Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804023736/ac6123sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536804023736/ac6123Isup2.hkl |
CCDC reference: 255398
Key indicators
- Single-crystal X-ray study
- T = 298 K
- Mean (C-C) = 0.004 Å
- R factor = 0.033
- wR factor = 0.104
- Data-to-parameter ratio = 13.2
checkCIF/PLATON results
No syntax errors found
Alert level C PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ? PLAT155_ALERT_4_C The Triclinic Unitcell is NOT Reduced .......... ? PLAT156_ALERT_4_C Axial System Input Cell not Standard ........... ? PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors for O1 PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors for O2
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 5 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 2 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: WinAFC Diffractometer Control Software (Rigaku, 1999); cell refinement: WinAFC Diffractometer Control Software; data reduction: TEXSAN (Molecular Structure Corporation, 2001); program(s) used to solve structure: SIR92 (Altomare et al., 1994); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: TEXSAN.
[Cu(C15H14NO)2] | Z = 2 |
Mr = 512.09 | F(000) = 534.0 |
Triclinic, P1 | Dx = 1.354 Mg m−3 |
Hall symbol: -P 1 | Mo Kα radiation, λ = 0.7107 Å |
a = 11.943 (4) Å | Cell parameters from 25 reflections |
b = 11.944 (5) Å | θ = 11.0–12.5° |
c = 9.102 (3) Å | µ = 0.90 mm−1 |
α = 89.81 (3)° | T = 298 K |
β = 91.89 (3)° | Block, brown |
γ = 75.43 (3)° | 0.20 × 0.20 × 0.15 mm |
V = 1255.9 (8) Å3 |
Rigaku AFC-7R diffractometer | Rint = 0.028 |
ω–2θ scans | θmax = 27.5° |
Absorption correction: ψ scan (North et al., 1968) | h = −15→15 |
Tmin = 0.835, Tmax = 0.874 | k = −15→15 |
6444 measured reflections | l = −11→4 |
5773 independent reflections | 3 standard reflections every 150 reflections |
4237 reflections with I > 2σ(I) | intensity decay: 0.9% |
Refinement on F2 | H-atom parameters constrained |
R[F2 > 2σ(F2)] = 0.033 | w = 1/[σ2(Fo2) + (0.0553P)2 + 0.2726P] where P = (Fo2 + 2Fc2)/3 |
wR(F2) = 0.104 | (Δ/σ)max < 0.001 |
S = 1.01 | Δρmax = 0.41 e Å−3 |
4237 reflections | Δρmin = −0.46 e Å−3 |
320 parameters |
