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The title compound, [Zn(C15H11N7O4)(H2O)2](NO3)(PF6)·3H2O, contains a mononuclear zinc(II) complex. The Zn2+ centre is seven-coordinated in a slightly distorted penta­gonal-bipyramidal geometry, with the two water O atoms located in the apical positions, and the pyridine N atom, the two imine N atoms and two carbonyl O atoms of the uracil groups located in the equatorial plane. The charge is balanced by PF6- and NO3- anions.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S0108270107008633/gd3092sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S0108270107008633/gd3092Isup2.hkl
Contains datablock I

CCDC reference: 645511

Computing details top

Data collection: X-AREA (Stoe & Cie, 2002); cell refinement: X-AREA; data reduction: X-RED32 (Stoe & Cie, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

trans-Diaqua{5,5'-[(E,E)-pyridine-2,6- diylbis(methylidynenitrilo)]bis[pyrimidine-2,4(1H,3H)-dione]}zinc(II) nitrate hexafluoridophosphate trihydrate top
Crystal data top
[Zn(C15H11N7O4)(H2O)2](PF6)(NO3)·3H2OZ = 2
Mr = 715.74F(000) = 724
Triclinic, P1Dx = 1.841 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 8.8127 (7) ÅCell parameters from 14841 reflections
b = 11.5868 (9) Åθ = 1.8–28.0°
c = 13.5365 (11) ŵ = 1.13 mm1
α = 81.433 (6)°T = 296 K
β = 77.957 (6)°Prism, yellow
γ = 73.665 (6)°0.64 × 0.43 × 0.24 mm
V = 1291.22 (18) Å3
Data collection top
Stoe IPDS-II
diffractometer
6038 independent reflections
Radiation source: sealed X-ray tube, 12 x 0.4 mm long-fine focus5161 reflections with I > 2σ(I)
Plane graphite monochromatorRint = 0.034
Detector resolution: 6.67 pixels mm-1θmax = 27.8°, θmin = 2.3°
ω scansh = 1111
Absorption correction: integration
(X-RED32; Stoe & Cie, 2002)
k = 1515
Tmin = 0.669, Tmax = 0.836l = 1716
18919 measured reflections
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.030H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.083 w = 1/[σ2(Fo2) + (0.0485P)2 + 0.2167P]
where P = (Fo2 + 2Fc2)/3
S = 1.04(Δ/σ)max = 0.001
6038 reflectionsΔρmax = 0.35 e Å3
429 parametersΔρmin = 0.34 e Å3
10 restraintsExtinction correction: SHELXL97, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methodsExtinction coefficient: 0.0030 (7)
