Acta Crystallographica Section E

Structure Reports Online

Volume 63, Part 2 (February 2007)

inorganic compounds


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Acta Cryst. (2007). E63, i41-i42    [ doi:10.1107/S1600536806056509 ]

Iron(II) hydrazinium sulfate

K. Srinivasan, S. Govindarajan and W. T. A. Harrison

Abstract: The title compound, poly[[dihydraziniumiron(II)]-di-[mu]-sulfato-[kappa]4O:O'], [Fe(SO4)2(N2H5)2]n, contains fairly regular trans-FeN2O4 octahedra. The Fe atoms (site symmetry \overline{1}) are bridged by pairs of sulfate groups into infinite [100] chains, which are cross-linked by a network of N-H...O hydrogen bonds. Fe(N2H5)2(SO4)2 is isostructural with its zinc, chromium(II) and cadmium-containing analogues.

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