(C₄H₁₂N₂)₃[Ga₄(OH)₂(H₂PO₄)₂(HPO₄)₄(PO₄)₂]: a new organically templated gallium phosphate

The solvothermal reaction of gallium oxide with phospho­ric acid in water/ethyl­ene glycol in the presence of piperazine gave the title compound, bis­(piperazinium) bis­(di­hydrogen­phos­phato)tetra-μ₂-hydrogenphosphato-di-μ₃-hydroxo-di-μ₃-phosphato-tetra­gallate(III), (C₄H₁₂N₂)₃[Ga₄(OH)₂(H₂PO₄)₂(HPO₄)₄(PO₄)₂]. The compound is isostructural with its Fe^III analogue, and contains one-dimensional anionic chains with piperazinium cations lying between them. The tetranuclear anionic building blocks and the piperazinium cations lie on inversion centres.

Key indicators

• Single-crystal X-ray study
• T = 295 K
• Mean [sigma](C-C) = 0.006 Å
• R factor = 0.029
• wR factor = 0.078
• Data-to-parameter ratio = 13.7

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT420_ALERT_2_B D-H Without Acceptor       O17    -   H17    ...          ?

Alert level C
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       2.00 Ratio
PLAT244_ALERT_4_C Low   'Solvent' Ueq as Compared to Neighbors for         N1
PLAT731_ALERT_1_C Bond    Calc     0.81(4), Rep   0.820(10) ......       4.00 su-Ra
              O8   -H8      1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     0.82(3), Rep   0.820(10) ......       3.00 su-Ra
              O12  -H12     1.555   1.555
PLAT731_ALERT_1_C Bond    Calc     0.81(4), Rep   0.810(10) ......       4.00 su-Ra
              O15  -H15     1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.81(4), Rep   0.820(10) ......       4.00 su-Ra
              O8   -H8      1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.82(3), Rep   0.820(10) ......       3.00 su-Ra
              O12  -H12     1.555   1.555
PLAT735_ALERT_1_C D-H     Calc     0.81(4), Rep   0.810(10) ......       4.00 su-Ra
              O15  -H15     1.555   1.555
PLAT736_ALERT_1_C H...A   Calc     1.88(4), Rep   1.880(10) ......       4.00 su-Ra
              H8   -O4      1.555   1.455
PLAT736_ALERT_1_C H...A   Calc     1.73(4), Rep   1.730(10) ......       4.00 su-Ra
              H12  -O16     1.555   2.555
PLAT736_ALERT_1_C H...A   Calc     2.04(3), Rep   2.030(10) ......       3.00 su-Ra
              H15  -O3      1.555   2.566
PLAT764_ALERT_4_C Overcomplete CIF Bond List Detected (Rep/Expd) .       1.19 Ratio

Alert level G
FORMU01_ALERT_1_G  There is a discrepancy between the atom counts in the
            _chemical_formula_sum and _chemical_formula_moiety. This is
            usually due to the moiety formula being in the wrong format.
            Atom count from _chemical_formula_sum:   C12 H46 Ga4 N6 O34 P8
            Atom count from _chemical_formula_moiety:C120 H360 N6300 O1020 P240

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
  14 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

  13 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   1 ALERT type 2 Indicator that the structure model may be wrong or deficient
   0 ALERT type 3 Indicator that the structure quality may be low
   2 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

---

Computing details

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Bruker, 2001); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Bis(piperazinium) bis(dihydrogenphosphato)tetra-µ₂-hydrogenphosphato- di-µ₃-hydroxo-di-µ₃-phosphato-tetragallate(III)

Crystal data

(C4H12N2)3[Ga4(OH)2(H2PO4)2(HPO4)4(PO4)2]	Z = 1
Mr = 1345.19	F(000) = 676
Triclinic, P1	Dx = 2.298 Mg m^−3
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 6.2754 (3) Å	Cell parameters from 6645 reflections
b = 13.0604 (5) Å	θ = 3.0–28.1°
c = 13.6268 (6) Å	µ = 3.20 mm^−1
α = 117.208 (1)°	T = 295 K
β = 98.796 (1)°	Needle, colourless
γ = 93.053 (1)°	0.50 × 0.15 × 0.10 mm
V = 971.90 (7) Å^3

