006 (5)
N20.037 (6)0.030 (5)0.038 (8)0.007 (4)0.018 (6)0.007 (6)
N30.039 (7)0.032 (7)0.043 (8)0.006 (6)0.012 (6)0.000 (6)
N40.033 (6)0.033 (7)0.039 (7)0.009 (5)0.009 (5)0.004 (5)
N50.017 (5)0.033 (8)0.036 (6)0.003 (6)0.003 (5)0.010 (6)
N60.011 (5)0.045 (8)0.026 (5)0.006 (5)0.006 (4)0.003 (6)
N110.024 (6)0.031 (6)0.045 (8)0.004 (5)0.013 (7)0.001 (6)
N120.029 (6)0.037 (6)0.048 (8)0.005 (4)0.017 (6)0.012 (6)
N130.020 (6)0.027 (6)0.034 (7)0.011 (5)0.003 (5)0.006 (5)
N140.024 (6)0.045 (7)0.032 (7)0.004 (5)0.009 (5)0.000 (5)
N150.015 (5)0.025 (8)0.042 (6)0.006 (6)0.001 (5)0.009 (5)
N160.020 (5)0.049 (9)0.032 (6)0.003 (5)0.006 (4)0.007 (6)
C10.045 (7)0.032 (7)0.019 (8)0.005 (6)0.008 (8)0.008 (7)
C20.051 (8)0.023 (7)0.044 (11)0.004 (6)0.015 (9)0.004 (8)
C30.040 (7)0.038 (8)0.022 (9)0.005 (6)0.002 (8)0.015 (8)
C40.042 (8)0.036 (11)0.032 (10)0.006 (7)0.004 (9)0.012 (9)
C50.047 (8)0.048 (13)0.052 (13)0.008 (8)0.018 (11)0.025 (11)
C60.039 (8)0.039 (10)0.042 (10)0.018 (6)0.001 (8)0.002 (7)
C70.056 (9)0.034 (10)0.039 (11)0.017 (7)0.012 (8)0.002 (7)
C80.045 (8)0.037 (10)0.026 (9)0.014 (7)0.012 (7)0.009 (7)
C90.059 (10)0.050 (13)0.026 (10)0.007 (8)0.012 (9)0.008 (9)
C100.055 (10)0.058 (15)0.056 (14)0.008 (9)0.026 (10)0.008 (12)
C110.033 (7)0.034 (10)0.032 (7)0.001 (8)0.001 (5)0.002 (7)
C120.037 (7)0.048 (12)0.043 (9)0.002 (9)0.017 (6)0.020 (9)
C130.025 (7)0.048 (12)0.050 (9)0.016 (8)0.012 (6)0.012 (9)
C140.043 (10)0.047 (13)0.035 (10)0.005 (9)0.010 (8)0.028 (9)
C150.023 (7)0.049 (13)0.063 (14)0.003 (9)0.014 (8)0.022 (11)
N70.071 (13)0.153 (15)0.073 (10)0.033 (10)0.013 (8)0.033 (13)
C160.13 (2)0.21 (3)0.079 (12)0.046 (19)0.035 (13)0.04 (2)
C170.18 (3)0.11 (3)0.089 (12)0.01 (2)0.010 (18)0.02 (2)
C180.12 (2)0.143 (17)0.092 (19)0.027 (14)0.011 (15)0.021 (18)
C190.15 (3)0.15 (3)0.16 (3)0.06 (3)0.03 (3)0.01 (3)
C200.077 (17)0.14 (2)0.094 (13)0.027 (13)0.004 (12)0.008 (17)
C210.10 (3)0.11 (3)0.21 (4)0.029 (16)0.01 (2)0.01 (3)
C220.112 (19)0.144 (18)0.082 (18)0.005 (13)0.011 (14)0.040 (18)
C230.10 (3)0.135 (16)0.22 (4)0.011 (18)0.05 (3)0.08 (3)
C310.034 (7)0.040 (8)0.058 (12)0.006 (6)0.003 (9)0.012 (9)
C320.036 (7)0.037 (8)0.038 (10)0.002 (6)0.018 (9)0.006 (8)
C330.036 (7)0.036 (8)0.049 (11)0.001 (6)0.020 (9)0.001 (9)
C340.032 (7)0.047 (13)0.088 (17)0.014 (8)0.030 (11)0.018 (12)
C350.028 (7)0.055 (14)0.042 (12)0.012 (8)0.006 (9)0.009 (10)
C360.026 (7)0.033 (9)0.025 (9)0.009 (6)0.001 (7)0.010 (6)
C370.024 (7)0.028 (9)0.029 (9)0.016 (6)0.001 (7)0.005 (6)
C380.024 (7)0.018 (8)0.042 (10)0.010 (6)0.007 (7)0.010 (6)
C390.032 (9)0.062 (14)0.047 (12)0.005 (8)0.002 (9)0.002 (10)
C400.032 (8)0.054 (13)0.037 (11)0.011 (8)0.024 (8)0.015 (10)
C410.022 (7)0.044 (11)0.031 (7)0.006 (7)0.003 (5)0.005 (8)
C420.027 (7)0.029 (10)0.038 (7)0.006 (7)0.001 (5)0.012 (8)
