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The title compound, [Zn(NCS)2(C14H13NO)2], is a butterfly-shaped mononuclear compound. The ZnII atom is coordinated by two N atoms from two thio­cyanate anions and two O atoms from two Schiff base ligands in a slightly distorted tetrahedral geometry.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804008335/ac6095sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536804008335/ac6095Isup2.hkl
Contains datablock I

CCDC reference: 239050

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.010 Å
  • R factor = 0.073
  • wR factor = 0.172
  • Data-to-parameter ratio = 13.0

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT029_ALERT_3_B _diffrn_measured_fraction_theta_full Low ....... 0.95
Alert level C PLAT048_ALERT_1_C MoietyFormula Not Given ........................ ? PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ? PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent ..... ? PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.15 Ratio PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... N3 PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... C13 PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... C28 PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... C29 PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C15 PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C27 PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C30 PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 10 PLAT360_ALERT_2_C Short C(sp3)-C(sp3) Bond C12 - C14 ... 1.43 Ang. PLAT360_ALERT_2_C Short C(sp3)-C(sp3) Bond C27 - C28 ... 1.43 Ang. PLAT360_ALERT_2_C Short C(sp3)-C(sp3) Bond C28 - C29 ... 1.41 Ang. PLAT410_ALERT_2_C Short Intra H...H Contact H8A .. H11A .. 1.98 Ang. PLAT410_ALERT_2_C Short Intra H...H Contact H23A .. H26A .. 1.95 Ang. PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 76 ZN1 -N4 -C30 -S2 82.00 16.00 1.555 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 80 ZN1 -N3 -C15 -S1 81.00 27.00 1.555 1.555 1.555 1.555
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 19 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 13 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 3 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Siemens, 1996); cell refinement: SMART; data reduction: SAINT (Siemens, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997a); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997a); molecular graphics: SHELXTL (Sheldrick, 1997b); software used to prepare material for publication: SHELXTL.

Bis[2-(cyclopropyliminiomethyl)naphthalato]dithiocyanatozinc(II) top
Crystal data top
[Zn(NCS)2(C14H13NO)2]Z = 2
Mr = 604.04F(000) = 624
Triclinic, P1Dx = 1.479 Mg m3
a = 8.849 (2) ÅMo Kα radiation, λ = 0.71073 Å