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Zn10.56128 (2)0.385383 (16)0.726780 (16)0.03108 (7)
P10.27565 (7)0.03925 (5)0.89168 (5)0.05083 (15)
F10.4111 (2)0.10057 (17)0.89979 (15)0.0817 (5)
F20.3749 (2)0.08926 (15)0.92808 (18)0.0947 (6)
F30.1382 (2)0.01849 (16)0.87896 (15)0.0810 (5)
F40.1730 (2)0.16878 (14)0.85108 (15)0.0857 (5)
F50.1907 (3)0.06393 (18)1.00371 (14)0.0922 (6)
F60.3577 (2)0.01579 (17)0.77745 (13)0.0809 (5)
O10.74965 (16)0.41660 (11)0.61262 (10)0.0354 (3)
H1A0.8383 (17)0.396 (2)0.628 (2)0.054 (7)*
H1B0.737 (3)0.4848 (12)0.5856 (18)0.049 (7)*
O20.34621 (17)0.36206 (13)0.82151 (12)0.0411 (3)
H2A0.331 (3)0.2965 (14)0.842 (2)0.070 (9)*
H2B0.263 (2)0.404 (2)0.807 (2)0.071 (9)*
O30.61097 (19)0.13222 (11)0.56565 (12)0.0481 (4)
O40.52837 (17)0.25497 (10)0.62627 (11)0.0388 (3)
O50.0909 (2)0.86168 (13)0.52158 (13)0.0587 (4)
O60.40197 (16)0.49641 (10)0.61920 (10)0.0372 (3)
O71.04819 (19)0.52294 (14)0.77855 (14)0.0564 (4)
O80.8650 (2)0.64341 (16)0.70210 (16)0.0700 (5)
O90.9689 (3)0.71094 (17)0.80123 (19)0.0823 (6)
O100.70983 (19)0.63545 (12)0.50765 (12)0.0443 (3)
H10A0.694 (3)0.6969 (16)0.535 (2)0.063 (8)*
H10B0.641 (2)0.646 (2)0.4736 (17)0.053 (7)*
O111.0404 (2)0.34908 (16)0.65804 (16)0.0562 (4)
H11A1.034 (4)0.402 (2)0.694 (2)0.075 (10)*
H11B1.103 (3)0.358 (3)0.6050 (14)0.064 (9)*
O120.0874 (3)0.91021 (15)0.36087 (19)0.0745 (6)
H12A0.095 (4)0.855 (2)0.334 (2)0.082 (10)*
H12B0.047 (5)0.885 (4)0.4113 (19)0.110 (14)*
N10.67566 (18)0.39680 (13)0.85076 (11)0.0320 (3)
N20.70098 (18)0.19865 (12)0.77485 (12)0.0321 (3)
N30.73319 (19)0.09415 (12)0.68466 (13)0.0397 (4)
H3N0.77810.16970.69650.048*
N40.57755 (19)0.06123 (12)0.59374 (12)0.0350 (3)
H4N0.52300.08540.54540.042*
N50.48609 (18)0.57946 (12)0.76695 (12)0.0323 (3)
N60.2180 (2)0.84701 (13)0.65379 (14)0.0447 (4)
H6N0.17870.92270.66110.054*
N70.2467 (2)0.67921 (13)0.57134 (13)0.0384 (3)
H7N0.22460.64760.52420.046*
N80.9603 (2)0.62623 (15)0.76057 (14)0.0453 (4)
C10.6542 (2)0.50227 (16)0.88640 (14)0.0346 (4)
C20.7271 (3)0.5124 (2)0.96472 (16)0.0446 (4)
H20.71190.58700.98820.053*
C30.8228 (3)0.4091 (2)1.00719 (17)0.0487 (5)
H30.87300.41351.06000.058*
C40.8439 (2)0.2994 (2)0.97128 (16)0.0441 (4)
H40.90710.22890.99970.053*
C50.7685 (2)0.29677 (16)0.89164 (14)0.0350 (4)