Data collection

Bruker SMART 1K CCD diffractometer	4155 independent reflections
Radiation source: fine-focus sealed tube	3742 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.037
ω scans	θmax = 28.1°, θmin = 1.7°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −8→8
Tmin = 0.512, Tmax = 0.726	k = −16→16
9405 measured reflections	l = −17→17

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.029	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.078	H atoms treated by a mixture of independent and constrained refinement
S = 1.03	w = 1/[σ^2(Fo^2) + (0.0443P)^2 + 0.7591P] where P = (Fo^2 + 2Fc^2)/3
4155 reflections	(Δ/σ)max = 0.001
304 parameters	Δρmax = 0.76 e Å^−3
5 restraints	Δρmin = −0.73 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ga1	0.17098 (4)	0.35530 (2)	0.23964 (2)	0.01109 (9)
Ga2	0.51621 (4)	0.61654 (2)	0.49250 (2)	0.01162 (9)
P1	0.67664 (10)	0.39526 (5)	0.31399 (5)	0.01054 (14)
P2	0.17618 (11)	0.62581 (5)	0.29816 (5)	0.01215 (14)
P3	−0.08049 (11)	0.24252 (6)	−0.02624 (6)	0.01387 (15)
P4	0.14848 (11)	0.16429 (5)	0.32991 (6)	0.01353 (14)
O1	0.4732 (3)	0.34862 (15)	0.21935 (15)	0.0132 (4)
O2	−0.1219 (3)	0.36538 (17)	0.26491 (16)	0.0187 (4)
O3	0.3361 (3)	0.65857 (15)	0.60594 (15)	0.0142 (4)
O4	0.6940 (3)	0.52964 (15)	0.38366 (15)	0.0150 (4)
O5	0.1689 (3)	0.49589 (16)	0.22294 (16)	0.0172 (4)
O6	0.2284 (3)	0.69390 (16)	0.23761 (16)	0.0193 (4)
O7	0.3379 (3)	0.67140 (16)	0.40864 (17)	0.0222 (4)
O8	−0.0531 (3)	0.65631 (18)	0.3263 (2)	0.0251 (5)
H8	−0.113 (6)	0.621 (3)	0.353 (3)	0.038*
O9	−0.0432 (3)	0.35564 (17)	−0.03871 (17)	0.0199 (4)
H9	−0.090 (6)	0.340 (3)	−0.1039 (13)	0.030*
O10	0.0858 (3)	0.26177 (16)	0.07626 (15)	0.0160 (4)
O11	−0.3140 (3)	0.21481 (19)	−0.0259 (2)	0.0272 (5)
O12	−0.0017 (4)	0.14770 (19)	−0.12953 (18)	0.0297 (5)
H12	−0.076 (6)	0.086 (2)	−0.176 (3)	0.045*
O13	0.1649 (3)	0.20857 (16)	0.24506 (16)	0.0169 (4)
