metal-organic compounds
The chloro-bridged dimeric structure of the title compound, bis[benzothiazole-2(3H)-thione]-1S;2S-di--chloro-1:24Cl-bis(triphenylphosphine)-1P;2P-di-copper(I) dihydrate, [Cu2Cl2(C7H5NS2)2(Ph3P)2].2H2O, is reported. The molecule is centrosymmetric with a CuCu distance of 3.400 (2) Å and two Cu--Cl distances of 2.396 (2) and 2.516 (2) Å. The heterocyclic ligand benzothiazole-2(3H)-thione acts as a monodentate ligand coordinating to copper through the S atom, with a Cu-S distance of 2.304 (3) Å. A hydrogen bond between the -Cl and heterocyclic N atom is also found, with a ClN distance of 3.134 (6) Å and ClH-N angle of 162.4°.
Supporting information
Crystallographic Information File (CIF) |
CCDC reference: 128411