Acta Crystallographica Section E

Structure Reports Online

Volume 64, Part 7 (July 2008)


metal-organic compounds



Acta Cryst. (2008). E64, m851-m852    [ doi:10.1107/S1600536808015687 ]

Bis(5-chlorosalicylato-[kappa]O)bis(1,10-phenanthroline-[kappa]2N,N')cadmium(II)

D. Wen, J. Xie and X. Jiang

Abstract: In the title complex, [Cd(C7H4ClO3)2(C12H8N2)2], the Cd atom is coordinated by two 5-chlorosalicylate ligands and two 1,10-phenanthroline ligands, displaying a distorted octahedral coordination geometry. The crystal structure is stabilized by O-H...O and C-H...O hydrogen bonds and [pi]-[pi] interactions between the 1,10-phenanthroline ligands and 5-chlorosalicylate ligands, with a centroid-centroid distance between neighbouring aromatic rings of 3.730 (1) Å.

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