Refinement. Refinement using reflections with F2 > 0.0 σ(F2). The weighted R-factor (wR), goodness of fit (S) and R-factor (gt) are based on F, with F set to zero for negative F. The threshold expression of F2 > 2.0 σ(F2) is used only for calculating R-factor (gt). |
x | y | z | Uiso*/Ueq | ||
Cu1 | 0.0000 | 0.0000 | 0.0000 | 0.0410 (1) | |
Cu2 | 0.0000 | 0.5000 | 0.5000 | 0.0418 (1) | |
O1 | −0.1000 (2) | 0.0348 (2) | −0.1688 (2) | 0.0596 (4) | |
O2 | −0.0998 (2) | 0.5165 (1) | 0.3307 (2) | 0.0607 (4) | |
N1 | −0.0450 (1) | −0.1498 (1) | 0.0299 (2) | 0.0402 (3) | |
N2 | −0.0452 (1) | 0.6718 (1) | 0.5301 (2) | 0.0407 (3) | |
C1 | −0.2118 (2) | −0.1040 (2) | −0.1410 (2) | 0.0407 (4) | |
C2 | −0.1893 (2) | −0.0049 (2) | −0.2057 (2) | 0.0419 (4) | |
C3 | −0.2666 (2) | 0.0519 (2) | −0.3192 (3) | 0.0516 (5) | |
C4 | −0.3612 (2) | 0.0138 (2) | −0.3629 (3) | 0.0575 (6) | |
C5 | −0.3841 (2) | −0.0829 (3) | −0.2975 (3) | 0.0645 (6) | |
C6 | −0.3098 (2) | −0.1408 (2) | −0.1887 (3) | 0.0545 (5) | |
C7 | −0.1346 (2) | −0.1730 (2) | −0.0313 (2) | 0.0415 (4) | |
C8 | 0.0256 (2) | −0.2396 (2) | 0.1305 (2) | 0.0433 (4) | |
C9 | 0.1326 (2) | −0.3066 (2) | 0.0540 (3) | 0.0605 (6) | |
C10 | 0.2161 (2) | −0.3872 (2) | 0.1586 (2) | 0.0477 (5) | |
C11 | 0.1926 (2) | −0.4866 (2) | 0.2124 (3) | 0.0580 (5) | |
C12 | 0.2691 (3) | −0.5575 (2) | 0.3126 (3) | 0.0701 (7) | |
C13 | 0.3686 (3) | −0.5290 (3) | 0.3583 (3) | 0.0805 (9) | |
C14 | 0.3928 (3) | −0.4317 (3) | 0.3049 (4) | 0.0852 (9) | |
C15 | 0.3171 (2) | −0.3612 (2) | 0.2060 (3) | 0.0634 (6) | |
C16 | −0.2125 (2) | 0.7107 (2) | 0.3596 (2) | 0.0412 (4) | |
C17 | −0.1900 (2) | 0.6011 (2) | 0.2951 (2) | 0.0437 (4) | |
C18 | −0.2672 (2) | 0.5829 (2) | 0.1820 (3) | 0.0531 (5) | |
C19 | −0.3629 (2) | 0.6689 (2) | 0.1405 (3) | 0.0612 (6) | |
C20 | −0.3863 (2) | 0.7759 (2) | 0.2056 (3) | 0.0668 (7) | |
C21 | −0.3117 (2) | 0.7968 (2) | 0.3136 (3) | 0.0567 (5) | |
C22 | −0.1352 (2) | 0.7405 (2) | 0.4689 (2) | 0.0430 (4) | |
C23 | 0.0250 (2) | 0.7260 (2) | 0.6305 (2) | 0.0442 (4) | |
C24 | 0.1312 (2) | 0.7415 (2) | 0.5539 (3) | 0.0596 (6) | |
C25 | 0.2135 (2) | 0.7803 (2) | 0.6587 (2) | 0.0465 (5) | |
C26 | 0.3144 (2) | 0.7033 (2) | 0.7089 (3) | 0.0608 (6) | |
C27 | 0.3890 (2) | 0.7348 (3) | 0.8086 (4) | 0.0806 (8) | |
