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The title complex, (penta­fluoro­propionato){tris­[2-(di­methyl­amino­methyl)­phenyl]­phosphine}silver(I), [P(C6H4CH2NMe2-2)3]Ag[OC(O)CF2CF3] or [Ag(C3F5O2)(C27H36N3P)], possesses a tetracoordinated silver(I) ion, with silver in a distorted tetrahedral environment. In the solid state, two independent mol­ecules are found in the asymmetric unit. The P(C6H4CH2NMe2-2)3 group acts as a tripodal ligand.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803028320/br6130sup1.cif
Contains datablocks global, 3

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536803028320/br61303sup2.hkl
Contains datablock 3

CCDC reference: 231830

Key indicators

  • Single-crystal X-ray study
  • T = 173 K
  • R factor = 0.033
  • wR factor = 0.080
  • Data-to-parameter ratio = 20.3

checkCIF/PLATON results

No syntax errors found



Alert level A GEOM005_ALERT_1_A _geom_angle_atom_site_label_1 is missing Label identifying the atom site 1. PLAT027_ALERT_3_A _diffrn_reflns_theta_full (too) Low ............ 0.00 Deg. PLAT029_ALERT_3_A _diffrn_measured_fraction_theta_full Low ....... 0.00 PLAT037_ALERT_1_A _diffrn_reflns_theta_full .......... Not Given . ? PLAT038_ALERT_1_A _diffrn_measured_fraction_theta_max Not Given . ? PLAT039_ALERT_1_A _diffrn_measured_fraction_theta_full Not Given . ? PLAT761_ALERT_1_A CIF Contains no X-H Bonds ...................... ? PLAT762_ALERT_1_A CIF Contains no X-Y-H or H-Y-H Angles .......... ?
Alert level B PLAT220_ALERT_2_B Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.79 Ratio PLAT222_ALERT_3_B Large Non-Solvent H Ueq(max)/Ueq(min) ... 4.87 Ratio
Alert level C PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density .... 2.69 PLAT164_ALERT_4_C Nr. of Refined C-H H-Atoms in Heavy-At Struct... 72 PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 2.77 Ratio PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C29 PLAT301_ALERT_3_C Main Residue Disorder ......................... 2.00 Perc.
8 ALERT level A = In general: serious problem 2 ALERT level B = Potentially serious problem 5 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 6 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 4 ALERT type 2 Indicator that the structure model may be wrong or deficient 4 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 2001); software used to prepare material for publication: SHELXL97.

(Pentafluoropropionato){tris[2-(dimethylaminomethyl)phenyl]phosphine}silver(I) top
