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The dinuclear cation in the title compound, [Cu2(C10H8N2)(C12H8N2)2(C18H15P)2](BF4)2, lies on a centre of inversion. Each CuI atom is coordinated by 1,10-phenanthroline, triphenyl­phosphine and a bridging 4,4′-bipyridine mol­ecule, and has a distorted tetra­hedral coordination geometry. The two CuI atoms are displaced by 0.32 (1) Å on either side of the mean plane of the 4,4′-bipyridine unit.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S160053680605149X/bi2107sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S160053680605149X/bi2107Isup2.hkl
Contains datablock I

CCDC reference: 633618

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.008 Å
  • R factor = 0.058
  • wR factor = 0.163
  • Data-to-parameter ratio = 16.1

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.65 Ratio PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Cu1 - P1 .. 5.96 su PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C3 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for C15 PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for B1 PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 8 PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of . 31.00 A   3
Alert level G PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature 293 K
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 7 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 5 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1998); software used to prepare material for publication: SHELXTL.

(µ-4,4'-Bipyridine-κ2N:N')bis[(1,10-phenanthroline- κ2N,N')(triphenylphosphine-κP)copper(I)] bis(tetrafluoroborate) top
Crystal data top
[Cu2(C10H8N2)(C12H8N2)2(C18H15P)2](BF4)2F(000) = 1372
Mr = 1341.83Dx = 1.409 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 885 reflections
a = 14.192 (7) Åθ = 2.4–22.2°
b = 15.372 (7) ŵ = 0.79 mm1
c = 14.515 (6) ÅT = 293 K
β = 92.495 (9)°Block, brown
V = 3164 (2) Å30.26 × 0.20 × 0.16 mm
Z = 2
Data collection top
Bruker SMART CCD
diffractometer
6518 independent reflections
Radiation source: fine-focus sealed tube3572 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.058
φ and ω scansθmax = 26.5°, θmin = 1.9°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1717
Tmin = 0.850, Tmax = 0.880k = 1917
17926 measured reflectionsl = 1318
