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Aqua­[N-phenyl-2-(quinolin-8-yl­­oxy)acetamide]dinitratozinc(II)

aDepartment of Physics and Chemistry, Henan Polytechnic University, Jiaozuo 454000, People's Republic of China
*Correspondence e-mail: wangyuan08@hpu.edu.cn

(Received 13 January 2010; accepted 6 February 2010; online 13 February 2010)

In the title complex, [Zn(NO3)2(C17H14N2O2)(H2O)], the six-coordinated Zn atom is in a distorted octa­hedral geometry, the donor centers being two O atoms and one N atom from the tridentate organic ligand, a water O atom and two O atoms from two monodentate nitrate ions. In the crystal, O—H⋯O hydrogen bonds between the coordinated water mol­ecules and nitrate O atoms and N—H⋯O hydrogen bonds between the main ligand and nitrate O atoms consolidate the three-dimensional network.

Related literature

For the synthesis of N-phenyl-2-(quinolin-8-yl­oxy)acetamide, see: Li et al. (2005[Li, X.-M., Wen, Y.-H., Li, M.-J. & Zhang, S.-S. (2005). Acta Cryst. E61, o2389-o2390.]); Wu et al. (2006[Wu, W.-N., Yuan, W.-B., Tang, N., Yang, R.-D., Yan, L. & Xu, Z.-H. (2006). Spectrochim. Acta A, 65, 912-918.]). For the crystal structure of the hydrate of this mol­ecule, see: Li et al. (2005[Li, X.-M., Wen, Y.-H., Li, M.-J. & Zhang, S.-S. (2005). Acta Cryst. E61, o2389-o2390.]). For the coordination ability of related amides to lanthanides, see: Cai & Tan (2002[Cai, Z.-H. & Tan, M.-Y. (2002). J. Rare Earths, 20, 382-384.]); Wu et al. (2006[Wu, W.-N., Yuan, W.-B., Tang, N., Yang, R.-D., Yan, L. & Xu, Z.-H. (2006). Spectrochim. Acta A, 65, 912-918.]).

[Scheme 1]

Experimental

Crystal data
  • [Zn(NO3)2(C17H14N2O2)(H2O)]

  • Mr = 485.71

  • Triclinic, [P \overline 1]

  • a = 7.9980 (14) Å

  • b = 9.5109 (16) Å

  • c = 13.359 (2) Å

  • α = 94.876 (2)°

  • β = 96.496 (2)°

  • γ = 106.031 (2)°

  • V = 963.2 (3) Å3

  • Z = 2

  • Mo Kα radiation

  • μ = 1.34 mm−1

  • T = 296 K

  • 0.30 × 0.19 × 0.11 mm

Data collection
  • Bruker SMART CCD diffractometer

  • Absorption correction: multi-scan (SADABS; Bruker, 1997[Bruker (1997). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.745, Tmax = 0.863

  • 10541 measured reflections

  • 4030 independent reflections

  • 3454 reflections with I > 2σ(I)

  • Rint = 0.028

Refinement
  • R[F2 > 2σ(F2)] = 0.034

  • wR(F2) = 0.093

  • S = 1.05

  • 4030 reflections

  • 281 parameters

  • H-atom parameters constrained

  • Δρmax = 0.66 e Å−3

  • Δρmin = −0.39 e Å−3

Table 1
Selected geometric parameters (Å, °)

Zn1—O6 2.0231 (17)
Zn1—O3 2.0494 (17)
Zn1—O9 2.0818 (17)
Zn1—O2 2.1110 (15)
Zn1—N1 2.1166 (17)
Zn1—O1 2.2612 (16)
O6—Zn1—O3 103.05 (7)
O6—Zn1—O9 86.57 (8)
O3—Zn1—O9 170.28 (7)
O6—Zn1—O2 93.07 (7)
O3—Zn1—O2 95.75 (7)
O9—Zn1—O2 85.04 (7)
O6—Zn1—N1 120.13 (8)
O3—Zn1—N1 86.60 (7)
O9—Zn1—N1 87.29 (7)
O2—Zn1—N1 145.38 (7)
O6—Zn1—O1 163.42 (7)
O3—Zn1—O1 86.10 (7)
O9—Zn1—O1 84.93 (7)
O2—Zn1—O1 72.04 (6)
N1—Zn1—O1 73.67 (6)

Table 2
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A DA D—H⋯A
O9—H9A⋯O6i 0.82 1.99 2.803 (3) 173
O9—H9B⋯O4ii 0.88 1.97 2.797 (3) 155
N2—H2⋯O8iii 0.86 2.07 2.869 (3) 155
Symmetry codes: (i) -x+1, -y+2, -z; (ii) x+1, y, z; (iii) x, y-1, z.