Crystal data top
[Ag(C3F5O2)(C27H36N3P)]F(000) = 2880
Mr = 704.46Dx = 1.498 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 8602 reflections
a = 16.8535 (7) Åθ = 2.2–31.2°
b = 14.8719 (6) ŵ = 0.76 mm1
c = 26.0014 (11) ÅT = 173 K
β = 106.567 (1)°Irregular, colorless
V = 6246.5 (4) Å30.50 × 0.28 × 0.25 mm
Z = 8
Data collection top
Bruker SMART CCD area-detector
diffractometer
21437 independent reflections
Radiation source: fine-focus sealed tube17914 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.036
ω scansθmax = 32.0°, θmin = 1.6°
Absorption correction: multi-scan
(SADABS; Sheldrick, 2001)
h = 2524
Tmin = 0.775, Tmax = 0.827k = 022
105617 measured reflectionsl = 038
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.033Hydrogen site location: difference Fourier map
wR(F2) = 0.080All H-atom parameters refined
S = 1.09 w = 1/[σ2(Fo2) + (0.0303P)2 + 6.2345P]
where P = (Fo2 + 2Fc2)/3
21437 reflections(Δ/σ)max = 0.006
1054 parametersΔρmax = 1.21 e Å3
0 restraintsΔρmin = 0.45 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.414830 (8)0.320664 (9)0.636157 (5)0.01734 (3)
Ag20.129597 (8)0.729055 (9)0.633881 (5)0.01615 (3)
P10.38391 (3)0.29310 (3)0.540969 (16)0.01345 (7)
P20.10642 (3)0.79331 (3)0.712572 (16)0.01192 (7)
F10.44839 (12)0.43849 (11)0.83499 (6)0.0515 (4)
F20.32098 (9)0.41318 (11)0.78878 (5)0.0414 (4)
F30.36863 (10)0.31724 (12)0.87683 (6)0.0442 (4)
F40.47132 (11)0.26081 (15)0.85454 (8)0.0470 (6)0.919 (5)
F50.34786 (15)0.23319 (11)0.80644 (8)0.0469 (6)0.919 (5)
F4A0.4915 (11)0.3168 (15)0.8673 (7)0.034 (5)*0.081 (5)
F5A0.3945 (14)0.2297 (12)0.8246 (8)0.032 (5)*0.081 (5)
F60.02333 (9)0.66277 (10)0.43834 (5)0.0363 (3)
F70.14996 (10)0.64176 (10)0.43615 (5)0.0381 (3)
F80.09324 (9)0.79701 (9)0.39336 (5)0.0315 (3)
F90.18595 (11)0.81644 (12)0.46846 (6)0.0503 (4)
F100.05760 (12)0.83926 (10)0.46229 (6)0.0499 (4)
O10.37072 (9)0.34240 (12)0.71032 (5)0.0296 (3)
O20.50182 (10)0.37105 (15)0.75743 (6)0.0412 (4)
O30.08189 (10)0.70947 (11)0.54502 (5)0.0278 (3)
O40.19142 (10)0.62571 (12)0.54170 (6)0.0338 (3)
N10.50177 (11)0.45034 (11)0.63193 (6)0.0216 (3)
N20.47774 (9)0.17242 (11)0.65556 (6)0.0178 (3)
N30.21221 (11)0.27262 (17)0.55946 (7)0.0362 (5)
N40.25909 (10)0.80999 (13)0.64796 (6)0.0237 (3)
N50.13701 (10)0.57626 (10)0.67111 (6)0.0190 (3)
N60.01422 (9)0.91003 (10)0.62628 (6)0.0178 (3)
C10.48136 (10)0.31860 (11)0.52484 (6)0.0148 (3)
C20.52585 (11)0.39708 (11)0.54529 (6)0.0164 (3)
