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The title compound, [TaCl3(C17H14N3)2].C7H8, is formed when 2,6-bis(phenylamino)pyridine and tantalum(V) chloride are refluxed in toluene. The organic ligand looses an amino proton and forms a σ bond with the metal atom while its pyridine N atom acts as a donor. A small chelate ring is formed. The two bidentate ligands and three Cl atoms afford a seven-coordinate central atom.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks ta26ap, global

fcf

Structure factor file (CIF format)
Contains datablock ta26ap

CCDC reference: 128234

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