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The title compound, [Au(CF3){P(C6H5)3}], is the first mononuclear gold(I) complex with an Au-CF3 bond. The Au coordination is nearly linear with P-Au-C 178.56 (11)°, Au-P 2.2859 (9) and Au-C 2.045 (4) Å.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks I, default

fcf

Structure factor file (CIF format)
Contains datablock s420

CCDC reference: 126381

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