C30.60245 (12)0.41167 (13)0.53577 (7)0.0211 (3)
C40.63486 (12)0.35195 (14)0.50600 (8)0.0233 (4)
C50.59003 (12)0.27565 (13)0.48483 (7)0.0216 (3)
C60.51422 (11)0.25873 (12)0.49455 (7)0.0180 (3)
C70.49228 (12)0.46916 (12)0.57458 (7)0.0199 (3)
C80.58891 (14)0.44013 (19)0.66224 (8)0.0342 (5)
C90.4647 (2)0.52536 (16)0.65375 (10)0.0382 (6)
C100.37270 (10)0.17215 (11)0.52731 (6)0.0150 (3)
C110.42666 (11)0.10998 (12)0.56110 (7)0.0163 (3)
C120.41497 (13)0.01859 (13)0.54903 (8)0.0246 (4)
C130.35134 (15)0.01211 (14)0.50571 (9)0.0286 (4)
C140.29830 (13)0.04904 (13)0.47329 (8)0.0251 (4)
C150.30948 (11)0.14043 (13)0.48409 (7)0.0190 (3)
C160.49951 (11)0.13595 (12)0.60832 (7)0.0169 (3)
C170.55446 (12)0.18308 (15)0.69981 (8)0.0250 (4)
C180.42031 (13)0.11377 (14)0.67300 (8)0.0232 (4)
C190.30530 (11)0.34628 (12)0.48555 (7)0.0172 (3)
C200.23147 (13)0.37930 (16)0.49306 (8)0.0287 (4)
C210.17411 (16)0.42161 (19)0.45007 (10)0.0417 (6)
C220.18776 (16)0.42910 (17)0.40063 (9)0.0377 (5)
C230.25934 (14)0.39541 (14)0.39241 (8)0.0272 (4)
C240.31853 (12)0.35546 (12)0.43512 (7)0.0195 (3)
C250.21204 (14)0.3673 (2)0.54576 (9)0.0369 (6)
C260.20575 (18)0.2608 (3)0.61388 (10)0.0560 (10)
C270.14459 (16)0.2241 (3)0.52182 (10)0.0509 (9)
C280.42756 (12)0.36264 (13)0.75102 (7)0.0206 (3)
C290.39833 (12)0.37969 (12)0.80148 (7)0.0188 (3)
C300.39742 (13)0.29661 (15)0.83551 (8)0.0266 (4)
C310.15414 (10)0.90446 (11)0.72538 (6)0.0147 (3)
C320.23085 (10)0.92117 (12)0.71515 (6)0.0170 (3)
C330.26034 (12)1.00923 (14)0.72008 (7)0.0242 (4)
C340.21729 (14)1.07944 (14)0.73481 (8)0.0280 (4)
C350.14366 (13)1.06243 (13)0.74668 (8)0.0248 (4)
C360.11292 (11)0.97500 (12)0.74215 (7)0.0185 (3)
C370.28546 (11)0.84851 (14)0.70264 (7)0.0203 (3)
C380.32142 (14)0.7425 (2)0.64388 (10)0.0382 (6)
C390.25364 (17)0.8807 (2)0.60784 (8)0.0382 (6)
C400.16858 (10)0.72608 (11)0.76952 (6)0.0141 (3)
C410.16574 (10)0.63135 (12)0.76667 (6)0.0158 (3)
C420.21480 (11)0.58228 (13)0.80990 (7)0.0199 (3)
C430.26587 (12)0.62460 (14)0.85509 (7)0.0219 (3)
C440.26789 (11)0.71766 (14)0.85790 (7)0.0208 (3)
C450.21952 (11)0.76761 (13)0.81525 (7)0.0173 (3)
C460.10912 (12)0.58009 (12)0.72023 (7)0.0189 (3)
C470.07435 (15)0.52787 (15)0.62914 (8)0.0293 (4)
C480.21715 (14)0.53025 (15)0.68098 (9)0.0282 (4)
C490.00722 (10)0.80243 (11)0.72771 (6)0.0138 (3)
C500.06694 (10)0.81669 (11)0.68665 (7)0.0159 (3)
C510.14170 (11)0.81815 (13)0.69999 (8)0.0207 (3)
C520.14386 (12)0.80649 (13)0.75265 (8)0.0225 (4)