O14	0.7171 (3)	0.75314 (16)	0.55420 (16)	0.0190 (4)
O15	−0.0965 (3)	0.15218 (18)	0.3437 (2)	0.0249 (5)
H15	−0.157 (6)	0.209 (2)	0.370 (3)	0.037*
O16	0.2094 (4)	0.04272 (16)	0.28906 (17)	0.0228 (4)
O17	0.3037 (3)	0.45211 (15)	0.41223 (15)	0.0127 (4)
H17	0.195 (3)	0.465 (3)	0.439 (3)	0.019*
N1	−0.5940 (4)	0.1043 (2)	0.0372 (2)	0.0278 (6)
H1C	−0.5025	0.1483	0.0222	0.033*
H1D	−0.6982	0.1465	0.0671	0.033*
N2	0.5715 (4)	0.5805 (2)	−0.0373 (2)	0.0253 (5)
H2C	0.6989	0.5583	−0.0562	0.030*
H2D	0.5487	0.6412	−0.0501	0.030*
N3	0.3831 (5)	−0.0810 (2)	0.3895 (2)	0.0298 (6)
H3C	0.3342	−0.1544	0.3354	0.036*
H3D	0.3359	−0.0326	0.3633	0.036*
C1	−0.4750 (8)	0.0736 (3)	0.1180 (3)	0.0507 (12)
H1A	−0.5750	0.0302	0.1378	0.061*
H1B	−0.4073	0.1437	0.1860	0.061*
C2	−0.6957 (7)	−0.0018 (3)	−0.0690 (4)	0.0552 (13)
H2A	−0.7715	0.0203	−0.1224	0.066*
H2B	−0.8012	−0.0469	−0.0537	0.066*
C3	0.5857 (5)	0.6180 (3)	0.0849 (3)	0.0222 (6)
H3A	0.4558	0.6512	0.1076	0.027*
H3B	0.7102	0.6777	0.1283	0.027*
C4	0.2930 (6)	−0.0589 (3)	0.4915 (3)	0.0353 (8)
H4A	0.3361	−0.1143	0.5172	0.042*
H4B	0.1352	−0.0695	0.4727	0.042*
C5	0.3920 (5)	0.4822 (3)	−0.1097 (3)	0.0243 (6)
H5A	0.3957	0.4565	−0.1884	0.029*
H5B	0.2527	0.5089	−0.0965	0.029*
C6	0.6242 (6)	−0.0636 (3)	0.4152 (3)	0.0345 (8)
H6A	0.6789	−0.0761	0.3484	0.041*
H6B	0.6761	−0.1193	0.4386	0.041*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Ga1	0.01051 (15)	0.01008 (14)	0.01066 (15)	0.00174 (10)	0.00143 (10)	0.00337 (11)
Ga2	0.01470 (16)	0.00928 (14)	0.00940 (14)	0.00181 (10)	0.00160 (10)	0.00340 (11)
P1	0.0093 (3)	0.0102 (3)	0.0099 (3)	0.0013 (2)	0.0018 (2)	0.0029 (2)
P2	0.0143 (3)	0.0104 (3)	0.0108 (3)	0.0017 (2)	0.0009 (2)	0.0048 (3)
P3	0.0141 (3)	0.0120 (3)	0.0116 (3)	0.0008 (2)	−0.0011 (2)	0.0034 (3)
P4	0.0162 (3)	0.0086 (3)	0.0124 (3)	0.0001 (2)	−0.0005 (2)	0.0032 (3)