C60.7807 (2)0.18665 (16)0.84530 (15)0.0376 (4)
H60.84380.11190.86670.045*
C70.6928 (2)0.10487 (14)0.72336 (14)0.0323 (3)
C80.7592 (2)0.01489 (15)0.73960 (15)0.0374 (4)
H80.82350.04340.78900.045*
C90.6401 (2)0.06020 (15)0.61210 (15)0.0355 (4)
C100.5948 (2)0.14764 (14)0.64621 (14)0.0318 (3)
C110.5471 (2)0.60389 (16)0.83566 (15)0.0369 (4)
H110.52500.68230.85310.044*
C120.3819 (2)0.66073 (14)0.70943 (14)0.0326 (3)
C130.3163 (2)0.77968 (16)0.71708 (16)0.0409 (4)
H130.33920.81620.76690.049*
C140.1780 (2)0.80077 (16)0.57883 (16)0.0408 (4)
C150.3465 (2)0.60453 (14)0.63195 (14)0.0319 (3)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Zn10.03582 (11)0.02593 (10)0.03140 (12)0.00389 (7)0.01115 (8)0.00306 (7)
P10.0547 (3)0.0403 (3)0.0531 (3)0.0147 (2)0.0030 (3)0.0038 (2)
F10.0849 (11)0.0866 (11)0.0872 (13)0.0438 (10)0.0080 (9)0.0185 (9)
F20.0927 (13)0.0548 (9)0.1280 (18)0.0008 (9)0.0356 (12)0.0052 (10)
F30.0638 (9)0.0761 (10)0.1056 (14)0.0325 (8)0.0036 (9)0.0047 (10)
F40.0990 (13)0.0509 (8)0.0935 (13)0.0074 (8)0.0134 (11)0.0071 (8)
F50.1180 (15)0.0882 (12)0.0574 (10)0.0283 (11)0.0167 (10)0.0085 (9)
F60.0894 (12)0.0908 (12)0.0672 (11)0.0430 (10)0.0177 (9)0.0287 (9)
O10.0384 (7)0.0284 (6)0.0370 (7)0.0050 (5)0.0081 (6)0.0013 (5)
O20.0401 (7)0.0369 (7)0.0450 (8)0.0088 (6)0.0075 (6)0.0018 (6)
O30.0639 (9)0.0252 (6)0.0582 (9)0.0042 (6)0.0234 (8)0.0093 (6)
O40.0513 (8)0.0218 (5)0.0443 (8)0.0039 (5)0.0190 (6)0.0019 (5)
O50.0696 (10)0.0389 (7)0.0596 (10)0.0083 (7)0.0301 (9)0.0032 (7)
O60.0454 (7)0.0249 (5)0.0401 (7)0.0004 (5)0.0163 (6)0.0060 (5)
O70.0502 (9)0.0467 (8)0.0662 (11)0.0060 (6)0.0247 (8)0.0017 (7)
O80.0697 (11)0.0590 (10)0.0869 (14)0.0054 (8)0.0503 (11)0.0056 (9)
O90.1091 (16)0.0472 (9)0.1002 (17)0.0103 (10)0.0520 (14)0.0090 (10)
O100.0569 (9)0.0294 (6)0.0503 (9)0.0065 (6)0.0241 (7)0.0038 (6)
O110.0489 (9)0.0534 (9)0.0658 (12)0.0102 (7)0.0128 (9)0.0063 (9)
O120.1031 (15)0.0314 (8)0.0952 (16)0.0015 (8)0.0569 (13)0.0059 (9)
N10.0354 (7)0.0314 (7)0.0305 (7)0.0062 (6)0.0113 (6)0.0036 (6)
N20.0366 (7)0.0257 (6)0.0332 (8)0.0050 (5)0.0095 (6)0.0018 (5)
N30.0450 (9)0.0210 (6)0.0491 (10)0.0012 (6)0.0130 (7)0.0036 (6)
N40.0447 (8)0.0228 (6)0.0374 (8)0.0044 (6)0.0132 (7)0.0024 (6)
N50.0352 (7)0.0273 (6)0.0326 (8)0.0033 (5)0.0087 (6)0.0028 (5)
