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The reaction of dimethyl sulfoxide and ethyl bromoacetate at room temperature gives the title compound (CH3)3S.Br, which consists of layers of pyramidal trimethylsulfonium ions and bromide ions.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock PER_T

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 127957

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