C430.023 (6)0.035 (10)0.036 (7)0.001 (7)0.003 (6)0.005 (8)
C440.022 (8)0.072 (15)0.020 (8)0.004 (9)0.001 (7)0.002 (9)
C450.014 (6)0.028 (10)0.054 (12)0.004 (7)0.007 (7)0.017 (9)
N170.038 (8)0.064 (10)0.043 (8)0.016 (6)0.002 (7)0.001 (6)
C460.072 (11)0.061 (14)0.053 (13)0.008 (10)0.000 (11)0.017 (9)
C470.19 (4)0.09 (3)0.14 (3)0.02 (2)0.05 (3)0.05 (2)
C480.082 (15)0.076 (16)0.066 (11)0.022 (11)0.008 (12)0.033 (10)
C490.051 (16)0.16 (3)0.12 (2)0.027 (15)0.040 (16)0.07 (2)
C500.071 (11)0.068 (15)0.071 (14)0.040 (11)0.020 (12)0.006 (10)
C510.10 (2)0.036 (15)0.11 (2)0.026 (13)0.011 (16)0.016 (12)
C520.057 (13)0.061 (14)0.076 (12)0.004 (9)0.008 (12)0.021 (10)
C530.092 (18)0.067 (17)0.09 (2)0.024 (14)0.030 (16)0.003 (13)
B10.023 (8)0.035 (8)0.035 (7)0.001 (6)0.013 (7)0.008 (6)
B110.016 (8)0.035 (8)0.044 (7)0.002 (6)0.005 (7)0.004 (6)
Geometric parameters (Å, º) top
W1—S12.144 (5)N7—C221.499 (15)
W1—S22.314 (5)C16—H16A0.990
W1—S32.318 (4)C16—H16B0.990
W1—N22.265 (14)C16—C171.478 (18)
W1—N42.246 (13)C17—H17A0.980
W1—N62.329 (14)C17—H17B0.980
W2—S22.322 (4)C17—H17C0.980
W2—S32.331 (5)C18—H18A0.990
W2—S41.859 (9)C18—H18B0.990
W2—S52.448 (6)C18—C191.503 (18)
W2—S82.423 (5)C19—H19A0.980
W3—S112.124 (5)C19—H19B0.980
W3—S122.330 (5)C19—H19C0.980
W3—S132.316 (5)C20—H20A0.990
W3—N122.241 (14)C20—H20B0.990
W3—N142.193 (13)C20—C211.504 (18)
W3—N162.371 (15)C21—H21A0.980
W4—S122.328 (5)C21—H21B0.980
W4—S132.320 (5)C21—H21C0.980
W4—S141.939 (8)C22—H22A0.990
W4—S152.406 (6)C22—H22B0.990
W4—S182.386 (7)C22—C231.507 (18)
S5—S62.060 (9)C23—H23A0.980
S6—S71.975 (13)C23—H23B0.980
S7—S82.059 (8)C23—H23C0.980
S15—S161.954 (12)C31—C321.39 (3)
S16—S171.857 (16)C31—C341.49 (3)
S17—S182.018 (12)C32—H320.950
N1—N21.364 (19)C32—C331.35 (3)
N1—C31.35 (2)C33—C351.51 (2)
N1—B11.48 (3)C34—H34A0.980
N2—C11.35 (2)C34—H34B0.980
N3—N41.43 (2)C34—H34C0.980
N3—C81.38 (2)C35—H35A0.980
N3—B11.48 (3)C35—H35B0.980
N4—C61.36 (2)C35—H35C0.980
N5—N61.387 (17)C36—C371.38 (2)
N5—C131.40 (2)C36—C391.49 (3)
N5—B11.51 (2)C37—H370.950
N6—C111.39 (2)C37—C381.36 (2)
N11—N121.371 (19)C38—C401.53 (2)
N11—C331.33 (2)C39—H39A0.980
N11—B111.52 (3)C39—H39B0.980
N12—C311.38 (2)C39—H39C0.980
N13—N141.400 (19)C40—H40A0.980
N13—C381.33 (2)C40—H40B0.980
N13—B111.56 (3)C40—H40C0.980
N14—C361.39 (2)C41—C421.42 (2)
N15—N161.378 (18)C41—C441.50 (2)
N15—C431.35 (2)C42—H420.950
N15—B111.49 (3)C42—C431.37 (2)
N16—C411.36 (2)C43—C451.52 (2)
C1—C21.44 (2)C44—H44A0.980
C1—C41.46 (2)C44—H44B0.980
C2—H20.950C44—H44C0.980
C2—C31.38 (3)C45—H45A0.980
C3—C51.46 (2)C45—H45B0.980
C4—H4A0.980C45—H45C0.980
C4—H4B0.980N17—C461.502 (14)
C4—H4C0.980N17—C481.509 (14)
C5—H5A0.980N17—C501.519 (14)
C5—H5B0.980N17—C521.524 (14)
C5—H5C0.980C46—H46A0.990
C6—C71.36 (2)C46—H46B0.990
C6—C91.44 (3)C46—C471.487 (18)
C7—H70.950C47—H47A0.980