C530.07112 (12)0.79274 (13)0.79285 (8)0.0226 (3)
C540.00399 (11)0.79058 (12)0.78041 (7)0.0183 (3)
C550.06644 (11)0.83300 (12)0.62946 (7)0.0184 (3)
C560.00169 (14)0.91593 (16)0.57416 (8)0.0266 (4)
C570.05039 (13)0.99378 (13)0.63779 (8)0.0238 (4)
C580.12919 (12)0.67111 (13)0.52268 (7)0.0210 (3)
C590.10288 (12)0.68855 (13)0.46112 (7)0.0213 (3)
C600.10923 (14)0.78696 (14)0.44634 (7)0.0249 (4)
H30.6308 (15)0.4650 (17)0.5482 (10)0.025 (6)*
H40.6851 (16)0.3636 (17)0.4992 (10)0.026 (6)*
H50.6093 (16)0.2381 (17)0.4640 (10)0.025 (6)*
H60.4862 (15)0.2052 (17)0.4807 (10)0.023 (6)*
H7A0.4345 (14)0.4785 (15)0.5578 (9)0.016 (5)*
H7B0.5186 (14)0.5271 (16)0.5721 (9)0.020 (6)*
H8A0.5906 (17)0.4290 (19)0.6983 (11)0.036 (7)*
H8B0.6141 (16)0.3903 (19)0.6475 (11)0.030 (7)*
H8C0.621 (2)0.493 (2)0.6596 (13)0.051 (9)*
H9A0.4704 (17)0.5118 (19)0.6916 (11)0.036 (7)*
H9B0.404 (2)0.533 (2)0.6335 (12)0.046 (9)*
H9C0.487 (2)0.578 (2)0.6486 (13)0.052 (9)*
H120.4500 (16)0.0212 (18)0.5690 (10)0.029 (7)*
H130.3449 (17)0.073 (2)0.4991 (11)0.040 (8)*
H140.2523 (17)0.0279 (19)0.4431 (11)0.036 (7)*
H150.2732 (15)0.1814 (17)0.4614 (10)0.024 (6)*
H16A0.5338 (14)0.1797 (15)0.5987 (9)0.015 (5)*
H16B0.5355 (15)0.0807 (17)0.6185 (10)0.024 (6)*
H17A0.5419 (15)0.2108 (17)0.7287 (10)0.025 (6)*
H17B0.5907 (17)0.2215 (18)0.6885 (11)0.030 (7)*
H17C0.5837 (15)0.1268 (18)0.7105 (10)0.025 (6)*
H18A0.3679 (15)0.1068 (16)0.6440 (10)0.022 (6)*
H18B0.4417 (16)0.0562 (19)0.6815 (10)0.029 (6)*
H18C0.4059 (16)0.1406 (18)0.7014 (11)0.029 (6)*
H210.125 (2)0.439 (2)0.4540 (13)0.057 (10)*
H220.148 (2)0.455 (2)0.3719 (13)0.056 (9)*
H230.2691 (17)0.4018 (19)0.3580 (11)0.037 (7)*
H240.3689 (15)0.3351 (16)0.4294 (9)0.018 (5)*
H25B0.160 (2)0.395 (2)0.5458 (13)0.057 (10)*
H25C0.2572 (17)0.3976 (19)0.5757 (11)0.034 (7)*
H26A0.2057 (17)0.1978 (19)0.6214 (11)0.028 (7)*
H26B0.248 (2)0.291 (2)0.6387 (13)0.046 (8)*
H26C0.154 (2)0.290 (2)0.6159 (13)0.054 (9)*
H27A0.1476 (18)0.164 (2)0.5296 (11)0.032 (8)*
H27B0.1501 (18)0.2300 (19)0.4853 (12)0.037 (7)*
H27C0.089 (2)0.240 (3)0.5230 (15)0.073 (12)*
H330.3079 (17)1.0174 (18)0.7133 (10)0.031 (7)*
H340.2375 (17)1.135 (2)0.7364 (11)0.036 (7)*
H350.1129 (17)1.1097 (19)0.7561 (11)0.034 (7)*
H360.0641 (15)0.9635 (16)0.7500 (9)0.021 (6)*
H37A0.2900 (14)0.7988 (16)0.7281 (9)0.019 (6)*
H37B0.3392 (16)0.8733 (17)0.7081 (10)0.026 (6)*
H38A0.3047 (17)0.7167 (19)0.6093 (11)0.035 (7)*
H38B0.3247 (18)0.695 (2)0.6725 (12)0.040 (8)*