C28 | 0.3650 (3) | 0.8445 (3) | 0.8608 (3) | 0.0796 (9) | |
C29 | 0.2663 (3) | 0.9236 (3) | 0.8129 (3) | 0.0717 (8) | |
C30 | 0.1900 (2) | 0.8919 (2) | 0.7110 (3) | 0.0586 (6) | |
H1 | −0.2526 | 0.1181 | −0.3662 | 0.0621* | |
H2 | −0.4120 | 0.0543 | −0.4391 | 0.0694* | |
H3 | −0.4503 | −0.1086 | −0.3280 | 0.0779* | |
H4 | −0.3250 | −0.2074 | −0.1442 | 0.0655* | |
H5 | −0.1520 | −0.2429 | −0.0013 | 0.0501* | |
H6 | 0.0484 | −0.2038 | 0.2155 | 0.0523* | |
H7 | −0.0190 | −0.2912 | 0.1586 | 0.0523* | |
H8 | 0.1095 | −0.3507 | −0.0225 | 0.0729* | |
H9 | 0.1705 | −0.2533 | 0.0133 | 0.0729* | |
H10 | 0.1238 | −0.5068 | 0.1809 | 0.0697* | |
H11 | 0.2521 | −0.6257 | 0.3495 | 0.0844* | |
H12 | 0.4207 | −0.5772 | 0.4272 | 0.0967* | |
H13 | 0.4620 | −0.4121 | 0.3363 | 0.1025* | |
H14 | 0.3352 | −0.2935 | 0.1692 | 0.0760* | |
H15 | −0.2525 | 0.5104 | 0.1340 | 0.0642* | |
H16 | −0.4143 | 0.6541 | 0.0654 | 0.0737* | |
H17 | −0.4534 | 0.8345 | 0.1761 | 0.0804* | |
H18 | −0.3269 | 0.8706 | 0.3584 | 0.0683* | |
H19 | −0.1526 | 0.8190 | 0.4989 | 0.0518* | |
H20 | −0.0202 | 0.7993 | 0.6595 | 0.0535* | |
H21 | 0.0488 | 0.6777 | 0.7149 | 0.0535* | |
H22 | 0.1700 | 0.6698 | 0.5127 | 0.0717* | |
H23 | 0.1073 | 0.7978 | 0.4778 | 0.0717* | |
H24 | 0.3324 | 0.6263 | 0.6731 | 0.0732* | |
H25 | 0.4577 | 0.6797 | 0.8414 | 0.0970* | |
H26 | 0.4168 | 0.8661 | 0.9304 | 0.0955* | |
H27 | 0.2498 | 1.0003 | 0.8494 | 0.0864* | |
H28 | 0.1218 | 0.9472 | 0.6778 | 0.0704* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Cu1 | 0.0358 (2) | 0.0481 (2) | 0.0405 (2) | −0.0149 (1) | −0.0101 (1) | 0.0113 (1) |
Cu2 | 0.0364 (2) | 0.0447 (2) | 0.0410 (2) | −0.0056 (1) | −0.0094 (1) | −0.0067 (1) |
O1 | 0.0580 (9) | 0.070 (1) | 0.0582 (9) | −0.0343 (8) | −0.0263 (8) | 0.0270 (8) |
O2 | 0.0596 (10) | 0.0521 (9) | 0.0593 (10) | 0.0032 (7) | −0.0271 (8) | −0.0141 (7) |
N1 | 0.0376 (8) | 0.0439 (8) | 0.0375 (8) | −0.0080 (6) | −0.0025 (6) | 0.0079 (6) |
N2 | 0.0379 (8) | 0.0483 (9) | 0.0374 (8) | −0.0139 (7) | −0.0023 (7) | −0.0067 (7) |
C1 | 0.0369 (9) | 0.048 (1) | 0.0381 (10) | −0.0120 (8) | −0.0029 (7) | −0.0013 (8) |
C2 | 0.0377 (10) | 0.049 (1) | 0.0393 (10) | −0.0122 (8) | −0.0076 (8) | 0.0023 (8) |