C7—C81.36 (3)C47—H47B0.980
C8—C101.47 (3)C47—H47C0.980
C9—H9A0.980C48—H48A0.990
C9—H9B0.980C48—H48B0.990
C9—H9C0.980C48—C491.489 (17)
C10—H10A0.980C49—H49A0.980
C10—H10B0.980C49—H49B0.980
C10—H10C0.980C49—H49C0.980
C11—C121.38 (3)C50—H50A0.990
C11—C141.50 (2)C50—H50B0.990
C12—H120.950C50—C511.497 (17)
C12—C131.36 (3)C51—H51A0.980
C13—C151.48 (2)C51—H51B0.980
C14—H14A0.980C51—H51C0.980
C14—H14B0.980C52—H52A0.990
C14—H14C0.980C52—H52B0.990
C15—H15A0.980C52—C531.505 (17)
C15—H15B0.980C53—H53A0.980
C15—H15C0.980C53—H53B0.980
N7—C161.505 (15)C53—H53C0.980
N7—C181.507 (15)B1—H11.000
N7—C201.529 (15)B11—H111.000
S1—W1—S2102.3 (2)H16B—C16—C17107.1
S1—W1—S3104.20 (18)C16—C17—H17A109.5
S1—W1—N291.8 (4)C16—C17—H17B109.5
S1—W1—N490.7 (4)C16—C17—H17C109.5
S1—W1—N6164.1 (3)H17A—C17—H17B109.5
S2—W1—S3101.34 (16)H17A—C17—H17C109.5
S2—W1—N2163.2 (4)H17B—C17—H17C109.5
S2—W1—N486.6 (4)N7—C18—H18A108.0
S2—W1—N686.2 (4)N7—C18—H18B108.0
S3—W1—N283.6 (4)N7—C18—C19117.3 (18)
S3—W1—N4161.0 (4)H18A—C18—H18B107.2
S3—W1—N686.9 (4)H18A—C18—C19108.0
N2—W1—N484.1 (5)H18B—C18—C19108.0
N2—W1—N678.0 (5)C18—C19—H19A109.5
N4—W1—N676.3 (5)C18—C19—H19B109.5
S2—W2—S3100.71 (15)C18—C19—H19C109.5
S2—W2—S4107.6 (4)H19A—C19—H19B109.5
S2—W2—S5144.1 (2)H19A—C19—H19C109.5
S2—W2—S879.03 (17)H19B—C19—H19C109.5
S3—W2—S4107.7 (3)N7—C20—H20A108.4
S3—W2—S576.11 (17)N7—C20—H20B108.4
S3—W2—S8148.3 (2)N7—C20—C21115.3 (19)
S4—W2—S5107.4 (4)H20A—C20—H20B107.5
S4—W2—S8102.4 (3)H20A—C20—C21108.4
S5—W2—S885.8 (2)H20B—C20—C21108.4
S11—W3—S12101.65 (19)C20—C21—H21A109.5
S11—W3—S13104.80 (19)C20—C21—H21B109.5
S11—W3—N1289.8 (4)C20—C21—H21C109.5
S11—W3—N1492.7 (4)H21A—C21—H21B109.5
S11—W3—N16165.5 (3)H21A—C21—H21C109.5
S12—W3—S13100.99 (16)H21B—C21—H21C109.5
S12—W3—N12165.7 (4)N7—C22—H22A107.9
S12—W3—N1487.4 (4)N7—C22—H22B107.9
S12—W3—N1685.9 (4)N7—C22—C23117.5 (18)
S13—W3—N1284.0 (4)H22A—C22—H22B107.2
S13—W3—N14158.4 (4)H22A—C22—C23107.9
S13—W3—N1685.6 (4)H22B—C22—C23107.9
N12—W3—N1483.5 (5)C22—C23—H23A109.5
N12—W3—N1681.1 (5)C22—C23—H23B109.5
N14—W3—N1675.1 (5)C22—C23—H23C109.5
S12—W4—S13100.92 (16)H23A—C23—H23B109.5
S12—W4—S14109.0 (3)H23A—C23—H23C109.5
S12—W4—S15143.2 (2)H23B—C23—H23C109.5
S12—W4—S1877.7 (2)N12—C31—C32108.2 (16)
S13—W4—S14105.6 (3)N12—C31—C34123.0 (17)
S13—W4—S1580.3 (2)C32—C31—C34128.3 (18)
S13—W4—S18147.1 (2)C31—C32—H32126.7
S14—W4—S15105.9 (3)C31—C32—C33106.7 (17)
S14—W4—S18105.8 (3)H32—C32—C33126.7
S15—W4—S1882.0 (3)N11—C33—C32109.5 (16)
W1—S2—W276.14 (14)N11—C33—C35122.8 (17)
W1—S3—W275.90 (14)C32—C33—C35127.7 (18)
W2—S5—S6112.2 (4)C31—C34—H34A109.5
S5—S6—S7100.9 (5)C31—C34—H34B109.5
S6—S7—S8100.0 (4)C31—C34—H34C109.5
W2—S8—S7106.7 (3)H34A—C34—H34B109.5
W3—S12—W475.31 (15)H34A—C34—H34C109.5
W3—S13—W475.71 (16)H34B—C34—H34C109.5
W4—S15—S16117.4 (5)C33—C35—H35A109.5