H38C0.375 (2)0.770 (2)0.6489 (13)0.050 (9)*
H39A0.2119 (16)0.9236 (18)0.6084 (10)0.026 (6)*
H39C0.2387 (17)0.8585 (19)0.5751 (12)0.036 (7)*
H39B0.3090 (18)0.912 (2)0.6127 (11)0.039 (7)*
H420.2122 (15)0.5197 (18)0.8064 (10)0.026 (6)*
H430.2984 (16)0.5903 (18)0.8823 (11)0.030 (7)*
H440.2992 (15)0.7449 (17)0.8867 (10)0.023 (6)*
H450.2211 (15)0.8270 (17)0.8172 (10)0.022 (6)*
H46A0.0546 (15)0.6080 (17)0.7093 (10)0.023 (6)*
H46B0.1027 (14)0.5195 (16)0.7317 (9)0.021 (6)*
H47A0.0922 (17)0.5241 (19)0.5972 (11)0.035 (7)*
H47B0.0194 (17)0.5619 (19)0.6200 (11)0.035 (7)*
H47C0.0675 (16)0.4678 (19)0.6417 (11)0.032 (7)*
H48A0.2607 (16)0.5627 (18)0.7084 (11)0.029 (6)*
H48B0.2150 (17)0.468 (2)0.6916 (12)0.040 (8)*
H48C0.2324 (16)0.5325 (18)0.6493 (11)0.031 (7)*
H510.1924 (16)0.8291 (17)0.6721 (10)0.029 (7)*
H520.1940 (16)0.8106 (17)0.7600 (10)0.028 (6)*
H530.0715 (15)0.7823 (16)0.8277 (10)0.023 (6)*
H540.0525 (15)0.7799 (16)0.8083 (9)0.018 (6)*
H55A0.0446 (14)0.7807 (16)0.6161 (9)0.019 (6)*
H55B0.1232 (17)0.8409 (18)0.6068 (11)0.032 (7)*
H56A0.0252 (16)0.8622 (19)0.5666 (10)0.031 (7)*
H56B0.0495 (16)0.9284 (17)0.5442 (10)0.026 (6)*
H56C0.0394 (16)0.9651 (18)0.5747 (10)0.030 (7)*
H57A0.0603 (14)0.9899 (16)0.6720 (10)0.021 (6)*
H57B0.0123 (16)1.0452 (18)0.6384 (10)0.031 (7)*
H57C0.1026 (18)1.0069 (19)0.6128 (12)0.038 (7)*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.01859 (6)0.02178 (6)0.01143 (5)0.00109 (5)0.00392 (4)0.00228 (4)
Ag20.01753 (6)0.01899 (6)0.01283 (5)0.00021 (4)0.00576 (4)0.00121 (4)
P10.01391 (18)0.01522 (18)0.01052 (16)0.00014 (14)0.00232 (13)0.00153 (13)
P20.01216 (17)0.01246 (17)0.01140 (16)0.00009 (14)0.00380 (13)0.00045 (13)
F10.0778 (12)0.0442 (9)0.0360 (7)0.0358 (8)0.0219 (8)0.0248 (7)
F20.0445 (8)0.0547 (9)0.0295 (6)0.0329 (7)0.0178 (6)0.0109 (6)
F30.0455 (8)0.0671 (11)0.0267 (6)0.0059 (7)0.0210 (6)0.0137 (7)
F40.0350 (9)0.0579 (14)0.0488 (10)0.0210 (9)0.0133 (8)0.0315 (9)
F50.0587 (14)0.0317 (9)0.0492 (10)0.0255 (8)0.0136 (10)0.0016 (7)
F60.0345 (7)0.0465 (8)0.0228 (6)0.0168 (6)0.0001 (5)0.0046 (5)
F70.0563 (9)0.0369 (7)0.0245 (6)0.0199 (7)0.0170 (6)0.0032 (5)
F80.0480 (8)0.0320 (6)0.0155 (5)0.0040 (6)0.0104 (5)0.0017 (5)
F90.0582 (10)0.0587 (10)0.0287 (7)0.0350 (8)0.0041 (7)0.0014 (7)
F100.0929 (13)0.0289 (7)0.0430 (8)0.0257 (8)0.0437 (9)0.0089 (6)
O10.0264 (7)0.0486 (9)0.0140 (6)0.0013 (7)0.0062 (5)0.0072 (6)
O20.0206 (7)0.0761 (14)0.0277 (8)0.0016 (8)0.0081 (6)0.0048 (8)
O30.0319 (8)0.0356 (8)0.0149 (6)0.0070 (6)0.0051 (5)0.0013 (5)