Data collection: SMART (Bruker, 1997[Bruker (1997). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 1997[Bruker (1997). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supporting information


Comment top

Including our previous work (Wu et al., 2006), the amide type ligands have been widely used to enhance the luminescent emissions of the lanthanide ions because of their excellent coordination ability (Cai & Tan, 2002). However, little work has been done on their transition metal complexes. Therefore, as part of our ongoing studies of the amide type ligands, the title complex was synthesized and characterized by X-ray diffraction.

As shown in Fig. 1, in the title complex, the six-coordinated Zn atom is in a distorted octahedral geometry with the donor centers of two O atoms and one N atom from the ligand, one O atom from one water molecule and two O atoms from two nitrate ions. The dihedral angle between phenyl ring and naphthyl ring is 22.5 (1)°.

In the crystal, O—H···O hydrogen bonds between the coordinated water molecules and nitrate O atoms, and N—H···O hydrogen bonds between the ligands and nitrate O atoms are helpful to consolidate the three-dimensional network (Fig. 2).

Related literature top

For the synthesis of N-phenyl-2-(quinolin-8-yloxy)acetamide, see: Li et al. (2005); Wu et al. (2006). For the crystal structure of the hydrate of this molecule, see: Li et al. (2005). For the coordination ability of related amides to lanthanides, see: Cai & Tan (2002); Wu et al. (2006).

Experimental top

N-phenyl-2-(quinolin-8-yloxy)acetamide (Wu et al., 2006; Li et al., 2005) (0.278 g, 1 mmol) was dissolved in acetonitrile (10 ml), then an acetonitrile solution (10 ml) containing zinc nitrate hexahydrate (0.295 g, 1 mmol) was added dropwise at room temperature. After stirring for 2 h, the mixture was filtered and set aside to crystallize at room temperature for 8 d, giving colorless prismatic crystals.

Refinement top

Atoms H9A and H9B (water molecule O9) were located in a difference map and their positions fixed, with Uiso(H) = 1.5Ueq(O9). Other H atoms bonded to C and N atoms were placed in calculated positions and treated using a riding-model approximation [aromatic groups: C—H = 0.93 Å and Uiso(H) = 1.2Ueq(carrier C); methylene group: C—H = 0.97 Å and Uiso(H) = 1.2Ueq(carrier C); amine group: N—H = 0.86 Å and Uiso(H2) = 1.2Ueq(N2)].