O1	0.0109 (8)	0.0151 (9)	0.0105 (8)	0.0024 (7)	0.0024 (7)	0.0032 (7)
O2	0.0123 (9)	0.0223 (10)	0.0186 (10)	0.0034 (7)	0.0058 (7)	0.0063 (8)
O3	0.0164 (9)	0.0144 (9)	0.0135 (9)	0.0039 (7)	0.0054 (7)	0.0072 (7)
O4	0.0173 (9)	0.0105 (9)	0.0135 (9)	0.0007 (7)	0.0057 (7)	0.0019 (7)
O5	0.0254 (10)	0.0109 (9)	0.0133 (9)	0.0034 (7)	0.0017 (8)	0.0046 (8)
O6	0.0269 (11)	0.0160 (9)	0.0156 (10)	0.0000 (8)	0.0021 (8)	0.0088 (8)
O7	0.0316 (12)	0.0123 (9)	0.0158 (10)	0.0025 (8)	−0.0075 (8)	0.0047 (8)
O8	0.0181 (10)	0.0231 (11)	0.0375 (13)	0.0049 (8)	0.0118 (9)	0.0151 (10)
O9	0.0233 (11)	0.0195 (10)	0.0167 (10)	0.0002 (8)	−0.0007 (8)	0.0101 (9)
O10	0.0184 (10)	0.0158 (9)	0.0099 (9)	0.0050 (7)	−0.0011 (7)	0.0036 (7)
O11	0.0170 (11)	0.0306 (12)	0.0385 (13)	−0.0024 (9)	0.0003 (9)	0.0221 (11)
O12	0.0315 (12)	0.0227 (11)	0.0165 (10)	0.0057 (9)	−0.0014 (9)	−0.0045 (9)
O13	0.0228 (10)	0.0118 (9)	0.0133 (9)	0.0023 (7)	0.0007 (7)	0.0044 (8)
O14	0.0254 (11)	0.0137 (9)	0.0124 (9)	−0.0054 (8)	−0.0020 (8)	0.0041 (8)
O15	0.0191 (11)	0.0220 (11)	0.0344 (12)	0.0010 (8)	0.0055 (9)	0.0141 (10)
O16	0.0336 (12)	0.0100 (9)	0.0193 (10)	0.0048 (8)	−0.0013 (9)	0.0041 (8)
O17	0.0124 (9)	0.0135 (9)	0.0114 (8)	0.0028 (7)	0.0038 (7)	0.0045 (7)
N1	0.0234 (13)	0.0160 (12)	0.0433 (17)	0.0095 (10)	0.0145 (12)	0.0103 (12)
N2	0.0270 (13)	0.0250 (13)	0.0275 (14)	−0.0018 (10)	0.0028 (11)	0.0168 (12)
N3	0.0444 (17)	0.0153 (12)	0.0239 (13)	0.0017 (11)	−0.0041 (12)	0.0079 (11)
C1	0.100 (4)	0.0215 (17)	0.0202 (17)	0.017 (2)	0.0047 (19)	0.0027 (14)
C2	0.042 (2)	0.0233 (18)	0.075 (3)	0.0031 (16)	−0.029 (2)	0.014 (2)
C3	0.0189 (14)	0.0197 (14)	0.0224 (14)	0.0016 (11)	0.0024 (11)	0.0059 (12)
C4	0.0373 (19)	0.0249 (16)	0.0372 (19)	−0.0021 (14)	0.0041 (15)	0.0109 (15)
C5	0.0213 (15)	0.0285 (16)	0.0214 (14)	0.0004 (12)	−0.0009 (11)	0.0121 (13)
C6	0.040 (2)	0.0243 (16)	0.0314 (18)	0.0051 (14)	0.0067 (15)	0.0064 (14)