N60.0541 (10)0.0226 (7)0.0519 (10)0.0020 (6)0.0141 (8)0.0027 (6)
N70.0461 (9)0.0290 (7)0.0369 (9)0.0006 (6)0.0150 (7)0.0023 (6)
N80.0394 (9)0.0426 (9)0.0491 (10)0.0057 (7)0.0115 (8)0.0059 (8)
C10.0370 (9)0.0361 (8)0.0313 (9)0.0076 (7)0.0084 (7)0.0057 (7)
C20.0495 (11)0.0507 (11)0.0385 (11)0.0127 (9)0.0128 (9)0.0129 (9)
C30.0516 (12)0.0624 (13)0.0376 (11)0.0120 (10)0.0203 (9)0.0098 (9)
C40.0439 (10)0.0516 (11)0.0366 (10)0.0055 (8)0.0181 (8)0.0009 (8)
C50.0359 (9)0.0379 (9)0.0301 (9)0.0055 (7)0.0110 (7)0.0002 (7)
C60.0397 (9)0.0307 (8)0.0390 (10)0.0020 (7)0.0126 (8)0.0013 (7)
C70.0352 (8)0.0255 (7)0.0349 (9)0.0058 (6)0.0054 (7)0.0032 (6)
C80.0386 (9)0.0291 (8)0.0426 (10)0.0026 (7)0.0125 (8)0.0017 (7)
C90.0404 (9)0.0241 (7)0.0391 (10)0.0050 (6)0.0048 (8)0.0038 (7)
C100.0365 (8)0.0225 (7)0.0353 (9)0.0057 (6)0.0063 (7)0.0027 (6)
C110.0435 (10)0.0302 (8)0.0380 (10)0.0071 (7)0.0098 (8)0.0077 (7)
C120.0362 (8)0.0259 (7)0.0335 (9)0.0038 (6)0.0080 (7)0.0018 (6)
C130.0483 (10)0.0293 (8)0.0436 (11)0.0040 (7)0.0120 (9)0.0054 (7)
C140.0452 (10)0.0293 (8)0.0405 (11)0.0006 (7)0.0094 (8)0.0029 (7)
C150.0345 (8)0.0266 (7)0.0314 (9)0.0027 (6)0.0075 (7)0.0003 (6)
Geometric parameters (Å, º) top
Zn1—O12.0917 (14)N2—C71.401 (2)
Zn1—O22.1168 (15)N3—C91.354 (3)
Zn1—N12.1672 (15)N3—C81.357 (2)
Zn1—O62.2419 (13)N3—H3N0.8600
Zn1—N22.2443 (14)N4—C91.364 (2)
Zn1—N52.2732 (14)N4—C101.368 (2)
Zn1—O42.2896 (13)N4—H4N0.8600
P1—F21.5663 (17)N5—C111.268 (2)
P1—F51.5738 (18)N5—C121.389 (2)
P1—F11.5799 (17)N6—C131.350 (3)
P1—F31.5883 (17)N6—C141.363 (3)
P1—F61.5923 (17)N6—H6N0.8600
P1—F41.6033 (17)N7—C151.363 (2)
O1—H1A0.81 (2)N7—C141.378 (2)
O1—H1B0.81 (2)N7—H7N0.8600
O2—H2A0.81 (2)C1—C21.383 (3)
O2—H2B0.81 (2)C1—C111.468 (3)
O3—C91.225 (2)C2—C31.380 (3)
O4—C101.232 (2)C2—H20.9300
O5—C141.212 (2)C3—C41.378 (3)
O6—C151.234 (2)C3—H30.9300
O7—N81.250 (2)C4—C51.387 (3)
O8—N81.228 (2)C4—H40.9300
O9—N81.222 (3)C5—C61.472 (3)
O10—H10A0.82 (2)C6—H60.9300
O10—H10B0.81 (2)C7—C81.350 (2)
O11—H11A0.82 (3)C7—C101.437 (3)
O11—H11B0.82 (2)C8—H80.9300
O12—H12A0.81 (3)C11—H110.9300
O12—H12B0.81 (3)C12—C131.347 (2)
N1—C11.330 (2)C12—C151.441 (2)
N1—C51.335 (2)C13—H130.9300
N2—C61.268 (2)
O1—Zn1—O2169.84 (6)C10—N4—H4N117.4
O1—Zn1—N194.96 (6)C11—N5—C12126.60 (15)
O2—Zn1—N194.72 (6)C11—N5—Zn1117.71 (12)