O40.0321 (8)0.0445 (9)0.0247 (7)0.0128 (7)0.0079 (6)0.0071 (6)
N10.0294 (8)0.0202 (7)0.0131 (6)0.0050 (6)0.0030 (6)0.0016 (5)
N20.0172 (7)0.0215 (7)0.0141 (6)0.0030 (5)0.0036 (5)0.0019 (5)
N30.0172 (8)0.0752 (15)0.0178 (7)0.0084 (9)0.0075 (6)0.0122 (8)
N40.0179 (7)0.0372 (9)0.0176 (7)0.0072 (6)0.0079 (6)0.0051 (6)
N50.0242 (7)0.0166 (7)0.0161 (6)0.0018 (6)0.0056 (5)0.0013 (5)
N60.0184 (7)0.0189 (7)0.0155 (6)0.0023 (5)0.0038 (5)0.0016 (5)
C10.0159 (7)0.0157 (7)0.0121 (6)0.0008 (6)0.0028 (5)0.0018 (5)
C20.0199 (8)0.0151 (7)0.0122 (6)0.0005 (6)0.0012 (6)0.0030 (5)
C30.0206 (8)0.0212 (8)0.0186 (7)0.0051 (7)0.0006 (6)0.0058 (6)
C40.0174 (8)0.0290 (9)0.0237 (8)0.0001 (7)0.0061 (7)0.0100 (7)
C50.0208 (8)0.0243 (9)0.0221 (8)0.0041 (7)0.0101 (7)0.0056 (7)
C60.0201 (8)0.0177 (8)0.0169 (7)0.0002 (6)0.0062 (6)0.0008 (6)
C70.0282 (9)0.0149 (7)0.0145 (7)0.0027 (7)0.0027 (6)0.0005 (6)
C80.0298 (11)0.0498 (14)0.0179 (8)0.0189 (10)0.0016 (7)0.0043 (9)
C90.0684 (18)0.0205 (10)0.0300 (11)0.0022 (11)0.0208 (11)0.0079 (8)
C100.0157 (7)0.0171 (7)0.0130 (6)0.0017 (6)0.0055 (5)0.0007 (5)
C110.0176 (7)0.0160 (7)0.0154 (7)0.0012 (6)0.0047 (6)0.0011 (6)
C120.0314 (10)0.0164 (8)0.0230 (8)0.0001 (7)0.0028 (7)0.0030 (7)
C130.0381 (11)0.0162 (8)0.0281 (9)0.0039 (8)0.0038 (8)0.0024 (7)
C140.0274 (10)0.0208 (9)0.0236 (8)0.0060 (7)0.0016 (7)0.0049 (7)
C150.0185 (8)0.0200 (8)0.0174 (7)0.0015 (6)0.0035 (6)0.0020 (6)
C160.0165 (7)0.0182 (8)0.0154 (7)0.0004 (6)0.0035 (6)0.0025 (6)
C170.0215 (9)0.0333 (11)0.0169 (7)0.0006 (8)0.0003 (6)0.0020 (7)
C180.0246 (9)0.0250 (9)0.0227 (8)0.0040 (7)0.0113 (7)0.0041 (7)
C190.0179 (8)0.0159 (7)0.0145 (7)0.0024 (6)0.0006 (6)0.0032 (6)
C200.0250 (9)0.0372 (11)0.0198 (8)0.0124 (8)0.0003 (7)0.0097 (8)
C210.0335 (12)0.0517 (15)0.0320 (11)0.0255 (11)0.0032 (9)0.0075 (10)
C220.0392 (13)0.0344 (12)0.0279 (10)0.0144 (10)0.0089 (9)0.0001 (9)
C230.0318 (10)0.0236 (9)0.0196 (8)0.0022 (8)0.0033 (7)0.0038 (7)
C240.0227 (8)0.0168 (8)0.0161 (7)0.0021 (6)0.0010 (6)0.0005 (6)
C250.0240 (10)0.0626 (16)0.0228 (9)0.0146 (10)0.0046 (8)0.0146 (10)
C260.0311 (13)0.120 (3)0.0206 (10)0.0212 (17)0.0130 (9)0.0121 (14)
C270.0255 (11)0.102 (3)0.0276 (11)0.0198 (14)0.0107 (9)0.0192 (14)
C280.0228 (8)0.0251 (9)0.0145 (7)0.0020 (7)0.0064 (6)0.0008 (6)
C290.0245 (8)0.0169 (8)0.0152 (7)0.0015 (6)0.0059 (6)0.0031 (6)
C300.0257 (9)0.0308 (10)0.0245 (9)0.0029 (8)0.0089 (7)0.0073 (8)
C310.0158 (7)0.0148 (7)0.0128 (6)0.0019 (6)0.0028 (5)0.0016 (5)
