Acta Crystallographica Section C

Crystal Structure Communications

Volume 65, Part 7 (July 2009)

metal-organic compounds

 

catena-Poly[[[aqua(ethylenediamine-²N,N')(nitrato-O)copper(II)]--4,4'-dithiodipyridine-²N:N'] nitrate monohydrate]

R. W. Seidel and I. M. Oppel

Abstract: The title compound, {[Cu(NO₃)(C₂H₄N₂)(C₁₀H₈N₂S₂)(H₂O)]NO₃·H₂O}_n, is composed of a one-dimensional linear coordination polymer involving cis-protected copper(II) ions and a 4,4'-dithiodipyridine bridging ligand. The polymeric chains run along the c-axis direction. N-HO and O-HO hydrogen bonds involving the coordinating amine groups, nitrate ions and water molecules, as well as cocrystallized noncoordinating nitrate ions and water molecules, generate a three-dimensional structure.

Formula: [Cu(NO₃)(C₂H₄N₂)(C₁₀H₈N₂S₂)(H₂O)]NO₃·H₂O

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