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.058Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.163H-atom parameters constrained
S = 1.00 w = 1/[σ2(Fo2) + (0.0746P)2 + 1.4838P]
where P = (Fo2 + 2Fc2)/3
6518 reflections(Δ/σ)max = 0.003
406 parametersΔρmax = 0.78 e Å3
0 restraintsΔρmin = 0.39 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Cu10.84510 (4)0.18547 (3)0.61886 (4)0.04451 (19)
P10.72864 (8)0.22427 (7)0.70523 (8)0.0441 (3)
N10.8246 (3)0.0785 (2)0.5380 (2)0.0473 (9)
N20.9533 (2)0.1068 (2)0.6760 (3)0.0476 (9)
N30.9052 (2)0.2946 (2)0.5637 (2)0.0450 (9)
C10.7596 (4)0.0646 (4)0.4717 (3)0.0728 (15)
H10.71930.10990.45400.087*
C20.7492 (5)0.0153 (5)0.4275 (4)0.100 (2)
H20.70210.02320.38160.120*
C30.8075 (6)0.0809 (5)0.4515 (5)0.105 (3)
H30.80090.13410.42140.126*
C40.8776 (4)0.0708 (3)0.5206 (4)0.0724 (17)
C50.9435 (6)0.1358 (4)0.5506 (6)0.101 (3)
H50.94000.19040.52320.121*
C61.0094 (5)0.1214 (4)0.6157 (6)0.102 (3)
H61.05260.16500.63140.122*
C71.0151 (4)0.0401 (4)0.6622 (4)0.0723 (17)
C81.0805 (4)0.0218 (5)0.7342 (5)0.096 (2)
H81.12320.06430.75440.115*
C91.0820 (4)0.0568 (6)0.7743 (5)0.093 (2)
H91.12550.06900.82230.111*
C101.0175 (3)0.1202 (4)0.7432 (4)0.0670 (14)
H101.01990.17460.77120.080*
C110.9512 (3)0.0266 (3)0.6350 (3)0.0503 (12)
C120.8824 (3)0.0113 (3)0.5629 (3)0.0497 (12)
C130.9869 (3)0.3240 (3)0.5990 (4)0.0569 (12)
H131.01980.28940.64200.068*
C141.0258 (3)0.4027 (3)0.5758 (3)0.0540 (12)
H141.08370.41930.60270.065*
C150.9799 (3)0.4567 (2)0.5133 (3)0.0396 (10)
C160.8957 (3)0.4258 (3)0.4763 (3)0.0650 (14)
H160.86150.45890.43290.078*
C170.8615 (4)0.3457 (3)0.5029 (4)0.0656 (14)
H170.80430.32690.47630.079*
C180.6229 (3)0.1576 (3)0.7100 (3)0.0509 (11)
C190.6280 (4)0.0705 (3)0.6881 (4)0.0690 (14)
H190.68380.04730.66750.083*
C200.5499 (5)0.0174 (4)0.6968 (5)0.100 (2)
H200.55390.04170.68340.120*
C210.4681 (5)0.0510 (5)0.7246 (5)0.102 (2)
H210.41610.01490.73040.123*
C220.4611 (4)0.1373 (5)0.7442 (4)0.092 (2)
H220.40410.16000.76250.111*
C230.5376 (3)0.1908 (4)0.7370 (4)0.0701 (15)
H230.53220.24970.75030.084*
C240.7702 (3)0.2359 (3)0.8251 (3)0.0494 (11)
C250.7269 (4)0.1995 (3)0.8988 (4)0.0644 (14)
H250.66870.17220.89000.077*
C260.7705 (5)0.2034 (4)0.9870 (4)0.0865 (19)
H260.74120.17781.03620.104*
C270.8534 (5)0.2434 (4)1.0018 (5)0.093 (2)
H270.88060.24661.06120.112*
C280.8985 (5)0.2798 (4)0.9293 (5)0.0874 (18)
H280.95640.30740.93930.105*
C290.8576 (4)0.2751 (3)0.8421 (4)0.0675 (14)
