Acta Crystallographica Section E

Structure Reports Online

Volume 57, Part 9 (September 2001)


metal-organic compounds



Acta Cryst. (2001). E57, m384-m386    [ doi:10.1107/S1600536801012909 ]

Bis[bis(2-pyridyl)amine-N,N'](nitrato-O,O')cobalt(II) nitrate

O. Castillo, A. Luque, N. De la Pinta and P. Román

Abstract: The crystal structure of the title compound, [Co(NO3)(C10H9N3)2]NO3, consists of mononuclear cations and uncoordinated nitrate anions held together by means of an extensive three-dimensional network of N-H...O and C-H...O hydrogen bonds. The CoII centre has a distorted octahedral geometry, coordinated with two O atoms of a bidentate nitrate ligand and with four pyridine N atoms of two bis(2-pyridyl)amine ligands in a trans-trans mode.

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