S15—S16—S1798.5 (6)C33—C35—H35B109.5
S16—S17—S18103.5 (7)C33—C35—H35C109.5
W4—S18—S17104.1 (4)H35A—C35—H35B109.5
N2—N1—C3109.8 (14)H35A—C35—H35C109.5
N2—N1—B1122.0 (13)H35B—C35—H35C109.5
C3—N1—B1128.0 (15)N14—C36—C37109.2 (15)
W1—N2—N1121.0 (10)N14—C36—C39122.7 (15)
W1—N2—C1128.4 (12)C37—C36—C39127.9 (17)
N1—N2—C1110.3 (14)C36—C37—H37126.1
N4—N3—C8105.5 (15)C36—C37—C38107.7 (15)
N4—N3—B1120.9 (13)H37—C37—C38126.1
C8—N3—B1133.6 (16)N13—C38—C37108.4 (14)
W1—N4—N3120.2 (11)N13—C38—C40122.9 (17)
W1—N4—C6131.8 (12)C37—C38—C40128.6 (16)
N3—N4—C6107.9 (13)C36—C39—H39A109.5
N6—N5—C13109.7 (13)C36—C39—H39B109.5
N6—N5—B1118.4 (14)C36—C39—H39C109.5
C13—N5—B1131.8 (14)H39A—C39—H39B109.5
W1—N6—N5121.4 (10)H39A—C39—H39C109.5
W1—N6—C11133.5 (10)H39B—C39—H39C109.5
N5—N6—C11105.0 (13)C38—C40—H40A109.5
N12—N11—C33109.7 (15)C38—C40—H40B109.5
N12—N11—B11119.5 (14)C38—C40—H40C109.5
C33—N11—B11130.7 (15)H40A—C40—H40B109.5
W3—N12—N11122.9 (11)H40A—C40—H40C109.5
W3—N12—C31131.1 (12)H40B—C40—H40C109.5
N11—N12—C31105.9 (14)N16—C41—C42109.3 (14)
N14—N13—C38110.6 (14)N16—C41—C44126.5 (15)
N14—N13—B11119.2 (13)C42—C41—C44124.2 (17)
C38—N13—B11130.0 (14)C41—C42—H42127.4
W3—N14—N13122.5 (11)C41—C42—C43105.2 (17)
W3—N14—C36133.1 (11)H42—C42—C43127.4
N13—N14—C36104.1 (12)N15—C43—C42109.3 (16)
N16—N15—C43109.4 (14)N15—C43—C45121.7 (16)
N16—N15—B11120.4 (14)C42—C43—C45129.0 (17)
C43—N15—B11130.2 (14)C41—C44—H44A109.5
W3—N16—N15119.0 (10)C41—C44—H44B109.5
W3—N16—C41134.1 (10)C41—C44—H44C109.5
N15—N16—C41106.6 (13)H44A—C44—H44B109.5
N2—C1—C2104.2 (16)H44A—C44—H44C109.5
N2—C1—C4128.1 (16)H44B—C44—H44C109.5
C2—C1—C4127.5 (17)C43—C45—H45A109.5
C1—C2—H2125.6C43—C45—H45B109.5
C1—C2—C3108.9 (16)C43—C45—H45C109.5
H2—C2—C3125.6H45A—C45—H45B109.5
N1—C3—C2106.4 (15)H45A—C45—H45C109.5
N1—C3—C5125.8 (17)H45B—C45—H45C109.5
C2—C3—C5127.6 (17)C46—N17—C48107.8 (12)
C1—C4—H4A109.5C46—N17—C50110.8 (13)
C1—C4—H4B109.5C46—N17—C52111.2 (12)
C1—C4—H4C109.5C48—N17—C50108.4 (12)
H4A—C4—H4B109.5C48—N17—C52111.0 (14)
H4A—C4—H4C109.5C50—N17—C52107.6 (11)
H4B—C4—H4C109.5N17—C46—H46A107.9
C3—C5—H5A109.5N17—C46—H46B107.9
C3—C5—H5B109.5N17—C46—C47117.7 (17)
C3—C5—H5C109.5H46A—C46—H46B107.2
H5A—C5—H5B109.5H46A—C46—C47107.9
H5A—C5—H5C109.5H46B—C46—C47107.9
H5B—C5—H5C109.5C46—C47—H47A109.5
N4—C6—C7108.3 (18)C46—C47—H47B109.5
N4—C6—C9123.7 (16)C46—C47—H47C109.5
C7—C6—C9127.9 (19)H47A—C47—H47B109.5
C6—C7—H7125.3H47A—C47—H47C109.5
C6—C7—C8109.3 (17)H47B—C47—H47C109.5
H7—C7—C8125.3N17—C48—H48A107.2
N3—C8—C7108.8 (16)N17—C48—H48B107.2
N3—C8—C10119.2 (19)N17—C48—C49120.4 (16)
C7—C8—C10131.8 (18)H48A—C48—H48B106.9
C6—C9—H9A109.5H48A—C48—C49107.2
C6—C9—H9B109.5H48B—C48—C49107.2
C6—C9—H9C109.5C48—C49—H49A109.5
H9A—C9—H9B109.5C48—C49—H49B109.5
H9A—C9—H9C109.5C48—C49—H49C109.5
H9B—C9—H9C109.5H49A—C49—H49B109.5
