Acta Crystallographica Section E

Structure Reports Online

Volume 59, Part 11 (November 2003)

inorganic compounds


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Acta Cryst. (2003). E59, i154-i155    [ doi:10.1107/S160053680302378X ]

Hexaamminechromium(III) diaquatetrachlorosodium(I)

E. Alig, L. Fink and M. Bolte

Abstract: The title compound, hexaamminechromium(III) diaquatetrachlorosodium(I), [Cr(NH3)6][NaCl4(H2O)2], is composed of discrete [Cr(NH3)6]3+ cations and [NaCl4(H2O)2]3- anions. The Cr and Na ions are octahedrally coordinated. The crystal packing is characterized by an alternating arrangement of anions and cations and is stabilized by numerous hydrogen bonds.

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