Acta Crystallographica Section C

Crystal Structure Communications

Volume 64, Part 4 (April 2008)

metal-organic compounds

 

1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(⁶-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2'-1,3-dioxolan]-2-yloxy}benzene)chromium

H. Paramahamsan, A. J. Pearson, N. M. Pinkerton and A. A. Pinkerton

Abstract: The tricarbonylchromium unit bound to the arene ring of the chiral title complex, [Cr(C₁₉H₂₆O₃)(CO)₃], is rotated by ca 25° in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack.

Formula: [Cr(C₁₉H₂₆O₃)(CO)₃]

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