O1—Zn1—O684.90 (5)C12—N5—Zn1115.62 (11)
O2—Zn1—O685.51 (6)C13—N6—C14123.15 (15)
N1—Zn1—O6143.02 (5)C13—N6—H6N118.4
O1—Zn1—N293.27 (5)C14—N6—H6N118.4
O2—Zn1—N292.68 (6)C15—N7—C14125.80 (17)
N1—Zn1—N271.81 (5)C15—N7—H7N117.1
O6—Zn1—N2145.17 (5)C14—N7—H7N117.1
O1—Zn1—N592.78 (5)O9—N8—O8119.57 (19)
O2—Zn1—N587.47 (5)O9—N8—O7119.98 (19)
N1—Zn1—N570.92 (5)O8—N8—O7120.5 (2)
O6—Zn1—N572.15 (5)N1—C1—C2121.89 (17)
N2—Zn1—N5142.61 (5)N1—C1—C11113.87 (16)
O1—Zn1—O487.17 (5)C2—C1—C11124.23 (17)
O2—Zn1—O486.83 (5)C3—C2—C1118.39 (18)
N1—Zn1—O4143.86 (5)C3—C2—H2120.8
O6—Zn1—O473.12 (4)C1—C2—H2120.8
N2—Zn1—O472.05 (5)C4—C3—C2119.92 (18)
N5—Zn1—O4145.13 (5)C4—C3—H3120.0
F2—P1—F591.51 (12)C2—C3—H3120.0
F2—P1—F192.66 (11)C3—C4—C5118.32 (19)
F5—P1—F191.19 (11)C3—C4—H4120.8
F2—P1—F389.35 (10)C5—C4—H4120.8
F5—P1—F390.38 (11)N1—C5—C4121.65 (17)
F1—P1—F3177.41 (11)N1—C5—C6114.02 (16)
F2—P1—F689.53 (12)C4—C5—C6124.33 (17)
F5—P1—F6178.65 (13)N2—C6—C5116.76 (16)
F1—P1—F689.63 (10)N2—C6—H6121.6
F3—P1—F688.76 (10)C5—C6—H6121.6
F2—P1—F4177.95 (12)C8—C7—N2128.70 (17)
F5—P1—F490.01 (11)C8—C7—C10118.95 (16)
F1—P1—F488.67 (11)N2—C7—C10112.32 (14)
F3—P1—F489.27 (10)C7—C8—N3120.79 (17)
F6—P1—F488.93 (11)C7—C8—H8119.6
Zn1—O1—H1A115.7 (19)N3—C8—H8119.6
Zn1—O1—H1B115.6 (18)O3—C9—N3123.25 (16)
H1A—O1—H1B108 (2)O3—C9—N4121.13 (18)
Zn1—O2—H2A123 (2)N3—C9—N4115.62 (16)
Zn1—O2—H2B118 (2)O4—C10—N4120.21 (16)
H2A—O2—H2B106 (3)O4—C10—C7123.73 (16)
C10—O4—Zn1115.25 (12)N4—C10—C7116.06 (14)
C15—O6—Zn1116.51 (12)N5—C11—C1116.72 (15)
H10A—O10—H10B108 (3)N5—C11—H11121.6
H11A—O11—H11B109 (3)C1—C11—H11121.6
H12A—O12—H12B111 (4)C13—C12—N5128.62 (17)
C1—N1—C5119.81 (16)C13—C12—C15119.19 (17)
C1—N1—Zn1120.68 (12)N5—C12—C15112.19 (14)
C5—N1—Zn1119.51 (12)C12—C13—N6121.32 (19)
C6—N2—C7125.53 (15)C12—C13—H13119.3
C6—N2—Zn1117.87 (12)N6—C13—H13119.3
C7—N2—Zn1116.60 (11)O5—C14—N6122.98 (17)
C9—N3—C8123.31 (15)O5—C14—N7122.0 (2)
C9—N3—H3N118.3N6—C14—N7114.97 (16)
C8—N3—H3N118.3O6—C15—N7120.95 (16)
C9—N4—C10125.18 (16)O6—C15—C12123.49 (16)
C9—N4—H4N117.4N7—C15—C12115.56 (15)
O1—Zn1—O4—C1096.53 (13)C1—C2—C3—C40.0 (3)
O2—Zn1—O4—C1091.68 (14)C2—C3—C4—C50.8 (3)
N1—Zn1—O4—C101.99 (18)C1—N1—C5—C40.2 (3)
O6—Zn1—O4—C10177.95 (14)Zn1—N1—C5—C4179.82 (15)
N2—Zn1—O4—C102.17 (13)C1—N1—C5—C6179.63 (16)