b = 9.803 (2) ÅCell parameters from 1459 reflections
c = 17.019 (3) Åθ = 2.5–21.3°
α = 86.25 (3)°µ = 1.10 mm1
β = 86.22 (3)°T = 293 K
γ = 67.20 (3)°Block, yellow
V = 1356.8 (5) Å30.27 × 0.25 × 0.18 mm
Data collection top
Bruker SMART CCD area-detector
diffractometer
4577 independent reflections
Radiation source: fine-focus sealed tube2544 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.079
φ and ω scansθmax = 25.0°, θmin = 2.3°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1010
Tmin = 0.756, Tmax = 0.827k = 811
6752 measured reflectionsl = 1920
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.073Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.172H atoms treated by a mixture of independent and constrained refinement
S = 0.93 w = 1/[σ2(Fo2) + (0.0777P)2]
where P = (Fo2 + 2Fc2)/3
4577 reflections(Δ/σ)max < 0.001
352 parametersΔρmax = 0.58 e Å3
6 restraintsΔρmin = 0.49 e Å3
Special details top

Experimental. All chemicals (reagent grade) used were commercially available. Elemental analyses for C, H and N were performed on a Perkin-Elmer 240 C elemental analyzer.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Zn10.32198 (9)0.20792 (8)0.25104 (4)0.0496 (3)
S10.3263 (2)0.5785 (2)0.40635 (12)0.0725 (6)
S20.1300 (2)0.2381 (3)0.11450 (13)0.0816 (7)
O10.3768 (5)0.0420 (4)0.3274 (2)0.0519 (10)
O20.4991 (5)0.1328 (5)0.1718 (2)0.0539 (11)
H2A0.58370.05830.18520.080*
N10.6044 (6)0.2022 (5)0.3714 (3)0.0505 (13)
H1A0.55860.13610.33200.080*
N20.7326 (7)0.1072 (6)0.1264 (3)0.0616 (15)
N30.3105 (7)0.3862 (6)0.2993 (4)0.0669 (16)
N40.1127 (7)0.2495 (6)0.2042 (4)0.0647 (16)
C10.3701 (7)0.0688 (6)0.4531 (3)0.0409 (14)
C20.3024 (7)0.0454 (6)0.3963 (4)0.0454 (15)
C30.1519 (8)0.1637 (7)0.4162 (4)0.0568 (17)
H3A0.10350.24150.37730.080*
C40.0770 (8)0.1678 (7)0.4874 (4)0.0547 (16)
H4A0.02300.25040.49920.080*
C50.0621 (8)0.0653 (7)0.6207 (4)0.0578 (17)
H5A0.03770.14930.63070.080*
C60.1233 (9)0.0399 (8)0.6781 (4)0.070 (2)
H6A0.06950.03230.72950.080*
C70.2667 (9)0.1603 (8)0.6608 (4)0.0642 (19)
H7A0.31120.23780.70040.080*
C80.3464 (7)0.1726 (7)0.5894 (4)0.0531 (16)
H8A0.44470.25800.57930.080*
C90.1407 (7)0.0574 (6)0.5465 (4)0.0467 (15)
C100.2876 (7)0.0633 (6)0.5290 (3)0.0429 (14)
C110.5225 (7)0.1851 (6)0.4370 (4)0.0465 (15)
H11A0.57000.25710.47870.080*
C120.7616 (9)0.3171 (8)0.3531 (4)0.068 (2)
H12A0.83700.28270.32350.080*
C130.7758 (11)0.4652 (8)0.3336 (6)0.097 (3)
H13A0.85370.51450.29250.080*
H13B0.67740.48500.33770.080*
C140.8419 (10)0.4414 (9)0.4049 (5)0.091 (3)
H14A0.78320.44760.45360.080*
H14B0.95880.47710.40850.080*
C170.4995 (7)0.1854 (6)0.1005 (3)0.0433 (14)
C160.6046 (7)0.1026 (7)0.0400 (4)0.0444 (14)
C180.3919 (8)0.3325 (7)0.0825 (4)0.0589 (17)
H18A0.32150.39060.12360.080*
C200.4842 (8)0.3704 (8)0.1305 (4)0.0627 (19)