C8—C10—H10A109.5H49A—C49—H49C109.5
C8—C10—H10B109.5H49B—C49—H49C109.5
C8—C10—H10C109.5N17—C50—H50A108.4
H10A—C10—H10B109.5N17—C50—H50B108.4
H10A—C10—H10C109.5N17—C50—C51115.6 (14)
H10B—C10—H10C109.5H50A—C50—H50B107.4
N6—C11—C12109.7 (15)H50A—C50—C51108.4
N6—C11—C14126.9 (16)H50B—C50—C51108.4
C12—C11—C14123.3 (17)C50—C51—H51A109.5
C11—C12—H12125.8C50—C51—H51B109.5
C11—C12—C13108.4 (17)C50—C51—H51C109.5
H12—C12—C13125.8H51A—C51—H51B109.5
N5—C13—C12106.9 (16)H51A—C51—H51C109.5
N5—C13—C15119.6 (16)H51B—C51—H51C109.5
C12—C13—C15133.4 (19)N17—C52—H52A108.2
C11—C14—H14A109.5N17—C52—H52B108.2
C11—C14—H14B109.5N17—C52—C53116.2 (15)
C11—C14—H14C109.5H52A—C52—H52B107.4
H14A—C14—H14B109.5H52A—C52—C53108.2
H14A—C14—H14C109.5H52B—C52—C53108.2
H14B—C14—H14C109.5C52—C53—H53A109.5
C13—C15—H15A109.5C52—C53—H53B109.5
C13—C15—H15B109.5C52—C53—H53C109.5
C13—C15—H15C109.5H53A—C53—H53B109.5
H15A—C15—H15B109.5H53A—C53—H53C109.5
H15A—C15—H15C109.5H53B—C53—H53C109.5
H15B—C15—H15C109.5N1—B1—N3113.0 (17)
C16—N7—C18111.9 (15)N1—B1—N5108.4 (14)
C16—N7—C20105.6 (14)N1—B1—H1109.2
C16—N7—C22109.0 (15)N3—B1—N5107.8 (15)
C18—N7—C20108.8 (15)N3—B1—H1109.2
C18—N7—C22110.2 (15)N5—B1—H1109.2
C20—N7—C22111.2 (14)N11—B11—N13110.8 (15)
N7—C16—H16A107.1N11—B11—N15109.2 (14)
N7—C16—H16B107.1N11—B11—H11109.6
N7—C16—C17120.7 (18)N13—B11—N15108.0 (14)
H16A—C16—H16B106.8N13—B11—H11109.6
H16A—C16—C17107.1N15—B11—H11109.6
S1—W1—S2—W288.89 (17)B11—N15—N16—C41176.5 (15)
S3—W1—S2—W218.56 (17)S11—W3—N16—N1518 (3)
N2—W1—S2—W2124.3 (13)S11—W3—N16—C41169.0 (13)
N4—W1—S2—W2178.9 (4)S12—W3—N16—N15140.2 (12)
N6—W1—S2—W2104.7 (3)S12—W3—N16—C4146.9 (17)
S3—W2—S2—W118.41 (17)S13—W3—N16—N15118.4 (12)
S4—W2—S2—W194.2 (3)S13—W3—N16—C4154.5 (17)
S5—W2—S2—W199.5 (3)N12—W3—N16—N1533.8 (12)
S8—W2—S2—W1166.1 (2)N12—W3—N16—C41139.1 (18)
S1—W1—S3—W287.46 (18)N14—W3—N16—N1551.8 (12)
S2—W1—S3—W218.51 (17)N14—W3—N16—C41135.3 (18)
N2—W1—S3—W2177.8 (4)W1—N2—C1—C2179.9 (12)
N4—W1—S3—W2131.9 (12)W1—N2—C1—C44 (3)
N6—W1—S3—W2104.0 (4)N1—N2—C1—C26 (2)
S2—W2—S3—W118.40 (17)N1—N2—C1—C4177.3 (17)
S4—W2—S3—W194.2 (4)N2—C1—C2—C36 (2)
S5—W2—S3—W1161.72 (19)C4—C1—C2—C3177.3 (17)
S8—W2—S3—W1104.8 (3)N2—N1—C3—C20 (2)
S2—W2—S5—S663.3 (5)N2—N1—C3—C5174.9 (18)
S3—W2—S5—S6152.4 (4)B1—N1—C3—C2175.2 (18)
S4—W2—S5—S6103.1 (5)B1—N1—C3—C50 (3)
S8—W2—S5—S61.4 (4)C1—C2—C3—N14 (2)
W2—S5—S6—S734.9 (5)C1—C2—C3—C5178.6 (18)
S5—S6—S7—S855.6 (5)W1—N4—C6—C7175.3 (13)
S6—S7—S8—W258.5 (5)W1—N4—C6—C90 (3)
S2—W2—S8—S7179.0 (4)N3—N4—C6—C71 (2)
S3—W2—S8—S786.4 (4)N3—N4—C6—C9177.1 (17)
S4—W2—S8—S775.1 (5)N4—C6—C7—C84 (2)
S5—W2—S8—S731.7 (4)C9—C6—C7—C8179.1 (19)
S13—W4—S12—W320.11 (18)C6—C7—C8—N35 (2)
S14—W4—S12—W390.8 (3)C6—C7—C8—C10180 (2)
S15—W4—S12—W3108.5 (3)N4—N3—C8—C74 (2)
S18—W4—S12—W3166.5 (2)N4—N3—C8—C10179.5 (17)