Geometric parameters (Å, º)

Ga1—O2	1.9212 (19)	O15—H15	0.81 (1)
Ga1—O13	1.9499 (18)	O17—Ga2^i	2.1190 (18)
Ga1—O5	1.9512 (18)	O17—H17	0.81 (1)
Ga1—O10	1.9530 (18)	N1—C1	1.454 (5)
Ga1—O1	1.9586 (18)	N1—C2	1.487 (5)
Ga1—O17	2.0959 (18)	N1—H1C	0.900
Ga2—O7	1.8746 (19)	N1—H1D	0.900
Ga2—O14	1.8823 (19)	N2—C3	1.491 (4)
Ga2—O3	1.9474 (18)	N2—C5	1.496 (4)
Ga2—O4	1.9583 (18)	N2—H2C	0.900
Ga2—O17^i	2.1191 (18)	N2—H2D	0.900
Ga2—O17	2.1651 (18)	N3—C6	1.481 (5)
P1—O2^ii	1.5069 (19)	N3—C4	1.492 (5)
P1—O1	1.5362 (18)	N3—H3C	0.900
P1—O3^i	1.5535 (19)	N3—H3D	0.900
P1—O4	1.5549 (18)	C1—C2^iv	1.492 (6)
P2—O7	1.517 (2)	C1—H1A	0.970
P2—O6	1.517 (2)	C1—H1B	0.970
P2—O5	1.5228 (19)	C2—C1^iv	1.492 (6)
P2—O8	1.570 (2)	C2—H2A	0.970
P3—O11	1.492 (2)	C2—H2B	0.970
P3—O10	1.5192 (18)	C3—C5^v	1.503 (4)
P3—O12	1.563 (2)	C3—H3A	0.970
P3—O9	1.572 (2)	C3—H3B	0.970
P4—O16	1.5160 (19)	C4—C6^vi	1.515 (5)
P4—O14^i	1.5190 (19)	C4—H4A	0.970
P4—O13	1.524 (2)	C4—H4B	0.970
P4—O15	1.585 (2)	C5—C3^v	1.503 (4)
O2—P1^iii	1.5069 (19)	C5—H5A	0.970
O3—P1^i	1.5535 (19)	C5—H5B	0.970
O8—H8	0.82 (1)	C6—C4^vi	1.515 (5)
O9—H9	0.82 (1)	C6—H6A	0.970
O12—H12	0.82 (1)	C6—H6B	0.970
O14—P4^i	1.5190 (19)
O2—Ga1—O13	90.37 (8)	P4—O13—Ga1	138.52 (12)
O2—Ga1—O5	89.56 (8)	P4^i—O14—Ga2	135.72 (12)
O13—Ga1—O5	176.00 (8)	P4—O15—H15	120 (3)
O2—Ga1—O10	95.07 (8)	Ga1—O17—Ga2^i	123.73 (8)
O13—Ga1—O10	86.64 (8)	Ga1—O17—Ga2	125.78 (9)
O5—Ga1—O10	89.38 (8)	Ga2^i—O17—Ga2	94.30 (7)
O2—Ga1—O1	178.05 (8)	Ga1—O17—H17	101 (2)
O13—Ga1—O1	89.92 (8)	Ga2^i—O17—H17	103 (2)
O5—Ga1—O1	90.29 (8)	Ga2—O17—H17	106 (2)
O10—Ga1—O1	86.87 (8)	C1—N1—C2	110.7 (3)
O2—Ga1—O17	92.28 (8)	C1—N1—H1C	109.5
O13—Ga1—O17	92.40 (7)	C2—N1—H1C	109.5
O5—Ga1—O17	91.60 (7)	C1—N1—H1D	109.5
O10—Ga1—O17	172.60 (7)	C2—N1—H1D	109.5
O1—Ga1—O17	85.78 (7)	H1C—N1—H1D	108.1
O7—Ga2—O14	90.22 (9)	C3—N2—C5	112.1 (2)
O7—Ga2—O3	92.91 (9)	C3—N2—H2C	109.2
O14—Ga2—O3	101.00 (8)	C5—N2—H2C	109.2
O7—Ga2—O4	100.09 (9)	C3—N2—H2D	109.2
O14—Ga2—O4	91.66 (8)	C5—N2—H2D	109.2
O3—Ga2—O4	161.83 (8)	H2C—N2—H2D	107.9
O7—Ga2—O17^i	175.71 (8)	C6—N3—C4	111.3 (3)
O14—Ga2—O17^i	93.46 (8)	C6—N3—H3C	109.4
O3—Ga2—O17^i	84.22 (7)	C4—N3—H3C	109.4