Computing details top

Data collection: SMART (Bruker, 1997); cell refinement: SAINT (Bruker, 1997); data reduction: SAINT (Bruker, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. The molecular structure shown with 50% probability displacement ellipsoids.
[Figure 2] Fig. 2. The crystal packing for the title complex via hydrogen bonds (dashed lines).
Aqua[N-phenyl-2-(quinolin-8-yloxy)acetamide]dinitratozinc(II) top
Crystal data top
[Zn(NO3)2(C17H14N2O2)(H2O)]Z = 2
Mr = 485.71F(000) = 496
Triclinic, P1Dx = 1.675 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 7.9980 (14) ÅCell parameters from 4639 reflections
b = 9.5109 (16) Åθ = 2.6–26.4°
c = 13.359 (2) ŵ = 1.34 mm1
α = 94.876 (2)°T = 296 K
β = 96.496 (2)°Prism, colorless
γ = 106.031 (2)°0.30 × 0.19 × 0.11 mm
V = 963.2 (3) Å3
Data collection top
Bruker SMART CCD
diffractometer
4030 independent reflections
Radiation source: fine-focus sealed tube3454 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.028
ϕ and ω scansθmax = 26.7°, θmin = 2.2°
Absorption correction: multi-scan
(SADABS; Bruker, 1997)
h = 1010
Tmin = 0.745, Tmax = 0.863k = 1111
10541 measured reflectionsl = 1616
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.034Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.093H-atom parameters constrained
S = 1.05 w = 1/[σ2(Fo2) + (0.0544P)2 + 0.1851P]
where P = (Fo2 + 2Fc2)/3
4030 reflections(Δ/σ)max < 0.001
281 parametersΔρmax = 0.66 e Å3
0 restraintsΔρmin = 0.39 e Å3
Crystal data top
[Zn(NO3)2(C17H14N2O2)(H2O)]γ = 106.031 (2)°
Mr = 485.71V = 963.2 (3) Å3
Triclinic, P1Z = 2
a = 7.9980 (14) ÅMo Kα radiation
b = 9.5109 (16) ŵ = 1.34 mm1
c = 13.359 (2) ÅT = 296 K
α = 94.876 (2)°0.30 × 0.19 × 0.11 mm
β = 96.496 (2)°
Data collection top
Bruker SMART CCD
diffractometer
4030 independent reflections
Absorption correction: multi-scan
(SADABS; Bruker, 1997)
3454 reflections with I > 2σ(I)
Tmin = 0.745, Tmax = 0.863Rint = 0.028
10541 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0340 restraints
wR(F2) = 0.093H-atom parameters constrained
S = 1.05Δρmax = 0.66 e Å3
4030 reflectionsΔρmin = 0.39 e Å3
281 parameters
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Zn10.40610 (3)0.96202 (3)0.180722 (18)0.03178 (10)
O10.3965 (2)0.74601 (17)0.24213 (12)0.0397 (4)
O20.2694 (2)0.78947 (17)0.06551 (12)0.0379 (4)
O30.1934 (2)0.9611 (2)0.25329 (13)0.0468 (4)
O40.0719 (3)0.9596 (3)0.26368 (17)0.0721 (6)
O50.0289 (3)0.9897 (3)0.12235 (16)0.0820 (8)
O60.4097 (3)1.1192 (2)0.08737 (14)0.0524 (5)
O70.3915 (4)1.2818 (2)0.20478 (17)0.0757 (7)
O80.3628 (4)1.3175 (2)0.04674 (17)0.0769 (7)
O90.6309 (2)0.9394 (2)0.12457 (14)0.0566 (5)
H9A0.61020.92050.06260.085*
H9B0.73720.94030.15130.085*
N10.5583 (2)1.0166 (2)0.32636 (13)0.0337 (4)
N20.2226 (3)0.5535 (2)0.00405 (15)0.0401 (5)
H20.23060.46950.01170.048*
N30.0477 (3)0.9699 (2)0.21100 (16)0.0447 (5)
N40.3863 (3)1.2425 (2)0.11447 (17)0.0480 (5)