H290.88900.29870.79310.081*
C300.6806 (3)0.3289 (3)0.6666 (3)0.0474 (11)
C310.7023 (3)0.4066 (3)0.7095 (3)0.0579 (12)
H310.73680.40660.76540.069*
C320.6733 (4)0.4851 (3)0.6703 (5)0.0768 (16)
H320.68820.53730.69990.092*
C330.6228 (4)0.4855 (4)0.5883 (5)0.0854 (18)
H330.60400.53790.56140.102*
C340.5998 (4)0.4083 (5)0.5454 (5)0.0907 (19)
H340.56430.40840.49000.109*
C350.6292 (4)0.3308 (3)0.5845 (4)0.0736 (15)
H350.61400.27880.55470.088*
B10.6996 (5)0.2007 (5)0.2675 (6)0.080 (2)
F10.6244 (4)0.1931 (4)0.3168 (4)0.194 (3)
F20.7778 (4)0.2170 (3)0.3161 (4)0.159 (2)
F30.7113 (3)0.1178 (3)0.2326 (4)0.1578 (19)
F40.6833 (3)0.2545 (2)0.1956 (2)0.1069 (12)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Cu10.0474 (3)0.0311 (3)0.0552 (4)0.0012 (2)0.0047 (2)0.0003 (2)
P10.0461 (7)0.0335 (6)0.0530 (7)0.0005 (5)0.0065 (5)0.0021 (5)
N10.054 (2)0.044 (2)0.044 (2)0.0073 (18)0.0078 (18)0.0001 (17)
N20.040 (2)0.050 (2)0.053 (2)0.0025 (17)0.0028 (18)0.0078 (18)
N30.044 (2)0.035 (2)0.056 (2)0.0041 (16)0.0059 (18)0.0051 (16)
C10.082 (4)0.079 (4)0.057 (3)0.023 (3)0.003 (3)0.001 (3)
C20.129 (6)0.102 (5)0.067 (4)0.047 (5)0.005 (4)0.028 (4)
C30.159 (8)0.068 (4)0.091 (5)0.061 (5)0.052 (5)0.038 (4)
C40.102 (5)0.037 (3)0.081 (4)0.022 (3)0.047 (4)0.012 (3)
C50.144 (7)0.026 (3)0.140 (7)0.009 (4)0.097 (6)0.005 (4)
C60.101 (6)0.056 (4)0.155 (8)0.032 (4)0.086 (5)0.041 (5)
C70.068 (4)0.061 (4)0.091 (4)0.022 (3)0.041 (3)0.032 (3)
C80.063 (4)0.116 (6)0.111 (6)0.031 (4)0.023 (4)0.056 (5)
C90.051 (4)0.142 (7)0.084 (5)0.013 (4)0.010 (3)0.035 (5)
C100.047 (3)0.083 (4)0.071 (4)0.004 (3)0.000 (3)0.012 (3)
C110.051 (3)0.037 (3)0.065 (3)0.006 (2)0.026 (2)0.016 (2)
C120.061 (3)0.033 (2)0.057 (3)0.006 (2)0.028 (2)0.002 (2)
C130.051 (3)0.039 (3)0.080 (3)0.001 (2)0.007 (2)0.013 (2)
C140.047 (3)0.041 (3)0.073 (3)0.009 (2)0.010 (2)0.008 (2)
C150.041 (2)0.035 (2)0.043 (2)0.0015 (18)0.006 (2)0.0012 (19)
C160.059 (3)0.058 (3)0.076 (3)0.020 (2)0.019 (3)0.031 (3)
C170.059 (3)0.059 (3)0.077 (4)0.022 (3)0.015 (3)0.014 (3)
C180.052 (3)0.045 (3)0.055 (3)0.007 (2)0.001 (2)0.003 (2)
C190.063 (3)0.050 (3)0.094 (4)0.008 (3)0.001 (3)0.007 (3)
C200.080 (5)0.057 (4)0.162 (7)0.024 (3)0.014 (4)0.023 (4)
C210.071 (5)0.101 (6)0.132 (6)0.040 (4)0.023 (4)0.049 (5)
C220.055 (4)0.128 (6)0.095 (5)0.004 (4)0.014 (3)0.035 (4)
C230.055 (3)0.071 (4)0.086 (4)0.001 (3)0.021 (3)0.002 (3)
