Acta Crystallographica Section C

Crystal Structure Communications

Volume 60, Part 7 (July 2004)

metal-organic compounds

ta1446 scheme

Acta Cryst. (2004). C60, m314-m315 [ doi:10.1107/S010827010401087X ]

Dichloro(methanol-O)[(methoxy)tris(1-methyl-1H-imidazol-2-yl)methane-²N³]iron(II) (ca 153 K)

M. P. Batten, A. J. Canty, K. J. Cavell, T. Rüther, B. W. Skelton and A. H. White

Abstract: In the quasi-trigonal-bipyramidal environment of the five-coordinate Fe^II atom in the title compound, [FeCl₂(C₁₄H₁₈N₆O)(CH₄O)], the methanol and one of the N-atom donors of the potentially tridentate ligand are disposed axially: Fe-N(axial) is 2.149 (2) Å, Fe-N(equatorial) is 2.108 (2) Å and N-Fe-O is 174.14 (7)°.

Formula: [FeCl₂(C₁₄H₁₈N₆O)(CH₄O)]

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