Acta Crystallographica Section E

Structure Reports Online

Volume 60, Part 12 (December 2004)

metal-organic compounds

 

catena-Poly[[aquanitritosilver(I)]--1,4-diazabicyclo[2,2,2]octane-²N:N']

Z.-L. You, H.-L. Zhu and W.-S. Liu

Abstract: The title compound, [Ag(NO₂)(C₆H₁₂N₂)(H₂O)]_n, is a polymeric 1,4-diazabicyclo[2,2,2]octane-Ag^I complex. Each Ag atom is five-coordinated by two N atoms from two different 1,4-diazabicyclo[2,2,2]octane ligands, two O atoms of one nitrite anion and another O atom of a coordinated water molecule, forming a severely distorted square-pyramidal coordination environment. In the crystal structure, molecules are connected by intermolecular O-HO hydrogen bonds, forming a three-dimensional network.

Copyright © International Union of Crystallography
IUCr Webmaster