N5—Zn1—O4—C10172.66 (12)Zn1—N1—C5—C60.3 (2)
O1—Zn1—O6—C1596.35 (14)C3—C4—C5—N10.9 (3)
O2—Zn1—O6—C1587.02 (14)C3—C4—C5—C6179.70 (19)
N1—Zn1—O6—C154.87 (18)C7—N2—C6—C5178.04 (16)
N2—Zn1—O6—C15175.25 (12)Zn1—N2—C6—C52.3 (2)
N5—Zn1—O6—C151.77 (13)N1—C5—C6—N21.3 (3)
O4—Zn1—O6—C15175.07 (14)C4—C5—C6—N2178.13 (19)
O1—Zn1—N1—C189.29 (14)C6—N2—C7—C83.2 (3)
O2—Zn1—N1—C187.62 (14)Zn1—N2—C7—C8177.12 (16)
O6—Zn1—N1—C11.18 (19)C6—N2—C7—C10178.97 (18)
N2—Zn1—N1—C1178.89 (15)Zn1—N2—C7—C100.68 (19)
N5—Zn1—N1—C11.95 (13)N2—C7—C8—N3177.21 (17)
O4—Zn1—N1—C1178.72 (12)C10—C7—C8—N30.5 (3)
O1—Zn1—N1—C590.74 (14)C9—N3—C8—C70.7 (3)
O2—Zn1—N1—C592.36 (14)C8—N3—C9—O3176.69 (19)
O6—Zn1—N1—C5178.84 (12)C8—N3—C9—N42.7 (3)
N2—Zn1—N1—C51.08 (13)C10—N4—C9—O3175.53 (18)
N5—Zn1—N1—C5178.03 (15)C10—N4—C9—N33.8 (3)
O4—Zn1—N1—C51.26 (19)Zn1—O4—C10—N4177.27 (13)
O1—Zn1—N2—C692.30 (15)Zn1—O4—C10—C72.8 (2)
O2—Zn1—N2—C695.95 (15)C9—N4—C10—O4177.21 (17)
N1—Zn1—N2—C61.85 (14)C9—N4—C10—C72.8 (3)
O6—Zn1—N2—C6178.07 (13)C8—C7—C10—O4179.50 (18)
N5—Zn1—N2—C66.61 (19)N2—C7—C10—O41.5 (3)
O4—Zn1—N2—C6178.25 (15)C8—C7—C10—N40.5 (3)
O1—Zn1—N2—C787.38 (13)N2—C7—C10—N4178.57 (15)
O2—Zn1—N2—C784.38 (13)C12—N5—C11—C1179.89 (17)
N1—Zn1—N2—C7178.47 (14)Zn1—N5—C11—C13.2 (2)
O6—Zn1—N2—C71.61 (18)N1—C1—C11—N51.5 (3)
N5—Zn1—N2—C7173.71 (11)C2—C1—C11—N5178.12 (19)
O4—Zn1—N2—C71.42 (12)C11—N5—C12—C134.1 (3)
O1—Zn1—N5—C1191.52 (15)Zn1—N5—C12—C13178.96 (17)
O2—Zn1—N5—C1198.65 (15)C11—N5—C12—C15174.96 (18)
N1—Zn1—N5—C112.77 (14)Zn1—N5—C12—C152.02 (19)
O6—Zn1—N5—C11175.26 (15)N5—C12—C13—N6179.09 (19)
N2—Zn1—N5—C117.55 (19)C15—C12—C13—N60.1 (3)
O4—Zn1—N5—C11179.43 (13)C14—N6—C13—C120.1 (3)
O1—Zn1—N5—C1285.74 (13)C13—N6—C14—O5179.3 (2)
O2—Zn1—N5—C1284.09 (13)C13—N6—C14—N70.5 (3)
N1—Zn1—N5—C12179.97 (14)C15—N7—C14—O5179.5 (2)
O6—Zn1—N5—C122.00 (12)C15—N7—C14—N60.8 (3)
N2—Zn1—N5—C12175.19 (11)Zn1—O6—C15—N7179.13 (13)
O4—Zn1—N5—C123.31 (18)Zn1—O6—C15—C121.4 (2)
C5—N1—C1—C20.7 (3)C14—N7—C15—O6179.93 (18)
Zn1—N1—C1—C2179.31 (15)C14—N7—C15—C120.5 (3)
C5—N1—C1—C11178.89 (16)C13—C12—C15—O6179.59 (18)
Zn1—N1—C1—C111.1 (2)N5—C12—C15—O60.5 (3)
N1—C1—C2—C30.8 (3)C13—C12—C15—N70.1 (3)
C11—C1—C2—C3178.75 (19)N5—C12—C15—N7179.06 (15)
 

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