H20A0.41200.47170.13990.080*
C210.5799 (9)0.2906 (9)0.1903 (4)0.068 (2)
H21A0.57610.33460.24250.080*
C220.6831 (9)0.1463 (8)0.1751 (4)0.0628 (18)
H22A0.74540.08580.21740.080*
C230.6955 (8)0.0861 (8)0.1015 (4)0.0580 (17)
H23A0.77380.01290.09180.080*
C240.4902 (8)0.3087 (7)0.0540 (4)0.0515 (16)
C250.6005 (7)0.1610 (7)0.0389 (4)0.0483 (15)
C260.7146 (8)0.0445 (7)0.0580 (4)0.0550 (16)
H26A0.78050.09980.01490.080*
C270.8409 (10)0.2589 (9)0.1425 (5)0.078 (2)
H27A0.78840.32080.16740.080*
C280.9754 (13)0.3418 (11)0.0916 (6)0.129 (4)
H28A0.99630.28870.04560.080*
H28B1.00240.44520.08490.080*
C291.0087 (10)0.2972 (12)0.1636 (8)0.123 (4)
H29A1.05020.37330.20420.080*
H29B1.04400.21630.16470.080*
C300.0122 (8)0.2472 (7)0.1659 (4)0.0537 (16)
C190.3883 (8)0.3908 (7)0.0079 (4)0.0626 (19)
H19A0.31630.49130.00400.080*
C150.3151 (7)0.4663 (7)0.3438 (4)0.0511 (16)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Zn10.0514 (5)0.0450 (5)0.0456 (5)0.0105 (4)0.0062 (3)0.0017 (3)
S10.0772 (14)0.0653 (12)0.0757 (14)0.0259 (11)0.0046 (10)0.0248 (10)
S20.0641 (13)0.0937 (16)0.0853 (16)0.0262 (12)0.0313 (11)0.0098 (12)
O10.063 (3)0.037 (2)0.043 (3)0.007 (2)0.000 (2)0.0036 (18)
O20.054 (3)0.054 (3)0.046 (3)0.013 (2)0.007 (2)0.000 (2)
N10.048 (3)0.042 (3)0.054 (3)0.008 (3)0.005 (3)0.002 (2)
N20.059 (4)0.053 (4)0.060 (4)0.008 (3)0.010 (3)0.013 (3)
N30.081 (4)0.045 (4)0.076 (4)0.024 (3)0.013 (3)0.002 (3)
N40.058 (4)0.063 (4)0.071 (4)0.020 (3)0.010 (3)0.002 (3)
C10.036 (3)0.035 (3)0.050 (4)0.011 (3)0.003 (3)0.005 (3)
C20.048 (4)0.037 (4)0.049 (4)0.012 (3)0.010 (3)0.002 (3)
C30.057 (4)0.045 (4)0.058 (4)0.006 (3)0.013 (4)0.000 (3)
C40.051 (4)0.038 (4)0.059 (4)0.000 (3)0.001 (3)0.003 (3)
C50.057 (4)0.050 (4)0.057 (4)0.011 (3)0.009 (3)0.004 (3)
C60.076 (5)0.073 (5)0.058 (5)0.028 (5)0.010 (4)0.005 (4)
C70.068 (5)0.054 (4)0.058 (5)0.013 (4)0.005 (4)0.018 (3)
C80.046 (4)0.051 (4)0.047 (4)0.002 (3)0.006 (3)0.005 (3)
C90.042 (4)0.042 (4)0.056 (4)0.015 (3)0.001 (3)0.010 (3)
C100.040 (3)0.042 (4)0.048 (4)0.015 (3)0.012 (3)0.000 (3)
C110.050 (4)0.041 (4)0.046 (4)0.013 (3)0.007 (3)0.002 (3)
C120.062 (5)0.050 (4)0.075 (5)0.005 (4)0.014 (4)0.001 (4)
C130.077 (6)0.055 (5)0.145 (9)0.010 (4)0.003 (6)0.027 (5)
C140.066 (5)0.086 (6)0.075 (6)0.020 (5)0.004 (4)0.007 (5)
C170.043 (4)0.046 (4)0.043 (4)0.020 (3)0.009 (3)0.000 (3)
C160.045 (4)0.044 (4)0.049 (4)0.021 (3)0.003 (3)0.007 (3)
C180.059 (4)0.051 (4)0.057 (4)0.010 (4)0.003 (3)0.002 (3)
C200.069 (5)0.073 (5)0.046 (4)0.029 (4)0.010 (4)0.011 (4)
C210.077 (5)0.089 (6)0.047 (4)0.042 (5)0.004 (4)0.006 (4)
C220.070 (5)0.070 (5)0.053 (5)0.030 (4)0.004 (4)0.006 (4)
C230.052 (4)0.067 (5)0.052 (4)0.020 (4)0.002 (3)0.006 (4)
C240.053 (4)0.054 (4)0.048 (4)0.022 (4)0.004 (3)0.001 (3)
C250.049 (4)0.053 (4)0.050 (4)0.027 (3)0.005 (3)0.002 (3)