C3 | 0.050 (1) | 0.056 (1) | 0.048 (1) | −0.0140 (10) | −0.0147 (9) | 0.0084 (9) |
C4 | 0.045 (1) | 0.073 (1) | 0.051 (1) | −0.010 (1) | −0.0168 (10) | 0.004 (1) |
C5 | 0.051 (1) | 0.090 (2) | 0.058 (1) | −0.031 (1) | −0.017 (1) | 0.005 (1) |
C6 | 0.051 (1) | 0.067 (1) | 0.052 (1) | −0.028 (1) | −0.0068 (10) | 0.003 (1) |
C7 | 0.042 (1) | 0.0425 (10) | 0.0404 (10) | −0.0119 (8) | 0.0000 (8) | 0.0031 (8) |
C8 | 0.044 (1) | 0.047 (1) | 0.0379 (10) | −0.0085 (8) | −0.0025 (8) | 0.0101 (8) |
C9 | 0.055 (1) | 0.071 (2) | 0.042 (1) | 0.009 (1) | 0.0042 (10) | 0.013 (1) |
C10 | 0.047 (1) | 0.050 (1) | 0.038 (1) | 0.0010 (9) | 0.0035 (8) | 0.0052 (8) |
C11 | 0.061 (1) | 0.059 (1) | 0.053 (1) | −0.014 (1) | 0.003 (1) | 0.003 (1) |
C12 | 0.087 (2) | 0.052 (1) | 0.062 (2) | 0.000 (1) | 0.016 (1) | 0.018 (1) |
C13 | 0.065 (2) | 0.092 (2) | 0.064 (2) | 0.017 (2) | −0.002 (1) | 0.025 (1) |
C14 | 0.053 (2) | 0.113 (3) | 0.084 (2) | −0.012 (2) | −0.016 (1) | 0.014 (2) |
C15 | 0.056 (1) | 0.063 (1) | 0.070 (2) | −0.013 (1) | 0.001 (1) | 0.008 (1) |
C16 | 0.0380 (10) | 0.046 (1) | 0.0384 (10) | −0.0092 (8) | −0.0029 (8) | 0.0023 (8) |
C17 | 0.040 (1) | 0.048 (1) | 0.041 (1) | −0.0096 (8) | −0.0075 (8) | 0.0031 (8) |
C18 | 0.052 (1) | 0.057 (1) | 0.049 (1) | −0.0142 (10) | −0.0144 (10) | −0.0005 (9) |
C19 | 0.049 (1) | 0.078 (2) | 0.054 (1) | −0.015 (1) | −0.019 (1) | 0.006 (1) |
C20 | 0.053 (1) | 0.074 (2) | 0.062 (2) | 0.004 (1) | −0.018 (1) | 0.005 (1) |
C21 | 0.054 (1) | 0.054 (1) | 0.054 (1) | 0.000 (1) | −0.008 (1) | 0.0005 (10) |
C22 | 0.045 (1) | 0.0433 (10) | 0.042 (1) | −0.0121 (8) | 0.0004 (8) | −0.0033 (8) |
C23 | 0.046 (1) | 0.051 (1) | 0.0382 (10) | −0.0171 (9) | −0.0020 (8) | −0.0102 (8) |
C24 | 0.055 (1) | 0.091 (2) | 0.042 (1) | −0.035 (1) | 0.0020 (10) | −0.015 (1) |
C25 | 0.046 (1) | 0.063 (1) | 0.0380 (10) | −0.0260 (10) | 0.0040 (8) | −0.0074 (9) |
C26 | 0.054 (1) | 0.066 (1) | 0.064 (1) | −0.017 (1) | 0.001 (1) | −0.008 (1) |
C27 | 0.051 (1) | 0.115 (3) | 0.074 (2) | −0.018 (2) | −0.011 (1) | −0.009 (2) |
C28 | 0.061 (2) | 0.133 (3) | 0.061 (2) | −0.053 (2) | 0.000 (1) | −0.025 (2) |
C29 | 0.090 (2) | 0.076 (2) | 0.065 (2) | −0.048 (2) | 0.020 (1) | −0.027 (1) |