O4—Ga2—O17^i	82.03 (7)	C6—N3—H3D	109.4
O7—Ga2—O17	90.81 (8)	C4—N3—H3D	109.4
O14—Ga2—O17	175.17 (8)	H3C—N3—H3D	108.0
O3—Ga2—O17	83.66 (7)	N1—C1—C2^iv	110.2 (3)
O4—Ga2—O17	83.52 (7)	N1—C1—H1A	109.6
O17^i—Ga2—O17	85.70 (7)	C2^iv—C1—H1A	109.6
O2^ii—P1—O1	110.15 (11)	N1—C1—H1B	109.6
O2^ii—P1—O3^i	108.70 (11)	C2^iv—C1—H1B	109.6
O1—P1—O3^i	110.62 (10)	H1A—C1—H1B	108.1
O2^ii—P1—O4	109.04 (11)	N1—C2—C1^iv	110.0 (3)
O1—P1—O4	109.66 (10)	N1—C2—H2A	109.7
O3^i—P1—O4	108.64 (10)	C1^iv—C2—H2A	109.7
O7—P2—O6	109.64 (12)	N1—C2—H2B	109.7
O7—P2—O5	112.67 (11)	C1^iv—C2—H2B	109.7
O6—P2—O5	110.90 (11)	H2A—C2—H2B	108.2
O7—P2—O8	107.81 (13)	N2—C3—C5^v	111.4 (2)
O6—P2—O8	104.07 (12)	N2—C3—H3A	109.3
O5—P2—O8	111.36 (12)	C5^v—C3—H3A	109.3
O11—P3—O10	117.07 (12)	N2—C3—H3B	109.3
O11—P3—O12	113.12 (14)	C5^v—C3—H3B	109.3
O10—P3—O12	105.33 (11)	H3A—C3—H3B	108.0
O11—P3—O9	110.66 (12)	N3—C4—C6^vi	110.5 (3)
O10—P3—O9	105.89 (11)	N3—C4—H4A	109.6
O12—P3—O9	103.67 (13)	C6^vi—C4—H4A	109.6
O16—P4—O14^i	110.83 (11)	N3—C4—H4B	109.6
O16—P4—O13	111.70 (12)	C6^vi—C4—H4B	109.6
O14^i—P4—O13	112.09 (11)	H4A—C4—H4B	108.1
O16—P4—O15	104.79 (12)	N2—C5—C3^v	111.0 (2)
O14^i—P4—O15	107.08 (12)	N2—C5—H5A	109.4
O13—P4—O15	110.00 (11)	C3^v—C5—H5A	109.4
P1—O1—Ga1	125.91 (11)	N2—C5—H5B	109.4
P1^iii—O2—Ga1	165.68 (14)	C3^v—C5—H5B	109.4
P1^i—O3—Ga2	126.09 (10)	H5A—C5—H5B	108.0
P1—O4—Ga2	126.95 (11)	N3—C6—C4^vi	109.5 (3)
P2—O5—Ga1	137.72 (12)	N3—C6—H6A	109.8
P2—O7—Ga2	140.06 (12)	C4^vi—C6—H6A	109.8
P2—O8—H8	118 (3)	N3—C6—H6B	109.8
P3—O9—H9	109 (3)	C4^vi—C6—H6B	109.8
P3—O10—Ga1	143.80 (12)	H6A—C6—H6B	108.2
P3—O12—H12	124 (3)
O2^ii—P1—O1—Ga1	175.43 (12)	O12—P3—O10—Ga1	175.8 (2)
O3^i—P1—O1—Ga1	55.23 (15)	O9—P3—O10—Ga1	66.4 (2)
O4—P1—O1—Ga1	−64.57 (15)	O2—Ga1—O10—P3	36.5 (2)
O13—Ga1—O1—P1	−87.38 (13)	O13—Ga1—O10—P3	126.6 (2)
O5—Ga1—O1—P1	96.61 (13)	O5—Ga1—O10—P3	−53.0 (2)
O10—Ga1—O1—P1	−174.02 (14)	O1—Ga1—O10—P3	−143.3 (2)
O17—Ga1—O1—P1	5.03 (13)	O16—P4—O13—Ga1	−165.63 (16)
O13—Ga1—O2—P1^iii	103.5 (5)	O14^i—P4—O13—Ga1	−40.6 (2)
O5—Ga1—O2—P1^iii	−80.5 (5)	O15—P4—O13—Ga1	78.4 (2)
O10—Ga1—O2—P1^iii	−169.9 (5)	O2—Ga1—O13—P4	−64.95 (19)