C260.051 (4)0.051 (4)0.055 (4)0.009 (3)0.001 (3)0.008 (3)
C270.074 (5)0.072 (5)0.075 (6)0.018 (5)0.007 (4)0.007 (4)
C280.130 (7)0.087 (6)0.106 (7)0.023 (5)0.016 (6)0.008 (5)
C290.066 (6)0.097 (8)0.189 (12)0.010 (5)0.045 (7)0.014 (7)
C300.050 (4)0.053 (4)0.050 (4)0.013 (3)0.007 (3)0.004 (3)
C190.063 (5)0.047 (4)0.065 (5)0.009 (4)0.002 (4)0.006 (3)
C150.046 (4)0.046 (4)0.055 (4)0.011 (3)0.001 (3)0.000 (3)
Geometric parameters (Å, º) top
Zn1—O11.940 (4)C12—C141.427 (10)
Zn1—O21.943 (4)C12—C131.466 (10)
Zn1—N31.944 (6)C12—H12A0.9601
Zn1—N41.949 (6)C13—C141.451 (11)
S1—C151.614 (8)C13—H13A0.9600
S2—C301.613 (8)C13—H13B0.9599
O1—C21.302 (7)C14—H14A0.9600
O2—C171.288 (6)C14—H14B0.9600
O2—H2A0.8501C17—C161.407 (8)
N1—C111.274 (7)C17—C181.413 (8)
N1—C121.440 (8)C16—C261.419 (9)
N1—H1A0.9001C16—C251.422 (8)
N2—C261.270 (8)C18—C191.355 (8)
N2—C271.443 (9)C18—H18A0.9601
N3—C151.139 (8)C20—C211.356 (10)
N4—C301.144 (7)C20—C241.395 (8)
C1—C21.401 (8)C20—H20A0.9599
C1—C111.412 (8)C21—C221.372 (10)
C1—C101.435 (8)C21—H21A0.9600
C2—C31.424 (8)C22—C231.343 (9)
C3—C41.338 (8)C22—H22A0.9599
C3—H3A0.9598C23—C251.373 (9)
C4—C91.399 (8)C23—H23A0.9600
C4—H4A0.9600C24—C191.413 (9)
C5—C61.349 (9)C24—C251.416 (9)
C5—C91.392 (8)C26—H26A0.9603
C5—H5A0.9600C27—C281.426 (12)
C6—C71.388 (10)C27—C291.448 (11)
C6—H6A0.9601C27—H27A0.9600
C7—C81.352 (9)C28—C291.413 (13)
C7—H7A0.9600C28—H28A0.9600
C8—C101.404 (8)C28—H28B0.9600
C8—H8A0.9599C29—H29A0.9600
C9—C101.407 (8)C29—H29B0.9599
C11—H11A0.9600C19—H19A0.9601
O1—Zn1—O2101.46 (18)H13A—C13—H13B115.3
O1—Zn1—N3111.0 (2)C12—C14—C1361.2 (5)
O2—Zn1—N3114.5 (2)C12—C14—H14A116.1
O1—Zn1—N4112.0 (2)C13—C14—H14A116.7
O2—Zn1—N4109.5 (2)C12—C14—H14B119.2
N3—Zn1—N4108.3 (2)C13—C14—H14B118.8
C2—O1—Zn1124.5 (4)H14A—C14—H14B114.6
C17—O2—Zn1125.8 (4)O2—C17—C16122.4 (6)
C17—O2—H2A117.0O2—C17—C18118.8 (6)
Zn1—O2—H2A117.2C16—C17—C18118.8 (6)
C11—N1—C12127.1 (5)C17—C16—C26119.1 (6)
C11—N1—H1A116.6C17—C16—C25121.8 (6)
C12—N1—H1A116.3C26—C16—C25119.2 (6)
C26—N2—C27123.8 (6)C19—C18—C17120.2 (6)
C15—N3—Zn1162.6 (6)C19—C18—H18A120.4
C30—N4—Zn1163.9 (6)C17—C18—H18A119.4
C2—C1—C11120.1 (5)C21—C20—C24121.1 (7)
C2—C1—C10119.6 (5)C21—C20—H20A120.5
C11—C1—C10120.2 (5)C24—C20—H20A118.4
O1—C2—C1120.1 (5)C20—C21—C22119.3 (7)
O1—C2—C3121.6 (5)C20—C21—H21A120.4
C1—C2—C3118.3 (6)C22—C21—H21A120.2
C4—C3—C2121.4 (6)C23—C22—C21120.6 (7)
C4—C3—H3A119.7C23—C22—H22A118.9
C2—C3—H3A118.9C21—C22—H22A120.5
C3—C4—C9122.5 (6)C22—C23—C25122.5 (7)
C3—C4—H4A119.1C22—C23—H23A119.1
C9—C4—H4A118.4C25—C23—H23A118.3
C6—C5—C9121.9 (6)C20—C24—C19121.1 (7)
C6—C5—H5A119.8C20—C24—C25118.9 (6)
C9—C5—H5A118.3C19—C24—C25119.9 (6)
C5—C6—C7117.9 (7)C23—C25—C24117.3 (6)
C5—C6—H6A121.3C23—C25—C16125.4 (6)
C7—C6—H6A120.8C24—C25—C16117.3 (6)
C8—C7—C6122.0 (6)N2—C26—C16125.0 (6)
C8—C7—H7A118.6N2—C26—H26A118.1
