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This paper describes the formation of two kinds of mixed crystals of MgCl2 and NaCl by ball milling magnesium chloride-ethanol adducts together with sodium chloride. X-ray diffraction analysis of the ball-milled MgCl2.2.5C2H5OH-NaCl powder shows that the two mixed crystals are NaMgCl3 and Na2MgCl4.

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