S11—W3—S12—W487.64 (17)B1—N3—C8—C7179.0 (19)
S13—W3—S12—W420.16 (18)B1—N3—C8—C103 (3)
N12—W3—S12—W4129.7 (17)W1—N6—C11—C12177.6 (13)
N14—W3—S12—W4179.9 (4)W1—N6—C11—C142 (3)
N16—W3—S12—W4104.9 (4)N5—N6—C11—C123 (2)
S11—W3—S13—W485.13 (18)N5—N6—C11—C14177.7 (17)
S12—W3—S13—W420.19 (18)N6—C11—C12—C130 (2)
N12—W3—S13—W4173.4 (4)C14—C11—C12—C13179.8 (18)
N14—W3—S13—W4131.5 (11)C11—C12—C13—N52 (2)
N16—W3—S13—W4105.2 (4)C11—C12—C13—C15180 (2)
S12—W4—S13—W320.20 (18)N6—N5—C13—C124 (2)
S14—W4—S13—W393.3 (3)N6—N5—C13—C15178.3 (17)
S15—W4—S13—W3162.8 (2)B1—N5—C13—C12174.2 (18)
S18—W4—S13—W3104.4 (4)B1—N5—C13—C153 (3)
S12—W4—S15—S1662.9 (6)C18—N7—C16—C1761 (3)
S13—W4—S15—S16158.2 (5)C20—N7—C16—C17179 (3)
S14—W4—S15—S1698.2 (6)C22—N7—C16—C1762 (3)
S18—W4—S15—S166.1 (5)C16—N7—C18—C19174 (3)
W4—S15—S16—S1727.4 (8)C20—N7—C18—C1957 (3)
S15—S16—S17—S1853.0 (7)C22—N7—C18—C1965 (3)
S16—S17—S18—W462.4 (6)C16—N7—C20—C2170 (3)
S12—W4—S18—S17175.6 (5)C18—N7—C20—C2150 (3)
S13—W4—S18—S1793.2 (5)C22—N7—C20—C21172 (2)
S14—W4—S18—S1769.1 (5)C16—N7—C22—C2365 (3)
S15—W4—S18—S1735.2 (5)C18—N7—C22—C23172 (3)
C3—N1—N2—W1178.3 (12)C20—N7—C22—C2351 (3)
C3—N1—N2—C14 (2)W3—N12—C31—C32179.0 (13)
B1—N1—N2—W16 (2)W3—N12—C31—C349 (3)
B1—N1—N2—C1179.7 (16)N11—N12—C31—C322 (2)
S1—W1—N2—N1122.9 (12)N11—N12—C31—C34174.9 (19)
S1—W1—N2—C150.1 (15)N12—C31—C32—C332 (2)
S2—W1—N2—N125 (2)C34—C31—C32—C33174 (2)
S2—W1—N2—C1162.3 (11)N12—N11—C33—C321 (2)
S3—W1—N2—N1133.0 (13)N12—N11—C33—C35179.9 (17)
S3—W1—N2—C154.0 (15)B11—N11—C33—C32178.7 (18)
N4—W1—N2—N132.4 (13)B11—N11—C33—C352 (3)
N4—W1—N2—C1140.6 (16)C31—C32—C33—N111 (2)
N6—W1—N2—N144.8 (12)C31—C32—C33—C35178 (2)
N6—W1—N2—C1142.2 (16)W3—N14—C36—C37173.2 (12)
C8—N3—N4—W1178.5 (11)W3—N14—C36—C393 (3)
C8—N3—N4—C61.4 (19)N13—N14—C36—C370.0 (18)
B1—N3—N4—W14 (2)N13—N14—C36—C39176.0 (16)
B1—N3—N4—C6179.2 (16)N14—C36—C37—C380.0 (19)
S1—W1—N4—N3124.7 (12)C39—C36—C37—C38175.8 (18)
S1—W1—N4—C651.6 (17)N14—N13—C38—C370.0 (19)
S2—W1—N4—N3133.0 (12)N14—N13—C38—C40178.2 (15)
S2—W1—N4—C650.7 (16)B11—N13—C38—C37175.1 (16)
S3—W1—N4—N317 (2)B11—N13—C38—C403 (3)
S3—W1—N4—C6166.4 (12)C36—C37—C38—N130 (2)
N2—W1—N4—N333.0 (12)C36—C37—C38—C40178.1 (17)
N2—W1—N4—C6143.3 (17)W3—N16—C41—C42173.3 (12)
N6—W1—N4—N346.1 (12)W3—N16—C41—C448 (3)
N6—W1—N4—C6137.6 (17)N15—N16—C41—C420 (2)
C13—N5—N6—W1176.1 (12)N15—N16—C41—C44178.4 (17)
C13—N5—N6—C114.1 (19)N16—C41—C42—C432 (2)
B1—N5—N6—W15.3 (19)C44—C41—C42—C43179.0 (17)
B1—N5—N6—C11174.5 (15)N16—N15—C43—C424 (2)
S1—W1—N6—N512 (2)N16—N15—C43—C45177.6 (15)
S1—W1—N6—C11167.5 (12)B11—N15—C43—C42174.8 (16)
S2—W1—N6—N5135.5 (12)B11—N15—C43—C453 (3)
S2—W1—N6—C1144.3 (16)C41—C42—C43—N154 (2)
S3—W1—N6—N5123.0 (12)C41—C42—C43—C45178.1 (18)
S3—W1—N6—C1157.3 (16)C48—N17—C46—C47178 (2)
N2—W1—N6—N538.8 (12)C50—N17—C46—C4759 (3)
