Acta Crystallographica Section E

Structure Reports Online

Volume 59, Part 7 (July 2003)

metal-organic compounds

 

[(R,R)-1-(N-Benzylideneamino)-2-(diphenylphosphino)cyclohexane-²N,P]dichloro(triphenylphosphine-P)ruthenium(II)

A. Caiazzo, A. J. Lough and A. K. Yudin

Abstract: The title compound, [RuCl₂(C₁₈H₁₅P)(C₂₅H₂₆NP)], crystallizes with two molecules in the asymmetric unit. The coordination geometry is a distorted square pyramid, with the P atom of the -PPh₂ moiety at the apical position. This is the first reported structure determination of a compound containing the (R,R)-1-(N-benzylideneamino)-2-(diphenylphosphino)cyclohexane ligand.

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