C10.6333 (3)1.1531 (3)0.36958 (19)0.0450 (6)
H10.61031.23010.33750.054*
C20.7469 (4)1.1865 (3)0.4625 (2)0.0530 (7)
H2A0.79611.28400.49120.064*
C30.7839 (4)1.0767 (3)0.50957 (19)0.0528 (7)
H30.86051.09850.57030.063*
C40.7068 (3)0.9290 (3)0.46704 (17)0.0431 (6)
C50.7382 (4)0.8075 (4)0.5099 (2)0.0566 (7)
H50.81260.82230.57110.068*
C60.6612 (4)0.6687 (4)0.4632 (2)0.0608 (8)
H60.68420.58970.49270.073*
C70.5464 (4)0.6413 (3)0.37011 (19)0.0510 (7)
H70.49580.54560.33830.061*
C80.5119 (3)0.7573 (3)0.32834 (17)0.0370 (5)
C90.5925 (3)0.9046 (3)0.37403 (16)0.0343 (5)
C100.3655 (3)0.6234 (3)0.16737 (18)0.0411 (5)
H10A0.28770.53630.18800.049*
H10B0.47500.60330.15670.049*
C110.2808 (3)0.6650 (2)0.07116 (17)0.0339 (5)
C120.1501 (3)0.5535 (3)0.10558 (18)0.0381 (5)
C130.1263 (4)0.4259 (3)0.1706 (2)0.0494 (6)
H130.15770.34650.14650.059*
C140.0558 (4)0.4166 (3)0.2714 (2)0.0610 (8)
H140.04080.33110.31500.073*
C150.0081 (4)0.5329 (3)0.3068 (2)0.0629 (8)
H150.03940.52670.37440.076*
C160.0308 (4)0.6595 (3)0.2417 (2)0.0604 (8)
H160.00180.73820.26610.072*
C170.1011 (4)0.6711 (3)0.1408 (2)0.0493 (6)
H170.11540.75660.09740.059*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Zn10.03517 (16)0.03244 (16)0.02720 (15)0.01224 (11)0.00243 (10)0.00149 (10)
O10.0471 (9)0.0359 (9)0.0332 (8)0.0153 (7)0.0107 (7)0.0015 (7)
O20.0448 (9)0.0303 (8)0.0348 (8)0.0113 (7)0.0075 (7)0.0007 (6)
O30.0357 (9)0.0719 (12)0.0367 (9)0.0229 (8)0.0013 (7)0.0082 (8)
O40.0428 (11)0.1124 (19)0.0713 (15)0.0334 (12)0.0168 (10)0.0182 (13)
O50.0611 (14)0.148 (2)0.0473 (13)0.0476 (15)0.0026 (10)0.0271 (14)
O60.0806 (13)0.0421 (10)0.0500 (11)0.0342 (10)0.0243 (10)0.0164 (8)
O70.115 (2)0.0597 (14)0.0523 (13)0.0335 (13)0.0008 (12)0.0042 (11)
O80.126 (2)0.0575 (13)0.0664 (14)0.0540 (14)0.0119 (13)0.0232 (11)
O90.0378 (10)0.0931 (15)0.0413 (10)0.0280 (10)0.0000 (8)0.0016 (10)
N10.0325 (10)0.0397 (11)0.0271 (9)0.0100 (8)0.0001 (7)0.0016 (8)
N20.0509 (12)0.0290 (10)0.0365 (11)0.0114 (9)0.0060 (9)0.0010 (8)
N30.0375 (11)0.0521 (13)0.0450 (12)0.0175 (9)0.0009 (9)0.0022 (10)
N40.0587 (14)0.0367 (11)0.0504 (13)0.0177 (10)0.0046 (11)0.0070 (10)
C10.0481 (14)0.0432 (14)0.0376 (13)0.0074 (11)0.0004 (11)0.0016 (11)
C20.0539 (16)0.0532 (16)0.0370 (14)0.0016 (13)0.0032 (12)0.0062 (12)
C30.0450 (15)0.0700 (19)0.0307 (13)0.0029 (13)0.0070 (11)0.0007 (12)
C40.0370 (13)0.0630 (16)0.0257 (11)0.0110 (11)0.0010 (9)0.0032 (11)
C50.0592 (17)0.079 (2)0.0327 (13)0.0256 (15)0.0087 (12)0.0133 (14)
C60.077 (2)0.068 (2)0.0456 (16)0.0351 (17)0.0035 (14)0.0193 (14)
C70.0645 (17)0.0495 (15)0.0398 (14)0.0212 (13)0.0035 (12)0.0092 (12)
C80.0382 (12)0.0444 (13)0.0282 (11)0.0142 (10)0.0012 (9)0.0045 (9)
C90.0299 (11)0.0461 (13)0.0263 (11)0.0110 (9)0.0023 (8)0.0043 (9)
C100.0516 (14)0.0333 (12)0.0362 (12)0.0150 (10)0.0056 (10)0.0008 (10)
C110.0323 (11)0.0328 (12)0.0340 (12)0.0080 (9)0.0006 (9)0.0021 (9)
C120.0377 (12)0.0352 (12)0.0351 (12)0.0043 (9)0.0016 (9)0.0008 (9)