C30 | 0.061 (1) | 0.060 (1) | 0.056 (1) | −0.018 (1) | 0.006 (1) | −0.004 (1) |
Cu1—O1 | 1.893 (2) | C12—C13 | 1.369 (5) |
Cu1—O1i | 1.893 (2) | C12—H11 | 0.950 |
Cu1—N1 | 2.013 (2) | C13—C14 | 1.359 (5) |
Cu1—N1i | 2.013 (2) | C13—H12 | 0.950 |
Cu2—O2 | 1.896 (2) | C14—C15 | 1.376 (4) |
Cu2—O2ii | 1.896 (2) | C14—H13 | 0.950 |
Cu2—N2 | 2.008 (2) | C15—H14 | 0.950 |
Cu2—N2ii | 2.008 (2) | C16—C17 | 1.403 (3) |
O1—C2 | 1.306 (3) | C16—C21 | 1.410 (3) |
O2—C17 | 1.308 (2) | C16—C22 | 1.442 (3) |
N1—C7 | 1.283 (3) | C17—C18 | 1.412 (3) |
N1—C8 | 1.479 (2) | C18—C19 | 1.372 (3) |
N2—C22 | 1.286 (2) | C18—H15 | 0.950 |
N2—C23 | 1.477 (3) | C19—C20 | 1.378 (4) |
C1—C2 | 1.409 (3) | C19—H16 | 0.950 |
C1—C6 | 1.407 (3) | C20—C21 | 1.370 (4) |
C1—C7 | 1.441 (3) | C20—H17 | 0.950 |
C2—C3 | 1.413 (3) | C21—H18 | 0.950 |
C3—C4 | 1.368 (4) | C22—H19 | 0.950 |
C3—H1 | 0.950 | C23—C24 | 1.518 (4) |
C4—C5 | 1.389 (4) | C23—H20 | 0.950 |
C4—H2 | 0.950 | C23—H21 | 0.950 |
C5—C6 | 1.369 (3) | C24—C25 | 1.504 (4) |
C5—H3 | 0.950 | C24—H22 | 0.950 |
C6—H4 | 0.950 | C24—H23 | 0.950 |
C7—H5 | 0.950 | C25—C26 | 1.382 (3) |
C8—C9 | 1.518 (3) | C25—C30 | 1.381 (3) |
C8—H6 | 0.950 | C26—C27 | 1.370 (4) |
C8—H7 | 0.950 | C26—H24 | 0.950 |
C9—C10 | 1.509 (3) | C27—C28 | 1.359 (5) |
C9—H8 | 0.950 | C27—H25 | 0.950 |
C9—H9 | 0.950 | C28—C29 | 1.369 (4) |
C10—C11 | 1.378 (4) | C28—H26 | 0.950 |
C10—C15 | 1.376 (4) | C29—C30 | 1.398 (4) |
C11—C12 | 1.391 (4) | C29—H27 | 0.950 |
C11—H10 | 0.950 | C30—H28 | 0.950 |
O1—Cu1—O1i | 180.0 | C13—C12—H11 | 120.0 |
O1—Cu1—N1 | 90.68 (7) | C12—C13—C14 | 119.8 (3) |
O1—Cu1—N1i | 89.32 (7) | C12—C13—H12 | 120.1 |
O1i—Cu1—N1 | 89.32 (7) | C14—C13—H12 | 120.1 |
O1i—Cu1—N1i | 90.68 (7) | C13—C14—C15 | 120.2 (3) |
N1—Cu1—N1i | 180.0 | C13—C14—H13 | 119.8 |
O2—Cu2—O2ii | 180.0 | C15—C14—H13 | 119.9 |
O2—Cu2—N2 | 90.66 (7) | C10—C15—C14 | 121.2 (3) |
O2—Cu2—N2ii | 89.34 (7) | C10—C15—H14 | 119.3 |
O2ii—Cu2—N2 | 89.34 (7) | C14—C15—H14 | 119.4 |
O2ii—Cu2—N2ii | 90.66 (7) | C17—C16—C21 | 119.7 (2) |
N2—Cu2—N2ii | 180.0 | C17—C16—C22 | 122.2 (2) |
Cu1—O1—C2 | 129.1 (1) | C21—C16—C22 | 118.1 (2) |
Cu2—O2—C17 | 128.8 (1) | O2—C17—C16 | 123.7 (2) |
Cu1—N1—C7 | 123.9 (1) | O2—C17—C18 | 118.5 (2) |
Cu1—N1—C8 | 119.9 (1) | C16—C17—C18 | 117.8 (2) |
