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The title compound, C18H19N3O2PdS32+.2PF6-.CH3NO2, shows a distorted square-planar coordination geometry with an S2N2 donor set and a long-range apical interaction [Pd...S1 2.898 (3) Å] to the third thia donor. This compares with a value of 2.948 (3) Å in the corresponding complex where there is no electron-withdrawing nitro group in the 5-position of the phenanthroline ligand [Blake et al. (1996). J. Chem. Soc. Dalton Trans. pp. 1885-1895].

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks qa0064, global

hkl

Structure factor file (CIF format)
Contains datablock s3pdnp

CCDC reference: 130793

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