C130.0568 (16)0.0402 (14)0.0447 (14)0.0107 (12)0.0035 (12)0.0051 (11)
C140.072 (2)0.0539 (17)0.0426 (15)0.0062 (14)0.0029 (14)0.0165 (13)
C150.075 (2)0.0621 (19)0.0345 (14)0.0007 (15)0.0108 (13)0.0008 (13)
C160.073 (2)0.0503 (17)0.0489 (16)0.0117 (14)0.0149 (14)0.0106 (13)
C170.0614 (17)0.0370 (13)0.0413 (14)0.0084 (12)0.0077 (12)0.0008 (11)
Geometric parameters (Å, º) top
Zn1—O62.0231 (17)C3—C41.408 (4)
Zn1—O32.0494 (17)C3—H30.9300
Zn1—O92.0818 (17)C4—C51.403 (4)
Zn1—O22.1110 (15)C4—C91.418 (3)
Zn1—N12.1166 (17)C5—C61.354 (4)
Zn1—O12.2612 (16)C5—H50.9300
O1—C81.369 (3)C6—C71.418 (4)
O1—C101.416 (3)C6—H60.9300
O2—C111.220 (3)C7—C81.358 (3)
O3—N31.264 (3)C7—H70.9300
O4—N31.238 (3)C8—C91.421 (3)
O5—N31.214 (3)C10—C111.518 (3)
O6—N41.266 (3)C10—H10A0.9700
O7—N41.225 (3)C10—H10B0.9700
O8—N41.228 (3)C12—C171.384 (4)
O9—H9A0.8200C12—C131.385 (3)
O9—H9B0.8812C13—C141.385 (4)
N1—C11.320 (3)C13—H130.9300
N1—C91.360 (3)C14—C151.370 (4)
N2—C111.339 (3)C14—H140.9300
N2—C121.414 (3)C15—C161.379 (4)
N2—H20.8600C15—H150.9300
C1—C21.409 (4)C16—C171.384 (4)
C1—H10.9300C16—H160.9300
C2—C31.347 (4)C17—H170.9300
C2—H2A0.9300
O6—Zn1—O3103.05 (7)C5—C4—C3124.3 (2)
O6—Zn1—O986.57 (8)C5—C4—C9119.0 (2)
O3—Zn1—O9170.28 (7)C3—C4—C9116.6 (2)
O6—Zn1—O293.07 (7)C6—C5—C4120.6 (2)
O3—Zn1—O295.75 (7)C6—C5—H5119.7
O9—Zn1—O285.04 (7)C4—C5—H5119.7
O6—Zn1—N1120.13 (8)C5—C6—C7121.5 (3)
O3—Zn1—N186.60 (7)C5—C6—H6119.3
O9—Zn1—N187.29 (7)C7—C6—H6119.3
O2—Zn1—N1145.38 (7)C8—C7—C6118.8 (3)
O6—Zn1—O1163.42 (7)C8—C7—H7120.6
O3—Zn1—O186.10 (7)C6—C7—H7120.6
O9—Zn1—O184.93 (7)C7—C8—O1124.8 (2)
O2—Zn1—O172.04 (6)C7—C8—C9121.5 (2)
N1—Zn1—O173.67 (6)O1—C8—C9113.7 (2)
C8—O1—C10119.01 (18)N1—C9—C4122.7 (2)
C8—O1—Zn1114.78 (14)N1—C9—C8118.74 (19)
C10—O1—Zn1114.98 (13)C4—C9—C8118.6 (2)
C11—O2—Zn1120.10 (14)O1—C10—C11105.98 (18)
N3—O3—Zn1124.92 (15)O1—C10—H10A110.5
N4—O6—Zn1123.50 (16)C11—C10—H10A110.5
Zn1—O9—H9A109.5O1—C10—H10B110.5
Zn1—O9—H9B135.6C11—C10—H10B110.5
H9A—O9—H9B114.8H10A—C10—H10B108.7
C1—N1—C9118.3 (2)O2—C11—N2124.8 (2)
C1—N1—Zn1123.78 (16)O2—C11—C10121.6 (2)
C9—N1—Zn1117.69 (14)N2—C11—C10113.54 (19)
C11—N2—C12129.5 (2)C17—C12—C13120.1 (2)
C11—N2—H2115.3C17—C12—N2123.6 (2)
C12—N2—H2115.3C13—C12—N2116.3 (2)
O5—N3—O4122.1 (2)C12—C13—C14120.1 (3)
O5—N3—O3120.4 (2)C12—C13—H13120.0
O4—N3—O3117.5 (2)C14—C13—H13120.0
O7—N4—O8123.7 (2)C15—C14—C13120.1 (3)
O7—N4—O6119.6 (2)C15—C14—H14120.0
O8—N4—O6116.7 (2)C13—C14—H14120.0
N1—C1—C2122.5 (3)C14—C15—C16119.7 (3)
N1—C1—H1118.7C14—C15—H15120.1
C2—C1—H1118.7C16—C15—H15120.1
C3—C2—C1119.7 (3)C15—C16—C17121.1 (3)
C3—C2—H2A120.2C15—C16—H16119.5
C1—C2—H2A120.2C17—C16—H16119.5
C2—C3—C4120.1 (2)C16—C17—C12119.0 (3)
C2—C3—H3119.9C16—C17—H17120.5
C4—C3—H3119.9C12—C17—H17120.5
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O9—H9A···O6i0.821.992.803 (3)173
O9—H9B···O4ii0.881.972.797 (3)155
N2—H2···O8iii0.862.072.869 (3)155
Symmetry codes: (i) x+1, y+2, z; (ii) x+1, y, z; (iii) x, y1, z.

