Acta Crystallographica Section E

Structure Reports Online

Volume 64, Part 8 (August 2008)

inorganic compounds


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Acta Cryst. (2008). E64, i46    [ doi:10.1107/S1600536808018898 ]

Lithium manganese(II) diaquaborophosphate monohydrate

R.-C. Zhuang, X.-Y. Chen and J.-X. Mi

Abstract: The title compound, LiMn(H2O)2[BP2O8]·H2O, is built up of an open framework of helical borophosphate ribbons interconnected by MnO4(H2O)2 octahedra, forming one-dimensional channels along [001] occupied by Li+ cations and disordered H2O molecules (site occupancy 0.5). The Li cations reside in two partially occupied sites [occupancies = 0.42 (3) and 0.289 (13)] near the helices.

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