Acta Crystallographica Section E

Structure Reports Online

Volume 59, Part 9 (September 2003)


metal-organic compounds



Acta Cryst. (2003). E59, m700-m702    [ doi:10.1107/S1600536803017252 ]

trans-(6-Amino-2-pyridinio)iodobis(triphenylphosphine)palladium(II) iodide ethyl acetate solvate

W. Clegg and L. Horsburgh

Abstract: The title compound, [Pd(C5H6N2){(C6H5)3P}2]I·C4H8O2, has a square-planar geometry for Pd, coordinated by two trans-phosphines, an iodo, and an aminopyridyl ligand. The cation, anion and solvent molecule all lie on a crystallographic mirror plane, and are connected together by N-H...I and N-H...O hydrogen bonds.

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