Experimental details

Crystal data
Chemical formula[Zn(NO3)2(C17H14N2O2)(H2O)]
Mr485.71
Crystal system, space groupTriclinic, P1
Temperature (K)296
a, b, c (Å)7.9980 (14), 9.5109 (16), 13.359 (2)
α, β, γ (°)94.876 (2), 96.496 (2), 106.031 (2)
V3)963.2 (3)
Z2
Radiation typeMo Kα
µ (mm1)1.34
Crystal size (mm)0.30 × 0.19 × 0.11
Data collection
DiffractometerBruker SMART CCD
diffractometer
Absorption correctionMulti-scan
(SADABS; Bruker, 1997)
Tmin, Tmax0.745, 0.863
No. of measured, independent and
observed [I > 2σ(I)] reflections
10541, 4030, 3454
Rint0.028
(sin θ/λ)max1)0.631
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.034, 0.093, 1.05
No. of reflections4030
No. of parameters281
H-atom treatmentH-atom parameters constrained
Δρmax, Δρmin (e Å3)0.66, 0.39

Computer programs: SMART (Bruker, 1997), SAINT (Bruker, 1997), SHELXS97 (Sheldrick, 2008), SHELXL97 (Sheldrick, 2008), SHELXTL (Sheldrick, 2008).

Selected geometric parameters (Å, º) top
Zn1—O62.0231 (17)Zn1—O22.1110 (15)
Zn1—O32.0494 (17)Zn1—N12.1166 (17)
Zn1—O92.0818 (17)Zn1—O12.2612 (16)
O6—Zn1—O3103.05 (7)O9—Zn1—N187.29 (7)
O6—Zn1—O986.57 (8)O2—Zn1—N1145.38 (7)
O3—Zn1—O9170.28 (7)O6—Zn1—O1163.42 (7)
O6—Zn1—O293.07 (7)O3—Zn1—O186.10 (7)
O3—Zn1—O295.75 (7)O9—Zn1—O184.93 (7)
O9—Zn1—O285.04 (7)O2—Zn1—O172.04 (6)
O6—Zn1—N1120.13 (8)N1—Zn1—O173.67 (6)
O3—Zn1—N186.60 (7)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O9—H9A···O6i0.821.992.803 (3)173.3
O9—H9B···O4ii0.881.972.797 (3)154.9
N2—H2···O8iii0.862.072.869 (3)154.7
Symmetry codes: (i) x+1, y+2, z; (ii) x+1, y, z; (iii) x, y1, z.
 

Acknowledgements

The authors are grateful for financial support from the Henan Administration of Science and Technology (grant No. 092102210363), the Main Teacher Project of Henan Province (grant No. 649082) and the Doctoral Foundation of Henan Polytechnic University (B2009–65 648359 and B2009–70 648364).

References

First citationBruker (1997). SMART, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.  Google Scholar
First citationCai, Z.-H. & Tan, M.-Y. (2002). J. Rare Earths, 20, 382–384.  Google Scholar
First citationLi, X.-M., Wen, Y.-H., Li, M.-J. & Zhang, S.-S. (2005). Acta Cryst. E61, o2389–o2390.  Web of Science CSD CrossRef IUCr Journals Google Scholar
First citationSheldrick, G. M. (2008). Acta Cryst. A64, 112–122.  Web of Science CrossRef CAS IUCr Journals Google Scholar
First citationWu, W.-N., Yuan, W.-B., Tang, N., Yang, R.-D., Yan, L. & Xu, Z.-H. (2006). Spectrochim. Acta A, 65, 912–918.  CrossRef Google Scholar

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