N2—W1—N6—C11141.4 (17)C52—N17—C46—C4760 (3)
N4—W1—N6—N548.0 (12)C46—N17—C48—C49179 (2)
N4—W1—N6—C11131.8 (17)C50—N17—C48—C4961 (2)
C33—N11—N12—W3178.9 (13)C52—N17—C48—C4957 (3)
C33—N11—N12—C312 (2)C46—N17—C50—C5161 (2)
B11—N11—N12—W33 (2)C48—N17—C50—C5157 (2)
B11—N11—N12—C31179.9 (17)C52—N17—C50—C51178 (2)
S11—W3—N12—N11132.0 (13)C46—N17—C52—C5351 (2)
S11—W3—N12—C3152.0 (18)C48—N17—C52—C5369 (2)
S12—W3—N12—N1112 (3)C50—N17—C52—C53173 (2)
S12—W3—N12—C31164.4 (14)N4—N3—B1—N159 (2)
S13—W3—N12—N11123.1 (13)N4—N3—B1—N561 (2)
S13—W3—N12—C3152.9 (18)C8—N3—B1—N1124 (2)
N14—W3—N12—N1139.2 (14)C8—N3—B1—N5116 (2)
N14—W3—N12—C31144.7 (19)N2—N1—B1—N361 (2)
N16—W3—N12—N1136.7 (13)N2—N1—B1—N559 (2)
N16—W3—N12—C31139.4 (19)C3—N1—B1—N3124.8 (18)
C38—N13—N14—W3174.1 (11)C3—N1—B1—N5115.8 (18)
C38—N13—N14—C360.0 (18)N6—N5—B1—N164 (2)
B11—N13—N14—W310.2 (19)N6—N5—B1—N358.8 (19)
B11—N13—N14—C36175.7 (14)C13—N5—B1—N1118 (2)
S11—W3—N14—N13120.8 (12)C13—N5—B1—N3119 (2)
S11—W3—N14—C3651.4 (15)N16—N15—B11—N1166 (2)
S12—W3—N14—N13137.7 (12)N16—N15—B11—N1354.3 (19)
S12—W3—N14—C3650.2 (15)C43—N15—B11—N11114.5 (19)
S13—W3—N14—N1324 (2)C43—N15—B11—N13124.8 (18)
S13—W3—N14—C36163.9 (11)N12—N11—B11—N1355 (2)
N12—W3—N14—N1331.3 (12)N12—N11—B11—N1564 (2)
N12—W3—N14—C36140.9 (16)C33—N11—B11—N13123 (2)
N16—W3—N14—N1351.2 (12)C33—N11—B11—N15118 (2)
N16—W3—N14—C36136.6 (16)N14—N13—B11—N1163.1 (19)
C43—N15—N16—W3171.9 (11)N14—N13—B11—N1556.5 (19)
C43—N15—N16—C412.8 (19)C38—N13—B11—N11122.2 (18)
B11—N15—N16—W38.8 (19)C38—N13—B11—N15118.2 (18)

Experimental details

(1)(2)
Crystal data
Chemical formula(C8H20N)[W2S4(S)4(C15H22BN6)](C8H20N)[W2S4(S)4(C15H22BN6)]
Mr1051.631051.63
Crystal system, space groupMonoclinic, P21/nMonoclinic, P21/n
Temperature (K)150150
a, b, c (Å)10.5173 (2), 17.5635 (3), 19.4889 (4)17.8602 (10), 18.8742 (10), 20.6188 (10)
β (°) 104.878 (2) 90.343 (5)
V3)3479.31 (11)6950.4 (6)
Z48
Radiation typeMo KαMo Kα
µ (mm1)7.127.12
Crystal size (mm)0.32 × 0.24 × 0.080.52 × 0.38 × 0.04
Data collection
DiffractometerOxford Diffraction Gemini A Ultra
diffractometer
Oxford Diffraction Gemini A Ultra
diffractometer
Absorption correctionMulti-scan
(CrysAlis PRO; Oxford Diffraction, 2009)
Multi-scan
(CrysAlis PRO; Oxford Diffraction, 2009)
Tmin, Tmax0.210, 0.6000.120, 0.765
No. of measured, independent and
observed [I > 2σ(I)] reflections
17702, 7333, 5814 23985, 11129, 6168
Rint0.0250.119
(sin θ/λ)max1)0.6740.638
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.036, 0.098, 1.09 0.066, 0.171, 0.97
No. of reflections733311129
No. of parameters383759
No. of restraints0760
H-atom treatmentGEOMH-atom parameters constrained
Δρmax, Δρmin (e Å3)2.98, 1.863.82, 2.26

Computer programs: CrysAlis PRO (Oxford Diffraction, 2009), SHELXTL (Sheldrick, 2008), SHELXTL and local programs.

