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The crystal structure of α-l,2,4,5-tetrachlorobenzene has been investigated by spectroscopic methods and packing calculations. With the existing unit-cell parameters, the crystal has been found to belong to space group P{\bar 1} with two unrelated molecules located at (0,0,0) and (1/2, 1/2, 0). Atomic positions are given. The structure is closely related to that of the monoclinic βphase. Calculated lattice vibration frequencies are in good agreement with experiment.
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