C320.0159 (7)0.0214 (8)0.0121 (6)0.0039 (6)0.0014 (5)0.0016 (6)
C330.0226 (9)0.0278 (10)0.0196 (8)0.0109 (7)0.0016 (7)0.0046 (7)
C340.0345 (11)0.0181 (9)0.0255 (9)0.0100 (8)0.0007 (8)0.0031 (7)
C350.0303 (10)0.0161 (8)0.0234 (8)0.0011 (7)0.0002 (7)0.0019 (7)
C360.0202 (8)0.0152 (7)0.0184 (7)0.0004 (6)0.0027 (6)0.0004 (6)
C370.0142 (7)0.0313 (9)0.0158 (7)0.0050 (7)0.0052 (6)0.0024 (7)
C380.0193 (9)0.0615 (17)0.0372 (12)0.0030 (10)0.0135 (9)0.0214 (12)
C390.0447 (14)0.0544 (16)0.0167 (8)0.0223 (12)0.0106 (9)0.0009 (9)
C400.0139 (7)0.0160 (7)0.0133 (6)0.0016 (6)0.0052 (5)0.0015 (5)
C410.0167 (7)0.0170 (7)0.0158 (7)0.0021 (6)0.0077 (6)0.0021 (6)
C420.0213 (8)0.0194 (8)0.0213 (8)0.0048 (6)0.0098 (6)0.0060 (6)
C430.0193 (8)0.0281 (9)0.0184 (7)0.0049 (7)0.0056 (6)0.0098 (7)
C440.0182 (8)0.0290 (9)0.0137 (7)0.0001 (7)0.0020 (6)0.0022 (6)
C450.0172 (7)0.0199 (8)0.0146 (7)0.0005 (6)0.0043 (6)0.0010 (6)
C460.0227 (8)0.0143 (7)0.0205 (7)0.0003 (6)0.0077 (6)0.0004 (6)
C470.0407 (12)0.0211 (9)0.0229 (9)0.0068 (8)0.0040 (8)0.0049 (7)
C480.0345 (11)0.0273 (10)0.0249 (9)0.0123 (8)0.0116 (8)0.0009 (8)
C490.0147 (7)0.0122 (7)0.0155 (6)0.0004 (5)0.0059 (5)0.0009 (5)
C500.0149 (7)0.0142 (7)0.0185 (7)0.0005 (6)0.0045 (6)0.0020 (6)
C510.0145 (7)0.0195 (8)0.0282 (8)0.0004 (6)0.0060 (6)0.0024 (7)
C520.0185 (8)0.0197 (8)0.0338 (9)0.0014 (6)0.0147 (7)0.0024 (7)
C530.0259 (9)0.0218 (8)0.0248 (8)0.0003 (7)0.0149 (7)0.0010 (7)
C540.0205 (8)0.0192 (8)0.0170 (7)0.0003 (6)0.0083 (6)0.0008 (6)
C550.0158 (7)0.0202 (8)0.0170 (7)0.0003 (6)0.0013 (6)0.0015 (6)
C560.0306 (10)0.0308 (10)0.0198 (8)0.0022 (8)0.0093 (7)0.0042 (7)
C570.0240 (9)0.0200 (9)0.0254 (9)0.0050 (7)0.0039 (7)0.0022 (7)
C580.0250 (9)0.0223 (8)0.0154 (7)0.0016 (7)0.0050 (6)0.0009 (6)
C590.0256 (9)0.0219 (9)0.0155 (7)0.0008 (7)0.0043 (6)0.0045 (6)
C600.0358 (10)0.0249 (9)0.0152 (7)0.0005 (8)0.0093 (7)0.0025 (6)
Bond lengths (Å) top
Ag1—O12.2789 (13)F2—C291.346 (2)
Ag1—P12.4145 (4)F3—C301.334 (2)
Ag1—N22.4360 (16)F4—C301.315 (3)
Ag1—N12.4433 (16)F5—C301.341 (3)
Ag2—O32.2383 (13)F4A—C301.594 (19)
Ag2—P22.3892 (4)F5A—C301.032 (19)
Ag2—N42.4270 (16)F6—C591.357 (2)
Ag2—N52.4592 (15)F7—C591.353 (2)
P1—C101.8327 (18)F8—C601.335 (2)
P1—C191.8353 (17)F9—C601.331 (3)
P1—C11.8466 (17)F10—C601.319 (2)
P2—C311.8268 (17)O1—C281.245 (2)
P2—C491.8285 (16)O2—C281.221 (2)
P2—C401.8452 (16)O3—C581.250 (2)
F1—C291.348 (2)
 

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