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The structure of hexaaquagallium(III) hexahydrogentetracosaoxocobalt(III)hexamolybdate decahydrate, [Ga(H2O)6][Co(OH)6Mo6O18].10H2O, includes a polyanion with the so-called Anderson structure, of general formula H6[Xn+Mo6O24](6-n)- (X is a heteroatom), where all the O atoms in the central XO6 octahedron are protonated. The Ga3+ ion is coordinated by six water molecules and the Co3+ ion by six O atoms. Both ions are located at inversion centers.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, global

fcf

Structure factor file (CIF format)
Contains datablock ga

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