C240.056 (3)0.040 (3)0.053 (3)0.009 (2)0.003 (2)0.007 (2)
C250.066 (3)0.065 (3)0.062 (3)0.008 (3)0.008 (3)0.003 (3)
C260.125 (6)0.079 (4)0.056 (4)0.022 (4)0.007 (4)0.002 (3)
C270.108 (5)0.093 (5)0.075 (5)0.021 (4)0.033 (4)0.027 (4)
C280.087 (4)0.088 (4)0.086 (5)0.002 (4)0.013 (4)0.017 (4)
C290.070 (4)0.068 (3)0.064 (4)0.006 (3)0.002 (3)0.009 (3)
C300.046 (3)0.040 (3)0.057 (3)0.0036 (19)0.006 (2)0.003 (2)
C310.066 (3)0.043 (3)0.065 (3)0.006 (2)0.001 (3)0.002 (2)
C320.080 (4)0.040 (3)0.111 (5)0.007 (3)0.010 (4)0.004 (3)
C330.077 (4)0.064 (4)0.116 (5)0.019 (3)0.013 (4)0.034 (4)
C340.087 (4)0.092 (5)0.091 (5)0.014 (4)0.015 (4)0.022 (4)
C350.083 (4)0.059 (3)0.078 (4)0.011 (3)0.014 (3)0.008 (3)
B10.065 (4)0.086 (6)0.089 (5)0.021 (4)0.002 (4)0.025 (4)
F10.142 (4)0.269 (7)0.176 (5)0.088 (4)0.069 (4)0.135 (5)
F20.148 (4)0.134 (4)0.186 (5)0.038 (3)0.088 (4)0.028 (3)
F30.149 (4)0.106 (4)0.214 (5)0.014 (3)0.047 (4)0.011 (3)
F40.106 (3)0.112 (3)0.103 (3)0.028 (2)0.011 (2)0.049 (2)
Geometric parameters (Å, º) top
Cu1—N12.033 (4)C16—H160.930
Cu1—N32.060 (3)C17—H170.930
Cu1—N22.096 (4)C18—C191.379 (6)
Cu1—P12.1999 (14)C18—C231.386 (6)
P1—C241.822 (5)C19—C201.387 (7)
P1—C181.821 (5)C19—H190.930
P1—C301.826 (4)C20—C211.347 (9)
N1—C11.322 (6)C20—H200.930
N1—C121.358 (5)C21—C221.362 (9)
N2—C101.322 (6)C21—H210.9300
N2—C111.369 (6)C22—C231.369 (8)
N3—C171.316 (6)C22—H220.930
N3—C131.325 (5)C23—H230.930
C1—C21.391 (8)C24—C251.375 (6)
C1—H10.930C24—C291.391 (7)
C2—C31.340 (10)C25—C261.398 (8)
C2—H20.930C25—H250.930
C3—C41.391 (9)C26—C271.338 (9)
C3—H30.930C26—H260.930
C4—C121.405 (6)C27—C281.374 (9)
C4—C51.423 (9)C27—H270.930
C5—C61.319 (9)C28—C291.372 (8)
C5—H50.930C28—H280.930
C6—C71.420 (9)C29—H290.930
C6—H60.930C30—C351.370 (7)
C7—C81.395 (9)C30—C311.376 (6)
C7—C111.414 (6)C31—C321.389 (7)
C8—C91.341 (9)C31—H310.930
C8—H80.930C32—C331.362 (8)
C9—C101.398 (8)C32—H320.930
C9—H90.930C33—C341.372 (8)
C10—H100.930C33—H330.930
C11—C121.420 (6)C34—C351.377 (7)
C13—C141.378 (6)C34—H340.930
C13—H130.930C35—H350.930
C14—C151.373 (6)B1—F21.313 (8)
C14—H140.930B1—F11.317 (8)
C15—C161.374 (6)B1—F41.344 (7)
C15—C15i1.504 (8)B1—F31.383 (9)
C16—C171.385 (6)
N1—Cu1—N3119.04 (14)C15—C16—C17120.5 (4)
N1—Cu1—N281.13 (15)C15—C16—H16119.7
N3—Cu1—N2108.35 (14)C17—C16—H16119.7
N1—Cu1—P1117.14 (10)N3—C17—C16123.8 (5)
N3—Cu1—P1109.56 (10)N3—C17—H17118.1
N2—Cu1—P1119.09 (11)C16—C17—H17118.1