C7—N1—C8 | 116.1 (2) | C17—C18—C19 | 120.8 (2) |
Cu2—N2—C22 | 124.0 (1) | C17—C18—H15 | 119.6 |
Cu2—N2—C23 | 120.1 (1) | C19—C18—H15 | 119.6 |
C22—N2—C23 | 115.9 (2) | C18—C19—C20 | 121.5 (2) |
C2—C1—C6 | 119.5 (2) | C18—C19—H16 | 119.2 |
C2—C1—C7 | 122.2 (2) | C20—C19—H16 | 119.4 |
C6—C1—C7 | 118.2 (2) | C19—C20—C21 | 119.1 (2) |
O1—C2—C1 | 123.5 (2) | C19—C20—H17 | 120.5 |
O1—C2—C3 | 118.9 (2) | C21—C20—H17 | 120.4 |
C1—C2—C3 | 117.5 (2) | C16—C21—C20 | 121.2 (2) |
C2—C3—C4 | 121.4 (2) | C16—C21—H18 | 119.3 |
C2—C3—H1 | 119.3 | C20—C21—H18 | 119.5 |
C4—C3—H1 | 119.3 | N2—C22—C16 | 126.6 (2) |
C3—C4—C5 | 120.9 (2) | N2—C22—H19 | 116.7 |
C3—C4—H2 | 119.5 | C16—C22—H19 | 116.7 |
C5—C4—H2 | 119.6 | N2—C23—C24 | 110.1 (2) |
C4—C5—C6 | 119.0 (3) | N2—C23—H20 | 109.4 |
C4—C5—H3 | 120.5 | N2—C23—H21 | 109.2 |
C6—C5—H3 | 120.5 | C24—C23—H20 | 109.3 |
C1—C6—C5 | 121.5 (2) | C24—C23—H21 | 109.3 |
C1—C6—H4 | 119.3 | H20—C23—H21 | 109.5 |
C5—C6—H4 | 119.2 | C23—C24—C25 | 111.7 (2) |
N1—C7—C1 | 126.7 (2) | C23—C24—H22 | 108.9 |
N1—C7—H5 | 116.7 | C23—C24—H23 | 108.9 |
C1—C7—H5 | 116.7 | C25—C24—H22 | 108.9 |
N1—C8—C9 | 109.9 (2) | C25—C24—H23 | 109.0 |
N1—C8—H6 | 109.4 | H22—C24—H23 | 109.4 |
N1—C8—H7 | 109.4 | C24—C25—C26 | 120.4 (2) |
C9—C8—H6 | 109.4 | C24—C25—C30 | 121.7 (2) |
C9—C8—H7 | 109.4 | C26—C25—C30 | 117.9 (2) |
H6—C8—H7 | 109.5 | C25—C26—C27 | 121.8 (2) |
C8—C9—C10 | 111.9 (2) | C25—C26—H24 | 119.0 |
C8—C9—H8 | 108.9 | C27—C26—H24 | 119.2 |
C8—C9—H9 | 108.9 | C26—C27—C28 | 120.1 (3) |
C10—C9—H8 | 108.8 | C26—C27—H25 | 119.8 |
C10—C9—H9 | 108.8 | C28—C27—H25 | 120.0 |
H8—C9—H9 | 109.5 | C27—C28—C29 | 119.8 (3) |
C9—C10—C11 | 121.5 (2) | C27—C28—H26 | 119.9 |
C9—C10—C15 | 120.3 (2) | C29—C28—H26 | 120.2 |
C11—C10—C15 | 118.2 (2) | C28—C29—C30 | 120.3 (3) |
C10—C11—C12 | 120.5 (3) | C28—C29—H27 | 119.7 |
C10—C11—H10 | 119.8 | C30—C29—H27 | 120.0 |
C12—C11—H10 | 119.7 | C25—C30—C29 | 120.1 (2) |
C11—C12—C13 | 120.0 (3) | C25—C30—H28 | 120.0 |
C11—C12—H11 | 120.0 | C29—C30—H28 | 119.9 |
Cu1—O1—C2—C1 | −15.9 (3) | C1—C6—C5—C4 | 0.6 (4) |
Cu1—O1—C2—C3 | 165.9 (1) | C1—C7—N1—C8 | −175.1 (2) |
Cu1—O1i—C2i—C1i | 15.9 (3) | C2—C1—C6—C5 | 0.3 (3) |
