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Phase transformations that occur in both the heat-affected zone (HAZ) and the fusion zone (FZ) of a carbon–manganese steel spot weld have been investigated using time-resolved X-ray diffraction (TRXRD) with time resolutions down to 50 ms. It is found that in both zones the γ(f.c.c.) → α(b.c.c.) transformation on cooling is twice as fast as the forward transformation of α → γ on heating. Profile analysis of the major Bragg reflections recorded in the TRXRD patterns reveals similarities and differences in the microstructural evolution with time in the HAZ and in the FZ. The latter undergoes melting and solidification in addition to solid-state transformations. With increasing temperature, the (110) d-spacing of the α phase prior to and during the α → γ transformation and the (111) d-spacing of the γ phase just after the same transformation exhibit a decrease. The observed (and unusual) lattice contraction with temperature rise may be attributed to chemical effects, such as carbide precipitation in the α matrix, and/or mechanical effects due to stress relief. In the FZ, the γ-Fe that forms has a preferential (200) texture on solidification of the liquid, whereas, on cooling in the HAZ, the γ-Fe retains largely a (111) texture that is induced in the α → γ transformation on heating. On cooling in the HAZ, the width of the γ(111) reflection increases initially, which is indicative of microstrain developing in the f.c.c. lattice, but decreases as expected, with a reduction of thermal disorder, on further cooling until the completion of the γ → α transformation. In the FZ, however, the microstrain in the γ phase increases steadily on solidification and more rapidly for the duration of the γ → α transformation on further cooling. The final microstructure of the FZ is likely to consist of a single α phase dispersed in two morphological entities, whereas in the HAZ the α phase persists in one morphological entity in the final microstructure.