C24—P1—C18104.6 (2)C19—C18—C23118.5 (5)
C24—P1—C30107.9 (2)C19—C18—P1119.1 (4)
C18—P1—C30102.2 (2)C23—C18—P1122.4 (4)
C24—P1—Cu1110.55 (15)C18—C19—C20120.1 (5)
C18—P1—Cu1120.67 (16)C18—C19—H19120.0
C30—P1—Cu1110.08 (15)C20—C19—H19120.0
C1—N1—C12117.7 (4)C21—C20—C19120.2 (6)
C1—N1—Cu1129.0 (4)C21—C20—H20119.9
C12—N1—Cu1113.1 (3)C19—C20—H20119.9
C10—N2—C11117.5 (4)C20—C21—C22120.5 (6)
C10—N2—Cu1132.2 (3)C20—C21—H21119.7
C11—N2—Cu1110.3 (3)C22—C21—H21119.7
C17—N3—C13115.8 (4)C21—C22—C23120.3 (6)
C17—N3—Cu1123.7 (3)C21—C22—H22119.9
C13—N3—Cu1119.8 (3)C23—C22—H22119.9
N1—C1—C2122.4 (6)C22—C23—C18120.4 (5)
N1—C1—H1118.8C22—C23—H23119.8
C2—C1—H1118.8C18—C23—H23119.8
C3—C2—C1119.5 (6)C25—C24—C29117.6 (5)
C3—C2—H2120.3C25—C24—P1124.5 (4)
C1—C2—H2120.3C29—C24—P1117.4 (4)
C2—C3—C4121.2 (6)C24—C25—C26119.9 (5)
C2—C3—H3119.4C24—C25—H25120.0
C4—C3—H3119.4C26—C25—H25120.0
C3—C4—C12115.8 (6)C27—C26—C25121.3 (6)
C3—C4—C5125.7 (6)C27—C26—H26119.4
C12—C4—C5118.6 (6)C25—C26—H26119.4
C6—C5—C4122.5 (7)C26—C27—C28120.0 (6)
C6—C5—H5118.7C26—C27—H27120.0
C4—C5—H5118.7C28—C27—H27120.0
C5—C6—C7120.8 (7)C29—C28—C27119.5 (6)
C5—C6—H6119.6C29—C28—H28120.2
C7—C6—H6119.6C27—C28—H28120.2
C8—C7—C11117.4 (6)C28—C29—C24121.7 (6)
C8—C7—C6123.7 (6)C28—C29—H29119.2
C11—C7—C6118.9 (6)C24—C29—H29119.2
C9—C8—C7120.3 (6)C35—C30—C31118.3 (4)
C9—C8—H8119.9C35—C30—P1117.6 (4)
C7—C8—H8119.9C31—C30—P1123.6 (4)
C8—C9—C10119.4 (6)C30—C31—C32120.9 (5)
C8—C9—H9120.3C30—C31—H31119.6
C10—C9—H9120.3C32—C31—H31119.6
N2—C10—C9123.4 (6)C33—C32—C31119.8 (5)
N2—C10—H10118.3C33—C32—H32120.1
C9—C10—H10118.3C31—C32—H32120.1
N2—C11—C7122.1 (5)C32—C33—C34119.9 (5)
N2—C11—C12118.0 (4)C32—C33—H33120.0
C7—C11—C12119.8 (5)C34—C33—H33120.0
N1—C12—C4123.4 (5)C33—C34—C35119.9 (6)
N1—C12—C11117.3 (4)C33—C34—H34120.0
C4—C12—C11119.3 (5)C35—C34—H34120.0
N3—C13—C14123.8 (4)C30—C35—C34121.2 (5)
N3—C13—H13118.1C30—C35—H35119.4
C14—C13—H13118.1C34—C35—H35119.4
C15—C14—C13120.6 (4)F2—B1—F1114.2 (7)
C15—C14—H14119.7F2—B1—F4114.4 (7)
C13—C14—H14119.7F1—B1—F4111.1 (5)
C14—C15—C16115.4 (4)F2—B1—F3105.1 (5)
C14—C15—C15i122.1 (5)F1—B1—F3103.4 (7)
C16—C15—C15i122.6 (5)F4—B1—F3107.6 (6)
N1—Cu1—P1—C24127.1 (2)C3—C4—C12—C11179.2 (4)
N3—Cu1—P1—C2493.35 (19)C5—C4—C12—C111.1 (6)
N2—Cu1—P1—C2432.1 (2)N2—C11—C12—N11.7 (5)
N1—Cu1—P1—C184.8 (2)C7—C11—C12—N1178.2 (4)
N3—Cu1—P1—C18144.3 (2)N2—C11—C12—C4179.0 (4)
N2—Cu1—P1—C1890.2 (2)C7—C11—C12—C41.1 (6)
