Acta Crystallographica Section E

Structure Reports Online

Volume 62, Part 5 (May 2006)

inorganic compounds


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Acta Cryst. (2006). E62, i122-i123    [ doi:10.1107/S1600536806013328 ]

Pentaaquahydroxoscandium(III) dibromide, [Sc(H2O)5(OH)]Br2

U. Kolitsch

Abstract: [Sc(H2O)5(OH)]Br2 is a scandium(III) halide compound that contains centrosymmetric [Sc(H2O)5(OH)]24+ dimeric cationic units built from two edge-sharing (hydroxo-bridged) symmetrically equivalent Sc(H2O)5(OH)2 polyhedra. The mean Sc-O bond length is 2.156 Å. The hydrogen bonds (O...Br) are of low strength. All atoms are in general positions.

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