O17—Ga1—O2—P1^iii	11.1 (5)	O10—Ga1—O13—P4	−160.01 (19)
O7—Ga2—O3—P1^i	157.06 (14)	O1—Ga1—O13—P4	113.11 (18)
O14—Ga2—O3—P1^i	−112.15 (14)	O17—Ga1—O13—P4	27.34 (19)
O4—Ga2—O3—P1^i	21.2 (3)	O7—Ga2—O14—P4^i	137.80 (19)
O17^i—Ga2—O3—P1^i	−19.73 (13)	O3—Ga2—O14—P4^i	44.78 (19)
O17—Ga2—O3—P1^i	66.57 (13)	O4—Ga2—O14—P4^i	−122.11 (18)
O2^ii—P1—O4—Ga2	−165.27 (13)	O17^i—Ga2—O14—P4^i	−39.99 (19)
O1—P1—O4—Ga2	74.05 (15)	O2—Ga1—O17—Ga2^i	114.18 (11)
O3^i—P1—O4—Ga2	−46.95 (16)	O13—Ga1—O17—Ga2^i	23.72 (11)
O7—Ga2—O4—P1	−105.99 (14)	O5—Ga1—O17—Ga2^i	−156.20 (11)
O14—Ga2—O4—P1	163.50 (14)	O1—Ga1—O17—Ga2^i	−66.03 (10)
O3—Ga2—O4—P1	29.0 (3)	O2—Ga1—O17—Ga2	−119.51 (11)
O17^i—Ga2—O4—P1	70.23 (14)	O13—Ga1—O17—Ga2	150.03 (11)
O17—Ga2—O4—P1	−16.32 (13)	O5—Ga1—O17—Ga2	−29.88 (11)
O7—P2—O5—Ga1	41.8 (2)	O1—Ga1—O17—Ga2	60.29 (10)
O6—P2—O5—Ga1	165.16 (16)	O7—Ga2—O17—Ga1	44.73 (12)
O8—P2—O5—Ga1	−79.5 (2)	O3—Ga2—O17—Ga1	137.58 (11)
O2—Ga1—O5—P2	72.31 (19)	O4—Ga2—O17—Ga1	−55.33 (11)
O10—Ga1—O5—P2	167.38 (19)	O17^i—Ga2—O17—Ga1	−137.78 (13)
O1—Ga1—O5—P2	−105.75 (19)	O7—Ga2—O17—Ga2^i	−177.49 (9)
O17—Ga1—O5—P2	−19.96 (19)	O3—Ga2—O17—Ga2^i	−84.65 (7)
O6—P2—O7—Ga2	−133.0 (2)	O4—Ga2—O17—Ga2^i	82.45 (8)
O5—P2—O7—Ga2	−8.9 (3)	O17^i—Ga2—O17—Ga2^i	0.0
O8—P2—O7—Ga2	114.4 (2)	C2—N1—C1—C2^iv	58.1 (5)
O14—Ga2—O7—P2	149.9 (2)	C1—N1—C2—C1^iv	−58.0 (5)
O3—Ga2—O7—P2	−109.1 (2)	C5—N2—C3—C5^v	54.9 (3)
O4—Ga2—O7—P2	58.1 (2)	C6—N3—C4—C6^vi	58.2 (4)
O17—Ga2—O7—P2	−25.4 (2)	C3—N2—C5—C3^v	−54.6 (4)
O11—P3—O10—Ga1	−57.5 (3)	C4—N3—C6—C4^vi	−57.6 (4)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) x+1, y, z; (iii) x−1, y, z; (iv) −x−1, −y, −z; (v) −x+1, −y+1, −z; (vi) −x+1, −y, −z+1.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
N1—H1D···O10^iii	0.90	2.05	2.884 (3)	153
N1—H1C···O11	0.90	1.80	2.691 (3)	171
N3—H3C···O6^vii	0.90	1.82	2.717 (3)	174
N3—H3D···O16	0.90	1.84	2.726 (3)	170
O8—H8···O4^iii	0.82 (1)	1.88 (1)	2.674 (3)	166 (4)
O12—H12···O16^viii	0.82 (1)	1.73 (1)	2.540 (3)	171 (4)
O15—H15···O3^ix	0.81 (1)	2.03 (1)	2.829 (3)	166 (4)

Symmetry codes: (iii) x−1, y, z; (vii) x, y−1, z; (viii) −x, −y, −z; (ix) −x, −y+1, −z+1.