N1—Cu1—P1—C30113.7 (2)C17—N3—C13—C140.3 (7)
N3—Cu1—P1—C3025.8 (2)Cu1—N3—C13—C14170.4 (4)
N2—Cu1—P1—C30151.3 (2)N3—C13—C14—C150.5 (7)
N3—Cu1—N1—C175.7 (4)C13—C14—C15—C161.0 (7)
N2—Cu1—N1—C1178.2 (4)C13—C14—C15—C15i179.7 (5)
P1—Cu1—N1—C160.0 (4)C14—C15—C16—C170.8 (7)
N3—Cu1—N1—C12110.2 (3)C15i—C15—C16—C17180.0 (5)
N2—Cu1—N1—C124.1 (3)C13—N3—C17—C160.6 (8)
P1—Cu1—N1—C12114.2 (3)Cu1—N3—C17—C16169.7 (4)
N1—Cu1—N2—C10179.3 (4)C15—C16—C17—N30.0 (9)
N3—Cu1—N2—C1061.5 (4)C24—P1—C18—C19102.0 (4)
P1—Cu1—N2—C1064.5 (4)C30—P1—C18—C19145.6 (4)
N1—Cu1—N2—C113.1 (3)Cu1—P1—C18—C1923.2 (5)
N3—Cu1—N2—C11120.9 (3)C24—P1—C18—C2376.6 (5)
P1—Cu1—N2—C11113.1 (3)C30—P1—C18—C2335.9 (5)
N1—Cu1—N3—C1771.9 (4)Cu1—P1—C18—C23158.3 (4)
N2—Cu1—N3—C17161.8 (4)C23—C18—C19—C202.6 (8)
P1—Cu1—N3—C1766.7 (4)P1—C18—C19—C20176.0 (5)
N1—Cu1—N3—C13118.1 (3)C18—C19—C20—C211.6 (10)
N2—Cu1—N3—C1328.2 (4)C19—C20—C21—C220.2 (11)
P1—Cu1—N3—C13103.2 (3)C20—C21—C22—C230.9 (10)
C12—N1—C1—C20.2 (7)C21—C22—C23—C180.2 (9)
Cu1—N1—C1—C2174.2 (4)C19—C18—C23—C221.9 (8)
N1—C1—C2—C30.8 (10)P1—C18—C23—C22176.6 (4)
C1—C2—C3—C40.7 (10)C18—P1—C24—C250.4 (4)
C2—C3—C4—C120.4 (9)C30—P1—C24—C25108.6 (4)
C2—C3—C4—C5179.3 (6)Cu1—P1—C24—C25131.0 (4)
C3—C4—C5—C6178.9 (6)C18—P1—C24—C29172.1 (4)
C12—C4—C5—C60.8 (9)C30—P1—C24—C2979.7 (4)
C4—C5—C6—C72.6 (10)Cu1—P1—C24—C2940.8 (4)
C5—C6—C7—C8177.4 (6)C29—C24—C25—C260.6 (7)
C5—C6—C7—C112.5 (8)P1—C24—C25—C26172.3 (4)
C11—C7—C8—C90.6 (8)C24—C25—C26—C271.1 (8)
C6—C7—C8—C9179.5 (6)C25—C26—C27—C281.5 (9)
C7—C8—C9—C100.1 (9)C26—C27—C28—C290.3 (10)
C11—N2—C10—C90.5 (7)C27—C28—C29—C241.4 (9)
Cu1—N2—C10—C9177.0 (4)C25—C24—C29—C281.8 (8)
C8—C9—C10—N20.7 (9)P1—C24—C29—C28174.1 (4)
C10—N2—C11—C70.3 (6)C24—P1—C30—C35167.8 (4)
Cu1—N2—C11—C7178.3 (3)C18—P1—C30—C3557.9 (4)
C10—N2—C11—C12179.8 (4)Cu1—P1—C30—C3571.5 (4)
Cu1—N2—C11—C121.8 (4)C24—P1—C30—C3120.1 (4)
C8—C7—C11—N20.9 (7)C18—P1—C30—C31130.0 (4)
C6—C7—C11—N2179.3 (4)Cu1—P1—C30—C31100.7 (4)
C8—C7—C11—C12179.2 (4)C35—C30—C31—C320.4 (7)
C6—C7—C11—C120.7 (6)P1—C30—C31—C32171.7 (4)
C1—N1—C12—C41.4 (6)C30—C31—C32—C330.1 (8)
Cu1—N1—C12—C4176.3 (3)C31—C32—C33—C340.9 (9)
C1—N1—C12—C11179.2 (4)C32—C33—C34—C351.2 (10)
Cu1—N1—C12—C114.4 (4)C31—C30—C35—C340.1 (8)
C3—C4—C12—N11.5 (7)P1—C30—C35—C34172.5 (5)
C5—C4—C12—N1178.2 (4)C33—C34—C35—C300.7 (9)
Symmetry code: (i) x+2, y+1, z+1.
 

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