Cu1—O1i—C2i—C3i | −165.9 (1) | C2—C3—C4—C5 | −0.4 (3) |
Cu1—N1—C7—C1 | 6.5 (3) | C3—C2—C1—C6 | −1.3 (3) |
Cu1—N1—C8—C9 | −79.6 (2) | C3—C2—C1—C7 | 175.8 (2) |
Cu1—N1i—C7i—C1i | −6.5 (3) | C3—C4—C5—C6 | −0.6 (4) |
Cu1—N1i—C8i—C9i | 79.6 (2) | C5—C6—C1—C7 | −176.9 (2) |
Cu2—O2—C17—C16 | 16.9 (3) | C7—N1—C8—C9 | 101.9 (2) |
Cu2—O2—C17—C18 | −165.3 (2) | C8—C9—C10—C11 | 72.1 (3) |
Cu2—O2ii—C17ii—C16ii | −16.9 (3) | C8—C9—C10—C15 | −106.1 (3) |
Cu2—O2ii—C17ii—C18ii | 165.3 (2) | C9—C10—C11—C12 | −177.8 (2) |
Cu2—N2—C22—C16 | −6.2 (3) | C9—C10—C15—C14 | 178.0 (2) |
Cu2—N2—C23—C24 | 80.2 (2) | C10—C11—C12—C13 | −0.2 (4) |
Cu2—N2ii—C22ii—C16ii | 6.2 (3) | C10—C15—C14—C13 | −0.2 (5) |
Cu2—N2ii—C23ii—C24ii | −80.2 (2) | C11—C10—C15—C14 | −0.3 (4) |
O1—Cu1—N1—C7 | −16.5 (2) | C11—C12—C13—C14 | −0.3 (4) |
O1—Cu1—N1—C8 | 165.2 (1) | C12—C11—C10—C15 | 0.5 (3) |
O1—Cu1—N1i—C7i | −163.5 (2) | C12—C13—C14—C15 | 0.5 (5) |
O1—Cu1—N1i—C8i | 14.8 (1) | C16—C17—C18—C19 | −2.0 (4) |
O1—C2—C1—C6 | −179.5 (2) | C16—C21—C20—C19 | −0.6 (4) |
O1—C2—C1—C7 | −2.4 (3) | C16—C22—N2—C23 | 175.3 (2) |
O1—C2—C3—C4 | 179.7 (2) | C17—C16—C21—C20 | −0.6 (4) |
O2—Cu2—N2—C22 | 16.6 (2) | C17—C18—C19—C20 | 0.9 (4) |
O2—Cu2—N2—C23 | −164.9 (1) | C18—C17—C16—C21 | 1.9 (3) |
O2—Cu2—N2ii—C22ii | 163.4 (2) | C18—C17—C16—C22 | −175.9 (2) |
O2—Cu2—N2ii—C23ii | −15.1 (1) | C18—C19—C20—C21 | 0.4 (4) |
O2—C17—C16—C21 | 179.7 (2) | C20—C21—C16—C22 | 177.2 (2) |
O2—C17—C16—C22 | 1.9 (3) | C22—N2—C23—C24 | −101.2 (2) |
O2—C17—C18—C19 | −180.0 (2) | C23—C24—C25—C26 | 104.5 (3) |
N1—Cu1—O1—C2 | 21.6 (2) | C23—C24—C25—C30 | −73.7 (3) |
N1—Cu1—O1i—C2i | 158.4 (2) | C24—C25—C26—C27 | −177.5 (3) |
N1—C7—C1—C2 | 6.6 (3) | C24—C25—C30—C29 | 177.4 (2) |
N1—C7—C1—C6 | −176.3 (2) | C25—C26—C27—C28 | −0.2 (5) |
N1—C8—C9—C10 | 171.6 (2) | C25—C30—C29—C28 | 0.3 (4) |
N2—Cu2—O2—C17 | −22.4 (2) | C26—C25—C30—C29 | −0.8 (4) |
N2—Cu2—O2ii—C17ii | −157.6 (2) | C26—C27—C28—C29 | −0.3 (5) |
N2—C22—C16—C17 | −6.9 (4) | C27—C26—C25—C30 | 0.7 (4) |
N2—C22—C16—C21 | 175.4 (2) | C27—C28—C29—C30 | 0.3 (5) |
N2—C23—C24—C25 | −171.7 (2) | C27—C28—C29—C30 | 0.3 (5) |
C1—C2—C3—C4 | 1.3 (3) |
Symmetry codes: (i) −x, −y, −z; (ii) −x, −y+1, −z+1. |
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