Acta Crystallographica Section E

Structure Reports Online

Volume 63, Part 2 (February 2007)

inorganic compounds

 

Poly[triaquaocta--cyano-dicopper(II)molybdate(IV) monohydrate]

Y. Zhang, T. Hozumi, K. Hashimoto and S. Ohkoshi

Abstract: The structure of the title compound, Cu₂[Mo(CN)₈]·4H₂O, contains Mo^IV ions in a distorted square-antiprismatic geometry (site symmetry 1) linked through CN ligands to four Jahn-Teller-distorted octahedral Cu^II ions (site symmetry 2) and four trigonal-bipyramidal Cu^II ions (site symmetry 1).

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