C6—C7—H7A119.4C16—C26—H26A117.0
C7—C8—C10121.3 (6)C28—C27—N2124.3 (7)
C7—C8—H8A119.8C28—C27—C2958.9 (6)
C10—C8—H8A118.9N2—C27—C29121.5 (7)
C5—C9—C4121.5 (6)C28—C27—H27A110.9
C5—C9—C10120.4 (6)N2—C27—H27A114.9
C4—C9—C10118.2 (5)C29—C27—H27A114.9
C8—C10—C9116.5 (6)C29—C28—C2761.3 (6)
C8—C10—C1123.5 (5)C29—C28—H28A114.8
C9—C10—C1120.0 (5)C27—C28—H28A115.9
N1—C11—C1125.3 (5)C29—C28—H28B118.9
N1—C11—H11A116.6C27—C28—H28B121.0
C1—C11—H11A118.1H28A—C28—H28B114.7
C14—C12—N1123.9 (6)C28—C29—C2759.8 (6)
C14—C12—C1360.2 (5)C28—C29—H29A116.6
N1—C12—C13121.3 (6)C27—C29—H29A117.1
C14—C12—H12A112.7C28—C29—H29B120.8
N1—C12—H12A114.2C27—C29—H29B116.1
C13—C12—H12A114.1H29A—C29—H29B115.2
C14—C13—C1258.6 (5)N4—C30—S2177.6 (6)
C14—C13—H13A116.8C18—C19—C24121.9 (6)
C12—C13—H13A118.3C18—C19—H19A120.1
C14—C13—H13B118.9C24—C19—H19A118.0
C12—C13—H13B117.3N3—C15—S1178.6 (6)
O2—Zn1—O1—C2172.2 (4)C10—C1—C11—N1178.6 (5)
N3—Zn1—O1—C250.1 (5)C11—N1—C12—C147.5 (11)
N4—Zn1—O1—C271.1 (5)C11—N1—C12—C1380.4 (10)
O1—Zn1—O2—C17162.6 (4)N1—C12—C13—C14113.8 (8)
N3—Zn1—O2—C1777.8 (5)N1—C12—C14—C13109.7 (8)
N4—Zn1—O2—C1744.0 (5)Zn1—O2—C17—C16160.0 (4)
O1—Zn1—N3—C152 (2)Zn1—O2—C17—C1820.8 (7)
O2—Zn1—N3—C15112 (2)O2—C17—C16—C260.1 (8)
N4—Zn1—N3—C15126 (2)C18—C17—C16—C26179.1 (5)
O1—Zn1—N4—C3081 (2)O2—C17—C16—C25178.3 (5)
O2—Zn1—N4—C3031 (2)C18—C17—C16—C252.5 (8)
N3—Zn1—N4—C30156 (2)O2—C17—C18—C19179.4 (5)
Zn1—O1—C2—C1167.5 (4)C16—C17—C18—C191.3 (9)
Zn1—O1—C2—C312.5 (7)C24—C20—C21—C220.6 (10)
C11—C1—C2—O12.5 (8)C20—C21—C22—C233.1 (10)
C10—C1—C2—O1179.6 (5)C21—C22—C23—C253.9 (10)
C11—C1—C2—C3177.5 (5)C21—C20—C24—C19178.7 (6)
C10—C1—C2—C30.3 (8)C21—C20—C24—C251.0 (9)
O1—C2—C3—C4179.2 (5)C22—C23—C25—C242.1 (9)
C1—C2—C3—C40.8 (9)C22—C23—C25—C16178.3 (6)
C2—C3—C4—C90.0 (9)C20—C24—C25—C230.3 (8)
C9—C5—C6—C71.6 (10)C19—C24—C25—C23179.4 (6)
C5—C6—C7—C81.2 (11)C20—C24—C25—C16179.2 (5)
C6—C7—C8—C100.2 (10)C19—C24—C25—C161.0 (8)
C6—C5—C9—C4179.5 (6)C17—C16—C25—C23178.2 (5)
C6—C5—C9—C100.6 (9)C26—C16—C25—C230.2 (9)
C3—C4—C9—C5178.8 (6)C17—C16—C25—C242.3 (8)
C3—C4—C9—C101.3 (9)C26—C16—C25—C24179.3 (5)
C7—C8—C10—C91.1 (9)C27—N2—C26—C16177.5 (6)
C7—C8—C10—C1178.0 (5)C17—C16—C26—N23.6 (9)
C5—C9—C10—C80.8 (8)C25—C16—C26—N2178.0 (6)
C4—C9—C10—C8179.2 (5)C26—N2—C27—C2820.5 (13)
C5—C9—C10—C1178.4 (5)C26—N2—C27—C2992.1 (10)
C4—C9—C10—C11.7 (8)N2—C27—C28—C29109.1 (10)
C2—C1—C10—C8180.0 (5)N2—C27—C29—C28113.7 (9)
C11—C1—C10—C82.9 (8)Zn1—N4—C30—S282 (16)
C2—C1—C10—C90.9 (8)C17—C18—C19—C240.0 (10)
C11—C1—C10—C9176.2 (5)C20—C24—C19—C18179.7 (6)
C12—N1—C11—C1178.5 (6)C25—C24—C19—C180.1 (9)
C2—C1—C11—N14.3 (9)Zn1—N3—C15—S181 (27)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O2—H2A···N20.851.942.581 (7)132
N1—H1A···O10.901.862.565 (6)133
 

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