Selected geometric parameters (Å, º) for (1) top
W1—S12.1348 (18)W2—S32.3374 (16)
W1—S22.3224 (16)W2—S42.091 (2)
W1—S32.3269 (17)W2—S52.421 (2)
W1—N22.232 (5)W2—S82.3960 (19)
W1—N42.235 (5)S5—S62.019 (3)
W1—N62.343 (5)S6—S71.994 (4)
W2—S22.3190 (18)S7—S82.069 (3)
S1—W1—S2104.94 (7)S2—W2—S4108.08 (8)
S1—W1—S3104.05 (7)S2—W2—S575.55 (7)
S1—W1—N289.53 (15)S2—W2—S8141.82 (7)
S1—W1—N489.77 (15)S3—W2—S4109.19 (7)
S1—W1—N6162.42 (14)S3—W2—S5144.77 (7)
S2—W1—S3100.29 (6)S3—W2—S878.04 (6)
S2—W1—N283.74 (13)S4—W2—S5105.28 (8)
S2—W1—N4161.83 (15)S4—W2—S8108.43 (8)
S2—W1—N686.39 (13)S5—W2—S884.47 (8)
S3—W1—N2164.13 (15)W1—S2—W275.75 (5)
S3—W1—N486.05 (14)W1—S3—W275.31 (5)
S3—W1—N686.69 (13)W2—S5—S6106.08 (12)
N2—W1—N485.82 (19)S5—S6—S798.36 (14)
N2—W1—N678.20 (19)S6—S7—S8103.51 (14)
N4—W1—N676.93 (19)W2—S8—S7112.75 (12)
S2—W2—S3100.08 (6)
Selected geometric parameters (Å, º) for (2) top
W1—S12.144 (5)W3—N122.241 (14)
W1—S22.314 (5)W3—N142.193 (13)
W1—S32.318 (4)W3—N162.371 (15)
W1—N22.265 (14)W4—S122.328 (5)
W1—N42.246 (13)W4—S132.320 (5)
W1—N62.329 (14)W4—S141.939 (8)
W2—S22.322 (4)W4—S152.406 (6)
W2—S32.331 (5)W4—S182.386 (7)
W2—S41.859 (9)S5—S62.060 (9)
W2—S52.448 (6)S6—S71.975 (13)
W2—S82.423 (5)S7—S82.059 (8)
W3—S112.124 (5)S15—S161.954 (12)
W3—S122.330 (5)S16—S171.857 (16)
W3—S132.316 (5)S17—S182.018 (12)
S1—W1—S2102.3 (2)S12—W3—N12165.7 (4)
S1—W1—S3104.20 (18)S12—W3—N1487.4 (4)
S1—W1—N291.8 (4)S12—W3—N1685.9 (4)
S1—W1—N490.7 (4)S13—W3—N1284.0 (4)
S1—W1—N6164.1 (3)S13—W3—N14158.4 (4)
S2—W1—S3101.34 (16)S13—W3—N1685.6 (4)
S2—W1—N2163.2 (4)N12—W3—N1483.5 (5)
S2—W1—N486.6 (4)N12—W3—N1681.1 (5)
S2—W1—N686.2 (4)N14—W3—N1675.1 (5)
S3—W1—N283.6 (4)S12—W4—S13100.92 (16)
S3—W1—N4161.0 (4)S12—W4—S14109.0 (3)
S3—W1—N686.9 (4)S12—W4—S15143.2 (2)
N2—W1—N484.1 (5)S12—W4—S1877.7 (2)
N2—W1—N678.0 (5)S13—W4—S14105.6 (3)
N4—W1—N676.3 (5)S13—W4—S1580.3 (2)
S2—W2—S3100.71 (15)S13—W4—S18147.1 (2)
S2—W2—S4107.6 (4)S14—W4—S15105.9 (3)
S2—W2—S5144.1 (2)S14—W4—S18105.8 (3)
S2—W2—S879.03 (17)S15—W4—S1882.0 (3)
S3—W2—S4107.7 (3)W1—S2—W276.14 (14)
S3—W2—S576.11 (17)W1—S3—W275.90 (14)
S3—W2—S8148.3 (2)W2—S5—S6112.2 (4)
S4—W2—S5107.4 (4)S5—S6—S7100.9 (5)
S4—W2—S8102.4 (3)S6—S7—S8100.0 (4)
S5—W2—S885.8 (2)W2—S8—S7106.7 (3)
S11—W3—S12101.65 (19)W3—S12—W475.31 (15)
S11—W3—S13104.80 (19)W3—S13—W475.71 (16)
S11—W3—N1289.8 (4)W4—S15—S16117.4 (5)
S11—W3—N1492.7 (4)S15—S16—S1798.5 (6)
S11—W3—N16165.5 (3)S16—S17—S18103.5 (7)
S12—W3—S13100.99 (16)W4—S18—S17104.1 (4)
 

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