Acta Crystallographica Section E

Structure Reports Online

Volume 59, Part 11 (November 2003)

inorganic compounds


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Acta Cryst. (2003). E59, i145-i146    [ doi:10.1107/S1600536803021536 ]

Diamminehexabromodiscandium(III)

G. Meyer, N. Cesur and I. Pantenburg

Abstract: The title compound, [Sc2Br6(NH3)2], was obtained by the reaction of ammonium bromide, (NH4)Br, with scandium metal in a sealed tantalum metal container. The crystal structure contains zigzag chains of edge-connected [Sc(NH3)Br5] octahedra according to the formulation [Sc(NH3)1/1Br1/1Br4/2]. Sc(NH3)Br3 is isotypic with Sc(NH3)Cl3.

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